Aromatic hydrocarbon derivatives of fullerences

Rapid Communications in Mass Spectrometry - Tập 5 Số 10 - Trang 472-474 - 1991
Steven H. Hoke1, Jay Molstad1, Gregory L. Payne1, Robert J. Cotter2, Bart Kahr1, Dor Ben‐Amotz1, R. Graham Cooks1
1Department of Chemistry, Purdue University, West Lafayette, IN 47907–1393, USA
2The John Hopkins School of Medicine, Baltimore, MD, USA

Tóm tắt

AbstractThe fullerences C60 and C70 form adducts with toluene, p‐xylene and other aromatic compounds when refluxed in these solvents in the presences of FeCl3. Benzene derivatives are produced only when bromine is also present. Mass spectra of the reaction mixtures indicate the presence of derivatives including 1:1 adducts, as well as products of multiple additions of the aromatic molecules and their dehydrogenation products. Tandem mass spectrometry provides evidence for CC bonds formation between the adducts and fullerences.

Từ khóa


Tài liệu tham khảo

10.1021/ja00311a102

10.1021/ja00221a085

10.1126/science.252.5009.1160

10.1126/science.252.5003.312

(e)L. M.Roth Y.Huang J. T.Schwedler C. J.Cassady D.Ben‐Amotz B.KahrandB. S.Freiser(submitted);

(f)Y.HuangandB. S.Freiser(submitted).

10.1021/j100387a005

10.1021/ja00014a061

10.1126/science.252.5005.548

10.1021/ja00015a080

(c)W. A.KalsbeckandH. H.Thorp J. Electroanal. Chem.(accepted).

T.Weiske D. K.Böhme J.Hrusák W.KrätschmerandH.Schwarz Angew. Chem. Int. Ed. Engl.(in press).

10.1021/ja00008a077

P. J.Krusic E.Wasserman B.Malone E. R.HollerJr J. R.MortonandK. F.Preston(submitted).

10.1021/cm00015a005

D.Ben‐Amotz R. G.Cooks L.Dejarme J. C.Gunderson S. H.HokeII B.Kahr G. L.PayneandJ. M.Wood Chem. Phys. Lett.(in press).

R.Taylor J. P.Hare A. K.Abdul‐SadaandH. W.Kroto J. Chem. Soc. Chem. Commun.1423(1990).

10.1016/0020-7381(83)85037-2

Thông tin
Thông tin xuất bản

Rapid Communications in Mass Spectrometry

Tập 5 Số 10

472-474

Thông tin tác giả