Application of Light Hydrocarbons in Natural Gas Geochemistry of Gas Fields in China

Annual Review of Earth and Planetary Sciences - Tập 50 Số 1 - Trang 13-53 - 2022
Peng Cheng1, Jianzhong Li1, Tongshan Wang1, Qingchun Jiang1, Hua Jiang1, Xiaowan Tao1, Bin Bai1, Ziqi Feng2
1Research Institute of Petroleum Exploration and Development, PetroChina, Beijing, China
2School of Geosciences, China University of Petroleum, Qingdao, China

Tóm tắt

Light hydrocarbons (LHs) are an important component of natural gas whose chemical and isotopic compositions play a vital role in identifying gas genetic type, thermal maturity, gas–gas correlation, gas–source correlation, migration direction and phase, and secondary alterations (such as evaporative fractionation, biodegradation, and thermochemical sulfate reduction) experienced by the gas pool. Through review of geochemical research into LHs over recent decades, and analysis of chemical and isotopic compositions of LHs of gases and condensates from more than 40 gas fields in China, we present an overview of the genetic mechanisms of LHs and the impacts of various factors on their geochemical compositions. The primary objectives of this review are to demonstrate the application of LH chemical and isotopic composition characteristics to gas geochemistry research and to assess the applicability and reliability of geochemical identification diagrams and parameters for determining gas genetic types, maturity, source, secondary alteration, and migration direction and phase. ▪ Three main genetic mechanisms are proposed for the formation of light hydrocarbons: thermal decomposition, catalytic decomposition of organic matter, and microbial action. ▪ Chemical and isotopic compositions of light hydrocarbons with different carbon numbers and/or structures can be used to identify the genetic types and maturity of natural gas. ▪ Content ratios and carbon isotopes of characteristic light hydrocarbons are good indicators for gas–gas and gas–source correlations. ▪ Secondary alterations (evaporative fractionation, biodegradation, thermochemical sulfate reduction) and migration of gas can be indicated by chemical and isotopic compositions of light hydrocarbons.

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