Gắn kết heterojunction nano SbxOy/SnO2 lên graphene oxide giảm thiểu làm anot cho pin lithium ion với hiệu suất tốc độ đáng kể và độ ổn định chu kỳ xuất sắc

Ionics - Tập 27 - Trang 4205-4216 - 2021
Bin Zhang1, Chun Zhang1, Baoyong Liu1, Xiaozhong Zhou2, Guowei Huang3
1School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou, China
2Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Gansu Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
3State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou, China

Tóm tắt

Việc chế tạo heterojunction ở cấp đo nanomet có thể tăng cường động học phản ứng bề mặt và thúc đẩy quá trình truyền tải điện tích nhờ vào các trường điện vi mô bên trong các giao diện dị thể. Trong nghiên cứu này, các cấu trúc nano SbxOy/SnO2 được neo trên bề mặt graphene oxide giảm thiểu (SbxOy/SnO2/rGO) đã được chuẩn bị thông qua phương pháp solvothermal một bước đơn giản. Cấu trúc SbxOy/SnO2/rGO được sử dụng làm anot cho pin lithium ion sở hữu khả năng hiệu suất tần suất nổi bật, với khả năng xả và nạp cụ thể cao lần lượt là 518,6 và 515,3 mA h g−1 sau 1000 chu kỳ ở 4000 mA g−1, cũng như độ ổn định chu kỳ xuất sắc (tỷ lệ mất khả năng mỗi chu kỳ chỉ là 0,00379%). Các tính chất điện hóa xuất sắc của vật liệu SbxOy/SnO2/rGO có thể được quy cho việc xây dựng thành công các heterostructures nano.

Từ khóa

#nanometer heterojunction #SbxOy/SnO2 #graphene oxide #lithium ion batteries #electrochemical properties

Tài liệu tham khảo

Li M, Lu J, Chen Z, Amine K (2018) 30 years of lithium-ion batteries. Adv Mater 30(33):1800561 Mahmood N, Tang T, Hou Y (2016) Nanostructured anode materials for lithium ion batteries: progress, challenge and perspective. Adv Energy Mater 6(17):1600374 Tian Q, Chen Y, Zhang W, Chen J, Yang L (2020) Facile fabrication of double-shelled hollow SnO2@C nanoparticles with improved lithium storage via a novel heterogeneous template strategy. J Alloys Compd 820:153382 Chao M, Zhao L, Leng J, Liu X, Li Y, Zhang J, Tang Z (2020) Facile synthesis of CTAB assisted hierarchical-structure TiO2@SnO2 for lithium storage. Solid State Sci 100:106114 Li Y, Zhao Y, Ma C, Shi J, Zhao Y (2020) Highly monodispersed graphene/SnO2 hybrid nanosheets as bifunctional anode materials of Li-ion and Na-ion batteries. J Alloys Compd 821:153506 Wu L, Zheng J, Wang L, Xiong XH, Shao YY, Wang G, Wang J-H, Zhong SK, Wu MH (2019) PPy-encapsulated SnS2 nanosheets stabilized by defects on TiO2 support as durable anode material for lithium ion battery. Angew Chem Int Ed 58:811–815 Lakshmi K, Deivanayagam R, Shaijumon M (2021) Carbon nanotube ‘wired’ octahedral Sb2O3/graphene aerogel as efficient anode material for sodium and lithium ion batteries. J Alloys Compd 857:158267 Raza A, Ghani F, Lim J, Nah IW, Kim H-S (2021) Eco-friendly prepared mesoporous carbon encapsulated SnO2 nanoparticles for high-reversible lithium-ion battery anodes. Microporous Mesoporous Mater 314:110853 Lu X, Chen Y, Tian Q, Zhang W, Sui Z, Chen J (2021) Enabling improved cycling stability of hollow SnO2/C composite anode for lithium-ion battery by constructing a built-in porous carbon support. Appl Surf Sci 537:148052 Du Y, Zhang Y, Li L, Wang N, Chai Y (2021) Nano SnO2 and Sb2O3 combined with CNTs as a high-capacity lithium storage material. Appl Surf Sci 543:148870 Yu H, Zhang Y, Li L, Ding Z, Chen Y, Yuan Q, Sun R, Li K, Liu C, Wu J (2021) SnO2 nanoparticles embedded in 3D hierarchical honeycomb-like carbonaceous network for high-performance lithium ion battery. J Alloys Compd 858:157716 Shen H, Xia X, Yan S, Jiao X, Sun D, Lei W, Hao Q (2021) SnO2/NiFe2O4/graphene nanocomposites as anode materials for lithium ion batteries. J Alloys Compd 853:157017 Wang Q, Du Y-Y, Lai Y-Q, Liu F-Y, Jiang L-X, Jia M (2021) Three-dimensional antimony sulfide anode with carbon nanotube interphase modified for lithium-ion batteries. Int J Min Met Mater. https://doi.org/10.1007/s12613-021-2249-7 Meng J, Liu Z, Niu C, Xu L, Wang X, Li Q, Wei X, Yang W, Huang L, Mai L (2018) General oriented assembly of uniform carbon-confined metal oxide nanodots on graphene for stable and ultrafast lithium storage. Mater Horiz 5(1):78–85 Zheng S, Su L, Zheng L, Wu H, Wang L, Zhong H, Ren M, Li M (2020) Sub-10 nm SnO2/Fe3O4/graphene nanosheets: nanocatalysis to improve initial coulombic efficiency for lithium storage. J Alloys Compd 816:152624 Versaci D, Costanzo A, Ronchetti SM, Onida B, Amici J, Francia C, Bodoardo S (2021) Ultrasmall SnO2 directly grown on commercial C45 carbon as lithium-ion battery anodes for long cycling performance. Electrochim Acta 367:137489 Hu R, Ouyang Y, Liang T, Wang H, Liu J, Chen J, Yang C, Yang L, Zhu M (2017) Stabilizing the nanostructure of SnO2 anodes by transition metals: a route to achieve high initial coulombic efficiency and stable capacities for lithium storage. Adv Mater 29(13):1605006 Zhou X, Zhang Z, Lu X, Lv X, Ma G, Wang Q, Lei Z (2017) Sb2O3 nanoparticles anchored on graphene sheets via alcohol dissolution–reprecipitation method for excellent lithium-storage properties. ACS Appl Mater Interfaces 9(40):34927–34936 Zoller F, Böhm D, Bein T, Fattakhova-Rohlfing D (2019) Tin oxide based nanomaterials and their application as anodes in lithium-ion batteries and beyond. Chemsuschem 12(18):4140–4159 Shi J, Lin N, Liu D, Wang Y, Lin H (2020) Preparation of C/SnO2 composite with rice husk-based porous carbon carrier loading ultrasmall SnO2 nanoparticles for anode in lithium-ion batteries. J Electroanal Chem 857:113634 Zuo S, Li D, Wu Z, Sun Y, Lu Q, Wang F, Zhuo R, Yan D, Wang J, Yan P (2018) SnO2 /graphene oxide composite material with high rate performance applied in lithium storage capacity. Electrochim Acta 264:61–68 Zheng Y, Zhou TZ, Zhang CF, Mao JF, Liu HK, Guo ZP (2016) Boosted charge transfer in SnS/SnO2 heterostructures: toward high rate capability for sodium-ion batteries. Angew Chem Int Ed 128:3469–3474 Wang S, Liu S, Li X, Li C, Zang R, Man Z, Wu Y, Li P, Wang G (2018) SnS2/Sb2S3 heterostructures anchored on reduced graphene oxide nanosheets with superior rate capability for sodium-ion batteries. Chem-Eur J 24(15):3873–3881 Li X, Guo G, Qin N, Deng Z, Lu Z, Shen D, Zhao X, Li Y, Su B-L, Wang H-E (2018) SnS2/TiO2 nanohybrids chemically bonded on nitrogen-doped graphene for lithium-sulfur batteries: synergy of vacancy defects and heterostructures. Nanoscale 10(33):15505–15512 Lian Q, Zhou G, Zeng X, Wu C, Wei Y, Cui C, Wei W, Chen L, Li C (2016) Carbon coated SnS/SnO2 heterostructures wrapping on CNFs as an improved-performance anode for Li-ion batteries: lithiation-induced structural optimization upon cycling. ACS Appl Mater Interfaces 8(44):30256–30263 Li F, Luo GE, Yu JF, Huang WJ, Xu DH, Chen WY, Huang XY, Yang SY, Fang YP, Yu XY (2019) Terminal hollowed Fe2O3@SnO2 heterojunction nanorods anode materials with enhanced performance for lithium-ion battery. J Alloys Compd 773:778–787 Jiang Y, Guo Y, Lu W, Feng Z, Xi B, Kai S, Zhang J, Feng J, Xiong S (2017) Rationally incorporated MoS2/SnS2 nanoparticles on graphene sheets for lithium-ion and sodium-ion batteries. ACS Appl Mater Interfaces 9(33):27697–27706 Zhang Y, Wang P, Yin Y, Zhang X, Fan L, Zhang N, Sun K (2019) Heterostructured SnS-ZnS@C hollow nanoboxes embedded in graphene for high performance lithium and sodium ion batteries. Chem Eng J 356:1042–1051 Ou X, Cao L, Liang X, Zheng F, Zheng H-S, Yang X, Wang J-H, Yang C, Liu M (2019) Fabrication of SnS2/Mn2SnS4/carbon heterostructures for sodium-ion batteries with high initial coulombic efficiency and cycling stability. ACS Nano 13(3):3666–3676 Zhao B, Zhuang H, Yang Y, Wang Y, Tao H, Wang Z, Jiang J, Chen Z, Huang S, Jiang Y (2019) Composition-dependent lithium storage performances of SnS/SnO2 heterostructures sandwiching between spherical graphene. Electrochim Acta 300:253–262 Yang LY, Xie JR, Abliz A, Liu J, Wu R, Tang SS, Wang SY, Wu LL, Zhu YY (2019) Hollow paramecium-like SnO2/TiO2 heterostructure designed for sodium storage. J Solid State Chem 274:176–181 Man X, Liang P, Shu H, Zhang L, Wang D, Chao D, Liu Z, Du X, Wan H, Wang H (2018) Interface synergistic effect from layered metal sulfides of MoS2/SnS2 van der Waals heterojunction with enhanced Li-ion storage performance. J Phys Chem C 122(43):24600–24608 Lu X, Wang P, Liu K, Niu C, Wang H (2018) Encapsulating nanoparticulate Sb/MoOx into porous carbon nanofibers via electrospinning for efficient lithium storage. Chem Eng J 336:701–709 Wang H, Yang X, Wu Q, Zhang Q, Chen H, Jing H, Wang J, Mi S-B, Rogach AL, Niu C (2018) Encapsulating silica/antimony into porous electrospun carbon nanofibers with robust structure stability for high-efficiency lithium storage. ACS Nano 12(4):3406–3416 Cao D, Wang H, Li B, Li C, Xie S, Rogach AL, Niu C (2016) Hydrothermal synthesis of SnO2 embedded MoO3-x nanocomposites and their synergistic effects on lithium storage. Electrochim Acta 216:79–87 Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80(6):1339–1339 Zhou X, Zhang Z, Xu X, Yan J, Ma G, Lei Z (2016) Anchoring Sb6O13 nanocrystals on graphene sheets for enhanced lithium storage. ACS Appl Mater Interfaces 8(51):35398–35406 Hu X, Wang G, Wang B, Liu X, Wang H (2019) Co3Sn2/SnO2 heterostructures building double shell micro-cubes wrapped in three-dimensional graphene matrix as promising anode materials for lithium-ion and sodium-ion batteries. Chem Eng J 355:986–998 Huang S, Wang M, Jia P, Wang B, Zhang J, Zhao Y (2019) N-graphene motivated SnO2@SnS2 heterostructure quantum dots for high performance lithium/sodium storage. Energy Storage Mater 20:225–233 Ma C, Jiang J, Han Y, Gong X, Yang Y, Yang G (2019) The composite of carbon nanotube connecting SnO2/reduced graphene clusters as highly reversible anode material for lithium-/sodium-ion batteries and full cell. Compos Part B-Eng 169:109–117 Li Y, Zhao Y, Ma C, Shi J, Zhao Y (2019) Highly monodispersed graphene/SnO2 hybrid nanosheets as bifunctional anode materials of Li-ion and Na-ion batteries. J Alloys Compd 821:153506 Zhou X, Zhang Z, Wang J, Wang Q, Ma G, Lei Z (2017) Sb2O4/reduced graphene oxide composite as high-performance anode material for lithium ion batteries. J Alloys Compd 699:611–618 Chang L, Yi Z, Wang Z, Wang L, Cheng Y (2019) Ultrathin SnO2 nanosheets anchored on graphene with improved electrochemical kinetics for reversible lithium and sodium storage. Appl Surf Sci 484:646–654 Xu H, Wang D, Zhang W, Zhu J, Zhang T, Guo X, Zhang Y, Sun Z, Chen J (2018) SnO2 nanorods encapsulated within a 3D interconnected graphene network architecture as high-performance lithium-ion battery anodes. Sustain Energ Fuels 2(1):262–270 Kong Z, Liu X, Wang T, Fu A, Li Y, Guo P, Guo Y-G, Li H, Zhao XS (2019) Three-dimensional hollow spheres of porous SnO2/rGO composite as high-performance anode for sodium ion batteries. Appl Surf Sci 479:198–208 Wang H, Zhu C, Chao D, Yan Q, Fan HJ (2017) Nonaqueous hybrid lithium-ion and sodium-ion capacitors. Adv Mater 29(46):1702093 Zhang K, Park M, Zhou L, Lee G-H, Li W, Kang Y-M, Chen J (2016) Urchin-like CoSe2 as a high-performance anode material for sodium-ion batteries. Adv Funct Mater 26(37):6728–6735