An ESR study of the radical interactions of NOx with lignin-containing pulps and papers and several model lignin compounds

Research on Chemical Intermediates - Tập 21 Số 3 - Trang 425-439 - 1995
Pemberton, R. S.1, Depew, M. C.1, Pollington, S. D.1, Wan, J. K. S.1
1Department of Chemistry, Queen's University, Kingston, (Canada)

Tóm tắt

The reactions of alkyl peroxyl radicals with cellulosic and lignin-containing papers have significance in both the problems of brightness reversion and paper aging phenomena. Since transient peroxyl radicals are elusive to ESR and other spectroscopic detection, we have explored the controlled study of the interactions of nitrogen oxides with paper and some model lignin compounds in solution as a comparable model of free radical oxidation. Formations of intermediate iminoxyl and nitroxide radicals are identified by ESR with products in some model systems analysed by GC/MS to elucidate the primary mechanisms of the interactions of these gaseous free radicals with papers and with some simple organic model lignin compounds.

Tài liệu tham khảo

citation_journal_title=J. Pulp Paper Sci.; citation_author=G.J. Leary; citation_volume=20; citation_publication_date=1994; citation_pages=J154-J154; citation_id=CR1 citation_journal_title=Res. Chem. Intermed.; citation_author=I.A. Shkrob, M.C. Depew, J.K.S. Wan; citation_volume=17; citation_publication_date=1992; citation_pages=271-271; citation_doi=10.1163/156856792X00182; citation_id=CR2 citation_journal_title=J. Pulp and Paper Science; citation_author=N. Gurnagul, R. Howard, X. Zou; citation_volume=19; citation_publication_date=1993; citation_pages=J160-J160; citation_id=CR3 citation_journal_title=Tappi Journal; citation_author=N. Gurnagul, X. Zou; citation_volume=77; citation_publication_date=1994; citation_pages=199-199; citation_id=CR4 citation_journal_title=Instrumentation Science and Technology; citation_author=M.S. Ioffe, M. Catherine Depew, Jeffrey K.S. Wan; citation_volume=22; citation_publication_date=1994; citation_pages=343-343; citation_doi=10.1080/10739149408001193; citation_id=CR5 citation_journal_title=J. Wood Chem. and Technol.; citation_author=J.K.S. Wan, M.Y. Tse, C. Heitner; citation_volume=13; citation_publication_date=1993; citation_pages=327-327; citation_doi=10.1080/02773819308020521; citation_id=CR6 E.G. Rozantsev,Free Nitroxyl Radicals, H. Ulrich (Ed.), Plenum Press, (1970), and references therein. citation_journal_title=Can. J. Chem.; citation_author=W.H. Wolodarsky, J. Faniran, J.K.S. Wan; citation_volume=51; citation_publication_date=1973; citation_pages=4072-4072; citation_doi=10.1139/v73-606; citation_id=CR8 citation_journal_title=J. Am. Chem. Soc.; citation_author=J.R. Thomas; citation_volume=86; citation_publication_date=1964; citation_pages=1446-1446; citation_doi=10.1021/ja01061a043; citation_id=CR9 B.C. Gilbert and R.O.C. Norman,J. Chem Soc. (B), 86, (1966);ibid. J. Chem Soc. (B), 722 (1966). citation_journal_title=J. Phys. Chem.; citation_author=M.F. Chiu, B.C. Gilbert, B.T. Sutcliffe; citation_volume=76; citation_publication_date=1972; citation_pages=553-553; citation_doi=10.1021/j100648a018; citation_id=CR11 citation_title=Photochemistry of Lignocellulosic Materials; citation_inbook_title=ACS Symposium Series ; citation_publication_date=1993; citation_pages=99-99; citation_id=CR12; citation_author=J.K.S. Wan; citation_author=I.A. Shkrob; citation_author=M.C. Depew; citation_publisher=ACS citation_journal_title=J. Org. Chem.; citation_author=C.A. Burkhard, J.F. Brown; citation_volume=29; citation_publication_date=1964; citation_pages=2235-2235; citation_doi=10.1021/jo01031a030; citation_id=CR13 L. Zhang and G. Gellerstedt,International Symposium on Wood and Pulping Chemistry, Proceedings, p. 759 (1992). citation_title=The Infra-red Spectra of Complex Molecules; citation_publication_date=1958; citation_id=CR15; citation_author=L.J. Bellamy; citation_publisher=Methuen and Co. Ltd.