Bột PMMA pha tạp với aluminat tạo ra từ phương pháp một bước thuận lợi để loại bỏ ion đồng từ dung dịch nước

International Nano Letters - Tập 9 - Trang 317-325 - 2019
Misagh Ghamari1, Amin Imani2, James F. Williams3, Mahdi Ghasemifard1,3
1Nanotechnology Lab, Esfarayen University of Technology, Esfarayen, Iran
2Department of Materials Engineering, The University of British Columbia, Vancouver, Canada
3Department of Physics, The University of Western Australia, Perth, Australia

Tóm tắt

Một loại vật liệu nano compozit polymethyl methacrylate/boehmite mới với hiệu suất hấp phụ Cu(II) được tăng cường một cách đáng kể đã được tổng hợp từ $${\text{Al}}({\text{NO}}_{3} )_{3} \cdot 9{\text{H}}_{2} {\text{O}}$$ bằng phương pháp sol-gel đơn giản. Nghiên cứu đã khám phá ảnh hưởng của hàm lượng boehmite, thời gian tiếp xúc và hình thái của hợp kim (pH của quá trình tổng hợp) như là các yếu tố chính đối với hiệu suất loại bỏ và khả năng hấp phụ của hợp kim đối với ion đồng. Các hợp chất có hàm lượng boehmite từ 0.7 đến 5wt% và những hợp chất có hình thái khác nhau được chuẩn bị với các giá trị pH khác nhau cho thấy hành vi hấp phụ khác nhau. Các thí nghiệm hấp phụ theo mẻ cho thấy hiệu suất hấp phụ của các hợp kim được cải thiện khi tăng hàm lượng boehmite và thời gian tiếp xúc. Hiệu suất loại bỏ và khả năng hấp phụ cao nhất đạt được khi hợp kim được chuẩn bị ở pH 8 với hoạt tính xúc tác gia tăng đi kèm.

Từ khóa

#PMMA #boehmite #hấp phụ #ion đồng #phương pháp sol-gel

Tài liệu tham khảo

Wang, Q., Yang, Z.: Industrial water pollution, water environment treatment, and health risks in China. Environ. Pollut. 218, 358–365 (2016). https://doi.org/10.1016/j.envpol.2016.07.011 Asgari Lajayer, B., Najafi, N., Moghiseh, E., Mosaferi, M., Hadian, J.: Removal of heavy metals (Cu2+ and Cd2+) from effluent using gamma irradiation, titanium dioxide nanoparticles and methanol. J. Nanostructure Chem. 8, 483–496 (2018). https://doi.org/10.1007/s40097-018-0292-3 Asgari Lajayer, B., Ghorbanpour, M., Nikabadi, S.: Heavy metals in contaminated environment: destiny of secondary metabolite biosynthesis, oxidative status and phytoextraction in medicinal plants. Ecotoxicol. Environ. Saf. 145, 377–390 (2017). https://doi.org/10.1016/j.ecoenv.2017.07.035 Sadegh, H., Ali, G.A.M., Gupta, V.K., Makhlouf, A.S.H., Shahryari-ghoshekandi, R., Nadagouda, M.N., Sillanpää, M., Megiel, E.: The role of nanomaterials as effective adsorbents and their applications in wastewater treatment. J. Nanostructure Chem. 7, 1–14 (2017). https://doi.org/10.1007/s40097-017-0219-4 Ali Sarhan, A.: Adsorption characteristics of copper(II) ions from aqueous solution onto ionic cross-linked Pva/P(Aam-Nipaam) core-shell nanogels. J. Nanomed. Nanotechnol. 01, 1–9 (2015). https://doi.org/10.4172/2157-7439.S7-001 Tisato, F., Marzano, C., Porchia, M., Pellei, M., Santini, C.: Copper in diseases and treatments, and copper-based anticancer strategies. Med. Res. Rev. (2009). https://doi.org/10.1002/med.20174 Muhammad Ekramul Mahmud, H.N., Huq, A.K.O., Yahya, R. binti: The removal of heavy metal ions from wastewater/aqueous solution using polypyrrole-based adsorbents: a review. RSC Adv. 6, 14778–14791 (2016). https://doi.org/10.1039/c5ra24358k Ali, R.M., Hamad, H.A., Hussein, M.M., Malash, G.F.: Potential of using green adsorbent of heavy metal removal from aqueous solutions: adsorption kinetics, isotherm, thermodynamic, mechanism and economic analysis. Ecol. Eng. 91, 317–332 (2016). https://doi.org/10.1016/j.ecoleng.2016.03.015 Khoshsang, H., Ghaffarinejad, A., Kazemi, H., Wang, Y., Arandiyan, H.: One-pot synthesis of S-doped Fe2O3/C magnetic nanocomposite as an adsorbent for anionic dye removal: equilibrium and kinetic studies. J. Nanostructure Chem. 8, 23–32 (2018). https://doi.org/10.1007/s40097-017-0251-4 Khandel, P., Shahi, S.K.: Mycogenic nanoparticles and their bio-prospective applications: current status and future challenges. J. Nanostructure Chem. 8, 369–391 (2018). https://doi.org/10.1007/s40097-018-0285-2 Ghaemi, N., Daraei, P.: Enhancement in copper ion removal by PPy@Al2O3 polymeric nanocomposite membrane. J. Ind. Eng. Chem. 40, 26–33 (2016). https://doi.org/10.1016/j.jiec.2016.05.027 Fouladgar, M., Beheshti, M., Sabzyan, H.: Single and binary adsorption of nickel and copper from aqueous solutions by γ-alumina nanoparticles: equilibrium and kinetic modeling. J. Mol. Liq. 211, 1060–1073 (2015). https://doi.org/10.1016/j.molliq.2015.08.029 Xu, Z., Yu, J., Jaroniec, M.: Efficient catalytic removal of formaldehyde at room temperature using AlOOH nanoflakes with deposited Pt. Appl. Catal. B Environ. 163, 306–312 (2015). https://doi.org/10.1016/j.apcatb.2014.08.017 Sun, B., Li, X., Zhao, R., Yin, M., Wang, Z., Jiang, Z., Wang, C.: Hierarchical aminated PAN/γ-AlOOH electrospun composite nanofibers and their heavy metal ion adsorption performance. J. Taiwan Inst. Chem. Eng. 62, 219–227 (2016). https://doi.org/10.1016/j.jtice.2016.02.008 Dinari, M., Mohammadnezhad, G., Soltani, R.: Fabrication of poly(methyl methacrylate)/silica KIT-6 nanocomposites via in situ polymerization approach and their application for removal of Cu2+ from aqueous solution. RSC Adv. 6, 11419–11429 (2016). https://doi.org/10.1039/C5RA23500F Ghamari, M., Farzi, G.: Effect of morphology control on optical properties of PMMA/boehmite nano-hybrid prepared through facile one-pot process. J. Mater. Sci. Mater. Electron. 28, 16570–16574 (2017). https://doi.org/10.1007/s10854-017-7570-6 Mohammadnezhad, G., Dinari, M., Soltani, R.: The preparation of modified boehmite/PMMA nanocomposites by: in situ polymerization and the assessment of their capability for Cu2+ ion removal. New J. Chem. 40, 3612–3621 (2016). https://doi.org/10.1039/c5nj03109e Sun, W., Li, L., Stefanescu, E.A., Kessler, M.R., Bowler, N.: Dynamics of poly(methyl methacrylate)–montmorillonite nanocomposites: a dielectric study. J. Non Cryst. Solids. 410, 43–50 (2015). https://doi.org/10.1016/j.jnoncrysol.2014.11.030 Trung, N.B., Tam, T.Van, Dang, D.K., Babu, K.F., Kim, E.J., Kim, J., Choi, W.M.: Facile synthesis of three-dimensional graphene/nickel oxide nanoparticles composites for high performance supercapacitor electrodes. Chem. Eng. J. 264, 603–609 (2015). https://doi.org/10.1016/j.cej.2014.11.140 Ghamari, M., Farzi, G.: The impact of morphology control on the microhardness of PMMA/boehmite hybrid nanoparticles prepared via facile aqueous one-pot process. J. Sol Gel Sci. Technol. 84, 135–144 (2017). https://doi.org/10.1007/s10971-017-4487-8 Ghamari, M., Farzi, G.: Frequency and composition dependency of optical and dielectric properties of PMMA/boehmite nano-hybrid prepared via facile aqueous one-pot process. Mod. Phys. Lett. B 31, 1750120 (2017). https://doi.org/10.1142/S0217984917501202 Park, S.Y., Park, E.J., Lee, M.Y., Park, C., Kim, H.G., Jeong, E.D., Lim, K.T.: Preparation of Al(OH)3/PMMA nanocomposites by emulsion polymerization. Polym. Adv. Technol. 19, 1803–1808 (2008). https://doi.org/10.1002/pat.1197 Imani, A., Arabi, M., Farzi, G.: Effect of in situ oxidative preparation on electrical properties of epoxy/PANi/MWCNTs nanocomposites. J. Mater. Sci.: Mater. Electron. 27, 10364–10370 (2016). https://doi.org/10.1007/s10854-016-5122-0 Grohens, Y., Schultz, J., Prud’homme, R.E.: PMMA conformational changes on γ-alumina powder: influence of the polymer tacticity on the configuration of the adsorbed layer. Int. J. Adhes. Adhes. 17, 163–167 (1997). https://doi.org/10.1016/s0143-7496(96)00035-8 Pantoja, M., Díaz-Benito, B., Velasco, F., Abenojar, J., del Real, J.C.: Analysis of hydrolysis process of γ-methacryloxypropyltrimethoxysilane and its influence on the formation of silane coatings on 6063 aluminum alloy. Appl. Surf. Sci. 255, 6386–6390 (2009). https://doi.org/10.1016/j.apsusc.2009.02.022 Naskar, M.K., Chatterjee, M.: Boehmite nanoparticles by the two-reverse emulsion technique. J. Am. Ceram. Soc. 88, 3322–3326 (2005). https://doi.org/10.1111/j.1551-2916.2005.00600.x Laachachi, A., Ferriol, M., Cochez, M., Lopez Cuesta, J.-M., Ruch, D.: A comparison of the role of boehmite (AlOOH) and alumina (Al2O3) in the thermal stability and flammability of poly(methyl methacrylate). Polym. Degrad. Stab. 94, 1373–1378 (2009). https://doi.org/10.1016/j.polymdegradstab.2009.05.014 Miao, Y.E., Wang, R., Chen, D., Liu, Z., Liu, T.: Electrospun self-standing membrane of hierarchical SiO2 at γ-AlOOH (Boehmite) core/sheath fibers for water remediation. ACS Appl. Mater. Interfaces 4, 5353–5359 (2012). https://doi.org/10.1021/am3012998 Rajamani, M., Rajendrakumar, K.: Chitosan-boehmite desiccant composite as a promising adsorbent towards heavy metal removal. J. Environ. Manag. 244, 257–264 (2019). https://doi.org/10.1016/j.jenvman.2019.05.056 Imani, A., Oveisi, H.: Self-assembly assisted fabrication of nanoporous nickel(II) phosphate octahydrate microspheres catalyst with orange peel surface toward urea oxidation. ChemistrySelect 4, 7338–7342 (2019). https://doi.org/10.1002/slct.201901107