Aluminum coprecipitates with Fe (hydr)oxides: Does isomorphous substitution of Al3+ for Fe3+ in goethite occur?

Alvarez, 2007, Simultaneous incorporation of Mn and Al in the goethite structure, Geoderma, 140, 8 Bakoyannakis, 2003, Akaganeite and goethite-type nanocrystals: synthesis and characterization, Microporous Mesoporous Mater., 59, 35, 10.1016/S1387-1811(03)00274-9 Bazilevskaya E. (2009) Iron and aluminum hydroxide nanoparticles in the environment: from nano-scale to the field processes. Ph. D. Dissertation, The Pennsylvania State University, University Park. Blanch, 2008, The crystal chemistry of Al-bearing goethites: an infrared spectroscopic study, Miner. Mag., 72, 1043, 10.1180/minmag.2008.072.5.1043 Bye, 1964, Crystallization process in aluminum hydroxide gels, Kolloid Z., 198, 53, 10.1007/BF01499454 Chesworth, 1975, System SiO2–AlOOH–Fe2O3–H2O and kaolinitic stage of goethite facies, Clays Clay Miner., 23, 389, 10.1346/CCMN.1975.0230511 Coey, 1995, Spin flop in goethite, J. Phys.: Condens. Matter, 7, 759, 10.1088/0953-8984/7/4/006 Cornell, 2003 Colombo, 1996, Effect of time and temperature on the chemical composition and crystallization of mixed iron and aluminum species, Clays Clay Miner., 44, 113, 10.1346/CCMN.1996.0440110 De Juan, 2007, Multivariate Curve Resolution (MCR) from 2000: Progress in Concepts and Applications, Crit. Rev. Anal. Chem., 36, 163, 10.1080/10408340600970005 Denton, 1991, Vegard law, Phys. Rev. A, 43, 3161, 10.1103/PhysRevA.43.3161 Dzombak, 1990 Eggleton, 1987, Non-crystalline Fe–Si–Al-oxy(hydr)oxides, Clay Clay Miner., 35, 29, 10.1346/CCMN.1987.0350104 Fazey, 1991, X-ray powder diffraction rietveld characterization of synthetic aluminum substituted goethite, Clays Clay Miner., 39, 248, 10.1346/CCMN.1991.0390304 Ford, 1999, Influence of sorbate–sorbent interactions on the crystallization kinetics of nickel and lead-ferrihydrite coprecipitates, Geochim. Cosmochim. Acta, 63, 39, 10.1016/S0016-7037(99)00010-1 Fysh, 1983, Fourier transform infrared studies of aluminous goethites and hematites, Clays Clay Miner., 31, 377, 10.1346/CCMN.1983.0310507 Garrido, 2008, Multivariate curve resolution-alternating least squares (MCR-ALS) applied to spectroscopic data from monitoring chemical reactions processes, Anal. Bioanal. Chem., 390, 2059, 10.1007/s00216-008-1955-6 Goh, 1987, Effect of iron on the nature of precipitation products of aluminum, Can. J. Soil Sci., 67, 135, 10.4141/cjss87-012 Gualtieri, 1999, The goethite–hematite phase transformation, Am. Miner., 84, 895, 10.2138/am-1999-5-624 Guo, 2011, Modeling the iron oxides and oxyhydroxides for the prediction of environmentally sensitive phase transformations, Phys. Rev. B., 83, 094112, 10.1103/PhysRevB.83.094112 Gustafsson J. P. (2010) Visual MINTEQ, version 3. Department of Land and Water Resource Engineering, KTH, Stockholm, Sweden. Hill, 1979, Crystal structure refinement and electron density distribution in diaspore, Phys. Chem. Miner., 5, 179, 10.1007/BF00307552 Hsu, 1989, Aluminum hydroxides and oxyhydroxides, 331 Jacob, 2007, Vegard’s law: a fundamental relation or approximation?, Int. J. Mater. Res., 9, 776, 10.3139/146.101545 Jaumot, 2005, A graphical user-friendly interface for MCR-ALS: a new tool for multivariate curve resolution under MATLAB, Chemom. Intell. Lab. Syst., 76, 101, 10.1016/j.chemolab.2004.12.007 Jolivet, 2004, Iron oxide chemistry: from molecular clusters to extended solid networks, Chem. Commun., 35, 48 Kosmas, 1986, Relationship among derivative spectroscopy, color, crystallite dimensions, and Al substitution of synthetic goethites and hematites, Clays Clay Miner., 34, 625, 10.1346/CCMN.1986.0340602 Kresse, 1996, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set, Phys. Rev. B, 54, 11169, 10.1103/PhysRevB.54.11169 Krishnan, 2006, Heat capacity measurements on uranium–cerium mixed oxides using differential scanning calorimetry, Thermochim. Acta, 440, 141, 10.1016/j.tca.2005.11.005 Kolesova, 1962, Infrared absorption spectra of diaspore (α-AlOOH). Boehmite (γ-AlOOH) and GaOOH, Zh. Strukt. Khim., 3, 656 Lövgren, 1990, Acid/base reactions and Al(III) complexation at the surface of goethite, Geochim. Cosmochim. Acta, 54, 1301, 10.1016/0016-7037(90)90154-D Majzlan, 2003, Thermodynamics of Fe oxides. Part I: Entropy at standard temperature and pressure and heat capacity of goethite (alpha-FeOOH), lepidocrocite (gamma-FeOOH), and maghemite (gamma-Fe2O3), Am. Miner., 88, 846, 10.2138/am-2003-5-613 Majzlan, 2003, Thermodynamics of the goethite-diaspore solid solution, Eur. J. Miner., 15, 495, 10.1127/0935-1221/2003/0015-0495 Martínez, 2000, Aging of coprecipitated Cu in alumina: changes in structural location, chemical form, and solubility, Geochim. Cosmochim. Acta, 64, 1729, 10.1016/S0016-7037(00)00344-6 Martínez, 1998, Coprecipitates of heavy metals in iron oxides: solid phase transformation and metal solubility after aging and thermal treatment, Clays Clay Miner., 46, 537, 10.1346/CCMN.1998.0460507 Murad, 1987, Magnetic-ordering in Al-rich goethites – influence of crystallinity, Am. Miner., 72, 194 Peryea, 1988, Relative solubility of corundum, gibbsite, boemite, and diaspore at standard state conditions, Clays Clay Miner., 36, 391, 10.1346/CCMN.1988.0360502 Piszora, 1998, X-ray powder diffraction study on the solubility limits in the goethite-diaspore solid solutions, Mater. Sci. Forum, 278–2, 584, 10.4028/www.scientific.net/MSF.278-281.584 Pollard, 1991, Magnetism in aluminous goethite, Phys. Chem. Miner., 18, 259, 10.1007/BF00202578 O’Day, 2004, X-ray absorption spectroscopic study of Fe reference compounds for the analysis of natural sediments, Am. Mineral., 89, 572, 10.2138/am-2004-0412 Qiyuan, 1995, Determination of the standard molar enthalpy of formation of α-AlOOH (diaspore), J. Chem. Thermodyn., 27, 443, 10.1006/jcht.1995.0045 Rollmann, 2004, First-principles calculation of the structure and magnetic phases of hematite, Phys. Rev. B, 69, 165107, 10.1103/PhysRevB.69.165107 Rosso, 2001, Structures and energies of AlOOH and FeOOH polymorphs from plane wave pseudopotential calculations, Am. Mineral., 86, 312, 10.2138/am-2001-2-314 Ruan, 1995, Dehydroxylation of aluminous goethite – unit-cell dimentions, crystal size and surface area, Clays Clay Miner., 43, 196, 10.1346/CCMN.1995.0430207 Ruan, 2001, The behavior of hydroxyl units of synthetic goethite and its dehydroxylated product hematite, Specrtochim. Acta A, 57, 2575, 10.1016/S1386-1425(01)00445-0 Ruan, 2002, Infrared spectroscopy of goethite dehydroxylation. II: Effect of aluminum substitution on the behavior of hydroxyl units, Spectrochim. Acta, 58, 479, 10.1016/S1386-1425(01)00556-X Saalfeld, 1974, Refinement of the crystal structure of gibbsite, Z. Kristallogr., 139, 129, 10.1524/zkri.1974.139.1-2.129 Sack, 1991, An internally consistent model for the thermodynamic properties of Fe–Mg–titanomagnetite–aluminate spinels, Contrib. Mineral. Petrol., 106, 474, 10.1007/BF00321989 Scheinost, 2001, Structural environment and oxidation state of Mn in goethite–groutite solid-solutions, Am. Miner., 86, 136, 10.2138/am-2001-0115 Schulze, 1984, The influence of aluminum on iron-oxides. 8: Unit cell dimensions of Al-substituted goethites and estimation of Al from them, Clays Clay Miner., 32, 36, 10.1346/CCMN.1984.0320105 Schulze, 1984, The influence of aluminium on iron oxides. X: Properties of A1-substituted goethites, Clay Miner., 19, 521, 10.1180/claymin.1984.019.4.02 Schwertmann, 1991 Schwertmann, 1999, From Fe(III) ions to ferrihydrite and then to hematite, J. Colloid Interface Sci., 209, 215, 10.1006/jcis.1998.5899 Schwertmann, 1989, Iron oxides, 379 Stanjek, 1992, Influence of aluminum on iron oxides. Part XVI: Hydroxyl and aluminum substitution in synthetic hematites, Clays Clay Miner., 40, 347, 10.1346/CCMN.1992.0400316 Stumm, 1996 Szytula, 1968, Neutron diffraction studies of α-FeOOH, Phys. Status Solidi, 26, 429, 10.1002/pssb.19680260205 Violante, 1998, Nature of mixed iron and aluminum gels as affected by Fe/Al molar ratio, pH and citrate, Clay Miner., 33, 511, 10.1180/000985598545679 Wells, 2006, Thermal and mineral properties of Al-, Cr-, Mn-, Ni-, and Ti-substituted goethite, Clays Clay Miner., 54, 176, 10.1346/CCMN.2006.0540204 Wolska, 1997, The substitution of Fe, Al, and OH in synthetic and natural iron oxides and (hydr)oxides, Adv. Soil Ecol., 30, 271