Alteration Mineralogy of the Zhengguang Epithermal Au-Zn Deposit, Northeast China: Interpretation of Shortwave Infrared Analyses During Mineral Exploration and Assessment

Economic Geology - Tập 116 Số 2 - Trang 389-406 - 2021
Le Wang1,2,3,4, J A Percival5, Jeffrey W. Hedenquist1, Kéiko Hattori1, Kezhang Qin2,3,4
1Department of Earth and Environmental Sciences, University of Ottawa, Ottawa, ON K1N 6N5, Canada
2Innovation Academy for Earth Science, CAS, Beijing 100029, PR China
3Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, P.R. China
4University of Chinese Academy of Sciences, Beijing 100049, P.R. China
5Geological Survey of Canada, Natural Resources Canada, Ottawa, ON K1A 0E8, Canada

Tóm tắt

Abstract Alteration mineralogy from shortwave infrared (SWIR) spectroscopy was compared with X-ray diffraction (XRD) analyses for samples from the Zhengguang intermediate sulfidation epithermal Au-Zn deposit, eastern Central Asian orogenic belt, northeast China. The SWIR and XRD analyses indicate that alteration minerals in the vein-adjacent halo mainly comprise quartz, illite, and locally pyrite (QIP) and chlorite, whereas samples from the pervasive propylitic alteration of host basaltic andesite lava contain epidote, chlorite, carbonate, montmorillonite, and locally illite. SWIR mineral identifications from automated mineral identification software may not always be accurate; thus, the results should be validated by the user. The wavelength position of the Al-OH (~2,200 nm; wAlOH) absorption feature can be used to approximate the composition of illite or white mica. However, caution is required when using the wAlOH value to assess paleotemperatures, as the composition of illite can be influenced by the composition of the host rocks or the hydrothermal fluid. In addition, values of the illite spectral maturity (ISM; ratio of the depth of the ~2,200 nm minima divided by the ~1,900 nm minima) can be affected by the presence of other hydrous minerals, quartz-sulfide veins, and absorption intensity (which can be a function of rock coloration). Despite these cautions, the spatial distribution and variation of the wAlOH and ISM values for illite suggest that the high paleotemperature hydrothermal upflow zones related to the Zhengguang Au-Zn deposit were located below ore zones I and IV, which are predicted to be proximal to the intrusive center of the system.

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Tài liệu tham khảo

Cao, 2018, Physicochemical processes in the magma chamber under the black mountain porphyry Cu-Au deposit, Philippines: Insights from mineral chemistry and implications for mineralization, Economic Geology, 113, 63, 10.5382/econgeo.2018.4544

Chang, 2011, Exploration tools for linked porphyry and epithermal deposits: Example from the Mankayan intrusion-centered Cu-Au district, Luzon, Philippines, Economic Geology, 106, 1365, 10.2113/econgeo.106.8.1365

Cudahy, 2008, Next generation mineral mapping: Queensland airborne HyMap and satellite ASTER surveys 2006–2008, 93

Dalton, 2004, Identification of spectrally similar materials using the USGS Tetracorder algorithm: The calcite-epidote-chlorite problem, Remote Sensing of Environment, 89, 455, 10.1016/j.rse.2003.11.011

Davies, 2008, Hydrothermal breccias and veins at the Kelian gold mine, Kalimantan, Indonesia: Genesis of a large epithermal gold deposit, Economic Geology, 103, 717, 10.2113/gsecongeo.103.4.717

Deng, 2013, Fluid inclusion constraints on the origin of the Zhengguang gold deposit, Heihe City, Heilongjiang Province, Acta Petrologica Sinica, 29, 231

Doublier, 2010, Application of SWIR spectroscopy in very low-grade metamorphic environments: A comparison with XRD methods: Geological Survey of Western Australia, Record 2010/7, 61

Duke, 1994, Near infrared spectra of muscovite, Tschermak substitution, and metamorphic reaction progress: Implications for remote sensing, Geology, 22, 621, 10.1130/0091-7613(1994)022<0621:NISOMT>2.3.CO;2

Einaudi, 2003, Sulfidation state of hydrothermal fluids: The porphyry–epithermal transition and beyond, Society of Economic Geologists Special Publication, 10, 285

Frey, 1987, Very low-grade metamorphism of clastic sedimentary rocks, Low temperature metamorphism, 9

Guggenheim, 2002, Report of the Association Internationale pour l’Étude des Argiles (AIPEA) nomenclature committee for 2001: Order, disorder and crystallinity in phyllosilicates and the use of the “crystallinity index”, Clay Minerals, 37, 389, 10.1180/0009855023720043

Guo, 2019, Mapping white mica alteration associated with the Jiama porphyry-skarn Cu deposit, central Tibet using field SWIR spectrometry, Ore Geology Reviews, 108, 147, 10.1016/j.oregeorev.2017.07.027

Halley, 2015, Footprints: Hydrothermal alteration and geochemical dispersion around porphyry copper deposits: Society of Economic Geologists, Newsletter, 1

Han, 2018, Hydrothermal alteration and short wavelength infrared (SWIR) characteristics of the Tongshankou porphyry-skarn Cu-Mo deposit, Yangtze craton, Eastern China, Ore Geology Reviews, 101, 143, 10.1016/j.oregeorev.2018.07.018

Harraden, 2013, Shortwave infrared spectral analysis of hydrothermal alteration associated with the Pebble porphyry copper-gold-molybdenum deposit, Iliamna, Alaska, Economic Geology, 108, 483, 10.2113/econgeo.108.3.483

Herrmann, 2001, Short wavelength infrared (SWIR) spectral analysis of hydrothermal alteration zones associated with base metal sulfide deposits at Rosebery and western Tharsis, Tasmania, and highway-reward, Queensland, Economic Geology, 96, 939

Howard, 2015, Geochemistry and hydrothermal alteration at the Mount Rawdon gold deposit, New England Orogen geology, tectonics, economics, 1

Jones, 2005, Short wavelength infrared spectral characteristics of the HW horizon: Implications for exploration in the Myra Falls volcanic-hosted massive sulfide camp, Vancouver Island, British Columbia, Canada, Economic Geology, 100, 273, 10.2113/gsecongeo.100.2.273

Kübler, 1967, La cristallinité de l’illite et les zones tout à fait supérieures du métamorphisme: Etages tectoniques, Colloque de Neuchatel 1966, 105

Laakso, 2015, Application of airborne, laboratory, and field hyperspectral methods to mineral exploration in the Canadian arctic: Recognition and characterization of volcanogenic massive sulfide-associated hydrothermal alteration in the Izok Lake deposit area, Nunavut, Canada, Economic Geology, 110, 925, 10.2113/econgeo.110.4.925

Manske, 2006, Roşia Montană, Romania: Europe’s largest gold deposit: Society of Economic Geologists, Newsletter, 1

Neal, 2018, Spectral characteristics of propylitic alteration minerals as a vectoring tool for porphyry copper deposits, Journal of Geochemical Exploration, 184, 179, 10.1016/j.gexplo.2017.10.019

Panalytical, 2018, TerraSpec® Halo user manual, Unpublished ASD Document, 600073, 86

Pang, 2017, Deformation characteristics of the Tongshan fault within Tongshan porphyry copper deposit, Heilongjiang Province, and restoration of alteration zones and ore bodies, Acta Petrologica Sinica, 33, 398

Percival, 2018, Customized spectral libraries for effective mineral exploration: Mining national mineral collections, Clays and Clay Minerals, 66, 297, 10.1346/CCMN.2018.064103

Pontual, 1997, Spectral interpretation field manual, G-MEX, 168

Pontual, 2010, Introduction to spectral geology, Manual for spectral geology workshop at Geological Survey of Canada: AusSpec International Pty. Ltd., Unpublished manual, 38

Simpson, M.P. , 2015, Reflectance spectrometry (SWIR) of alteration minerals surrounding the Favona epithermal vein, Waihi vein system, Hauraki Goldfield: Australasian Institute of Mining and Metallurgy New Zealand Branch Conference, Dunedin, Proceedings, p. 409–418.

Song, 2019, Gold behavior in intermediate sulfidation epithermal systems: A case study from the Zhengguang gold deposit, Heilongjiang Province, NE-China, Ore Geology Reviews, 106, 446, 10.1016/j.oregeorev.2019.02.001

Sonntag, 2012, Low potassium hydrothermal alteration in low sulfidation epithermal systems as detected by IRS and XRD: An example from the Co-O mine, Eastern Mindanao, Philippines, Ore Geology Reviews, 45, 47, 10.1016/j.oregeorev.2011.08.001

Sun, 2001, Application of short-wave infrared spectroscopy to define alteration zones associated with the Elura zinc-lead-silver deposit, NSW, Australia, Journal of Geochemical Exploration, 73, 11, 10.1016/S0375-6742(01)00167-4

Tappert, 2011, Automated drill core logging using visible and near-infrared reflectance spectroscopy: a case study from the Olympic Dam IOCG deposit, South Australia, Economic Geology, 106, 289, 10.2113/econgeo.106.2.289

Tappert, 2013, The mineral chemistry, near-infrared, and mid-infrared reflectance spectroscopy of phengite from the Olympic Dam IOCG deposit, South Australia, Ore Geology Reviews, 53, 26, 10.1016/j.oregeorev.2012.12.006

Tian, 2019, Short wavelength infra-red (SWIR) characteristics of hydrothermal alteration minerals in skarn deposits: Example from the Jiguanzui Cu-Au deposit, Eastern China, Ore Geology Reviews, 106, 134, 10.1016/j.oregeorev.2019.01.025

Thompson, 1999, Alteration mapping in exploration: application of short-wave infrared (SWIR) spectroscopy: Society of Economic Geologists, Newsletter, 1

Thompson, 2009, Mapping mineralogy with reflectance spectroscopy: Examples from volcanogenic massive sulfide deposits: Reviews in, Economic Geology, 16, 25

Wang, 2018, Volcanic-subvolcanic rocks and tectonic setting of Zhengguang intermediate sulfidation epithermal Au-Zn deposit, eastern CAOB, Journal of Asian Earth Sciences, 165, 328, 10.1016/j.jseaes.2018.07.023

Wang, 2020, Geology and genesis of the Early Paleozoic Zhengguang intermediate-sulfidation epithermal Au-Zn deposit, northeast China, Ore Geology Reviews, 124

Wu, 2009, Fluid inclusion study of the Tongshan porphyry copper deposit, Heilongjiang Province, China, Acta Petrologica Sinica, 25, 2995

Xu, 2017, Alteration and mineralization of Xinan Cu-Mo ore deposit in Zijinshan orefield, Fujian Province, and application of short wavelength infra-red technology (SWIR) to exploration, Mineral Deposits, 36, 1013

Yang, 1998, Spectral characterisation of the hydrothermal alteration at Hishikari, Japan: CSIRO Exploration and Mining, North Ryde, editor/s. Water-Rock Interaction, 587

Yang, 2005, Infrared spectral reflectance characterization of the hydrothermal alteration at the Tuwu Cu-Au deposit, Xinjiang, China, Mineralium Deposita, 40, 324, 10.1007/s00126-005-0479-7

Yang, 2011, Variations in composition and abundance of white mica in the hydrothermal alteration system at Hellyer, Tasmania, as revealed by infrared reflectance spectroscopy, Journal of Geochemical Exploration, 108, 143, 10.1016/j.gexplo.2011.01.001

Yang, 2012, Application of short wavelength infrared (SWIR) technique in exploration of poorly eroded porphyry Cu district: A case study of Niancun ore district, Tibet, Mineral Deposits, 31, 699

Yu, 1996, Tectonic setting of Ordovician volcanic rocks in Northwestern Xiaoxinganling, Heilongjiang Province, Acta Geoscientia Sinica, 17, 54

Zeng, 2014, Re-Os and U-Pb geochronology of the Duobaoshan porphyry Cu-Mo-(Au) deposit, northeast China, and its geological significance, Journal of Asian Earth Sciences, 79, 895, 10.1016/j.jseaes.2013.02.007