Ag+ ion transport studies in a polyvinyl alcohol-based polymer electrolyte system
Tóm tắt
Thick films of pure polyvinyl alcohol and polyvinyl alcohol doped with silver nitrate with different compositions have been prepared by solution cast technique. The FT-IR spectrum confirms the complexation process. The conductivity of the pure polyvinyl alcohol is of the order of 10−7 Sm−1 at 90 °C, and its value increases by two orders of magnitude when doped with 20 wt% of AgNO3. The activation energy, calculated from the Arrhenius plot for all compositions of the poly vinyl alcohol doped with silver nitrate, is between 0.24 and 0.35 eV. The migration energy for the ion in polymer electrolyte has been calculated from the modulus spectrum, and is in good agreement with the activation energy calculated from the Arrhenius plot. The modulus spectra indicate the non-Debye nature of the material.
Tài liệu tham khảo
Pantaloni S, Passerini S, Scrosati B (1987) J Electrochem Soc 134:753
Armand MB (1986) Annu Rev Mater Sci 16:245
Fenton BE, Parker JM, Wright PV (1973) Polymer 14:589
Armand M, Chabagno JM, Duclot MJ (1979) In: Vashishta P, Mundy JN, Shenoy GK (eds) Fast ion transport in solids. North-Holland, New York, p 131
Rao SS, Rao KVS, Sharefuddin M, Rao UVS (1994) Solid State Ionics 67:331
Abrantes TM, Alcacer LJ, Sequeira CAC (1986) Solid State Ionics 18(19):315
Chandra S, Hashmi SA, Saleem M, Agarwal RC (1993) Solid State Ionics 67:1
Rao SS, Rao KVS, Shareefuddin Md, Rao UVS, Chandra S (1994) Solid State Ionics 67:331
Rao SS, Rao UVS (1994) Mater Sci Lett 13:1771
Jaipal Reddy M, Rao SS, Laxminarsaiah E, Rao UVS (1995) Solid State Ionics 80:93
Armand M, Chabagno JM, Duclot MJ (1978) Extended abstracts. In: Second Int Conf on Solid Electrolytes, 20–22 Sept 1978, St Andrews, Scotland
Macdonald JR, Kenan WR (eds)(1978) Impedance spectroscopy: emphasizing solid materials and systems. Wiley, New York
Vijaykumar M, Selvasekarapandian S, Bhuvaneswari MS, Hirankumar G, Ramprasad G, Subramanian R, Angelo PC (2003) Physica B 334:390–397
Vien DL, Colthup NB, Fately WG, Grasselli JG (1991) Infrared and Raman characteristic frequencies of organic molecules, Academic, New York, p 85
Takahashi Y (1973) J Polym Sci 11:213
Vincent CA (1987) Prog Solid State Chem 17:347
Steele BCH, Weston SE (1981) Solid State Ionics 2:347
Miyamoto T, Shibayama K (1973) J Appl Phy 44:5372
Siekierski M, Wieczorek W, Przyluski J (1998) Electrochim Acta 43:1339
Joncher AK (1977) Nature 267:673
Funke K, Roling B, Lange M (1998) Solid State Ionics 105:195
Vijaykumar M, Hirankumar G, Bhuvaneswari MS, Selvasekarapandian S (2003) J Power Sources 117:143
Macedo PB, Moynihan CT, Bose R (1972) Phys Chem Glasses 13:171
Sayed MB (1992) J Phys Chem Solids 53:1041
Sayed MB (1996) Zeolites 16:157
Williams G, Watts DC (1970) T Farad Soc 66:80