Adsorptive performance of Tagetes flower waste based adsorbent for crystal violet dye removal from an aqueous solution

Environmental Sustainability - Tập 5 - Trang 493-506 - 2022
Lata Verma1, Dipti Sonkar1, Chandra Bhan1, Jiwan Singh1, Utkarsh Kumar2, B. C. Yadav2, Ashish Nayak3
1Laboratory of Environmental Nanotechnology and Bioremediation, Department of Environmental Science, Babasaheb Bhimrao Ambedkar University, Lucknow, India
2Department of Physics, Babasaheb Bhimrao Ambedkar University, Lucknow, India
3Deartment of Civil Engineering, Indian Institute of Technology, Kharagpur, India

Tóm tắt

Waste biomass of Tagetes (Marigold), was used for the synthesis of bioadsorbent at two different temperatures (250 °C and 500 °C) represented as FWAC-250 and FWAC-500. Both the materials were applied for the adsorption of crystal violet (CV) dye from an aqueous solution. The characterization of bioadsorbents was done using different analytical techniques such as scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and point of zero charge (pHZPC). The synthesized bioadsorbents were found to be potent for the adsorption of crystal violet dye from an aqueous solution. Different parameters such as effect of dose, solution pH, initial CV concentration, and the operating temperature were studied for the optimization of adsorption process. The obtained experimental data were also analyzed by isotherm, kinetics, and thermodynamic studies. The results revealed that experimental data of batch adsorption study was best fitted to the Langmuir model of isotherm and the pseudo-second-order kinetics. The adsorption capacity (qmax) was found 1.95 mg/g and 2.69 mg/g for FWAC-250 and FWAC-500, correspondingly. The thermodynamic study shows that the process of CV adsorption was endothermic in nature with both biosorbents FWAC-250 and FWAC-500. The biomass waste Tagetes flowers were found to be potential candidates for the treatment of CV from an aqueous solution in a cost-effective and eco-friendly way. Thus, the bioadsorbents can be significantly used to treat wastewater contaminated with CV dye on a large scale.

Tài liệu tham khảo

Ali I, Asim M, Khan TA (2012) Low cost adsorbents for the removal of organic pollutants from wastewater. J Environ Manag 113:170–183 Aljeboree AM, Alkaim AF, Al-Dujaili AH (2014) Adsorption isotherm, kinetic modeling and thermodynamics of CV on coconut husk-based activated carbon. Desalin Water Treat 53:1–12 Alvarez AME, Anaguano AH (2014) Flower wastes as a low-cost adsorbent for the removal of acid blue 9. Dyna 81(185):132–138 Ambaye TG, Vaccari M, van Hullebusch ED, Amrane A, Rtimi S (2021) Mechanisms and adsorption capacities of biochar for the removal of organic and inorganic pollutants from industrial wastewater. Int J Environ Sci Technol 18(10):3273–3294 Amodu OS, Ojumu TV, Ntwampe SK, Ayanda OS (2015) Rapid adsorption of crystal violet onto magnetic zeolite synthesized from fly ash and magnetite nanoparticles. J Encapsul Adsorpt Sci 5(04):191–203 Anyika C, Asri NAM, Majid ZA, Yahya A, Jaafar J (2017) Synthesis and characterization of magnetic activated carbon developed from palm kernel shells. Nanotechnol Environ Eng 2(1):16 Bani-Fwaz MZ, El-Zahhar AA, Abd-Rabboh HS, Hamdy MS, Shkir M (2019) Synthesis of NiO nanoparticles by thermal routes for adsorptive removal of crystal violet dye from aqueous solutions. Int J Environ Anal Chem 101:1126–1144 Barka N, Ouzaouit K, Abdennouri M, Makhfouk ME (2013) Dried prickly pear cactus (Opuntia ficus indica) cladodes as a low-cost and eco-friendly biosorbent for dyes removal from aqueous solutions. J Taiwan Inst Chem Eng 44:52–60 da Silva JS, da Rosa MP, Beck PH, Peres EC, Dotto GL, Kessler F, Grasel FS (2018) Preparation of an alternative adsorbent from Acacia Mearnsii wastes through acetosolv method and its application for dye removal. J Clean Prod 180:386–394 Dada AO, Olalekan AP, Olatunya AM, Dada O (2012) Langmuir, freundlich, Temkin and Dubinin-Radushkevich isotherm studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. J Appl Chem 3:38–45 Dastkhoon M, Ghaedi M, Asfaram A, Azqhandi MHA, Purkait MK (2017) Simultaneous removal of dyes onto nanowires adsorbent use of ultrasound assisted sorption to clean waste water: Chemometrics for modeling and optimization, multicomponent sorption and kinetic study. Chem Eng Res Des 124:222–237 Foroutan R, Peighambardoust SJ, Peighambardoust SH, Pateiro M, Lorenzo JM (2021) Adsorption of crystal violet dye using activated carbon of lemon wood and activated carbon/Fe3O4 magnetic nanocomposite from aqueous solutions: a kinetic, equilibrium and thermodynamic study. Molecules 26(8):1–19 Ganea IV, Nan A, Baciu C, Turcu R (2021) Effective removal of crystal violet dye using neoteric magnetic nanostructures based on functionalized poly (benzofuran-co-arylacetic acid): investigation of the adsorption behaviour and reusability. Nanomater 11(3):1–15 Gautam A, Rawat S, Verma L, Singh J, Sikarwar S, Yadav BC, Kalamdhad AS (2018) Green synthesis of iron nanoparticle from extract of waste tea: an application for phenol red removal from aqueous solution. Environ Nanotechnol Monit 10:377–387 Hamidzadeh S, Torabbeigi M, Shahtaheri SJ (2015) Removal of crystal violet from water by magnetically modified activated carbon and nanomagnetic iron oxide. J Environ Health Sci Eng 13(1):1–7 Homagai PL, Poudel R, Poudel S, Bhattarai A (2022) Adsorption and removal of crystal violet dye from aqueous solution by modified rice husk. Heliyon 8(4):e09261 Ibrahim M, Siddiqe A, Verma L, Singh J, Koduru JR (2019) Adsorptive removal of fluoride from aqueous solution by biogenic iron permeated activated carbon derived from sweet lime waste. Acta Chim Slov 66:123–136 Jadhav NL, Gondhalekar KA, Doltade SB, Pinjari DV (2018) Concentrated solar radiation aided green approach towards the synthesis of Fe3O4 nanoparticles by photochemical oxidation of FeCl2. Sol Energy 171:769–773 Jumaeri E, Kusumasturi S, Santosa J, Sutarno S (2017) Adsorption of crystal violet dye using zeolite A synthesized from coal fly ash. IOP Conf Ser Mater Sci and Eng 172:1–8 Kamath AA, Nayak NG, Sagar R (2021) Coconut flower sheath derived activated charcoal as efficient and cost effective adsorbent for crystal violet dye removal. Inorg Chem Commun 134:109077 Konicki W, Sibera D, Mijowska E, Lendzion-Bieluń Z, Narkiewicz U (2013) Equilibrium and kinetic studies on acid dye Acid Red 88 adsorption by magnetic ZnFe2O4 spinel ferrite nanoparticles. J Colloid Interface Sci 398:152–160 Kuang Y, Zhang X, Zhou S (2020) Adsorption of methylene blue in water onto activated carbon by surfactant modification. Water 12(2):587 Kumari HJ, Krishnamoorthy P, Arumugam TK, Radhakrishnan S, Vasudevan D (2017) An efficient removal of CV from waste water by adsorption onto TLAC/Chitosan composite: a novel low cost adsorbent. Int J Biol Macromol 96:324–333 Kyi PP, Quansah JO, Lee CG, Moon JK, Park SJ (2020) The removal of crystal violet from textile wastewater using palm kernel shell-derived biochar. Appl Sci 10(7):1–13 Lagergren S (1898) Zur theorie der sogenannten adsorption gelˆster stoffe. Kungliga Svenska Vetenskapsakademiens Handlingar 24(4):1–39 Li Z, Hanafy H, Zhang L, Sellaoui L, Netto MS, Oliveira ML, Seliem MK, Dotto GL, Bonilla-Petriciolet A, Li Q (2020) Adsorption of congo red and methylene blue dyes on an ashitaba waste and a walnut shell-based activated carbon from aqueous solutions: experiments, characterization and physical interpretations. Chem Eng J 388:24263 Loqman A, El Bali B, Lützenkirchen J, Weidler PG, Kherbeche A (2017) Adsorptive removal of crystal violet dye by a local clay and process optimization by response surface methodology. Appl Water Sci 7(7):3649–3660 Loulidi I, Boukhlifi F, Ouchabi M, Amar A, Jabri M, Kali A, Aziz F (2020) Adsorption of crystal violet onto an agricultural waste residue: kinetics, isotherm, thermodynamics, and mechanism of adsorption. Sci World J 2020:1–9 Lunge S, Singh S, Sinha A (2014) Magnetic iron oxide (Fe3O4) nanoparticles from tea waste for arsenic removal. J Magn Magn Mater 356:21–31 Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK (2010) Adsorption of hazardous dye crystal violet from wastewater by waste materials. J Colloid Interface Sci 343:463–473 Muthukumaran C, Sivakumar VM, Thirumarimurugan M (2016) Adsorption isotherms and kinetic studies of crystal violet dye removal from aqueous solution using surfactant modified magnetic nanoadsorbent. J Taiwan Inst Chem E 63:354–362 Naderi P, Shirani M, Semnani A, Goli A (2018) Efficient removal of crystal violet from aqueous solutions 55with Centaurea stem as a novel biodegradable bioadsorbent using response surface methodology and simulated annealing: kinetic, isotherm and thermodynamic studies. Ecotoxicol Environ Saf 163:372–381 Oloo CM, Onyari JM, Wanyonyi WC, Wabomba JN, Muinde VM (2020) Adsorptive removal of hazardous crystal violet dye form aqueous solution using Rhizophora mucronata stem-barks: equilibrium and kinetics studies. Environ Chem Ecotoxicol 2:64–72 Patil SA, Kumbhar PD, Satvekar BS, Harale NS, Bhise SC, Patil SK, Anuse MA (2022) Adsorption of toxic crystal violet dye from aqueous solution by using waste sugarcane leaf-based activated carbon: isotherm, kinetic and thermodynamic study. J Iran Chem Soc 19:2891–2906 Rajabi HR, Arjmand H, Hoseini SJ, Nasrabadi H (2015) Surface modified magnetic nanoparticles as efficient and green sorbents: synthesis, characterization, and application for the removal of anionic dye. J Magn Magn Mater 394:7–13 Rápó E, Tonk S (2021) Factors affecting synthetic dye adsorption; desorption studies: a review of results from the last five years (2017–2021). Molecules 26(17):5419 Sarabadan M, Bashiri H, Mousavi SM (2019) Adsorption of crystal violet dye by a zeolite-montmorillonite nano-adsorbent: modelling, kinetic and equilibrium studies. Clay Miner 54(4):357–368 Savithri S, Rajeshwari M, Nandhakumar V, Durgadevi K, Chandramohan M (2019) Adsorptive removal of crystal violet dye from aqueous solution using activated carbon prepared from Cassia fistula (L) fruit shell. Res J Chem Environ 23(9):71–75 Shakoor S, Nasar A (2018) Adsorptive decontamination of synthetic wastewater containing CV by employing Terminalia arjuna sawdust waste. Groundw Sustain Dev 7:30–38 Shoukat S, Bhatti HN, Igbal M, Noreen S (2017) Mango stone biocomposite preparation and application for crystal violet adsorption: a mechanistic study. Microporous Mesoporous Mater 239:180–189 Singh J, Reddy KJ, Changa YY, Kanga SH, Yang JK (2016) A novel reutilization method for automobile shredder residue as an adsorbent for the removal of methylene blue: mechanisms and heavy metal recovery using an ultrasonically assisted acid. Process Saf Environ 99:88–97 Sultana S, Islam K, Hasan MA, Khan HJ, Khan MAR, Deb A, Rahman MW (2022) Adsorption of crystal violet dye by coconut husk powder: isotherm, kinetics and thermodynamics perspectives. Environ Nanotechnol Monit Manag 17:100651 Vaghani SS, Patel MM, Satish CS (2012) Synthesis and characterization of pH-sensitive hydrogel composed of carboxymethyl chitosan for colon targeted delivery of ornidazol. Carbohydr Res 347:76–82 Verma L, Singh J (2019) Synthesis of novel biochar from waste plant litter biomass for the removal of arsenic (III and V) from aqueous solution: a mechanism characterization, kinetics and thermodynamics. J Environ Manag 248:109235 Verma L, Siddique MA, Singh J, Bharagava RN (2019) As(III) and As(V) removal by using iron impregnated biosorbents derived from waste biomass of Citrus limmeta (peel and pulp) from the aqueous solution and ground water. J Environ Manag 250:109452 Verma L, Azad A, Singh J (2021) Performance of a novel iron infused biochar developed from Raphanus sativus and Artocarpus heterophyllus refuse for trivalent and pentavalent arsenic adsorption from an aqueous solution: mechanism, isotherm and kinetics study. Int J Phytoremed 24:919–932 Weber WJ, Morris JC (1963) Kinetics of sorption on carbon from solutions. J Sanit Eng Div 89:31–60 Wu YH, Ma YL, Sun YG, Xue K, Ma QL, Ma T, Ji WX (2020) Graded synthesis of highly ordered MCM-41 and carbon/zeolite composite from coal gasification fine residue for crystal violet removal. J Clean Prod 277:123186 Zhang X, Wang H, He L, Lu K, Sarmah A, Li J, Bolan NS, Pei J, Huang H (2013) Using biochar for remediation of soils contaminated with heavy metals and organic pollutants. Environ Sci Pollut R 20(12):8472–8483 Zhu N, Yan T, Qiao J, Cao H (2016) Sorption of arsenic, phosphorus and chromium by bismuth impregnated biochar: sorption mechanism and depleted adsorbent utilization. Chemosphere 164:32–40