Adsorption of Nitrophenols from Aqueous Media by N-Vinylpyrrolidone-Based Polymeric Adsorbents

Moscow University Chemistry Bulletin - Tập 74 - Trang 88-92 - 2019
P. T. Sukhanov1, A. A. Kushnir1
1Voronezh State University of Engineering Technologies, Voronezh, Russia

Tóm tắt

The adsorption of nitrophenols by N-vinylpyrrolidone-based polymeric adsorbents is studied under static conditions. The adsorption constants and energy characteristics are calculated. The adsorption mechanism and correlations between partition coefficients and adsorbate hydrophobicity are revealed. The contribution of hydrophobic and specific interactions to the adsorption mechanism is substantiated. The studied polymers are recommended for concentrating and extracting nitrophenols from aqueous solutions.

Tài liệu tham khảo

Feng, X., Zhang, Q., Cong, P., and Zhu, Z., Anal. Methods, 2013, vol. 5, no. 19, p. 5286. Kim, T.S., Kim, J.K., Choi, K., Stenstrom, M.K., and Zoh, K.D., Chemosphere, 2006, vol. 62, p. 926. Janz, D.M., Dinitrophenols, in Encyclopedia of Toxicology, Wexler, P., Ed., Oxford: Academic, 2014, 3rd ed., p. 177. Burstein, F., Borisover, M., Lapides, I., and Yariv, S., J. Therm. Anal. Calorim., 2008, vol. 92, no. 1, p. 35. Fisal, A., Wan Mohd Ashri Wan Daud, Mohd Azmier Ahmad, and Rozinah Radzi, Chem. Eng. J., 2011, vol. 178, p. 461. Bastami, T.R. and Entezari, M.H., Chem. Eng. J., 2012, vol. 210, p. 510. Mukherjee, S., Kumar, S., Misra, A.K., and Fan, M., Chem. Eng. J., 2007, vol. 129, p. 133. Waters Chromatography Columns and Supplies Catalog, 2009–2010, p. 15. Korenman, I.M., Fotometricheskii analiz. Metody opredeleniya organicheskikh soedinenii (Photometric Analysis: Methods for the Determination of Organic Compounds), Moscow: Khimiya, 1975. Churilina, E.V., Kushnir, A.A., Sukhanov, P.T., and Shatalov, G.V., J. Anal. Chem., 2015, vol. 70, no. 2, p. 130. Churilina, E.V., Kushnir, A.A., Sukhanov, P.T., Mastyukova, T.V., Shatalov G.V., and Zarytovskikh, O.A., Russ. J. Gen. Chem., 2013, vol. 83, no. 11, p. 2032. Afonina, T.Yu., Dudarev, V.I., Oznobikhin, L.M., and Syrykh, Yu.S., Russ. J. Phys. Chem. A, 2007, vol. 81, no. 3, p. 360. Sukhanov, P.T., Kushnir, A.A., Bondareva, L.P., Churilina, E.V., Bogdaev, A.A., and Shatalov, G.V., Sorbtsionnye Khromatogr. Protsessy, 2015, vol. 15, no. 2, p. 224. Pomazkina, O.I., Filatova, E.G., and Pozhidaev, Yu.N., Fizikokhim. Poverkhn. Zashch. Mater., 2014, vol. 50, no. 3, p. 262. Schumak, L. and Chow, A., Talanta, 1987, vol. 34, no. 11, p. 957. Mohan, D., Sarswat, A., Singh, V.K., Alexandrefranco, M., and Pittman, C.U., Jr., Chem. Eng. J., 2011, vol. 172, no. 2–3, p. 1111. Fang, M., Lei, F., Zhou, J., Wu, Y., and Gong, Z., Chin. Chem. Lett., 2014, vol. 25, no. 11, p. 1492. An, F.Q., Gao, B.J., and Feng, X.Q., J. Appl. Polym. Sci., 2012, vol. 125, no. 4, p. 2549. Mehdinia, A., Baradaran Kayyal, T., Jabbari, A., Ovais Aziz-Zanjani, M., and Ziaei, E., J. Chromatogr. A, 2013, vol. 1283, p. 82. Mehdinia, A., Dadkhah, S., Baradaran Kayyal, T., and Jabbari, A., J. Chromatogr. A, 2014, vol. 1364, p. 12. Koubaissy, B., Joly, G., and Magnoux, P., Ind. Eng. Chem. Res., 2008, vol. 47, p. 9558. Ioannou, Z. and Simitzis, J., J. Hazard. Mater., 2009, vol. 171, no. 1–3, p. 954.