Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants

Chemical Engineering Journal - Tập 334 - Trang 1502-1517 - 2018
Jianlong Wang1,2,3
1Beijing Key Laboratory of Radioactive Wastes Treatment, Tsinghua University, Beijing 100084, PR China
2Collaborative Innovation Center for Advanced Nuclear Energy Technology, INET, Tsinghua University, Beijing 100084, PR China
3State Key Joint Laboratory of Environment Simulation and Pollution Control, Tsinghua University, Beijing 100084, PR China

Tóm tắt

Từ khóa


Tài liệu tham khảo

Wang, 2016, Removal of pharmaceuticals and personal care products (PPCPs) from wastewater: a review, J. Environ. Manage., 182, 620, 10.1016/j.jenvman.2016.07.049

Wang, 2017, Fe-based catalysts for heterogeneous catalytic ozonation of emerging contaminants in water and wastewater, Chem. Eng. J., 312, 79, 10.1016/j.cej.2016.11.118

Kahler, 2016, Acceleration of groundwater remediation by deep sweeps and vortex ejections induced by rapidly pulsed pumping, Water Resour. Res., 52, 3930, 10.1002/2015WR017157

Majone, 2015, In situ groundwater and sediment bioremediation: barriers and perspectives at European contaminated sites, New Biotechnol., 32, 133, 10.1016/j.nbt.2014.02.011

Li, 2014, Occurrence, sources, and fate of pharmaceuticals in aquatic environment and soil, Environ. Pollut., 187, 193, 10.1016/j.envpol.2014.01.015

Wang, 2016, Enhanced biodegradation of triclosan by means of gamma irradiation, Chemosphere, 167, 406, 10.1016/j.chemosphere.2016.10.028

Wang, 2012, Advanced oxidation processes for wastewater treatment: formation of hydroxyl radical and application, Crit. Rev. Environ. Sci. Technol., 42, 251, 10.1080/10643389.2010.507698

Wang, 2016, Irradiation treatment of pharmaceutical and personal care products (PPCPs) in water and wastewater: an overview, Radiat. Phys. Chem., 125, 56, 10.1016/j.radphyschem.2016.03.012

Wang, 2017, Carbamazepine degradation by gamma irradiation coupled to biological treatment, J. Hazard. Mater., 321, 639, 10.1016/j.jhazmat.2016.09.053

Lutze, 2015, Degradation of chlorotriazine pesticides by sulfate radicals and the influence of organic matter, Environ. Sci. Technol., 49, 1673, 10.1021/es503496u

Ghauch, 2012, Oxidation of bisoprolol in heated PS/H2O systems: kinetics and products, Chem. Eng. J., 183, 162, 10.1016/j.cej.2011.12.048

Ahmed, 2012, Sulfate radical anion oxidation of diclofenac and sulfamethoxazole for water decontamination, Chem. Eng. J., 197, 440, 10.1016/j.cej.2012.05.040

Liang, 2003, Thermally activated PS oxidation of trichloroethylene (TCE) and 1,1,1-trichloroethane (TCA) in aqueous systems and soil slurries, Soil Sediment Contam. Int. J., 12, 207, 10.1080/713610970

Flanagan, 1984, The active principle of Caro's acid, HSO5–: X-ray crystal structure of KHSO5·H2O, J. Chem. Soc., Chem. Commun., 23, 1574, 10.1039/C39840001574

Kolthoff, 1951, The Chemistry of PS. I. The kinetics and mechanism of the decomposition of the PS ion in aqueous medium1, J. Am. Chem. Soc., 73, 1, 10.1021/ja01151a024

Meunier, 2010, ChemInform abstract: metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage, Cheminform, 24, 1411, 10.1002/chin.199312319

E. Saputra, P.S. Utama, S. Muhammad, H.M. Ang, M.O. Tadé, S. Wang, Catalytic oxidation of toxic organics in aqueous solution for wastewater treatment [D]. Curtin University.

Yang, 2010, Degradation efficiencies of azo dye Acid Orange 7 by the interaction of heat UV and anions with common oxidants: PS, PMS and hydrogen peroxide, J. Hazard. Mater., 179, 552, 10.1016/j.jhazmat.2010.03.039

Devi, 2016, In-situ chemical oxidation: Principle and applications of peroxide and PS treatments in wastewater systems, Sci. Total Environ., 571, 643, 10.1016/j.scitotenv.2016.07.032

Waldemer, 2007, Oxidation of chlorinated ethenes by heat-activated persulfate: kinetics and products, Environ. Sci. Technol., 41, 1010, 10.1021/es062237m

Hori, 2008, Efficient decomposition of perfluorocarboxylic acids and alternative fluorochemical surfactants in hot water, Environ. Sci. Technol., 42, 7438, 10.1021/es800832p

Zrinyi, 2017, Oxidation of benzoic acid by heat-activated PS: effect of temperature on transformation pathway and product distribution, Water Res., 120, 43, 10.1016/j.watres.2017.04.066

Johnson, 2008, PS persistence under thermal activation conditions, Environ. Sci. Technol., 42, 9350, 10.1021/es8019462

Tsitonaki, 2010, In situ chemical oxidation of contaminated soil and groundwater using PS: a review, Crit. Rev. Environ. Sci. Technol., 40, 55, 10.1080/10643380802039303

Zhao, 2013, Effect and mechanism of PS activated by different methods for PAHs removal in soil, J. Hazard. Mater., 254–255, 228, 10.1016/j.jhazmat.2013.03.056

Suslick, 2008, Inside a collapsing bubble: sonoluminescence and the conditions during cavitation, Annu. Rev. Phys. Chem., 59, 659, 10.1146/annurev.physchem.59.032607.093739

Neppolian, 2010, Sonochemical oxidation of arsenic(III) to arsenic(V) using potassium peroxydisulfate as an oxidizing agent, Water Res., 44, 3687, 10.1016/j.watres.2010.04.003

Wei, 2017, Kinetics and mechanism of ultrasonic activation of PS: an in-situ EPR spin trapping study, Environ. Sci. Technol., 51, 3410, 10.1021/acs.est.6b05392

von Sonntag, 2008, Advanced oxidation processes: mechanistic aspects, Water Sci. Technol., 58, 1015, 10.2166/wst.2008.467

Matzek, 2016, Activated PS for organic chemical degradation: a review, Chemosphere, 151, 178, 10.1016/j.chemosphere.2016.02.055

Wang, 2017, Compatibility of surfactants and thermally activated prsulfate for enhanced subsurface remediation, Environ. Sci. Technol., 51, 7055, 10.1021/acs.est.6b05477

Antoniou, 2010, Degradation of microcystin-LR using sulfate radicals generated through photolysis, thermolysis and e-transfer mechanisms, Appl. Catal. B, 96, 290, 10.1016/j.apcatb.2010.02.013

Guo, 2013, Degradation of antibiotics amoxicillin by Co3O4 -catalyzed PMS system, Environ. Prog. Sustainable Energy, 32, 193, 10.1002/ep.10633

Mark, 1998, OH-radical formation by ultrasound in aqueous solution–Part II: terephthalate and Fricke dosimetry and the influence of various conditions on the sonolytic yield, Ultrason. Sonochem., 5, 41, 10.1016/S1350-4177(98)00012-1

Wang, 2011, Ultrasound enhanced catalytic ozonation of tetracycline in a rectangular air-lift reactor, Catal. Today, 175, 283, 10.1016/j.cattod.2011.06.001

Wang, 2014, Degradation of Acid Orange 7 by PS activated with zero valent iron in the presence of ultrasonic irradiation, Sep. Purif. Technol., 122, 41, 10.1016/j.seppur.2013.10.037

Tan, 2012, Heat-activated PS oxidation of diuron in water, Chem. Eng. J., 203, 294, 10.1016/j.cej.2012.07.005

Deng, 2013, Thermally activated PS (TAP) oxidation of antiepileptic drug carbamazepine in water, Chem. Eng. J., 228, 765, 10.1016/j.cej.2013.05.044

Nie, 2014, Degradation of chloramphenicol by thermally activated PS in aqueous solution, Chem. Eng. J., 246, 373, 10.1016/j.cej.2014.02.047

Ji, 2015, Heat-activated PS oxidation of atrazine: Implications for remediation of groundwater contaminated by herbicides, Chem. Eng. J., 263, 45, 10.1016/j.cej.2014.10.097

Fan, 2015, Kinetic and mechanistic investigations of the degradation of sulfamethazine in heat-activated PS oxidation process, J. Hazard. Mater., 300, 39, 10.1016/j.jhazmat.2015.06.058

Yang, 2017, Degradation of azole fungicide fluconazole in aqueous solution by thermally activated PS, Chem. Eng. J., 321, 113, 10.1016/j.cej.2017.03.103

Zhang, 2015, Degradation of p-nitrophenol by heat and metal ions co-activated PS, Chem. Eng. J., 264, 39, 10.1016/j.cej.2014.11.060

Guo, 2016, Kinetics and transformation pathways on oxidation of fluoroquinolones with thermally activated PS, Chem. Eng. J., 292, 82, 10.1016/j.cej.2016.01.009

Xu, 2016, Mineralization of naphtenic acids with thermally-activated PS: The important role of oxygen, J. Hazard. Mater., 318, 355, 10.1016/j.jhazmat.2016.07.009

Peng, 2016, Degradation performance and mechanism of decabromodiphenyl ether (BDE209) by ferrous-activated PS in spiked soil, Chem. Eng. J., 307, 750, 10.1016/j.cej.2016.08.129

Chen, 2015, Oxidative degradation of diclofenac by thermally activated PS: implication for ISCO, Environ. Sci. Pollut. Res., 23, 3824, 10.1007/s11356-015-5630-0

Gao, 2016, Sulfate radicals induced degradation of triclosan in thermally activated PS system, Chem. Eng. J., 306, 522, 10.1016/j.cej.2016.07.080

Ji, 2016, Thermo-activated PS oxidation system for tetracycline antibiotics degradation in aqueous solution, Chem. Eng. J., 298, 225, 10.1016/j.cej.2016.04.028

Liang, 2009, Identification of sulfate and hydroxyl radicals in thermally activated PS, Ind. Eng. Chem. Res., 48, 472, 10.1021/ie9002848

Yang, 2014, Comparison of halide impacts on the efficiency of contaminant degradation by sulfate and hydroxyl radical-based advanced oxidation processes, Environ. Sci. Technol., 48, 2344, 10.1021/es404118q

Qi, 2016, Activation of PMS by base: Implications for the degradation of organic pollutants, Chemosphere, 151, 280, 10.1016/j.chemosphere.2016.02.089

Zhou, 2015, Activation of PMS by benzoquinone: a novel nonradical oxidation process, Environ. Sci. Technol., 49, 12941, 10.1021/acs.est.5b03595

Peng, 2017, Different kinds of PS activation with base for the oxidation and mechanism of BDE209 in a spiked soil system, Sci. Total Environ., 574, 307, 10.1016/j.scitotenv.2016.09.057

Lou, 2017, Significantly enhanced base activation of PMS by polyphosphates: Kinetics and mechanism, Chemosphere, 173, 529, 10.1016/j.chemosphere.2017.01.093

Ghanbari, 2017, Application of PMS and its activation methods for degradation of environmental organic pollutants: review, Chem. Eng. J., 310, 41, 10.1016/j.cej.2016.10.064

Herrmann, 2007, On the photolysis of simple anions and neutral molecules as sources of O-/OH SOx- and Cl in aqueous solution, Phys. Chem. Chem. Phys., 9, 3935, 10.1039/B618565G

Lee, 2005, UV photolytic mechanism of n-nitrosodimethylamine in water: roles of dissolved oxygen and solution pH, Environ. Sci. Technol., 39, 9702, 10.1021/es051235j

Xia, 2011, Photoactivatable phospholipids bearing tetrafluorophenylazido chromophores exhibit unprecedented protonation-state-dependent 19F NMR signals, Org. Lett., 13, 4248, 10.1021/ol201593k

Wang, 2017, Degradation of chlorinated paraben by integrated irradiation and biological treatment process, J. Environ. Manage., 189, 29, 10.1016/j.jenvman.2016.11.067

Gao, 2012, Ultraviolet (UV) light-activated PS oxidation of sulfamethazine in water, Chem. Eng. J., 195–196, 248, 10.1016/j.cej.2012.04.084

Tan, 2013, Degradation of antipyrine by UV, UV/H₂O₂ and UV/PS, J. Hazard. Mater., 260, 1008, 10.1016/j.jhazmat.2013.06.060

Liu, 2013, Degradation of atenolol by UV/PMS: kinetics, effect of operational parameters and mechanism, Chemosphere, 93, 2717, 10.1016/j.chemosphere.2013.08.090

Wang, 2014, Oxidative degradation of TMAH solution with UV PS activation, Chem. Eng. J., 254, 472, 10.1016/j.cej.2014.05.116

Qian, 2016, Perfluorooctanoic acid degradation using UV-PS process: modeling of the degradation and chlorate formation, Environ. Sci. Technol., 50, 772, 10.1021/acs.est.5b03715

Xie, 2015, Removal of 2-MIB and geosmin using UV/PS: contributions of hydroxyl and sulfate radicals, Water Res., 69, 223, 10.1016/j.watres.2014.11.029

Mahdiahmed, 2014, Ciprofloxacin oxidation by UV-C activated PMS in wastewater, J. Hazard. Mater., 265, 41, 10.1016/j.jhazmat.2013.11.034

Dhaka, 2017, Aqueous phase degradation of methyl paraben using UV-activated PS method, Chem. Eng. J., 321, 11, 10.1016/j.cej.2017.03.085

Xiao, 2016, Comparative evaluation of iodoacids removal by UV/PS and UV/H2O2 processes, Water Res., 102, 629, 10.1016/j.watres.2016.07.004

Ghauch, 2017, Contribution of PS in UV-254 nm activated systems for complete degradation of chloramphenicol antibiotic in water, Chem. Eng. J., 317, 1012, 10.1016/j.cej.2017.02.133

Wang, 2016, Degradation kinetics and mechanism of 2,4-Di-tert-butylphenol with UV/PS, Chem. Eng. J., 304, 201, 10.1016/j.cej.2016.06.092

Hou, 2017, Degradation kinetics and pathways of haloacetonitriles by the UV/PS process, Chem. Eng. J., 320, 478, 10.1016/j.cej.2017.03.042

Bu, 2016, Degradation of oxcarbazepine by UV-activated PS oxidation: kinetics, mechanisms, and pathways, Environ. Sci. Pollut. Res., 23, 2848, 10.1007/s11356-015-5524-1

Liu, 2016, Kinetics and mechanism investigation on the destruction of oxytetracycline by UV-254 nm activation of PS, J. Hazard. Mater., 305, 229, 10.1016/j.jhazmat.2015.11.043

Ao, 2017, Degradation of sulfamethoxazole by medium pressure UV and oxidants: PMS PS, and hydrogen peroxide, Chem. Eng. J., 313, 629, 10.1016/j.cej.2016.12.089

Yang, 2017, Degradation of sulfamethoxazole by UV, UV/H2O2 and UV/PS (PDS): formation of oxidation products and effect of bicarbonate, Water Res., 118, 196, 10.1016/j.watres.2017.03.054

Khan, 2016, Efficient degradation of lindane in aqueous solution by iron (II) and/or UV activated PMS, J. Photochem. Photobiol., A, 316, 37, 10.1016/j.jphotochem.2015.10.004

Khan, 2017, Kinetics and mechanism of sulfate radical- and hydroxyl radical-induced degradation of highly chlorinated pesticide lindane in UV/PMS system, Chem. Eng. J., 318, 135, 10.1016/j.cej.2016.05.150

Zhang, 2016, Kinetic and mechanistic investigation of azathioprine degradation in water by UV, UV/H2O2 and UV/PS, Chem. Eng. J., 302, 526, 10.1016/j.cej.2016.05.085

Fang, 2017, Monochlorophenols degradation by UV/PS is immune to the presence of chloride: illusion or reality?, Chem. Eng. J., 323, 124, 10.1016/j.cej.2017.04.094

Huang, 2017, Oxidative degradation of tetramethylammonium hydroxide (TMAH) by UV/PS and associated acute toxicity assessment, J. Environ. Sci. Health Part A Toxic/Hazard. Subst. Environ. Eng., 1

Cui, 2016, Removal of trace level amounts of twelve sulfonamides from drinking water by UV-activated PMS, Sci. Total Environ., 572, 244, 10.1016/j.scitotenv.2016.07.183

Xu, 2017, The UV/PMS process for the mineralization of artificial sweetener sucralose, Chem. Eng. J., 317, 561, 10.1016/j.cej.2017.02.058

Zhang, 2016, Degradation of trimethoprim by gamma irradiation in the presence of PS, Radiat. Phys. Chem., 127, 85, 10.1016/j.radphyschem.2016.06.019

Shah, 2016, Synergistic effects of HSO5− in the gamma radiation driven process for the removal of chlorendic acid: a new alternative for water treatment, Chem. Eng. J., 306, 512, 10.1016/j.cej.2016.07.031

Li, 2013, Removal of 1,1,1-trichloroethane from aqueous solution by a sono-activated PS process, Ultrason. Sonochem., 20, 855, 10.1016/j.ultsonch.2012.11.014

Chakma, 2017, Mechanistic investigations in sono-hybrid (ultrasound/Fe2+/UVC) techniques of PS activation for degradation of Azorubine, Ultrason. Sonochem., 38, 652, 10.1016/j.ultsonch.2016.08.015

Ferkous, 2017, PS-enhanced sonochemical degradation of naphthol blue black in water: evidence of sulfate radical formation, Ultrason. Sonochem., 34, 580, 10.1016/j.ultsonch.2016.06.027

Wang, 2016, Removal of carbamazepine from aqueous solution using sono-activated PS process, Ultrason. Sonochem., 29, 156, 10.1016/j.ultsonch.2015.09.008

Li, 2016, Simultaneous degradation of 1,1,1-trichloroethane and solvent stabilizer 1,4-dioxane by a sono-activated PS process, Chem. Eng. J., 284, 750, 10.1016/j.cej.2015.08.153

Liu, 2017, Ultrasound irritation enhanced heterogeneous activation of PMS with Fe3O4 for degradation of azo dye, Ultrason. Sonochem., 34, 953, 10.1016/j.ultsonch.2016.08.005

Yen, 2011, Application of PS to remediate petroleum hydrocarbon-contaminated soil: feasibility and comparison with common oxidants, J. Hazard. Mater., 186, 2097, 10.1016/j.jhazmat.2010.12.129

Hu, 2016, Cobalt-catalyzed sulfate radical-based advanced oxidation: a review on heterogeneous catalysts and applications, Appl. Catal. B, 181, 103, 10.1016/j.apcatb.2015.07.024

Anipsitakis, 2004, Radical generation by the interaction of transition metals with common oxidants, Environ. Sci. Technol., 38, 3705, 10.1021/es035121o

Rastogi, 2009, Sulfate radical-based ferrous–PMS oxidative system for PCBs degradation in aqueous and ediment systems, Appl. Catal. B, 85, 171, 10.1016/j.apcatb.2008.07.010

Rodriguez, 2014, Oxidation of Orange G by PS activated by Fe(II), Fe(III) and zero valent iron, Chemosphere, 101, 86, 10.1016/j.chemosphere.2013.12.037

Zou, 2013, Rapid acceleration of ferrous iron/PMS oxidation of organic pollutants by promoting Fe(III)/Fe(II) cycle with hydroxylamine, Environ. Sci. Technol., 47, 11685, 10.1021/es4019145

Usman, 2012, Application of magnetite-activated PS oxidation for the degradation of PAHs in contaminated soils, Chemosphere, 87, 234, 10.1016/j.chemosphere.2012.01.001

Teel, 2011, PS activation by naturally occurring trace minerals, J. Hazard. Mater., 196, 153, 10.1016/j.jhazmat.2011.09.011

Anipsitakis, 2003, Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of PMS with cobalt[J], Environ. Sci. Technol., 37, 4790, 10.1021/es0263792

Ding, 2016, Efficient degradation of carbamazepine by easily recyclable microscaled CuFeO2 mediated heterogeneous activation of PMS, J. Hazard. Mater., 317, 686, 10.1016/j.jhazmat.2016.06.004

Liang, 2009, pH dependence of PS activation by EDTA/Fe(III) for degradation of trichloroethylene, J. Contam. Hydrol., 106, 173, 10.1016/j.jconhyd.2009.02.008

Raja, 2007, Highly dispersed PTFE/Co3O4 flexible films as photocatalyst showing fast kinetic performance for the discoloration of azo-dyes under solar irradiation, J. Photochem. Photobiol., A, 187, 332, 10.1016/j.jphotochem.2006.10.033

Wang, 2010, Cobalt exchanged zeolites for heterogeneous catalytic oxidation of phenol in the presence of peroxymonosulphate, Appl. Catal. B, 99, 163, 10.1016/j.apcatb.2010.06.013

Yan, 2011, Degradation of sulfamonomethoxine with Fe3O4 magnetic nanoparticles as heterogeneous activator of PS, J. Hazard. Mater., 186, 1398, 10.1016/j.jhazmat.2010.12.017

Shukla, 2010, Activated carbon supported cobalt catalysts for advanced oxidation of organic contaminants in aqueous solution, Appl. Catal. B, 100, 529, 10.1016/j.apcatb.2010.09.006

Hu, 2011, An easily recyclable Co/SBA-15 catalyst: heterogeneous activation of PMS for the degradation of phenol in water, Appl. Catal. B, 102, 19, 10.1016/j.apcatb.2010.11.019

Wang, 2014, Facile synthesis of hierarchically structured magnetic MnO2/ZnFe2O4 hybrid materials and their performance in heterogeneous activation of PMS, Acs Appl. Mater. Interfaces, 6, 19914, 10.1021/am505309b

Zeng, 2015, Spatial confinement of a Co3O4 catalyst in hollow metal-organic frameworks as a nanoreactor for improved degradation of organic pollutants, Environ. Sci. Technol., 49, 2350, 10.1021/es505014z

Liu, 2015, Activation of PMS with magnetic Fe3O4–MnO2 core–shell nanocomposites for 4-chlorophenol degradation, Chem. Eng. J., 262, 854, 10.1016/j.cej.2014.10.043

Su, 2013, Heterogeneous activation of Oxone by CoxFe3−xO4 nanocatalysts for degradation of rhodamine B, J. Hazard. Mater., 244–245, 736, 10.1016/j.jhazmat.2012.11.005

Chi, 2015, Activation of PMS by BiFeO3 microspheres under visible light irradiation for decomposition of organic pollutants, Rsc Adv., 5, 67412, 10.1039/C5RA07536J

Yao, 2015, Sulfate radicals induced from PMS by cobalt manganese oxides (Co(x)Mn(3-x)O4) for Fenton-Like reaction in water, J. Hazard. Mater., 296, 128, 10.1016/j.jhazmat.2015.04.014

Lei, 2015, Heterogeneous degradation of organic pollutants by PS activated by CuO-Fe3O4: mechanism, stability, effects of pH and bicarbonate ions, Environ. Sci. Technol., 49, 6838, 10.1021/acs.est.5b00623

Li, 2015, Heterogeneous Fenton oxidation of 2,4-dichlorophenol using iron-based nanoparticles and PS system, Chem. Eng. J., 264, 587, 10.1016/j.cej.2014.11.128

Leng, 2014, Degradation of Rhodamine B by PS activated with Fe3O4: effect of polyhydroquinone serving as an electron shuttle, Chem. Eng. J., 240, 338, 10.1016/j.cej.2013.11.090

Liang, 2013, Oxidative degradation of p -chloroaniline by copper oxidate activated PS, Chem. Eng. J., 218, 384, 10.1016/j.cej.2012.11.093

Zhang, 2015, Activation of PS by Co3O4 nanoparticles for orange G degradation, Rsc Adv., 6, 758, 10.1039/C5RA22457H

Li, 2016, FexCo3− xO4 nanocages derived from nanoscale metal–organic frameworks for removal of bisphenol A by activation of PMS, Appl. Catal. B, 181, 788, 10.1016/j.apcatb.2015.08.050

Pu, 2017, Activation performance and mechanism of a novel heterogeneous PS catalyst: Metal Organic Framework MIL-53(Fe) with FeII/FeIII mixed-valence coordinative unsaturated iron center, Catal. Sci. Technol., 7, 1129, 10.1039/C6CY02355J

Zhang, 2016, Catalytic degradation of diethyl phthalate in aqueous solution by PS activated with nano-scaled magnetic CuFe2O4/MWCNTs, Chem. Eng. J., 301, 1, 10.1016/j.cej.2016.04.096

Yue, 2016, Core-shell Fe3O4@MIL-101(Fe) composites as heterogeneous catalysts of PS activation for the removal of Acid Orange 7, Environ. Sci. Pollut. Res., 23, 15218, 10.1007/s11356-016-6702-5

Feng, 2017, L. C, L. H, L. C, S. K, Cu2O-promoted degradation of sulfamethoxazole by α-Fe2O3-catalyzed PMS under circumneutral conditions: synergistic effect, Cu/Fe ratios, and mechanisms, Environ. Technol.

Taha, 2016, Degradation of boscalid by nitrogen-doped/undoped TiO2 and PS ions using different activation conditions and the identification of its main degradation products using LC/MS/MS, Chem. Eng. J., 288, 845, 10.1016/j.cej.2015.12.053

Pan, 2017, Degradation of UV-filter benzophenone-3 in aqueous solution using PS catalyzed by cobalt ferrite, Chem. Eng. J., 326, 1197, 10.1016/j.cej.2017.06.068

Deng, 2016, Heterogeneous degradation of Orange II with PMS activated by ordered mesoporous MnFe2O4, Sep. Purif. Technol., 167, 181, 10.1016/j.seppur.2016.04.035

Jaafarzadeh, 2017, Efficient degradation of 2,4-dichlorophenoxyacetic acid by PMS/magnetic copper ferrite nanoparticles/ozone: a novel combination of advanced oxidation processes, Chem. Eng. J., 320, 436, 10.1016/j.cej.2017.03.036

Tan, 2017, Efficient degradation of paracetamol with nanoscaled magnetic CoFe2O4 and MnFe2O4 as a heterogeneous catalyst of PMS, Sep. Purif. Technol., 175, 47, 10.1016/j.seppur.2016.11.016

Lin, 2017, Electrospun magnetic cobalt-embedded carbon nanofiber as a heterogeneous catalyst for activation of oxone for degradation of amaranth dye, J. Colloid Interface Sci., 505, 728, 10.1016/j.jcis.2017.06.057

Yi, 2016, Epigallocatechin-3-gallate-coated Fe3O4 as a novel heterogeneous catalyst of PMS for diuron degradation: performance and mechanism, Chem. Eng. J., 302, 417, 10.1016/j.cej.2016.05.025

Du, 2016, Facile preparation of S/Fe composites as an effective peroxydisulfate activator for RhB degradation, Sep. Purif. Technol., 163, 145, 10.1016/j.seppur.2016.02.051

Zeng, 2017, Fe/Fe3C@N-doped porous carbon hybrids derived from nano-scale MOFs: robust and enhanced heterogeneous catalyst for PMS activation, Catal. Sci. Technol., 7, 396, 10.1039/C6CY02130A

Wang, 2017, Fe-Ag/GAC catalytic PS to degrade Acid Red 73, Sep. Purif. Technol., 184, 365, 10.1016/j.seppur.2017.05.005

Li, 2016, Fe-based MOFs for efficient adsorption and degradation of acid orange 7 in aqueous solution via PS activation, Appl. Surf. Sci., 369, 130, 10.1016/j.apsusc.2016.02.037

Kakavandi, 2016, Heterogeneous Fenton-like catalytic oxidation of tetracycline by AC@Fe3O4 as a heterogeneous PS activator: adsorption and degradation studies, J. Ind. Eng. Chem., 323

Gong, 2017, Heterogeneous activation of PMS by Fe-Co layered doubled hydroxide for efficient catalytic degradation of Rhoadmine B, Chem. Eng. J., 321, 222, 10.1016/j.cej.2017.03.117

Deng, 2017, Heterogeneous Activation of PMS using ordered mesoporous Co3O4 for the degradation of chloramphenicol at neutral pH, Chem. Eng. J., 308, 505, 10.1016/j.cej.2016.09.075

Li, 2017, Heterogeneous catalytic oxidation for the degradation of p -nitrophenol in aqueous solution by PS activated with CuFe2O4 magnetic nano-particles, Chem. Eng. J., 324, 63, 10.1016/j.cej.2017.04.104

Liu, 2016, Heterogeneous degradation of tetracycline by magnetic Ag/AgCl/modified zeolite X-PS system under visible light, Rsc Adv., 6, 35216, 10.1039/C6RA00695G

Yan, 2017, Heterogeneously catalyzed PS with a CuMgFe layered double hydroxide for the degradation of ethylbenzene, J. Hazard. Mater., 338, 372, 10.1016/j.jhazmat.2017.05.007

Gao, 2016, Insights into the mechanism of heterogeneous activation of PS with a clay/iron-based catalyst under visible LED light irradiation, Appl. Catal. B, 185, 22, 10.1016/j.apcatb.2015.12.002

Lin, 2017, LaMO 3 perovskites (M=Co, Cu, Fe and Ni) as heterogeneous catalysts for activating PMS in water, Chem. Eng. Sci., 160, 96, 10.1016/j.ces.2016.11.017

Lin, 2017, LiCoPO 4 (LCP) as an effective PMS activator for degradation of diethyl phthalate in aqueous solution without controlling pH: Efficiency, stability and mechanism, Chem. Eng. J., 315, 304, 10.1016/j.cej.2017.01.036

Du, 2016, Magnetic CoFe2O4 nanoparticles supported on titanate nanotubes (CoFe2O4/TNTs) as a novel heterogeneous catalyst for PMS activation and degradation of organic pollutants, J. Hazard. Mater., 308, 58, 10.1016/j.jhazmat.2016.01.035

Ding, 2017, Mechanism insight of degradation of norfloxacin by magnetite nanoparticles activated PS: Identification of radicals and degradation pathway, Chem. Eng. J., 308, 330, 10.1016/j.cej.2016.09.077

Sun, 2016, One-pot hydrothermal synthesis of octahedral CoFe/CoFe2O4 submicron composite as heterogeneous catalysts with enhanced PMS activity, J. Mater. Chem. A, 4, 9455, 10.1039/C6TA02126C

Li, 2016, PMS activated by amorphous particulate MnO2 for ineralization of benzene gas: redox reaction, weighting analysis, and numerical modelling, Chem. Eng. J., 301, 315, 10.1016/j.cej.2016.04.147

Feng, 2016, Sulfate radical-mediated degradation of sulfadiazine by CuFeO2 Rhombohedral crystal-catalyzed PMS: synergistic effects and mechanisms, Environ. Sci. Technol., 50, 3119, 10.1021/acs.est.5b05974

Khan, 2017, Synergistic degradation of phenols using PMS activated by CuO-Co3O4@MnO2 nanocatalyst, J. Hazard. Mater., 329, 262, 10.1016/j.jhazmat.2017.01.029

Li, 2016, Synthesis of novel core–shell Fe 0 @Fe3O4 as heterogeneous activator of PS for oxidation of dibutyl phthalate under neutral conditions, Chem. Eng. J., 301, 315, 10.1016/j.cej.2016.04.147

Yin, 2016, The mechanism of degradation of bisphenol A using the magnetically separable CuFe2O4/PMS heterogeneous oxidation process, J. Hazard. Mater., 309, 87, 10.1016/j.jhazmat.2016.01.023

Wei, 2017, Ultrasound enhanced heterogeneous activation of PMS by a Co-NiOx catalyst, Water Sci. Technol., 329, 262

Karthikeyan, 2015, In situ generation of hydroxyl radical by cobalt oxide supported porous carbon enhance removal of refractory organics in tannery dyeing wastewater, J. Colloid Interface Sci., 448, 163, 10.1016/j.jcis.2015.01.066

Fang, 2015, Manipulation of persistent free radicals in biochar to activate PS for contaminant degradation, Environ. Sci. Technol., 49, 5645, 10.1021/es5061512

Duan, 2015, Insights into heterogeneous catalysis of PS activation on dimensional-structured nanocarbons, Acs Catal., 5, 4629, 10.1021/acscatal.5b00774

Jans, 1998, Activated carbon and carbon black catalyzed transformation of aqueous ozone into OH-Radicals, Ozone Sci. Eng., 20, 67, 10.1080/01919519808547291

Yu, 2008, Adsorption characteristics of selected pharmaceuticals and an endocrine disrupting compound-Naproxen, carbamazepine and nonylphenol-on activated carbon, Water Res., 42, 2873, 10.1016/j.watres.2008.02.020

Sun, 2014, Catalytic oxidation of organic pollutants on pristine and surface nitrogen-modified carbon nanotubes with sulfate radicals, Appl. Catal. B Environ., 154–155, 134, 10.1016/j.apcatb.2014.02.012

Lee, 2015, Activation of PSs by carbon nanotubes: oxidation of organic compounds by nonradical mechanism, Chem. Eng. J., 266, 28, 10.1016/j.cej.2014.12.065

Chen, 2016, Activated carbon fiber for heterogeneous activation of PS: implication for the decolorization of azo dye, Environ. Sci. Pollut. Res. Int., 1

Chen, 2016, Decolorization of azo dye by PMS activated by carbon nanotube: radical versus non-radical mechanism, J. Hazard. Mater., 320, 571, 10.1016/j.jhazmat.2016.07.038

Lee, 2016, Activation of PSs by graphitized nanodiamonds for removal of organic compounds, Environ. Sci. Technol., 50, 10134, 10.1021/acs.est.6b02079

Kang, 2016, Carbocatalytic activation of PS for removal of antibiotics in water solutions, Chem. Eng. J., 288, 399, 10.1016/j.cej.2015.12.040

Ouyang, 2017, Degradation of 1,4-Dioxane by biochar supported nano magnetite particles activating PS, Chemosphere, 10.1016/j.chemosphere.2017.05.156

Ma, 2016, Enhanced degradation of 2,4–dinitrotoluene in groundwater by PS activated using iron–carbon micro–electrolysis, Chem. Eng. J., 311, 183, 10.1016/j.cej.2016.11.083

Li, 2015, Granular activated carbon supported iron as heterogeneous PS catalyst for the pretreatment of mature landfill leachate, Rsc Adv., 6, 987, 10.1039/C5RA21781D

Guo, 2017, In-situ sulfur-doped carbon as a metal-free catalyst for PS activated oxidation of aqueous organics, Catal. Today

Duan, 2017, Metal-free activation of PS by cubic mesoporous carbons for catalytic oxidation via radical and nonradical processes, Catal. Today

Chen, 2016, Metal-free catalysis of PS activation and organic-pollutant degradation by nitrogen-doped graphene and aminated graphene, Environ. Pollut., 215, 96, 10.1016/j.envpol.2016.04.088

Liu, 2017, Nitrogen-doped carbon material as a catalyst for the degradation of direct red23 based on PS oxidation, Sep. Purif. Technol., 184, 213, 10.1016/j.seppur.2017.04.045

Xin, 2017, Non-photochemical production of singlet oxygen via activation of PS by carbon nanotubes, Water Res., 113, 80, 10.1016/j.watres.2017.02.016

Yang, 2016, Promoting effect of ammonia modification on activated carbon catalyzed PMS oxidation, Sep. Purif. Technol., 160, 81, 10.1016/j.seppur.2016.01.020

Duan, 2016, Surface controlled generation of reactive radicals from PS by carbocatalysis on nanodiamonds, Appl. Catal. B, 194, 7, 10.1016/j.apcatb.2016.04.043

Yang, 2008, Heterogeneous activation of PMS by supported cobalt catalysts for the degradation of 2,4-dichlorophenol in water: the effect of support, cobalt precursor, and UV radiation, Appl. Catal. B, 77, 300, 10.1016/j.apcatb.2007.07.020

Rao, 2016, Degradation of ibuprofen by a synergistic UV/Fe(III)/Oxone process, Chem. Eng. J., 283, 65, 10.1016/j.cej.2015.07.057

Siegel, 2004, NAD(P)H:quinone oxidoreductase 1: role as a superoxide scavenger, Mol. Pharmacol., 65, 1238, 10.1124/mol.65.5.1238

Fang, 2013, Activation of PS by quinones: free radical reactions and implication for the degradation of PCBs, Environ. Sci. Technol., 47, 4605, 10.1021/es400262n

Bandala, 2008, Decontamination of soil washing wastewater using solar driven advanced oxidation processes, J. Hazard. Mater., 160, 402, 10.1016/j.jhazmat.2008.03.011

Do, 2009, Application of a PMS/cobalt (PMS/Co(II)) system to treat diesel-contaminated soil, Chemosphere, 77, 1127, 10.1016/j.chemosphere.2009.08.061

Fan, 2016, Electrokinetic delivery of PS to remediate PCBs polluted soils: effect of different activation methods, Chemosphere, 144, 138, 10.1016/j.chemosphere.2015.08.074

Monteagudo, 2016, Application of activated PS for removal of intermediates from antipyrine wastewater degradation refractory towards hydroxyl radical, J. Hazard. Mater., 306, 77, 10.1016/j.jhazmat.2015.12.001

Kattel, 2016, Ferrous ion-activated persulphate process for landfill leachate treatment: removal of organic load, phenolic micropollutants and nitrogen, Environ. Technol.

Huang, 2009, Efficient decolorization of azo dye Reactive Black B involving aromatic fragment degradation in buffered Co2+/PMS oxidative processes with a ppb level dosage of Co2+-catalyst, J. Hazard. Mater., 170, 1110, 10.1016/j.jhazmat.2009.05.091

Sun, 2012, Highly efficient degradation of ofloxacin by UV/Oxone/Co2+ oxidation process, Environ. Sci. Pollut. Res. Int., 19, 1536, 10.1007/s11356-011-0654-6

Chan, 2009, Degradation of atrazine by cobalt-mediated activation of PMS: different cobalt counteranions in homogenous process and cobalt oxide catalysts in photolytic heterogeneous process, Water Res., 43, 2513, 10.1016/j.watres.2009.02.029

Ren, 2015, Sulfate radicals induced from PMS by magnetic ferrospinel MFe2O4 (M = Co, Cu, Mn, and Zn) as heterogeneous catalysts in the water, Appl. Catal. B, 165, 572, 10.1016/j.apcatb.2014.10.051

Zhu, 2013, Cobalt implanted TiO2 nanocatalyst for heterogeneous activation of PMS, Rsc Adv., 3, 520, 10.1039/C2RA22039C

Qi, 2014, Degradation of sulfamethoxazole by microwave-activated PS: kinetics, mechanism and acute toxicity, Chem. Eng. J., 249, 6, 10.1016/j.cej.2014.03.086

Bennedsen, 2012, Influence of chloride and carbonates on the reactivity of activated PS, Chemosphere, 86, 1092, 10.1016/j.chemosphere.2011.12.011

Yuan, 2011, Effects of chloride ion on degradation of Acid Orange 7 by sulfate radical-based advanced oxidation process: implications for formation of chlorinated aromatic compounds, J. Hazard. Mater., 196, 173, 10.1016/j.jhazmat.2011.09.007

Wang, 2011, Effects of chloride ions on bleaching of azo dyes by Co2+/oxone reagent: kinetic analysis, J. Hazard. Mater., 190, 1083, 10.1016/j.jhazmat.2011.04.016

Ji, 2017, The role of nitrite in sulfate radical-based degradation of phenolic compounds: An unexpected nitration process relevant to groundwater remediation by in-situ chemical oxidation, Water Res., 123, 249, 10.1016/j.watres.2017.06.081

Qi, 2014, Modeling the heterogeneous PMS/Co-MCM41 process for the degradation of caffeine and the study of influence of cobalt sources, Chem. Eng. J., 235, 10, 10.1016/j.cej.2013.08.113

Rezaei, 2016, Impact of natural organic matter on the degradation of 2,4-dichlorophenoxy acetic acid in a fluidized bed photocatalytic reactor, Chem. Eng. J., 310, 457, 10.1016/j.cej.2016.05.086

Yang, 2015, Production of sulfate radical and hydroxyl radical by reaction of ozone with PMS: a novel advanced oxidation process, Environ. Sci. Technol., 49, 7330, 10.1021/es506362e

Buxton, 1998, Reactivity of chlorine atoms in aqueous solution Part 1. The equilibrium ClMNsbd+Cl-Cl2, J. Chem. Soc., Faraday Trans., 94, 653, 10.1039/a707377a

Buxton, 2000, The reactivity of chlorine atoms in aqueous solution. Part III. The reactions of Cl with solutes, Phys. Chem. Chem. Phys., 2, 237, 10.1039/a907133d

Lutze, 2015, Sulfate radical-based water treatment in presence of chloride: formation of chlorate, inter-conversion of sulfate radicals into hydroxyl radicals and influence of bicarbonate, Water Res., 72, 349, 10.1016/j.watres.2014.10.006

W.J. McElroy, A laser photolysis study of the reaction of SO4rad− with Cl- and subsequent decay of Cl2- in aqueous solution, Journal of Physical Chemistry, 94 (1990) 2435-2441.

G.V. Buxton, M. Bydder, G.A. Salmon, The reactivity of chlorine atoms in aqueous solution Part II. The equilibrium SO4−+Cl−ClNsbd+SO42−, Phys. Chem. Chem. Phys. 1 (1999) 269-273.

Fang, 2016, Enhanced AOX accumulation and aquatic toxicity during 2,4,6-trichlorophenol degradation in a Co(II)/PMS/Cl(-) system, Chemosphere, 144, 2415, 10.1016/j.chemosphere.2015.11.030

Ayoub, 2014, Assessment of bimetallic and trimetallic iron-based systems for PS activation: application to sulfamethoxazole degradation, Chem. Eng. J., 256, 280, 10.1016/j.cej.2014.07.002

Neta, 1977, ChemInform Abstract: rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds, Chemischer Informationsdienst, 8, 163, 10.1002/chin.197714152

Osali, 2015, UV/PS and UV/hydrogen peroxide processes for the treatment of salicylic acid: effect of operating parameters, kinetic, and energy consumption, Desalin. Water Treat., 56, 3087

Ge, 2016, Degradation of methyl orange by ozone in the presence of ferrous and PS ions in a rotating packed bed, Chemosphere, 146, 413, 10.1016/j.chemosphere.2015.12.058

Amr, 2014, Effect of ozone and ozone/PS processes on biodegradable and soluble characteristics of semiaerobic stabilized leachate, Environ. Prog. Sustainable Energy, 33, 184, 10.1002/ep.11779

Sánchez-Polo, 2006, Combination of ozone with activated carbon as an alternative to conventional advanced oxidation processes, Ozone Sci. Eng., 28, 237, 10.1080/01919510600714170