Acidic catalysts for the dehydration of glycerol: Activity and deactivation

Behr, 2008, Green Chem., 10, 13, 10.1039/B710561D T. Haas, D. Arntz, H. Klenk, W. Girke, Production of acrolein from glycerol, Pat. EP. 19,930,116,792 (1994). J.-L. Dubois, C. Duquenne, W. Hölderich, J. Kervenal, Process for dehydration glycerol to acrolein, Pat. WO 2006/087084 A2 (2006). Tsukuda, 2007, Catal. Commun., 8, 1349, 10.1016/j.catcom.2006.12.006 Chai, 2007, Green Chem., 9, 1130, 10.1039/b702200j Atia, 2008, J. Catal., 258, 71, 10.1016/j.jcat.2008.05.027 Antal, 1985, J. Analyt. Appl. Pyrol., 8, 291, 10.1016/0165-2370(85)80032-2 Cahi, 2007, J. Catal., 250, 342, 10.1016/j.jcat.2007.06.016 H. Redlingshöfer, C. Weckbecker, K. Huthmacher, A. Dörflein, Method for regenerating a catalyst for dehydrating of glycerine, Pat. WO/2008/092534 (2008). Parida, 1998, Appl. Catal. A: Gen., 166, 115, 10.1016/S0926-860X(97)00256-1 Lok, 1984, J. Am. Chem. Soc., 106, 6092, 10.1021/ja00332a063 Hall, 1950, J. Chem. Soc., 490, 10.1039/JR9500000490 Parida, 1996, J. Colloid Interf. Sci., 179, 233, 10.1006/jcis.1996.0208 B.M. Lok, C.A. Messina, R.L. Patton, R.T. Gajek, Patent USA 4.440.871 (1984). Tanabe, 1989, New solid acids and bases: their catalytic properties, Stud. Surf. Sci. Catal., 51, 5 Asthekar, 1994, J. Phys. Chem., 98, 4878, 10.1021/j100069a018 Schnabel, 1991, J. Chem. Soc. Faraday Trans., 87, 3574, 10.1039/FT9918703569 Nimlos, 2006, J. Phys. Chem. A, 110, 6145, 10.1021/jp060597q Dolgov, 1952, Zh. Obshch. Khim., 22, 950 Barrault, 2002, Catal. Today, 75, 177, 10.1016/S0920-5861(02)00062-7 Corma, 1985, Catal. Rev., 27, 29, 10.1080/01614948509342358 Corma, 1994, J. Catal., 145, 171, 10.1006/jcat.1994.1020 Corma, 2008, J. Catal., 257, 163, 10.1016/j.jcat.2008.04.016 Lonyi, 2001, Microporous Mesoporous Mater., 47, 293, 10.1016/S1387-1811(01)00389-4 J. Kijenski, A. Migdal, O. Osawaru, E. Smigiera, Pat. PL 37928306 (2006). Neuber, 1987, Stud. Surf. Sci. Catal., 34, 567, 10.1016/S0167-2991(09)60392-X Bautista, 1995, Appl. Catal. A: Gen., 130, 47, 10.1016/0926-860X(95)00106-9