A “waiting” carbon nitride radical anion: a charge storage material and key intermediate in direct C–H thiolation of methylarenes using elemental sulfur as the “S”-source

Chemical Science - Tập 9 Số 14 - Trang 3584-3591
Aleksandr Savateev1,2,3,4, Bogdan Kurpil1,2,3,4, Artem Mishchenko5,6,7, Guigang Zhang1,2,3,4, Markus Antonietti1,2,3,4
114476 Potsdam
2Department of Colloid Chemistry
3Germany
4Max-Planck Institute of Colloids and Interfaces
5Department for Heterophase Synthesis of Inorganic Compounds and Materials, V.I. Vernadsky Institute of General and Inorganic Chemistry, Palladina Ave., 32/34, Kiev, Ukraine
6Ukraine
7V.I. Vernadsky Institute of General and Inorganic Chemistry

Tóm tắt

Potassium poly(heptazine imide), a carbon nitride semiconductor, in the presence of hole scavengers and visible light gives stable radical anion with the specific density of unpaired electrons reaching 112 mmol g−1.

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Tài liệu tham khảo

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Chemical Science

Tập 9 Số 14

3584-3591

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