A study of shape selectivity in ethylation/disproportionation of ethylbenzene on ZSM-5 zeolites using a continuum and a Monte Carlo method

Chemical Engineering Science - Tập 52 - Trang 3173-3182 - 1997
Elias Klemm1, Jianguo Wang1, Gerhard Emig1
1Universität Erlangen-Nürnberg, Lehrstuhl für Technische Chemie I, Egerlandstr. 3, 91058 Erlangen, Germany

Tài liệu tham khảo

Beschmann, 1993, Isomerization of xylene and methylation of toluene on zeolite HZSM-5. Compound kinetics and selectivity, J. Catal., 141, 548, 10.1006/jcat.1993.1163 Bülow, 1991, Transport phenomena and reactions in 13X type zeolites, Vol. 65, 479 Chandawar, 1982, Alkylation in benzene with ethanol over ZSM-5 zeolites, Appl. Catal., 4, 287, 10.1016/0166-9834(82)80112-7 Frank, 1993, A Monte Carlo simulation of diffusion and reaction in zeolites, Microporous Materials, 1, 43, 10.1016/0927-6513(93)80007-H Hinderer, 1996, Three-dimensional Monte Carlo calculations of diffusion and reaction phenomena in zeolites, Chem. Engng Sci., 51, 2667, 10.1016/0009-2509(96)00134-0 Kaeding, 1985, Shape-selective reactions with zeolite catalysts. V. Alkylation or disproportionation of ethylbenzene to produce p- diethylbenzene, J. Catal., 95, 512, 10.1016/0021-9517(85)90129-0 Kaeding, 1981, Selective alkylation of toluene with methanol to produce para-xylene, J. Catal., 67, 159, 10.1016/0021-9517(81)90269-4 Karge, 1982, Conversion of alkylbenzenes over zeolite catalysts. I. Dealkylation and disproportionation of ethylbenzene over mordenites, Zeolites, 2, 94, 10.1016/S0144-2449(82)80008-0 Karge, 1983, Disproportionation of ethylbenzene: a potential test reaction for acidity of bifunctional zeolite catalysts, J. Catal., 82, 236, 10.1016/0021-9517(83)90135-5 Karge, 1984, A comparative study of pentasil zeolites and dealuminated mordenites as catalysts for the disproportionation of ethylbenzene, 101 Kim, 1989, Paraselectivity of pentasil zeolites, Stud. Surf. Sci. Catal., 46, 71, 10.1016/S0167-2991(08)60968-4 Klemm, 1997, A study of shape selectivity on zeolites in ethylbenzene disproportionation. Simulation and experiment, Chem. Engng Sci., 52, 2757, 10.1016/S0009-2509(97)00095-X Liang, 1995, A model for highly para-selective reactions in HZSM-5 zeolite catalyst, Chem. Engng Sci., 50, 2391, 10.1016/0009-2509(95)00095-M Lonyi, 1991, Paraselectivity of toluene ethylation over ZSM-5 catalysts, Zeolites, 11, 169, 10.1016/0144-2449(91)80412-S Palekar, 1986, Sorption accompanied by chemical reaction on zeolites, Catal. Rev. Sci. Engng, 28, 371, 10.1080/01614948608067542 Paparatto, 1987, Toluene ethylation on ZSM zeolites, J. Catal., 105, 227, 10.1016/0021-9517(87)90021-2 Theodorou, 1983, Diffusion and reaction in blocked and high occupancy zeolite catalysts, J. Catal., 83, 205, 10.1016/0021-9517(83)90043-X Wang, 1994, Monte Carlo simulation of xylene isomerization over zeolite catalysts, Catal. Lett., 26, 189, 10.1007/BF00824044 Wang, 1994, A Monte Carlo model for the simulation of diffusion and reaction in zeolite, J. Fuel Chem., 22, 355 Wang, 1995, Monte Carlo simulation of alkylation of toluene with alcohols over zeolite catalysts, Zeolites, 15, 288, 10.1016/0144-2449(94)00045-T Wei, 1982, A mathematical theory of enhanced para-xylene selectivity in molecular sieve catalysts, J. Catal., 76, 433, 10.1016/0021-9517(82)90272-X Young, 1982, Shape selective reactions with zeolite catalysts. III. Selectivity in xylene isomerization, toluene-methanol alkylation, and toluene disproportionation over ZSM-5 zeolite catalysts, J. Catal., 76, 418, 10.1016/0021-9517(82)90271-8