A review: the utilization potency of biopolymer as an eco-friendly scale inhibitors

Ully Zakyatul Husna1, Khaled Abdalla Elraies1, Juhairi Aris Shuhili1, Ahmed Abdulla Elryes1
1Department of Petroleum Engineering, Universiti Teknologi PETRONAS, 32610, Seri Iskandar, Perak, Malaysia

Tóm tắt

AbstractScale formation is one of the major issues in the petroleum industry. The development of these scale layers could result in production losses and equipment instability because of pipeline blockage, energy leakage, corrosion acceleration and severe accidents which will impact the safety of the production process. The utilization of chemical scale inhibitors (SIs) is considered an economical and successful route for the scale prevention. Two main components of the chemical SIs are phosphonate and polymer. Many of the phosphorous compounds are toxic and very expensive. Besides, portions of the phosphonate compounds are thermally less stable than polymeric scale inhibitors in a harsh environment of high temperature and high pressure (HTHP). This is considered as an issue as a good scale inhibitor should be able to be applied under wide range of temperature and pressure. Therefore, the continuous development in petroleum production imposes the need to develop a novel phosphorus-free scale inhibitor. Meanwhile, polymers have been broadly applied as a scale inhibitor in oil and gas fields because of their enhanced thermal stability and improved environmental compatibility. Polymeric scale inhibitors also show better dispersing efficiency. Today, the biopolymers have pulled in a tremendous consideration from the industry to replace the utilization of synthetic polymer due to their interesting qualities such as their lightness, strong mechanical properties, and appealing functionality. Biopolymers are insensitive toward brine salinity yet are vulnerable to biological degradation. Specifically, these polymers present enormous potential for environmental application because of their biodegradability, chemical adaptability and reactivity, biocompatibility, and nontoxicity. Recently, several new eco-friendly scale inhibitors have been reported in the literature. Hence, this paper provides a review of the utilization of biopolymer as scale inhibitor in the application of oil and gas industry under laboratory approach or field trial application. The types of scales, chemical scale inhibitors (SIs) and biopolymers are likewise reviewed here. The presented work in this paper is expected to enhance the fundamental understanding of scale formation, as well as contribute to the development process of biopolymer scale inhibitors.

Từ khóa


Tài liệu tham khảo

Adewole JK, Muritala KB (2019) Some applications of natural polymeric materials in oilfield operations: a review. J Petrol Explor Prod Technol 9(3):2297–2307. https://doi.org/10.1007/s13202-019-0626-9

Agustin MB, Ahmmad B, Alonzo SMM, Patriana FM (2014) Bioplastic based on starch and cellulose nanocrystals from rice straw. J Reinf Plast Compos 33(24):2205–2213. https://doi.org/10.1177/0731684414558325

Ahmad NAB (2012) Mitigation of calcium carbonate (CaCO3) inorganic scaling using green inhibitors (Issue January). Universiti Teknologi PETRONAS

Akpan EU, Enyi GC, Nasr GG, Yahaya AA (2018) Stabilizing biopolymers in water-based drilling fluids at high temperature using antioxidants, a formate salt, and polyglycol. J Eng Technol 6(2):469–486

Al Helal A, Soames A, Iglauer S, Gubner R, Barifcani A (2019) Evaluating chemical-scale-inhibitor performance in external magnetic fields using a dynamic scale loop. J Petrol Sci Eng 179(May):1063–1077. https://doi.org/10.1016/j.petrol.2019.04.093

Aljeban N, Al-Harbi B, Chen T, Balharth S (2020) Systematic calcium carbonate scale risk evaluation from downhole to topside flowline. https://doi.org/10.2118/202267-ms

Amjad Z, Demadis KD (2015) Mineral scales and deposits-scientific and technological approaches. elsevier B.V. https://doi.org/10.1201/9781420071450

Amjad Z (1995) Mineral scale formation and inhibition

Andrianov A, Popov KI, Andrianov A, Pervov A, Rudakova G, Oshchepkov M, & Kamagurov S (2016) Investigation of new biodegradable antiscalants efficiencies in various RO applications. Desalination for the environment: clean water and energy, May.

Azizi J, Shadizadeh SR, Khaksar Manshad A, Mohammadi AH (2019) A dynamic method for experimental assessment of scale inhibitor efficiency in oil recovery process by water flooding. Petroleum 5(3):303–314. https://doi.org/10.1016/j.petlm.2018.07.004

Azman N (2014) Scale study: the green inhibitors for silica polymerization [Universiti Teknologi PETRONAS]. In: Universiti Teknologi PETRONAS, vol 2014, Issue June. https://doi.org/10.1038/132817a0

Bailon F, Espitalier F, Cogne C, Peczalski R, Louisnard O (2015) Power ultrasonics: application of high-intensity ultrasound. Woodhead Publishing, Cambridge

Baraka-Lokmane S, Sorbie K, Poisson N, Kohler N (2009) Can green scale inhibitors replace phosphonate scale inhibitors?: Carbonate coreflooding experiments. Pet Sci Technol 27(4):427–441. https://doi.org/10.1080/10916460701764605

Belarbi Z, Gamby J, Makhloufi L, Sotta B, Tribollet B (2014) Inhibition of calcium carbonate precipitation by aqueous extract of Paronychia argentea. J Cryst Growth 386:208–214. https://doi.org/10.1016/j.jcrysgro.2013.09.048

Boak LS, Sorbie K (2010) New developments in the analysis of scale inhibitors. SPE Prod Oper 25(04):533–544. https://doi.org/10.2118/130401-pa

Boels L, Witkamp GJ (2011) Carboxymethyl inulin biopolymers: a green alternative for phosphonate calcium carbonate growth inhibitors. Cryst Growth Des 11(9):4155–4165. https://doi.org/10.1021/cg2007183

Can HK, Üner G (2015) Water-soluble anhydride containing alternating copolymers as scale inhibitors. Desalination 355:225–232. https://doi.org/10.1016/j.desal.2014.11.001

Chen X, Wang H, Wang C, Zhang W, Lv C, Zhu Y (2019) A novel antiscaling and anti-corrosive polymer-based functional coating. J Taiwan Inst Chem Eng 97:397–405. https://doi.org/10.1016/j.jtice.2019.01.016

Chew CB, Mat R (2015) The efficacy of calcium carbonate scale inhibition by commercial polymer scale inhibitors. Chem Eng Trans 45:1471–1476. https://doi.org/10.3303/CET1545246

Chilingar GV, Mourhatch R, Al-Qahtani GD (2008) The fundamentals of corrosion and scaling for petroleum and enviromental engineers. Gulf Publishing Company

Crabtree M, Eslinger D, Fletcher P, Miller M, Johnson A, King G (1999) Fighting scale : removal and prevention. Oilfield Review 11(03):30–45

Da Rosa KRSA, Bezerra MCM, Fontes RA, Ponzio EA, Rocha AA (2016) Study of thermal stability of scale inhibitors and its impact on processing plants. Soc Petrol Eng SPE Int Oilf Scale Conf Exhib. https://doi.org/10.2118/179907-ms

de Souza AVA, Rosário F, Cajaiba J (2019) Evaluation of calcium carbonate inhibitors using sintered metal filter in a pressurized dynamic system. Materials 12(11):1–13. https://doi.org/10.3390/ma12111849

Díez-Pascual AM (2019) Synthesis and applications of biopolymer composites. Int J Mol Sci 20(9). https://doi.org/10.3390/ijms20092321

Elayatt AK, Altarhoni HK, Elaoud MAM (2016) Evaluation of diethylene triamine-pentamethylene phosphonic acid ( DTPMP ) as scale inhibitor of calcium carbonate scales in oil field water. Am J Eng Res 12:130–142

Eubeler J (2010) Biodegradation of synthetic polymers in the acquatic environemnt. Bremen University, April

Fakhreeva AV, Voloshin AI, Chernyaeva EY, Sayapova VV, Tomilov YV, Khalikova G, Dokichev VA (2019) Polysaccharides as promising compounds for the creation of corrosion and scaling inhibitors. XXI YuCorr, pp 107–292

Fan C, Shi W, Zhang P, Lu H, Zhang N, Work S, Al-Saiari HA, Kan AT, Tomson MB (2012) Ultrahigh-temperature/ultrahigh-pressure scale control for deepwater oil and gas production. SPE J 17(1):177–186. https://doi.org/10.2118/141349-PA

Fevang S (2017) Synthesizing and testing for new biodegradable scale inhibitors. Universitetet i Stavanger

Fraser A, Davidson J, Feasey N, Jenkins A (2016) Limitations of common oilfield scale inhibitor chemistries. NACE Int Corr Conf Ser 4(7617):3276–3290

Frenier WW, Ziauddin M (2008) In: Wolf NA, Hartman RL (eds) Formation, removal, and inhibition of inorganic scale in the oilfield environment. Society of Petroleum Engineers

Gill JS (1996) Development of scale inhibitors. The NACE International Annual Conference and Exposition, p 229

Goncharuk VV, Kavitskaya AA, Skilskaya MD (2012) Sodium carboxymethyl cellulose as an inhibitor of scale formation in nanofiltration of hard artesian waters. Desalin Water Treat 47(1–3):235–242. https://doi.org/10.1080/19443994.2012.696408

Gu X, Qiu F, Zhou X, Qi J, Zhou Y, Yang D, Guo Q, Guo X (2013) Preparation and application of polymers as inhibitors for calcium carbonate and calcium phosphate scales. Int J Polym Mater Polym Biomater 62(6):323–329. https://doi.org/10.1080/00914037.2012.670824

Gudmundsson JS (2018) Flow assurance solids in oil and gas production. CRC Press Taylor & Francis Group

Hajirezaie S, Wu X, Reza M, Sakha S (2019) Numerical simulation of mineral precipitation in hydrocarbon reservoirs and wellbores. Fuel 238(June 2018):462–472. https://doi.org/10.1016/j.fuel.2018.10.101

Hasson D, Shemer H, Sher A (2011) State of the art of friendly “green” scale control inhibitors: a review article. Ind Eng Chem Res 50(12):7601–7607. https://doi.org/10.1021/ie200370v

Horizon Commercial Pool Supply. (n.d.). Saturation index. http://www.horizonpoolsupply.com/. Accessed 28 Dec 2020

Huang H, Yao Q, Jiao Q, Liu B, Chen H (2019) Polyepoxysuccinic acid with hyper-branched structure as an environmentally friendly scale inhibitor and its scale inhibition mechanism. J Saudi Chem Soc 23:61–74. https://doi.org/10.1016/j.jscs.2018.04.003

Ibrahim AF, Nasr-El-Din H, El-Baqi MA, Abdelhay A, Farouk H, Aref A, Reda A, Rafaat M, Gamal M (2019) Evaluation of a new treatment to remove calcium sulfate scale: lab studies and field application. SPE Western Reg Meeting Proc. https://doi.org/10.2118/195313-ms

Ituen EB, Ime-sunday JI, Essien EA (2017) Inhibition of oilfield scales using plant materials : a peep into green future. Chem Res J 2(5):284–292

Jainan A, Deenu A, Kamthai S (2018) Biopolymer film based on rice straw carboxymethyl cellulose (CMCr) and chiang mai university (CMU) purple rice carboxymethyl flour (CMF). Chiang Mai J Sci 45(5):2140–2151

Jimenez PD (2014) Improving squeeze scale inhibitor adsorption and flow back characteristics with surfactants. University of Stavanger

Karaseva ON, Lakshtanov LZ, Okhrimenko DV, Belova DA, Generosi J, Stipp SLS (2018) Biopolymer control on calcite precipitation. Cryst Growth Des 18(5):2972–2985. https://doi.org/10.1021/acs.cgd.8b00096

Kelland MA (2009) Production chemicals for the oil and gas industry. In: Production chemicals for the oil and gas industry. https://doi.org/10.1201/9781420092974

Khandanlou R, Ahmad MB, Shameli K, Saki E, Kalantari K (2014) Studies on properties of rice straw/polymer nanocomposites based on polycaprolactone and Fe3O4 nanoparticles and evaluation of antibacterial activity. Int J Mol Sci 15(10):18466–18483. https://doi.org/10.3390/ijms151018466

Khormali A, Petrakov DG (2016) Laboratory investigation of a new scale inhibitor for preventing calcium carbonate precipitation in oil reservoirs and production equipment. Pet Sci 13(2):320–327. https://doi.org/10.1007/s12182-016-0085-6

Kırboga S, Öner M (2012) Colloids and surfaces B : biointerfaces the inhibitory effects of carboxymethyl inulin on the seeded growth of calcium carbonate 91:18–25. https://doi.org/10.1016/j.colsurfb.2011.10.031

Ko S, Wang X, Zhao Y, Dai C, Lu YT, Deng G, Paudyal S, Mateen S, Kan AT, Tomson MB (2020) Prevention of mineral scale deposition using dispersants and inhibitors. Soc Petrol Eng SPE Int Oilf Scale Conf Exhib OSS. https://doi.org/10.2118/200670-ms

Koutsoukos PG, Kapetanaki E (2016) Mixed calcium carbonate and calcium sulfate scale. NACE Int Corr Conf Ser 3(7457):2376–2388

Kumar T, Vishwanatham S, Kundu SS (2010) A laboratory study on pteroyl- L -glutamic acid as a scale prevention inhibitor of calcium carbonate in aqueous solution of synthetic produced water. J Petrol Sci Eng 71(1–2):1–7. https://doi.org/10.1016/j.petrol.2009.11.014

Kumar S, Naiya TK, Kumar T (2018) Developments in oil field scale handling towards green technology—a review. J Petrol Sci Eng 169(May):428–444. https://doi.org/10.1016/j.petrol.2018.05.068

Lambert S (2013) Environmental risk of polymer and their degradation products. May, 1–198

Li J, Tang M, Ye Z, Chen L, Zhou Y (2017) Scale formation and control in oil and gas fields: a review. J Dispers Sci Technol 38(5):661–670. https://doi.org/10.1080/01932691.2016.1185953

Liu Y, Zou C, Li C, Lin L, Chen W (2016) Evaluation of β –cyclodextrin—polyethylene glycol as green scale inhibitors for produced-water in shale gas well. DES 377:28–33. https://doi.org/10.1016/j.desal.2015.09.007

Liu G, Xue M, Yang H (2017) Polyether copolymer as an environmentally friendly scale and corrosion inhibitor in seawater. Desalination 419(May):133–140. https://doi.org/10.1016/j.desal.2017.06.017

Liu J, Huang C (2013) Biodegradable composites from rice straw and cornstarch adhesives. Adv J Food Sci Technol 5(1):41–45. https://doi.org/10.19026/ajfst.5.3309

Liu D (2011) Research on performance evaluation and anti-scaling mechanism of green scale inhibitors by static and dynamic methods. Ecole nationale superieure d’arts et metiers

Lourteau T, Berriche H, Kécili K, Heim V, Bricault D, Litaudon M, Cachet X, Roussi F, Perrot H, Horner O (2019) Scale inhibition effect of Hylocereus undatus solution on calcium carbonate formation. J Cryst Growth 524(July):125161. https://doi.org/10.1016/j.jcrysgro.2019.125161

Lu H, Brooks J, Steven W, Mccabe B, Heath S (2019) A novel phosphonate scale inhibitor for scale control in ultra high temperature environments. NACE International 13182:1–15

Luo H, Chen D, Yang X, Zhao X, Feng H, Li M, Wang J (2015) Synthesis and performance of a polymeric scale inhibitor for oilfield application. J Petrol Explor Prod Technol 5(2):177–187. https://doi.org/10.1007/s13202-014-0123-0

Macedo RGMA, Marques NN, Paulucci LCS, Cunha JVM, Villetti MA, Castro BB, Balaban RC (2019) Water-soluble carboxymethylchitosan as green scale inhibitor in oil wells. Carbohyd Polym 215(December 2018):137–142. https://doi.org/10.1016/j.carbpol.2019.03.082

Mady MF, Kelland MA (2017) Study on various readily available proteins as new green scale inhibitors for oilfield scale control. Energy Fuels 31(6):5940–5947. https://doi.org/10.1021/acs.energyfuels.7b00508

Mady MF, Charoensumran P, Ajiro H, Kelland MA (2018) Synthesis and characterization of modified aliphatic polycarbonates as environmentally friendly oilfield scale inhibitors. Energy Fuels 32(6):6746–6755. https://doi.org/10.1021/acs.energyfuels.8b01168

Mahat SQA, Saaid IM, Lal B (2016) Green silica scale inhibitors for alkaline-surfactant-polymer flooding: a review. J Petrol Explor Prod Technol 6(3):379–385. https://doi.org/10.1007/s13202-015-0187-5

Mahmoodi L, Malayeri MR, Tabrizi FF (2021) Performance of a novel green scale inhibitor. E3S Web Conf 266. https://doi.org/10.1051/e3sconf/202126601019

Mazumder MAJ (2020) A review of green scale inhibitors: process, types, mechanism and properties. In: Coatings, vol 10, issue 10. MDPI AG, pp 1–29. https://doi.org/10.3390/coatings10100928

McCabe B, Heath S (2019) Development of a novel phosphonate scale inhibitor for scale control in geothermal applications. NACE Int 13275:1–12

Menzri R, Ghizellaoui S, Tlili M (2017) Calcium carbonate inhibition by green inhibitors: thiamine and pyridoxine. DES 404:147–154. https://doi.org/10.1016/j.desal.2016.11.005

Merdhah AB, Mohd Yassin AA (2009) Solubility of common oil field scales of injection water and high–barium concentration and high–salinity formation water. J Teknologi 50(1):67–77. https://doi.org/10.11113/jt.v50.176

Mohamed S, Meliani MH, Khaled EM, Fares C, Benghalia MA (2017) Corrosion effects and green scale inhibitors in the fracture mechanics properties of gas pipelines. Struct Integ Life 17(1):25–31

Mohammed AB (2007) The study of scale formation in oil reservoir during water injection at high-barium and high-salinity formation water. Universiti Teknologi Malaysia

Nagle G (2015) Polymer chemistries provide long-term scale prevention. August

Natsi PD, Rokidi S, Koutsoukos PG (2016) Calcium carbonate scale formation and prevention in aqueous solutions and mixed solvents. NACE Int Corr Conf Ser 3(7455):2348–2361

Obied MA, Alkhaldi MH, Mubarak TA, Yami IS, Sahman FM (2015) Polymer-based scale inhibitors for seawater injection operations in high-salinity formation water reservoirs. SPE Abu Dhabi International Petroleum Exhibition and Conference, SPE-177417-MS. https://doi.org/10.2118/177417-ms

Ohimor OE, Anigboro OE, Anih CE, Ononiwu PI (2019) Performance evaluation of biodegradable oilfield scale inhibitors for calcium carbonate scales. Int J Emerg Trends Eng Dev 3(9). https://doi.org/10.26808/rs.ed.i9v3.08

Olajire AA (2015) A review of oilfield scale management technology for oil and gas production. J Petrol Sci Eng 135:723–737. https://doi.org/10.1016/j.petrol.2015.09.011

Oun AA, Rhim JW (2015) Preparation and characterization of sodium carboxymethyl cellulose/cotton linter cellulose nanofibril composite films. Carbohyd Polym 127:101–109. https://doi.org/10.1016/j.carbpol.2015.03.073

Pecnik B, Hocevar M, Sirok B, Bizjan B (2016) Scale deposit removal by means of ultrasonic cavitation. Wear 356–357:45–52. https://doi.org/10.1016/j.wear.2016.03.012

Pervov AG, Andrianov AP, Danilycheva MN (2018) Preliminary evaluation of new green antiscalants for reverse osmosis water desalination. Water Sci Technol Water Supply 18(1):167–174. https://doi.org/10.2166/ws.2017.106

Popov K, Rudakova G, Larchenko V, Tusheva M, Kamagurov S, Dikareva J, Kovaleva N (2016). A comparative performance evaluation of some novel “green” and traditional antiscalants in calcium sulfate scaling. Adv Mater Sci Eng. https://doi.org/10.1155/2016/7635329

Ramzi M, Hosny R, El-Sayed M, Fathy M, Moghny TA (2016) Evaluation of scale inhibitors performance under simulated flowing field conditions using dynamic tube blocking test. Int J Chem Sci 14(1):16–28

Raval NP, Shah PU, Shah NK (2016) Nanoparticles loaded biopolymer as effective adsorbent for adsorptive removal of malachite green from aqueous solution. Water Conserv Sci Eng 1(1):69–81. https://doi.org/10.1007/s41101-016-0004-0

Rhudy JS (1993) Removal of mineral scale from reservoir core by scale dissolver. In: Proceedings of the 1993 SPE international symposium on oilfield chemistry, pp 97–106. https://doi.org/10.2523/25161-ms

Senthilmurugan B, Radhakrishnan JS, Arana V, Al-Foudari M (2019) High temperature kinetic scale inhibitor for flow assurance application. Int J Petrol Sci Technol 13(1):21–38

Shaw SS, Sorbie KS (2015) Synergistic properties of phosphonate and polymeric scale-inhibitor blends for barium sulfate scale inhibition. February.

Smith AM, Moxon S, Morris GA (2016) Biopolymers as wound healing materials. In: Wound healing biomaterials, vol 2. Elsevier Ltd, pp. 261–287. https://doi.org/10.1016/B978-1-78242-456-7.00013-1

Suhadi A, Hayatullah MS, Satria A, Wiryawan MD, Putranto P, Bukian N (2015) Experiences of downhole scale squeeze treatment to solve problem CaCO3 Scale in Zamrud Field, Indonesia. International conference on oleo and petrochemical engineering.

Verbeek CJR (2012) Products and applications of biopolymers. INTECH. https://doi.org/10.5772/32985

Viloria A, Castillo L, Garcia JA, Biomorgi J (2010) Aloe derived scale inhibitor (Patent No. US 7,645,722 B2). https://doi.org/10.13140/2.1.4522.3209

Wang H, Zhou Y, Sun W (2014) Performance of an maleic anhydride based polymers as scale inhibitor and Iron ( III ) scaling in industrial cooling water systems. Front Energy Mater Inform Eng 1044–1045:79–82. https://doi.org/10.4028/WWW.SCIENTIFIC.NET/AMR.1044-1045.79

Webb HK, Arnott J, Crawford RJ, Ivanova EP (2013) Plastic degradation and its environmental implications with special reference to poly(ethylene terephthalate). Polymers 5(1):1–18. https://doi.org/10.3390/polym5010001

Wilson D, Harris K (2010) Development of a ‘green’ hydrothermally stable scale inhibitor for topside and squeeze treatment. NACE Int 10135:1–13

Wilson D, Harris K, Toole M (2010) Towards a better environment: improved biodegradability from a polymeric scale inhibitor. NACE Int 10047:1–18

Wylde JJ, McAra EK (2004) Optimization of an oil soluble scale inhibitor for minimising formation damage: laboratory and field studies. Proc SPE Int Symp Form Damage Control 181–189. https://doi.org/10.2523/86477-ms

Yu W, Wang Y, Li A, Yang H (2018) Evaluation of the structural morphology of starch- graft -poly ( acrylic acid ) on its scale-inhibition ef fi ciency *. Water Res 141:86–95. https://doi.org/10.1016/j.watres.2018.04.021

Yuan X, Dong S, Zheng Q, Yang W, Huang T (2020) Novel and efficient curcumin based fluorescent polymer for scale and corrosion inhibition. Chem Eng J 389(January). https://doi.org/10.1016/j.cej.2020.124296

Yue GH, Zhang M, Yu YH (2014) Research on scale inhibition of green scale inhibitors used in the industrial recycling cooling system with reclaimed wastewater. Adv Mater Res 864–867:1767–1771. https://doi.org/10.4028/www.scientific.net/AMR.864-867.1767

Zahlan H, Saeed WS, Alrasheed R, Alandes NM, Aouak T (2019) Synthesis of poly (citric acid-co-glycerol) and its application as an inhibitor of CaCO3 deposition. Materials 12(22). https://doi.org/10.3390/ma12223800

Zakaria K, Salem AA, Ramzi M (2020) Cost-effective and eco-friendly organophosphorus-based inhibitors for mineral scaling in Egyptian oil reservoirs: Theoretical, experimental and quantum chemical studies. J Petrol Sci Eng 195(June):107519. https://doi.org/10.1016/j.petrol.2020.107519

Zarga Y, Elfil H, Ben Boubaker H (2014) Calcium sulfate and calcium carbonate simple and mixed precipitations. J New Sci 8(2):7–16

Zeng D, Yan H (2013a) Experimental study on a new corrosion and scale inhibitor. J Environ Prot 04(07):671–675. https://doi.org/10.4236/jep.2013.47077

Zeng D, Yan H (2013b) Study on an eco-friendly corrosion and scale inhibitor in simulated cooling water. Am J Eng Res (AJER) 2(5):39–43