A review on the status and challenges of electrocatalysts in lithium-sulfur batteries

Energy Storage Materials - Tập 20 - Trang 55-70 - 2019
Jiarui He1, Arumugam Manthiram1
1Materials Science and Engineering Program & Texas Materials Institute, University of Texas at Austin, Austin, TX, 78712, USA

Tóm tắt

Từ khóa


Tài liệu tham khảo

Manthiram, 2013, Challenges and prospects of lithium–sulfur batteries, Accounts Chem. Res., 46, 1125, 10.1021/ar300179v

Wang, 2016, Interwoven WSe2/CNTs hybrid network: a highly efficient and stable electrocatalyst for hydrogen evolution, Electrochem. Commun., 72, 74, 10.1016/j.elecom.2016.09.007

Manthiram, 2014, Rechargeable lithium–sulfur batteries, Chem. Rev., 114, 11751, 10.1021/cr500062v

Li, 2019, One-step nonlinear electrochemical synthesis of TexSy@PANI nanorod materials for Li-TexSy battery, Energy Storage Mater., 16, 31, 10.1016/j.ensm.2018.04.019

He, 2016, Highly-flexible 3D Li2S/graphene cathode for high-performance lithium sulfur batteries, J. Power Sources, 327, 474, 10.1016/j.jpowsour.2016.07.088

He, 2017, Self-assembled cauliflower-like FeS2 anchored into graphene foam as free-standing anode for high-performance lithium-ion batteries, Carbon, 114, 111, 10.1016/j.carbon.2016.12.001

Zhang, 2016, Cobalt-embedded nitrogen-doped hollow carbon nanorods for synergistically immobilizing the discharge products in lithium–sulfur battery, Energy Storage Mater., 5, 223, 10.1016/j.ensm.2016.04.002

Bhargav, 2018, Polyphenylene tetrasulfide as an inherently flexible cathode material for rechargeable lithium batteries, ACS Appl. Energy Mater., 1, 5859, 10.1021/acsaem.8b01350

Fu, 2013, Li2S-Carbon sandwiched electrodes with superior performance for lithium-sulfur batteries, Adv. Energy Mater., 4, 1300655, 10.1002/aenm.201300655

He, 2017, Tellurium-impregnated porous cobalt-doped carbon polyhedra as superior cathodes for lithium–tellurium batteries, ACS Nano, 11, 8144, 10.1021/acsnano.7b03057

Lu, 2019, High performance bimetal sulfides for lithium-sulfur batteries, Chem. Eng. J., 358, 955, 10.1016/j.cej.2018.10.104

Huang, 2015, Multi-functional separator/interlayer system for high-stable lithium-sulfur batteries: progress and prospects, Energy Storage Mater., 1, 127, 10.1016/j.ensm.2015.09.008

Wu, 2018, Metal-organic frameworks composites threaded on the CNT knitted separator for suppressing the shuttle effect of Lithium sulfur batteries, Energy Storage Mater., 14, 383, 10.1016/j.ensm.2018.06.009

He, 2016, Three-dimensional hierarchical reduced graphene oxide/tellurium nanowires: a high-performance freestanding cathode for Li–Te batteries, ACS Nano, 10, 8837, 10.1021/acsnano.6b04622

Lin, 2017, Electrocatalysis of polysulfide conversion by sulfur-deficient MoS2 nanoflakes for lithium–sulfur batteries, Energy Environ. Sci., 10, 1476, 10.1039/C7EE01047H

Guo, 2018, A perspective on energy densities of rechargeable Li-S batteries and alternative sulfur-based cathode materials, Energy Environ. Mater., 1, 20, 10.1002/eem2.12003

Lin, 2015, Enhanced performance of lithium sulfur battery with a reduced graphene oxide coating separator, J. Electrochem. Soc., 162, A1624, 10.1149/2.0891508jes

He, 2015, Self-assembled CoS2 nanoparticles wrapped by CoS2-quantum-dots-anchored graphene nanosheets as superior-capability anode for lithium-ion batteries, Electrochim. Acta, 182, 424, 10.1016/j.electacta.2015.09.131

Chen, 2018, Designing safe electrolyte systems for a high-stability lithium-sulfur battery, Adv. Energy Mater., 8, 1702348, 10.1002/aenm.201702348

Wang, 2019, N-doped Fe3C@C as an efficient polyselenide reservoir for high-performance sodium-selenium batteries, Energy Storage Mater., 16, 374, 10.1016/j.ensm.2018.06.014

Xu, 2018, Hybrid lithium-sulfur batteries with an advanced gel cathode and stabilized lithium-metal anode, Adv. Energy Mater., 1800813, 10.1002/aenm.201800813

He, 2017, Yolk-shelled C@Fe3O4 nanoboxes as efficient sulfur hosts for high-performance lithium-sulfur batteries, Adv. Mater., 29, 1702707, 10.1002/adma.201702707

Gupta, 2019, Highly solvating electrolytes for lithium–sulfur batteries, Adv. Energy Mater., 9, 1803096, 10.1002/aenm.201803096

He, 2016, Three-dimensional hierarchical graphene-CNT@Se: a highly efficient freestanding cathode for Li–Se batteries, ACS Energy Lett., 1, 16, 10.1021/acsenergylett.6b00015

Chen, 2018, A new hydrophilic binder enabling strongly anchoring polysulfides for high-performance sulfur electrodes in lithium-sulfur battery, Adv. Energy Mater., 8, 1702889, 10.1002/aenm.201702889

Bai, 2016, Refined sulfur nanoparticles immobilized in metal–organic polyhedron as stable cathodes for Li–S battery, ACS Appl. Mater. Interfaces, 8, 14328, 10.1021/acsami.6b04697

He, 2016, Three-dimensional CNT/graphene–Li2S aerogel as freestanding cathode for high-performance Li–S batteries, ACS Energy Lett., 1, 820, 10.1021/acsenergylett.6b00272

Nanda, 2018, A lithium-sulfur cell based on reversible lithium deposition from a Li2S cathode host onto a hostless-anode substrate, Adv. Energy Mater., 8, 1801556, 10.1002/aenm.201801556

Lei, 2018, A nonflammable and thermotolerant separator suppresses polysulfide dissolution for safe and long-cycle lithium-sulfur batteries, Adv. Energy Mater., 8, 1802441, 10.1002/aenm.201802441

Fu, 2013, In situ-formed Li2S in lithiated graphite electrodes for lithium–sulfur batteries, J. Am. Chem. Soc., 135, 18044, 10.1021/ja409705u

Sun, 2014, Sulfur nanocrystals confined in carbon nanotube network as a binder-free electrode for high-performance lithium sulfur batteries, Nano Lett., 14, 4044, 10.1021/nl501486n

He, 2015, Three-dimensional CNT/graphene–sulfur hybrid sponges with high sulfur loading as superior-capacity cathodes for lithium–sulfur batteries, J. Mater. Chem. A, 3, 18605, 10.1039/C5TA04445F

Fu, 2012, Enhanced cyclability of lithium–sulfur batteries by a polymer acid-doped polypyrrole mixed ionic–electronic conductor, Chem. Mater., 24, 3081, 10.1021/cm301661y

Liu, 2017, Nanostructured metal oxides and sulfides for lithium-sulfur batteries, Adv. Mater., 29, 1601759, 10.1002/adma.201601759

Chen, 2015, Conductive lewis base matrix to recover the missing link of Li2S8 during the sulfur redox cycle in Li–S battery, Chem. Mater., 27, 2048, 10.1021/cm5044667

Zhou, 2015, Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge, Nat. Commun., 6, 7760, 10.1038/ncomms8760

Peng, 2014, Strongly coupled interfaces between a heterogeneous carbon host and a sulfur-containing guest for highly stable lithium-sulfur batteries: mechanistic insight into capacity degradation, Adv. Mater. Interfaces, 1, 1400227, 10.1002/admi.201400227

Wei Seh, 2013, Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries, Nat. Commun., 4, 1331, 10.1038/ncomms2327

Chen, 2017, Self-templated formation of interlaced carbon nanotubes threaded hollow Co3S4 nanoboxes for high-rate and heat-resistant lithium–sulfur batteries, J. Am. Chem. Soc., 139, 12710, 10.1021/jacs.7b06973

Zhou, 2018, Low cost metal carbide nanocrystals as binding and electrocatalytic sites for high performance Li–S batteries, Nano Lett., 18, 1035, 10.1021/acs.nanolett.7b04505

Sun, 2017, Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries, Nat. Commun., 8, 14627, 10.1038/ncomms14627

Zheng, 2014, Lewis acid-base interactions between polysulfides and metal organic framework in lithium sulfur batteries, Nano Lett., 14, 2345, 10.1021/nl404721h

He, 2018, Direct impregnation of SeS2 into a MOF-derived 3D nanoporous Co–N–C architecture towards superior rechargeable lithium batteries, J. Mater. Chem. A, 6, 10466, 10.1039/C8TA02434K

Manthiram, 2015, Lithium-sulfur batteries: progress and prospects, Adv. Mater., 27, 1980, 10.1002/adma.201405115

Liu, 2018, Catalytic effects in lithium-sulfur batteries: promoted sulfur transformation and reduced shuttle effect, Adv. Sci., 5, 1700270, 10.1002/advs.201700270

Peng, 2016, Enhanced electrochemical kinetics on conductive polar mediators for lithium-sulfur batteries, Angew. Chem., 128, 13184, 10.1002/ange.201605676

Ji, 2009, A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries, Nat. Mater., 8, 500, 10.1038/nmat2460

Peng, 2014, Nanoarchitectured graphene/CNT@porous carbon with extraordinary electrical conductivity and interconnected micro/mesopores for lithium-sulfur batteries, Adv. Funct. Mater., 24, 2772, 10.1002/adfm.201303296

Lee, 2017, Sulfur-immobilized, activated porous carbon nanotube composite based cathodes for lithium-sulfur batteries, Small, 1602984, 10.1002/smll.201602984

Xu, 2013, Mesoporous carbon–carbon nanotube–sulfur composite microspheres for high-areal-capacity lithium–sulfur battery cathodes, ACS Appl. Mater. Interfaces, 5, 11355, 10.1021/am4035784

Li, 2011, Optimization of mesoporous carbon structures for lithium–sulfur battery applications, J. Mater. Chem., 21, 16603, 10.1039/c1jm12979a

Balach, 2015, Functional mesoporous carbon-coated separator for long-life, high-energy lithium-sulfur batteries, Adv. Funct. Mater., 25, 5285, 10.1002/adfm.201502251

He, 2016, Wrinkled sulfur@graphene microspheres with high sulfur loading as superior-capacity cathode for Li-S batteries, Mater. Today Energy, 1–2, 11, 10.1016/j.mtener.2016.10.001

Zhao, 2012, Graphene/single-walled carbon nanotube hybrids: one-step catalytic growth and applications for high-rate Li–S batteries, ACS Nano, 6, 10759, 10.1021/nn304037d

Zhou, 2016, High-performance lithium-sulfur batteries with a self-supported, 3D Li2S-doped graphene aerogel cathodes, Adv. Energy Mater., 6, 1501355, 10.1002/aenm.201501355

Xiao, 2012, A soft approach to encapsulate sulfur: polyaniline nanotubes for lithium-sulfur batteries with long cycle life, Adv. Mater., 24, 1176, 10.1002/adma.201103392

Zhou, 2013, Yolk–Shell structure of polyaniline-coated sulfur for lithium–sulfur batteries, J. Am. Chem. Soc., 135, 16736, 10.1021/ja409508q

Wang, 2014, Enhancing lithium–sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide, Nat. Commun., 5, 5002, 10.1038/ncomms6002

Hou, 2016, Design principles for heteroatom-doped nanocarbon to achieve strong anchoring of polysulfides for lithium-sulfur batteries, Small, 12, 3283, 10.1002/smll.201600809

Liang, 2012, Sulfur and nitrogen dual-doped mesoporous graphene electrocatalyst for oxygen reduction with synergistically enhanced performance, Angew. Chem. Int. Ed., 51, 11496, 10.1002/anie.201206720

Pang, 2015, A nitrogen and sulfur dual-doped carbon derived from Polyrhodanine@Cellulose for advanced lithium-sulfur batteries, Adv. Mater., 27, 6021, 10.1002/adma.201502467

Xu, 2018, Exceptional catalytic effects of black phosphorus quantum dots in shuttling-free lithium sulfur batteries, Nat. Commun., 9, 10.1038/s41467-018-06629-9

Sun, 2016, Entrapment of polysulfides by a black-phosphorus-modified separator for lithium-sulfur batteries, Adv. Mater., 28, 9797, 10.1002/adma.201602172

Li, 2017, Phosphorene as a polysulfide immobilizer and catalyst in high-performance lithium-sulfur batteries, Adv. Mater., 29, 1602734, 10.1002/adma.201602734

Lei, 2014, Oxygen-doped boron nitride nanosheets with excellent performance in hydrogen storage, Nano Energy, 6, 219, 10.1016/j.nanoen.2014.04.004

Fan, 2017, Functionalized boron nitride nanosheets/graphene interlayer for fast and long-life lithium-sulfur batteries, Adv. Energy Mater., 7, 1602380, 10.1002/aenm.201602380

Deng, 2018, Enhanced adsorptions to polysulfides on graphene-supported BN nanosheets with excellent Li-S battery performance in a wide temperature range, ACS Nano, 12, 11120, 10.1021/acsnano.8b05534

Liang, 2016, Kinetically enhanced electrochemical redox of polysulfides on polymeric carbon nitrides for improved lithium–sulfur batteries, ACS Appl. Mater. Interfaces, 8, 25193, 10.1021/acsami.6b05647

Zhang, 2018, Microemulsion assisted assembly of 3D porous S/Graphene@g-C3N4 hybrid sponge as free-standing cathodes for high energy density Li-S batteries, Adv. Energy Mater., 8, 1702839, 10.1002/aenm.201702839

Mahmood, 2016, Metal-organic framework-based nanomaterials for electrocatalysis, Adv. Energy Mater., 6, 1600423, 10.1002/aenm.201600423

Babu, 2015, Electrocatalysis of lithium polysulfides: current collectors as electrodes in Li/S battery configuration, Sci. Rep., 5, 10.1038/srep08763

Al Salem, 2015, Electrocatalytic polysulfide traps for controlling redox shuttle process of Li–S batteries, J. Am. Chem. Soc., 137, 11542, 10.1021/jacs.5b04472

Li, 2016, A novel synergistic composite with multi-functional effects for high-performance Li-S batteries, Energy Environ. Sci., 9, 1998, 10.1039/C6EE00104A

He, 2016, From metal–organic framework to Li2S@C–Co–N nanoporous architecture: a high-capacity cathode for lithium–sulfur batteries, ACS Nano, 10, 10981, 10.1021/acsnano.6b05696

Pang, 2014, Surface-enhanced redox chemistry of polysulphides on a metallic and polar host for lithium-sulphur batteries, Nat. Commun., 5, 4759, 10.1038/ncomms5759

Liang, 2015, A highly efficient polysulfide mediator for lithium–sulfur batteries, Nat. Commun., 6, 5682, 10.1038/ncomms6682

Zheng, 2017, Propelling polysulfides transformation for high-rate and long-life lithium–sulfur batteries, Nano Energy, 33, 306, 10.1016/j.nanoen.2017.01.040

Song, 2018, Vanadium dioxide-graphene composite with ultrafast anchoring behavior of polysulfides for lithium–sulfur batteries, ACS Appl. Mater. Interfaces, 10, 15733, 10.1021/acsami.8b02920

Imtiaz, 2018, Electrocatalysis on separator modified by molybdenum trioxide nanobelts for lithium-sulfur batteries, Adv. Mater. Inter., 5, 1800243, 10.1002/admi.201800243

Lin, 2018, Elucidating the catalytic activity of oxygen deficiency in the polysulfide conversion reactions of lithium-sulfur batteries, Adv. Energy Mater., 8, 1801868, 10.1002/aenm.201801868

Ma, 2017, Cerium oxide nanocrystal embedded bimodal micromesoporous nitrogen-rich carbon nanospheres as effective sulfur host for lithium–sulfur batteries, ACS Nano, 11, 7274, 10.1021/acsnano.7b03227

Li, 2014, V2O5 polysulfide anion barrier for long-lived Li–S batteries, Chem. Mater., 26, 3403, 10.1021/cm500575q

Rehman, 2016, Rational design of Si/SiO2@Hierarchical porous carbon spheres as efficient polysulfide reservoirs for high-performance Li-S battery, Adv. Mater., 28, 3167, 10.1002/adma.201506111

Hu, 2018, SnO2/Reduced graphene oxide interlayer mitigating the shuttle effect of Li–S batteries, ACS Appl. Mater. Interfaces, 10, 18665, 10.1021/acsami.8b03255

Hwang, 2016, High-energy, high-rate, lithium-sulfur batteries: synergetic effect of hollow TiO2-webbed carbon nanotubes and a dual functional carbon-paper interlayer, Adv. Energy Mater., 6, 1501480, 10.1002/aenm.201501480

Zhou, 2015, Enabling prominent high-rate and cycle performances in one lithium-sulfur battery: designing permselective gateways for Li+ transportation in holey-CNT/S cathodes, Adv. Mater., 27, 3774, 10.1002/adma.201501082

Zhang, 2016, High performance of electrochemical lithium storage batteries: ZnO-based nanomaterials for lithium-ion and lithium-sulfur batteries, Nanoscale, 8, 18578, 10.1039/C6NR07207K

Xiang, 2017, A flexible 3D multifunctional MgO-decorated carbon Foam@CNTs hybrid as self-supported cathode for high-performance lithium-sulfur batteries, Adv. Funct. Mater., 27, 1702573, 10.1002/adfm.201702573

Li, 2017, Ultrafine Nd2O3 nanoparticles doped carbon aerogel to immobilize sulfur for high performance lithium–sulfur batteries, J. Electroanal. Chem., 799, 617, 10.1016/j.jelechem.2017.04.060

Zhang, 2014, Al2O3-coated porous separator for enhanced electrochemical performance of lithium sulfur batteries, Electrochim. Acta, 129, 55, 10.1016/j.electacta.2014.02.077

Ren, 2018, CoO/Co-Activated porous carbon cloth cathode for high performance Li–S batteries, ChemSusChem, 11, 2695, 10.1002/cssc.201801212

Hao, 2017, Perovskite La0.6Sr0.4CoO3-δ as a new polysulfide immobilizer for high-energy lithium-sulfur batteries, Nano Energy, 40, 360, 10.1016/j.nanoen.2017.08.039

Jin, 2018, Emerging two-dimensional nanomaterials for electrocatalysis, Chem. Rev., 118, 6337, 10.1021/acs.chemrev.7b00689

Yuan, 2016, Powering lithium–sulfur battery performance by propelling polysulfide redox at sulfiphilic hosts, Nano Lett., 16, 519, 10.1021/acs.nanolett.5b04166

He, 2019, Metal sulfide-decorated carbon sponge as a highly efficient electrocatalyst and absorbant for polysulfide in high-loading Li2S batteries, Adv. Energy Mater., 1900584, 10.1002/aenm.201900584

Pu, 2017, Multifunctional Co3S4 @sulfur nanotubes for enhanced lithium-sulfur battery performance, Nano Energy, 37, 7, 10.1016/j.nanoen.2017.05.009

Chen, 2017, Metallic and polar Co9S8 inlaid carbon hollow nanopolyhedra as efficient polysulfide mediator for lithium - sulfur batteries, Nano Energy, 38, 239, 10.1016/j.nanoen.2017.05.064

He, 2018, MOF-derived cobalt sulfide grown on 3D graphene foam as an efficient sulfur host for long-life lithium-sulfur batteries, iScience, 4, 36, 10.1016/j.isci.2018.05.005

Babu, 2016, Transition metal dichalcogenide atomic layers for lithium polysulfides electrocatalysis, J. Am. Chem. Soc., 139, 171, 10.1021/jacs.6b08681

Lin, 2017, Electrocatalysis of polysulfide conversion by sulfur-deficient MoS2 nanoflakes for lithium–sulfur batteries, Energy Environ. Sci., 10, 1476, 10.1039/C7EE01047H

Ye, 2017, A 3D hybrid of chemically coupled nickel sulfide and hollow carbon spheres for high performance lithium-sulfur batteries, Adv. Funct. Mater., 27, 1702524, 10.1002/adfm.201702524

Ding, 2015, Sulfur–carbon yolk–shell particle based 3D interconnected nanostructures as cathodes for rechargeable lithium–sulfur batteries, J. Mater. Chem. A, 3, 1853, 10.1039/C4TA05659K

Gao, 2019, Cobalt-doped SnS2 with dual active centers of synergistic absorption-catalysis effect for high-S loading Li-S batteries, Adv. Funct. Mater., 1806724, 10.1002/adfm.201806724

Lu, 2019, High performance bimetal sulfides for lithium-sulfur batteries, Chem. Eng. J., 358, 955, 10.1016/j.cej.2018.10.104

Guo, 2018, Self-supported FeCo2S4 nanotube Arrays as binder-free cathodes for lithium–sulfur batteries, ACS Appl. Mater. Interfaces, 10, 43707, 10.1021/acsami.8b16948

He, 2018, Vertical Co9S8 hollow nanowall arrays grown on a Celgard separator as a multifunctional polysulfide barrier for high-performance Li–S batteries, Energy Environ. Sci., 11, 2560, 10.1039/C8EE00893K

He, 2019, Freestanding 1T MoS2/graphene heterostructures as a highly efficient electrocatalyst for lithium polysulfides in Li–S batteries, Energy Environ. Sci., 12, 344, 10.1039/C8EE03252A

Zhou, 2017, Catalytic oxidation of Li2S on the surface of metal sulfides for Li−S batteries, Proc. Natl. Acad. Sci. U.S.A., 114, 840, 10.1073/pnas.1615837114

Furimsky, 2003, Metal carbides and nitrides as potential catalysts for hydroprocessing, Appl. Catal. Gen., 240, 1, 10.1016/S0926-860X(02)00428-3

Zhong, 2018, Confining sulfur in integrated composite scaffold with highly porous carbon fibers/vanadium nitride arrays for high-performance lithium-sulfur batteries, Adv. Funct. Mater., 1706391, 10.1002/adfm.201706391

Deng, 2017, Co4N nanosheet assembled mesoporous sphere as a matrix for ultrahigh sulfur content lithium–sulfur batteries, ACS Nano, 11, 6031, 10.1021/acsnano.7b01945

Jiang, 2018, Mesoporous, conductive molybdenum nitride as efficient sulfur hosts for high-performance lithium-sulfur batteries, J. Power Sources, 395, 77, 10.1016/j.jpowsour.2018.05.061

Luo, 2018, Multifunctional interlayer based on molybdenum diphosphide catalyst and carbon nanotube film for lithium-sulfur batteries, Small, 14, 1702853, 10.1002/smll.201702853

Huang, 2018, Regulating the polysulfide redox conversion by iron phosphide nanocrystals for high-rate and ultrastable lithium-sulfur battery, Nano Energy, 51, 340, 10.1016/j.nanoen.2018.06.052

Zhong, 2018, Surface chemistry in cobalt phosphide-stabilized lithium–sulfur batteries, J. Am. Chem. Soc., 140, 1455, 10.1021/jacs.7b11434

Chen, 2013, Recent developments in transition metal carbides and nitrides as hydrogen evolution electrocatalysts, Chem. Commun. (Camb), 49, 8896, 10.1039/c3cc44076a

Pang, 2019, Lightweight metallic MgB2 mediates polysulfide redox and promises high-energy-density lithium-sulfur batteries, Joule, 3, 136, 10.1016/j.joule.2018.09.024

Zhou, 2017, Twinborn TiO2–TiN heterostructures enabling smooth trapping–diffusion–conversion of polysulfides towards ultralong life lithium–sulfur batteries, Energy Environ. Sci., 10, 1694, 10.1039/C7EE01430A

Song, 2018, Synchronous immobilization and conversion of polysulfides on a VO2–VN binary host targeting high sulfur load Li–S batteries, Energy Environ. Sci., 11, 2620, 10.1039/C8EE01402G

Ye, 2018, 2D Mon-VN heterostructure to regulate polysulfides for highly efficient lithium-sulfur batteries, Angew. Chem. Int. Ed., 57, 16703, 10.1002/anie.201810579

Wang, 2019, Rational design of Co9S8/CoO heterostructures with well-defined interfaces for lithium sulfur batteries: a study of synergistic adsorption-electrocatalysis function, Nano Energy, 60, 332, 10.1016/j.nanoen.2019.03.060