A review on the current progress of metal hydrides material for solid-state hydrogen storage applications

International Journal of Hydrogen Energy - Tập 41 Số 28 - Trang 12108-12126 - 2016
N.A.A. Rusman1, Mahidzal Dahari2
1Department of Mechanical Engineering, Faculty of Engineering, University of Malaya, 50603 Lembah Pantai, Kuala Lumpur, Malaysia
2Department of Electrical Engineering, Faculty of Engineering, University of Malaya, 50603 Lembah Pantai, Kuala Lumpur, Malaysia

Tóm tắt

Từ khóa


Tài liệu tham khảo

Mahfuz, 2014, Exergetic analysis of a solar thermal power system with PCM storage, Energy Convers Manag, 78, 486, 10.1016/j.enconman.2013.11.016

Jain, 2012, Effect of La-content on the hydrogenation properties of the Ce1−xLaxNi3Cr2 (x=0.2, 0.4, 0.6, 0.8, 1) alloys, Int J Hydrogen Energy, 37, 3683, 10.1016/j.ijhydene.2011.03.101

Pang, 2013, Liquid absorption and solid adsorption system for household, industrial and automobile applications: a review, Renew Sustain Energy Rev, 28, 836, 10.1016/j.rser.2013.08.029

Ravnsbæk, 2009, A series of mixed-metal borohydrides, Angew Chem Int Ed, 48, 6659, 10.1002/anie.200903030

Ouyang, 2012, The controllable hydrolysis rate for LaMg12 hydride, Int J Hydrogen Energy, 37, 12358, 10.1016/j.ijhydene.2012.05.098

Demirbas, 2007, Storage and transportation opportunities of hydrogen, Energy Sources Part B Econ Plan Policy, 2, 287, 10.1080/15567240600629419

Ouyang, 2013, Excellent hydrolysis performances of Mg3RE hydrides, Int J Hydrogen Energy, 38, 2973, 10.1016/j.ijhydene.2012.12.092

Thomas, 2000

Ivancic, 2010, Discovery of a new Al species in hydrogen reactions of NaAlH4, J Phys Chem Lett, 1, 2412, 10.1021/jz1007998

Laversenne BBL. Hydrogen storage using borohydrides. Entropy 184:183.3–242.3.

Zou, 2013, Hydrogen storage properties of Mg–TM–La (TM = Ti, Fe, Ni) ternary composite powders prepared through arc plasma method, Int J Hydrogen Energy, 38, 8852, 10.1016/j.ijhydene.2013.05.007

Choudhury, 2009, Nano-Ni doped Li–Mn–B–H system as a new hydrogen storage candidate, Int J Hydrogen Energy, 34, 6325, 10.1016/j.ijhydene.2009.06.004

George, 2010, Structural stability of metal hydrides, alanates and borohydrides of alkali and alkali- earth elements: a review, Int J Hydrogen Energy, 35, 5454, 10.1016/j.ijhydene.2010.03.078

Principi, 2009, The problem of solid state hydrogen storage, Energy, 34, 2087, 10.1016/j.energy.2008.08.027

Zlotea, 2013, Role of nanoconfinement on hydrogen sorption properties of metal nanoparticles hybrids, Coll Surf A Physicochem Eng Asp, 439, 117, 10.1016/j.colsurfa.2012.11.043

Ouyang, 2007, A new type of Mg-based metal hydride with promising hydrogen storage properties, Int J Hydrogen Energy, 32, 3929, 10.1016/j.ijhydene.2007.05.026

Liu, 2014, Mg-based nanocomposites with improved hydrogen storage performances, Int J Hydrogen Energy, 39, 14262, 10.1016/j.ijhydene.2014.03.125

Aceves, 2013, Safe, long range, inexpensive and rapidly refuelable hydrogen vehicles with cryogenic pressure vessels, Int J Hydrogen Energy, 38, 2480, 10.1016/j.ijhydene.2012.11.123

Afonso, 2013, Hydrogen storage properties of the destabilized 4NaBH4/5Mg2NiH4 composite system, J Phys Chem C, 117, 21105, 10.1021/jp406619p

Shashikala, 2012, 15-Hydrogen storage materials, 607

Dillon, 1997, Storage of hydrogen in single-walled carbon nanotubes, Nature, 386, 377, 10.1038/386377a0

Pan, 2004, Microporous metal organic materials: promising candidates as sorbents for hydrogen storage, J Am Chem Soc, 126, 1308, 10.1021/ja0392871

Zhou, 2006, Studies on the mechanism and capacity of hydrogen uptake by physisorption-based materials, Int J Hydrogen Energy, 31, 259, 10.1016/j.ijhydene.2005.04.048

Ho, 2008, Three-dimensional analysis for liquid hydrogen in a cryogenic storage tank with heat pipe–pump system, Cryogenics, 48, 31, 10.1016/j.cryogenics.2007.09.005

Blackman, 2006, Activation of carbon nanofibres for hydrogen storage, Carbon, 44, 1376, 10.1016/j.carbon.2005.11.015

Aceves, 2006, Vehicular storage of hydrogen in insulated pressure vessels, Int J Hydrogen Energy, 31, 2274, 10.1016/j.ijhydene.2006.02.019

Wang, 2009, Three-dimensional modeling of hydrogen sorption in metal hydride hydrogen storage beds, J Power Sources, 194, 997, 10.1016/j.jpowsour.2009.06.060

Teichmann, 2012, Liquid Organic Hydrogen Carriers as an efficient vector for the transport and storage of renewable energy, Int J Hydrogen Energy, 37, 18118, 10.1016/j.ijhydene.2012.08.066

Hu, 2015, A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation, Nat Commun, 4

Wang, 2008, Hydrogen-rich boron-containing materials for hydrogen storage, Dalton Trans, 5400, 10.1039/b807162d

Hong, 2013, Hydrogen desorption and absorption properties of Pd and MgO or nano-sized Ni-added MgH2 + LiBH4 composites, Mater Res Bull, 48, 3453, 10.1016/j.materresbull.2013.05.030

Jain, 2007, Hydrogenation behaviour of Ce-based AB5 intermetallic compounds, J Alloys Compd, 440, 84, 10.1016/j.jallcom.2006.08.326

Jain, 2010, Hydrogen storage in Mg: a most promising material, Int J Hydrogen Energy, 35, 5133, 10.1016/j.ijhydene.2009.08.088

Ma, 2013, Ti–η2-(C2H2) and HCC–TiH as high capacity hydrogen storage media, Int J Hydrogen Energy, 38, 16185, 10.1016/j.ijhydene.2013.09.151

Sai Raman, 2002, Investigations on the synthesis, structural and microstructural characterizations of Mg-based K2PtCl6 type (Mg2FeH6) hydrogen storage material prepared by mechanical alloying, J Alloys Compd, 333, 282, 10.1016/S0925-8388(01)01729-7

Targets for Onboard Hydrogen Storage Systems for Light-duty Vehicles, Freedom Car and Fuel Partnership, US Department of Energy. [cited 2016 2 April]; Available from: http://energy.gov/eere/fuelcells/doe-technical-targets-onboard-hydrogen-storage-light-duty-vehicles.

Wu, 2013, Improvement in hydrogen storage characteristics of Mg-based metal hydrides by doping nonmetals with high electronegativity: a first-principle study, Comput Mater Sci, 78, 83, 10.1016/j.commatsci.2013.05.018

Varin, 2006, Particle size, grain size and γ-MgH2 effects on the desorption properties of nanocrystalline commercial magnesium hydride processed by controlled mechanical milling, Nanotechnology, 17, 3856, 10.1088/0957-4484/17/15/041

Gasiorowski, 2004, Hydriding properties of nanocrystalline Mg2−xMxNi alloys synthesized by mechanical alloying (M=Mn, Al), J Alloys Compd, 364, 283, 10.1016/S0925-8388(03)00544-9

Falahati, 2013, Evaluation of hydrogen sorption models for AB5-type metal alloys by employing a gravimetric technique, Int J Hydrogen Energy, 38, 8838, 10.1016/j.ijhydene.2013.04.148

Palewski, 2005, Hydrogenation process of the Gd3M (M = Ni or Co) intermetallics compound, J Alloys Compd, 404–406, 584, 10.1016/j.jallcom.2004.10.095

Pan, 2003, The structural and electrochemical properties of La0.7Mg0.3(Ni0.85Co0.15)x (x=3.0–5.0) hydrogen storage alloys, Int J Hydrogen Energy, 28, 1219, 10.1016/S0360-3199(02)00285-9

Okada, 2002, Role of intermetallics in hydrogen storage materials, Mater Sci Eng A, 329–331, 305, 10.1016/S0921-5093(01)01580-5

Szajek, 2007, Electrochemical and electronic properties of nanocrystalline Mg-based hydrogen storage materials, J Alloys Compd, 436, 345, 10.1016/j.jallcom.2006.07.043

Wang, 2014, Hydrogenation of AB5 and AB2 metal hydride alloys studied by in situ X-ray diffraction, J Alloys Compd, 616, 300, 10.1016/j.jallcom.2014.07.125

Borzone, 2013, Dynamic measurements of hydrogen reaction with LaNi5−xSnx alloys, Int J Hydrogen Energy, 38, 7335, 10.1016/j.ijhydene.2013.04.035

Gutfleisch, 2003, Hydrogenation properties of nanocrystalline Mg- and Mg2Ni-based compounds modified with platinum group metals (PGMs), J Alloys Compd, 356–357, 598, 10.1016/S0925-8388(02)01283-5

Sharma, 2014, Effect of measurement parameters on thermodynamic properties of La-based metal hydrides, Int J Hydrogen Energy, 39, 5888, 10.1016/j.ijhydene.2014.01.174

Prigent, 2012, Modification of the hydrogenation properties of LaNi5 upon Ni substitution by Rh, Ir, Pt or Au, J Alloys Compd, 511, 95, 10.1016/j.jallcom.2011.08.094

Georgiadis, 2009, Design and optimization of advanced materials and processes for efficient hydrogen storage, Comput Chem Eng, 33, 1077, 10.1016/j.compchemeng.2008.09.009

Zhu, 2011, Structural and electrochemical hydrogen storage properties of Mg2Ni-based alloys, J Alloys Compd, 509, 5309, 10.1016/j.jallcom.2011.02.017

Shcherbakova, 2013, Effects of particle size and type of conductive additive on the electrode performances of gas atomized AB5-type hydrogen storage alloy, Int J Hydrogen Energy, 38, 12133, 10.1016/j.ijhydene.2013.03.123

Denys, 2007, Hydrogen storage properties and structure of La1−xMgx(Ni1−yMny)3 intermetallics and their hydrides, J Alloys Compd, 446–447, 166, 10.1016/j.jallcom.2006.12.137

Ye, 2002, Effect of rare earth composition on the high-rate capability and low-temperature capacity of AB5-type hydrogen storage alloys, J Power Sources, 111, 145, 10.1016/S0378-7753(02)00297-5

Mitrokhin, 2013, Hydrogen interaction with intermetallic compounds and alloys at high pressure, J Alloys Compd, 580, S90, 10.1016/j.jallcom.2013.03.100

Jain, 2007, Characterization and hydrogenation of CeNi5−xCrx (x = 0, 1, 2) alloys, J Alloys Compd, 430, 165, 10.1016/j.jallcom.2006.05.013

Young, 2014, Effects of Cu-substitution on La0.62Ce0.38(NiCoMnAlSiZr)5.3 metal hydride alloy, J Alloys Compd, 588, 235, 10.1016/j.jallcom.2013.11.039

Ćirić, 2012, A study on crystal structure, bonding and hydriding properties of Ti–Fe–Ni intermetallics–Behind substitution of iron by nickel, Int J Hydrogen Energy, 37, 8408, 10.1016/j.ijhydene.2012.02.047

Endo, 2013, Formation of BCC TiFe hydride under high hydrogen pressure, Int J Hydrogen Energy, 38, 6726, 10.1016/j.ijhydene.2013.03.120

Cuevas, 2005, Relationship between polymorphism and hydrogenation properties in Ti0.64Zr0.36Ni alloy, J Alloys Compd, 404–406, 545, 10.1016/j.jallcom.2005.02.072

Han, 2001, Synthesis of composite metal hydride alloy of A2B and AB type by mechanical alloying, J Power Sources, 92, 157, 10.1016/S0378-7753(00)00516-4

Dai, 2013, Mechanical and electronic properties of A1−xBxHy (A and B = Ti, Zr, Hf) hydride alloys: a first-principles study, J Alloys Compd, 581, 404, 10.1016/j.jallcom.2013.07.117

Akamaru, 2014, Alloying effects on the hydrogen-storage capability of Pd–TM–H (TM = Cu, Au, Pt, Ir) systems, J Alloys Compd, 614, 238, 10.1016/j.jallcom.2014.06.118

Orgaz, 2001, The electronic structure of the Laves phase intermetallics LnM2 (Ln=Y, La–Lu, M=Mg, Al) and the LaMg2H7 and CeMg2H7 hydrides, J Alloys Compd, 322, 45, 10.1016/S0925-8388(01)01212-9

Maeda, 2013, Cyclic stability test of AB2 type (Ti, Zr)(Ni, Mn, V, Fe)2.18 for stationary hydrogen storage in water contaminated hydrogen, J Alloys Compd, 580, S255, 10.1016/j.jallcom.2013.03.230

Young, 2013, Hydrogen storage properties of ZrVxNi3.5−x (x = 0.0–0.9) metal hydride alloys, J Alloys Compd, 580, S171, 10.1016/j.jallcom.2013.02.087

Young, 2014, Different failure modes for V-containing and V-free AB2 metal hydride alloys, J Power Sources, 251, 170, 10.1016/j.jpowsour.2013.11.035

Young, 2013, Electrochemical performance of AB2 metal hydride alloys measured at −40 °C, J Alloys Compd, 580, S349, 10.1016/j.jallcom.2013.01.125

Zhao, 2012, Structure and electrochemical hydrogen storage properties of A 2 B-type Ti–Zr–Ni alloys, Int J Hydrogen Energy, 37, 5050, 10.1016/j.ijhydene.2011.12.010

Latroche, 2003, Structural and thermodynamic studies of some hydride forming RM3-type compounds (R=lanthanide, M=transition metal), J Alloys Compd, 356–357, 461, 10.1016/S0925-8388(03)00116-6

Wang, 2009, Effect of La–Mg-based alloy addition on structure and electrochemical characteristics of Ti0.10 Zr0.15V0.35Cr0.10Ni0.30 hydrogen storage alloy, Int J Hydrogen Energy, 34, 2646, 10.1016/j.ijhydene.2009.01.067

Yao, 2008, The isothermal section at 500 °C of the La–Ni–V ternary system, J Alloys Compd, 448, 195, 10.1016/j.jallcom.2006.10.037

Kumar, 2013, Hydrogen solid solution thermodynamics of V1−xAlx (x: 0, 0.18, 0.37, 0.52) alloys, Int J Hydrogen Energy, 38, 9928, 10.1016/j.ijhydene.2013.05.122

Pickering, 2013, Ti–V–Mn based metal hydrides for hydrogen storage, J Alloys Compd, 580, S233, 10.1016/j.jallcom.2013.03.208

Leng, 2006, Hydrogen storage properties of Li−Mg−N−H systems with different ratios of LiH/Mg(NH2)2, J Phys Chem B, 110, 12964, 10.1021/jp061120h

Srinivasan, 2008, Effects of catalysts doping on the thermal decomposition behavior of Zn(BH4)2, Int J Hydrogen Energy, 33, 2268, 10.1016/j.ijhydene.2008.02.062

Züttel, 2003, LiBH4 a new hydrogen storage material, J Power Sources, 118, 1, 10.1016/S0378-7753(03)00054-5

Ley, 2014, Complex hydrides for hydrogen storage – new perspectives, Mater Today, 17, 122, 10.1016/j.mattod.2014.02.013

Huang, 2006, Effects of iron oxide (Fe2O3, Fe3O4) on hydrogen storage properties of Mg-based composites, J Alloys Compd, 422, 299, 10.1016/j.jallcom.2005.11.074

Albanese, 2013, Theoretical and experimental study on Mg(BH4)2–Zn(BH4)2 mixed borohydrides, J Alloys Compd, 580, S282, 10.1016/j.jallcom.2013.02.165

Schuth, 2004, Light metal hydrides and complex hydrides for hydrogen storage, Chem Commun, 2249, 10.1039/B406522K

Srinivasan, 2004, Long term cycling behavior of titanium doped NaAlH4 prepared through solvent mediated milling of NaH and Al with titanium dopant precursors, J Alloys Compd, 377, 283, 10.1016/j.jallcom.2004.01.044

Iosub, 2009, Direct synthesis of Mg(AlH4)2 and CaAlH5 crystalline compounds by ball milling and their potential as hydrogen storage materials, Int J Hydrogen Energy, 34, 906, 10.1016/j.ijhydene.2008.11.013

Gross, 2002, Dynamic in situ X-ray diffraction of catalyzed alanates, J Alloys Compd, 330–332, 691, 10.1016/S0925-8388(01)01463-3

Wiench, 2004, Solid-state 27Al NMR investigation of thermal decomposition of LiAlH4, J Solid State Chem, 177, 648, 10.1016/j.jssc.2003.08.006

Akbarzadeh, 2009, First-principles determination of crystal structures, phase stability, and reaction thermodynamics in the Li-Mg-Al-H hydrogen storage system, Phys Rev B, 79, 184102, 10.1103/PhysRevB.79.184102

Tang, 2007, Hydrogen storage properties of Na–Li–Mg–Al–H complex hydrides, J Alloys Compd, 446–447, 228, 10.1016/j.jallcom.2006.12.089

Mosher, 2007, Design, fabrication and testing of NaAlH4 based hydrogen storage systems, J Alloys Compd, 446–447, 707, 10.1016/j.jallcom.2007.01.042

Thomas, 2002, Microstructural characterization of catalyzed NaAlH4, J Alloys Compd, 330–332, 702, 10.1016/S0925-8388(01)01538-9

Bogdanović, 2009, Hydrogen storage in complex metal hydrides, J Serbian Chem Soc, 74, 183, 10.2298/JSC0902183B

Eberle, 2006, Hydrogen storage in metal–hydrogen systems and their derivatives, J Power Sources, 154, 456, 10.1016/j.jpowsour.2005.10.050

Jensen, 2001, Development of catalytically enhanced sodium aluminum hydride as a hydrogen-storage material, Appl Phys A, 72, 213, 10.1007/s003390100784

Callini, 2013, The role of Ti in alanates and borohydrides: catalysis and metathesis, J Phys Chem C, 118, 77, 10.1021/jp407999r

Urbanczyk, 2014, Aluminium alloy based hydrogen storage tank operated with sodium aluminium hexahydride Na3AlH6, Int J Hydrogen Energy, 39, 17118, 10.1016/j.ijhydene.2014.08.101

Gao, 2010, Confinement of NaAlH4 in nanoporous carbon: impact on H2 release, reversibility, and thermodynamics, J Phys Chem C, 114, 4675, 10.1021/jp910511g

Barkhordarian, 2007, Unexpected kinetic effect of MgB2 in reactive hydride composites containing complex borohydrides, J Alloys Compd, 440, L18, 10.1016/j.jallcom.2006.09.048

Vittetoe, 2009, Destabilization of LiAlH4 by nanocrystalline MgH2, Int J Hydrogen Energy, 34, 2333, 10.1016/j.ijhydene.2009.01.025

Xiong, 2007, Reversible hydrogen storage by a Li–Al–N–H complex, Adv Funct Mater, 17, 1137, 10.1002/adfm.200600759

Srinivasa Murthy, 2014, Advanced materials for solid state hydrogen storage: “Thermal engineering issues”, Appl Therm Eng, 72, 176, 10.1016/j.applthermaleng.2014.04.020

Nickels, 2008, Tuning the decomposition temperature in complex hydrides: synthesis of a mixed alkali metal borohydride, Angew Chem Int Ed, 47, 2817, 10.1002/anie.200704949

Arnbjerg, 2009, Structure and dynamics for LiBH4−LiCl solid solutions, Chem Mater, 21, 5772, 10.1021/cm902013k

Ichikawa, 2005, Composite materials based on light elements for hydrogen storage, Mater Trans, 46, 1, 10.2320/matertrans.46.1

Nakamori, 2004, Destabilization of Li-based complex hydrides, J Alloys Compd, 370, 271, 10.1016/j.jallcom.2003.08.089

Pinkerton, 2008, Reversible hydrogen storage in the lithium borohydride—calcium hydride coupled system, J Alloys Compd, 464, L1, 10.1016/j.jallcom.2007.09.125

Jeon, 2006, Mechanochemical synthesis and thermal decomposition of zinc borohydride, J Alloys Compd, 422, 273, 10.1016/j.jallcom.2005.11.045

Christensen, 2005, Metal ammine complexes for hydrogen storage, J Mater Chem, 15, 4106, 10.1039/b511589b

Smythe, 2010, Ammonia borane as a hydrogen carrier: dehydrogenation and regeneration, Eur J Inorg Chem, 2010, 509, 10.1002/ejic.200900932

Hwang, 2010, Hydrogen for vehicle applications from hydrothermolysis of ammonia borane: hydrogen yield, thermal characteristics, and ammonia formation, Ind Eng Chem Res, 49, 10994, 10.1021/ie100520r

Yang, 2010, High capacity hydrogen storage materials: attributes for automotive applications and techniques for materials discovery, Chem Soc Rev, 39, 656, 10.1039/B802882F

Kang, 2012, Efficient and highly rapid hydrogen release from ball-milled 3NH3BH3/MMgH3 (M = Na, K, Rb) mixtures at low temperatures, Int J Hydrogen Energy, 37, 4259, 10.1016/j.ijhydene.2011.11.111

Lee, 2009, Mechanistic study of LiNH2BH3 formation from (LiH)4 + NH3BH3 and subsequent dehydrogenation, Inorg Chem, 48, 7564, 10.1021/ic9001835

Wang, 2013, Theoretical study on the structure and dehydrogenation mechanism of mixed metal amidoborane, Na[Li(NH2BH3)]2, J Alloys Compd, 581, 59, 10.1016/j.jallcom.2013.07.022

Himmelberger, 2009, Base-promoted ammonia borane hydrogen-release, J Am Chem Soc, 131, 14101, 10.1021/ja905015x

Andreasen, 2008, Hydrogenation properties of Mg–Al alloys, Int J Hydrogen Energy, 33, 7489, 10.1016/j.ijhydene.2008.09.095

Aburto, 2007, Ab initio structural and electronic investigation of magnetic R Ni Sn (R=La, Ce, Pr, Nd) intermetallics and their hydrides, Phys Rev B, 75, 045130, 10.1103/PhysRevB.75.045130

de Castro, 2004, Structural characterization and dehydrogenation behavior of Mg–5 at.%Nb nano-composite processed by reactive milling, J Alloys Compd, 376, 251, 10.1016/j.jallcom.2004.01.021

Dornheim, 2007, Hydrogen storage in magnesium-based hydrides and hydride composites, Scr Mater, 56, 841, 10.1016/j.scriptamat.2007.01.003

Shao, 2008, Preparation of Mg-based hydrogen storage materials from metal nanoparticles, J Alloys Compd, 465, 527, 10.1016/j.jallcom.2007.11.003

Liang, 2004, Synthesis and hydrogen storage properties of Mg-based alloys, J Alloys Compd, 370, 123, 10.1016/j.jallcom.2003.09.031

Ponthieu, 2014, Thermodynamics and reaction pathways of hydrogen sorption in Mg6(Pd,TM) (TM = Ag, Cu and Ni) pseudo-binary compounds, Int J Hydrogen Energy, 39, 18291, 10.1016/j.ijhydene.2014.09.034

Kalisvaart, 2010, Hydrogen storage in binary and ternary Mg-based alloys: a comprehensive experimental study, Int J Hydrogen Energy, 35, 2091, 10.1016/j.ijhydene.2009.12.013

Yermakov, 2006, Hydrogen reaction kinetics of Mg-based alloys synthesized by mechanical milling, J Alloys Compd, 425, 367, 10.1016/j.jallcom.2006.01.039

Prigent, 2007, Ab initio study of the hydrogenation properties of Mg-based binary and ternary compounds Mg2X (X = Ni, Si) and YMgNi4, J Alloys Compd, 446–447, 90, 10.1016/j.jallcom.2006.11.104

Ouyang, 2014, Comparative investigation on the hydrogenation/dehydrogenation characteristics and hydrogen storage properties of Mg3Ag and Mg3Y, Int J Hydrogen Energy, 39, 13616, 10.1016/j.ijhydene.2014.02.135

He, 2008, Preparation and electrochemical properties of MgNi–MB (M = Co, Ti) composite alloys, J Alloys Compd, 450, 375, 10.1016/j.jallcom.2006.10.127

Chen, 2013, Hydrogen storage properties and thermal stability of amorphous Mg70(RE25Ni75)30 alloys, J Alloys Compd, 563, 1, 10.1016/j.jallcom.2013.01.159

Liu, 2014, Improved hydrogen storage properties of Mg-based nanocomposite by addition of LaNi5 nanoparticles, Int J Hydrogen Energy, 39, 18273, 10.1016/j.ijhydene.2014.03.041

Oelerich, 2001, Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mg-based materials, J Alloys Compd, 315, 237, 10.1016/S0925-8388(00)01284-6

Mirabile Gattia, 2014, Microstructure and kinetics evolution in MgH2–TiO2 pellets after hydrogen cycling, J Alloys Compd, 615, S689, 10.1016/j.jallcom.2013.12.003

Deledda, 2011, Hydride formation in Mg-based systems processed by reactive milling, Faraday Discuss, 151, 315, 10.1039/c1fd00023c

Milanese, 2010, Mg–Ni–Cu mixtures for hydrogen storage: a kinetic study, Intermetallics, 18, 203, 10.1016/j.intermet.2009.07.012

Molinas, 2009, Scaled-up production of a promising Mg-based hydride for hydrogen storage, Int J Hydrogen Energy, 34, 4597, 10.1016/j.ijhydene.2008.09.076

Zhang, 2002, The reduction of cycling capacity degradation of Mg–Ni-based electrode alloys by Fe substitution, Int J Hydrogen Energy, 27, 501, 10.1016/S0360-3199(01)00182-3

Akiba, 1999, Hydrogen-absorbing alloys, Curr Opin Solid State Mater Sci, 4, 267, 10.1016/S1359-0286(99)00026-1

Bobet, 2002, Hydrogen sorption of Mg-based mixtures elaborated by reactive mechanical grinding, J Alloys Compd, 336, 292, 10.1016/S0925-8388(01)01883-7

Fujii, 1997, Cooperative hydriding properties in a nanostructured Mg2Ni–H system, J Alloys Compd, 253–254, 80, 10.1016/S0925-8388(96)03058-7