A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research
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Papageorgopoulos D. DOE fuel cell technology program overview and introduction to the 2010 fuel cell pre-solicitation workshop in DOE fuel cell pre-solicitation workshop. Department of Energy, Lakewood, Colorado; 2010.
Wand G. Fuel cell history, Part One. 14.
Appleby, 1986, Solid polymer electrolyte fuel cells (SPEFCs), Energy, 11, 137
Raistrick ID. Modified gas diffusion electrode for proton exchange membrane fuel cells. In: Proceedings of the symposium on diaphragms, separation, and ion-exchange membranes. Ponnington (NJ): Electrochemical Society; 1986.
Gittleman C, DM, Jorgensen S, Waldecker J, Hirano S, Mehall M. Automotive fuel cell R&D needs. In: DOE fuel cell pre-solicitation workshop. Department of Energy, Lakewood, Colorado; 2010.
Garche, 2003, PEMFC fuel cell
Geiger, 2003, Fuel cell small stationary market survey, Fuel Cell Today
EERE UD. Hydrogen, fuel cells & infrastructure technologies program multi-year research, development and demonstration plan. In: EERE D, editor. 2007. p. 24.
Pander J. Hamburg speeds up preparation for fuel-cell cars. In: Spiegel. SPIEGELnet GmbH Hamburg; 2009.
DeMatio J. Kia’s big fuel cell plans. In: Automobile magazine; 2009.
Toyota, Toyota advanced fuel cell hybrid vehicle completes Government Field Evaluation. In: PRNewswire; 2009.
Zhang, 2009, A review of accelerated stress tests of MEA durability in PEM fuel cells, Int J Hydrogen Energy, 34, 388, 10.1016/j.ijhydene.2008.10.012
Borup R, et al. PEM fuel cell durability. 2008 DOE hydrogen program review June 9–13, 2008, 5. <http://www.hydrogen.energy.gov/pdfs/review08/fc_26_borup.pdf>.
Schmittinger, 2008, A review of the main parameters influencing long-term performance and durability of PEM fuel cells, J Power Sources, 180, 1, 10.1016/j.jpowsour.2008.01.070
Borup, 2007, Scientific aspects of polymer electrolyte fuel cell durability and degradation, Chem Rev, 107, 3904, 10.1021/cr050182l
Wood, 2009, 159
DOE. Hydrogen and fuel cell activities, progress, and plans: report to congress; January 2009, 4. <http://www.hydrogen.energy.gov/pdfs/epact_report_sec811.pdf>.
Directed technologies I. Mass production cost estimation for direct H2 PEM fuel cell systems for automotive applications: 2008 update 2009. p. 10.
DOE-EERE. Fuel cell technology challenges; 2008. <http://www1.eere.energy.gov/hydrogenandfuelcells/fuelcells/fc_challenges.html>.
Lipman, 2003, Market concepts, competing technologies and cost challenges for automotive and stationary applications, 1318
McNicol, 2001, Fuel cells for road transportation purposes – yes or no, J Power Sources, 100, 47, 10.1016/S0378-7753(01)00882-5
Stumper, 2008, Recent advances in fuel cell technology at Ballard, J Power Sources, 176, 468, 10.1016/j.jpowsour.2007.08.071
Kazim, 2003, Introduction of PEM fuel-cell vehicles in the transportation sector of the United Arab Emirates, Appl Energy, 74, 125, 10.1016/S0306-2619(02)00138-1
Jones, R. Honda FCX a step forward for fuel-cell cars. MSNBC 2007. <http://www.msnbc.msn.com/id/21796636/>.
Vann M. Chevrolet project driveway fuel cell program passes 1 million miles this week. GM fastlane blog; 2009 <http://fastlane.gmblogs.com/archives/2009/09/chevrolet_project_driveway_fuel_cell_program_passes_1_million_miles_this_week.html> [02.12.09].
Jerram, 2009, 2009 Light duty vehicle survey, Fuel Cell Today
Haraldsson, 2005, Fuel cell buses in the Stockholm CUTE project – first experiences from a climate perspective, J Power Sources, 145, 620, 10.1016/j.jpowsour.2004.12.081
Jerram, 2008, 2008 Bus survey, Fuel Cell Today
Adamson, 2009, 2009 Niche transport survey, Fuel Cell Today, 11
Hwang, 2005, Development of a lightweight fuel cell vehicle, J Power Sources, 141, 108, 10.1016/j.jpowsour.2004.08.056
Beckhaus, 2005, On-board fuel cell power supply for sailing yachts, J Power Sources, 145, 639, 10.1016/j.jpowsour.2004.12.078
Siemens. Italian navy orders two more submarines with Siemens fuel cell technology; 2009 <http://w1.siemens.com/press/en/pressrelease/?press=/en/pressrelease/2009/industry_solutions/iis200910926.htm> [10.05.09, 02.12.10].
Jerram, 2009, 2009 Hydrogen infrastructure survey, Fuel Cell Today
Wang, 2009, Three-dimensional modeling of hydrogen sorption in metal hydride hydrogen storage beds, J Power Sources, 194, 997, 10.1016/j.jpowsour.2009.06.060
Collins, 2007, Hydrogen storage in metal–organic frameworks, J Mater Chem, 17
Züttel, 2007, Tetrahydroborates as new hydrogen storage materials, Scripta Mater, 56, 823, 10.1016/j.scriptamat.2007.01.010
Bérubé, 2007, Size effects on the hydrogen storage properties of nanostructured metal hydrides: a review, Int J Energy Res, 31, 637, 10.1002/er.1284
Askri, 2009, Optimization of hydrogen storage in metal–hydride tanks, Int J Hydrogen Energy, 34, 897, 10.1016/j.ijhydene.2008.11.021
Butler, 2009, Portable fuel cell survey 2009, Fuel Cell Today
Narayanan SR, Valdez TI, Rohatgi N. Portable direct methanol fuel cell system. In: Vielstich W, Gasteiger HA, Lamm A, editor. Handbook of fuel cells. John Wiley and Sons; 2003.
Hayase, 2004, Miniature 250 μm thick fuel cell with monolithically fabricated silicon electrodes, Electrochem Solid-State Lett, 7, A231, 10.1149/1.1756859
Lee, 2005, Electroforming of metallic bipolar plates with micro-featured flow field, J Power Sources, 145, 369, 10.1016/j.jpowsour.2004.12.072
Ito, 2009, Fabrication and characterization of a thin μ-PEMFC with microfabricated grooves on electroformed current collector plate, Electrochem Solid-State Lett, 12, B154, 10.1149/1.3202382
Hahn, 2004, Development of a planar micro fuel cell with thin film and micro patterning technologies, J Power Sources, 131, 73, 10.1016/j.jpowsour.2004.01.015
Cha, 2004, The scaling behavior of flow patterns: a model investigation, J Power Sources, 134, 57, 10.1016/j.jpowsour.2004.03.036
Park, 2006, Design, fabrication, and initial testing of a miniature PEM fuel cell with micro-scale pyrolyzed carbon fluidic plates, J Power Sources, 162, 369, 10.1016/j.jpowsour.2006.06.077
Lin, 2008, Development and characterization of a miniature PEM fuel cell stack with carbon bipolar plates, J Power Sources, 176, 207, 10.1016/j.jpowsour.2007.10.079
Wang, 2010, Fabrication and characterization of micro PEM fuel cells using pyrolyzed carbon current collector plates, J Power Sources, 10.1016/j.jpowsour.2010.02.050
SiewHwa, 2005, Development of a polymeric micro fuel cell containing laser-micromachined flow channels, J Micromech Microeng, 15, 231, 10.1088/0960-1317/15/1/032
Müller, 2003, Micro-structured flow fields for small fuel cells, Microsyst Technol, 9, 159, 10.1007/s00542-001-0136-8
Yeom, 2005, Microfabrication and characterization of a silicon-based millimeter scale, PEM fuel cell operating with hydrogen, methanol, or formic acid, Sens Actuat B: Chem, 107, 882, 10.1016/j.snb.2004.12.050
Heinzel, 2002, Fuel cells for low power applications, J Power Sources, 105, 250, 10.1016/S0378-7753(01)00948-X
Henriques, 2010, Increasing the efficiency of a portable PEM fuel cell by altering the cathode channel geometry: a numerical and experimental study, Appl Energy, 87, 1400, 10.1016/j.apenergy.2009.09.001
Feitelberg, 2005, Reliability of plug power Gensys(TM) fuel cell systems, J Power Sources, 147, 203, 10.1016/j.jpowsour.2005.01.012
Plug power, SFO technologies sign GenSys manufacture, supply deal for India. Fuel Cells Bull 2009; 2009(12): 9–9.
Ballard. PEM fuel cell product portfolio; 2009.
Ballard looks to double shipments in 2009 for forklifts, backup power. Fuel Cells Bull 2009; 2009(3): 8–9.
Matsumura I. Toward a low-carbon society with hydrogen energy system – development of residential fuel cell system and fuel cell vehicle/hydrogen supply infrastructure. In: 6th Int. hydrogen & fuel cell expo keynote, Tokyo; 2010.
World’s largest ‘hydrogen town project’ starts in Japan; 2009. <http://www.japanfs.org/en/pages/028694.html>.
6 Japan firms to launch home fuel cell sales; 2009. <http://www.fuelcelltoday.com/online/news/articles/2009-01/ene-system>.
Wang, 2005, Development and performance of 5kW proton exchange membrane fuel cell stationary power system, Int J Hydrogen Energy, 30, 1031, 10.1016/j.ijhydene.2004.11.010
Ladewig, 2009, Analysis of the ripple current in a 5kW polymer electrolyte membrane fuel cell stack, Fuel Cells, 9, 157, 10.1002/fuce.200800049
Hwang, 2010, Development of a proton exchange membrane fuel cell cogeneration system, J Power Sources, 195, 2579, 10.1016/j.jpowsour.2009.10.087
Adamson, 2009, Fuel cell today small stationary survey 2009, Fuel Cell Today, 11
Gurau, 2009, A critical overview of computational fluid dynamics multiphase models for proton exchange membrane fuel cells, SIAM J Appl Math, 70, 410, 10.1137/080727993
Siegel, 2008, Review of computational heat and mass transfer modeling in polymer-electrolyte-membrane (PEM) fuel cells, Energy, 33, 1331, 10.1016/j.energy.2008.04.015
Djilali, 2007, Computational modelling of polymer electrolyte membrane (PEM) fuel cells: challenges and opportunities, Energy, 32, 269, 10.1016/j.energy.2006.08.007
Wang, 2008, Modeling two-phase flow in PEM fuel cell channels, J Power Sources, 179, 603, 10.1016/j.jpowsour.2008.01.047
Ma, 2004, Conductivity of PBI membranes for high-temperature polymer electrolyte fuel cells, J Electrochem Soc, 151, A8, 10.1149/1.1630037
Zhang, 2006, High temperature PEM fuel cells, J Power Sources, 160, 872, 10.1016/j.jpowsour.2006.05.034
Smitha, 2005, Solid polymer electrolyte membranes for fuel cell applications – a review, J Membrane Sci, 259, 10, 10.1016/j.memsci.2005.01.035
Arcella, 2006, Membrane electrode assemblies based on perfluorosulfonic ionomers for an evolving fuel cell technology, Desalination, 199, 6, 10.1016/j.desal.2006.03.128
Merlo, 2007, Membrane electrode assemblies based on HYFLON ion for an evolving fuel cell technology – separation science and technology, Separat Sci Technol, 42, 2891, 10.1080/01496390701558334
Li, 2009, High temperature proton exchange membranes based on polybenzimidazoles for fuel cells, Prog Polym Sci, 34, 449, 10.1016/j.progpolymsci.2008.12.003
Atkinson, 2005, Membranes for fuel cells compared in real time, Membrane Technol, 2005, 5, 10.1016/S0958-2118(05)00299-5
Gierke TD, Hsu WY. Perfluorinated ionomer membranes. In: Eisenberg A, Yeager HL, editors. ACS symposium series No. 180. American Chemical Society: Washington, DC; 1982.
Kreuer, 1982, Vehicle mechanism, a new model for the interpretation of the conductivity of fast proton conductors, Angew Chem Int Ed Engl, 21, 208, 10.1002/anie.198202082
Springer, 1991, Polymer electrolyte fuel cell model, J Electrochem Soc, 138, 2334, 10.1149/1.2085971
Cappadonia, 1994, Proton conduction of Nafion® 117 membrane between 140K and room temperature, J Electroanal Chem, 376, 189, 10.1016/0022-0728(94)03586-5
Wang, 2010, Cold start of polymer electrolyte fuel cells: three-stage startup characterization, Electrochim Acta, 55, 2636, 10.1016/j.electacta.2009.12.029
Thompson, 2006, Investigation of low-temperature proton transport in Nafion using direct current conductivity and differential scanning calorimetry, J Electrochem Soc, 153, A2351, 10.1149/1.2359699
Cappadonia, 1995, Conductance of Nafion 117 membranes as a function of temperature and water content, Solid State Ionics, 77, 65, 10.1016/0167-2738(94)00289-5
Zawodzinski, 1993, A comparative study of water uptake by and transport through ionomeric fuel cell membranes, J Electrochem Soc, 140, 1981, 10.1149/1.2220749
Ren, 2000, Water and methanol uptakes in Nafion membranes and membrane effects on direct methanol cell performance, J Electrochem Soc, 147, 92, 10.1149/1.1393161
Freger, 2008, Hydration of ionomers and schroeder’s paradox in Nafion, J Phys Chem B, 113, 24, 10.1021/jp806326a
Elfring, 2008, Thermodynamics of pore wetting and swelling in Nafion, J Membrane Sci, 315, 125, 10.1016/j.memsci.2008.02.016
Chen KS, Hickner MA. A new constitutive model for predicting proton conductivity in polymer electrolytes. In: ASME proceedings of IMECE’04, paper #60848; 2004.
Motupally, 2000, Diffusion of water in Nafion 115 membranes, J Electrochem Soc, 147, 3171, 10.1149/1.1393879
Ise, 1999, Electroosmotic drag in polymer electrolyte membranes: an electrophoretic NMR study, Solid State Ionics, 125, 213, 10.1016/S0167-2738(99)00178-2
Zawodzinski, 1993, Characterization of polymer electrolytes for fuel cell applications, Solid State Ionics, 60, 199, 10.1016/0167-2738(93)90295-E
Fuller, 1992, Experimental determination of the transport number of water in Nafion 117 membrane, J Electrochem Soc, 139, 1332, 10.1149/1.2069407
Xie, 1995, Water transport behavior in Nafion 117 membranes, J Electrochem Soc, 142, 3057, 10.1149/1.2048686
Ge, 2006, Experimental determination of electro-osmotic drag coefficient in Nafion membrane for fuel cells, J Electrochem Soc, 153, A1443, 10.1149/1.2203934
Ye, 2007, Measurement of water transport properties through membrane-electrode assemblies, J Electrochem Soc, 154, B676, 10.1149/1.2737379
Adachi, 2009, Correlation of in situ and ex situ measurements of water permeation through Nafion NRE211 proton exchange membranes, J Electrochem Soc, 156, B782, 10.1149/1.3116922
Bernardi, 1992, A mathematical model of the solid-polymer-electrolyte fuel cell, J Electrochem Soc, 139, 2477, 10.1149/1.2221251
Büchi, 1996, Microelectrode investigation of oxygen permeation in perfluorinated proton exchange membranes with different equivalent weights, J Electrochem Soc, 143, 927, 10.1149/1.1836560
Zawodzinski, 1995, The water content dependence of electro-osmotic drag in proton-conducting polymer electrolytes, Electrochim Acta, 40, 297, 10.1016/0013-4686(94)00277-8
Chen KS et al. Final report on LDRD project: elucidating performance of proton-exchange-membrane fuel cells via computational modeling with experimental discovery and validation, in SAND2006-6964, Sandia Technical Report; 2006.
Chen KS, Hickner MA. A new constitutive model for predicting proton conductivity in polymer electrolytes. In: Proceedings of 2004 international mechanical engineering congress and exhibits; 2004.
Weber, 2003, Transport in polymer-electrolyte membranes, J Electrochem Soc, 150, A1008, 10.1149/1.1580822
Weber, 2004, Transport in polymer-electrolyte membranes, J Electrochem Soc, 151, A311, 10.1149/1.1639157
Yu, 2005, PtCo/C cathode catalyst for improved durability in PEMFCs, J Power Sources, 144, 11, 10.1016/j.jpowsour.2004.11.067
Reiner A et al. Co-sputtering: a novel platinum–carbon catalyst preparation method. In: 3rd European PEFC forum, Lucerne; 2005. Poster 109.
Ismagilov, 2005, Development of active catalysts for low Pt loading cathodes of PEMFC by surface tailoring of nanocarbon materials, Catal Today, 102–103, 58, 10.1016/j.cattod.2005.02.007
Fernandez, 2004, Thermodynamic guidelines for the design of bimetallic catalysts for oxygen electroreduction and rapid screening by scanning electrochemical microscopy. M–Co (M: Pd, Ag, Au), J Am Chem Soc, 127, 357, 10.1021/ja0449729
González-Huerta, 2006, Electrocatalysis of oxygen reduction on carbon supported Ru-based catalysts in a polymer electrolyte fuel cell, J Power Sources, 153, 11, 10.1016/j.jpowsour.2005.03.188
Rao, 2005, Chemical and electrochemical depositions of platinum group metals and their applications, Coord Chem Rev, 249, 613, 10.1016/j.ccr.2004.08.015
Pharkya, 2005, Fabrication using high-energy ball-milling technique and characterization of Pt–Co electrocatalysts for oxygen reduction in polymer electrolyte fuel cells, J Fuel Cell Sci Technol, 2, 171, 10.1115/1.1895985
Travitsky N et al. Nanometric platinum and platinum-alloy-supported catalysts for oxygen reduction in PEM fuel cells. In: 3rd European PEFC forum, Lucerne, Switzerland; 2005.
Wells P et al., Preparation of Cr/Pt/C catalysts by the controlled surface modification of Pt/C using an organometallic precursor. In: 3rd European PEFC forum, Lucerne, Switzerland; 2005.
Debe MK. Advanced cathode catalysts and supports for PEM fuel cells. In: 2010 Hydrogen program annual merit review and peer evaluation meeting. Washington, DC; 2010.
Vante, 1986, Energy conversion catalysis using semiconducting transition metal cluster compounds, Nature, 323, 431, 10.1038/323431a0
Fernandez, 2005, Pd–Ti and Pd–Co–Au electrocatalysts as a replacement for platinum for oxygen reduction in proton exchange membrane fuel cells, J Am Chem Soc, 127, 13100, 10.1021/ja0534710
Bashyam, 2006, A class of non-precious metal composite catalysts for fuel cells, Nature, 443, 63, 10.1038/nature05118
Bezerra, 2008, A review of Fe–N/C and Co–N/C catalysts for the oxygen reduction reaction, Electrochim Acta, 53, 4937, 10.1016/j.electacta.2008.02.012
Wang, 2005, Recent development of non-platinum catalysts for oxygen reduction reaction, J Power Sources, 152, 1, 10.1016/j.jpowsour.2005.05.098
Zelenay P. Advanced cathode catalysts. In: 2010 Hydrogen program annual merit review and peer evaluation meeting, Washington, DC; 2010.
Eisman, 1986, Separators and ion-exchange membranes, Electrochem Soc Proc, 86, 186
Gottesfeld, 1988, A new approach to the problem of carbon monoxide poisoning in fuel cells operating at low temperatures, J Electrochem Soc, 135, 2651, 10.1149/1.2095401
Dhathathreyan, 2006
Mukherjee, 2007, Direct numerical simulation modeling of bilayer cathode catalyst layers in polymer electrolyte fuel cells, J Electrochem Soc, 154, B1121, 10.1149/1.2776221
Wang, 2008, Analysis of reaction rates in the cathode electrode of polymer electrolyte fuel cell I. Single-layer electrodes, J Electrochem Soc, 155, B1289, 10.1149/1.2988763
Wang, 2006, Direct numerical simulation (DNS) modeling of PEFC electrodes: Part I. Regular microstructure, Electrochim Acta, 51, 3139, 10.1016/j.electacta.2005.09.002
Wang, 2006, Direct numerical simulation (DNS) modeling of PEFC electrodes: Part II. Random microstructure, Electrochim Acta, 51, 3151, 10.1016/j.electacta.2005.09.003
Mukherjee, 2006, Stochastic microstructure reconstruction and direct numerical simulation of the PEFC catalyst layer, J Electrochem Soc, 153, A840, 10.1149/1.2179303
Song, 2004, Numerical study of PEM fuel cell cathode with non-uniform catalyst layer, Electrochim Acta, 50, 731, 10.1016/j.electacta.2004.01.114
Wang, 2009, Analysis of the reaction rates in the cathode electrode of polymer electrolyte fuel cells, J Electrochem Soc, 156, B403, 10.1149/1.3056057
Yoon, 2003, A multi-layer structured cathode for the PEMFC, J Power Sources, 118, 189, 10.1016/S0378-7753(03)00092-2
Ferreira, 2005, Instability of Pt/C electrocatalysts in proton exchange membrane fuel cells, J Electrochem Soc, 152, A2256, 10.1149/1.2050347
Borup, 2006, PEM fuel cell electrocatalyst durability measurements, J Power Sources, 163, 76, 10.1016/j.jpowsour.2006.03.009
Yasuda, 2006, Platinum dissolution and deposition in the polymer electrolyte membrane of a PEM fuel cell as studied by potential cycling, Phys Chem Chem Phys, 8, 746, 10.1039/B514342J
Kim, 2008, Dissolution and migration of platinum after long-term operation of a polymer electrolyte fuel cell under various conditions, J Power Sources, 183, 524, 10.1016/j.jpowsour.2008.05.062
Yasuda, 2006, Characteristics of a platinum black catalyst layer with regard to platinum dissolution phenomena in a membrane electrode assembly, J Electrochem Soc, 153, A1599, 10.1149/1.2210590
Wang, 2006, Effect of voltage on platinum dissolution, Electrochem Solid-State Lett, 9, A225, 10.1149/1.2180536
Akita, 2006, Analytical TEM study of Pt particle deposition in the proton-exchange membrane of a membrane-electrode-assembly, J Power Sources, 159, 461, 10.1016/j.jpowsour.2005.10.111
Garzon, 2006, The impact of hydrogen fuel contaminates on long-term PMFC performance, ECS Trans, 3, 695, 10.1149/1.2356190
Zhang, 2009, A review of platinum-based catalyst layer degradation in proton exchange membrane fuel cells, J Power Sources, 194, 588, 10.1016/j.jpowsour.2009.06.073
Uribe, 2002, Effect of ammonia as potential fuel impurity on proton exchange membrane fuel cell performance, J Electrochem Soc, 149, A293, 10.1149/1.1447221
Zamel, 2008, Transient analysis of carbon monoxide poisoning and oxygen bleeding in a PEM fuel cell anode catalyst layer, Int J Hydrogen Energy, 33, 1335, 10.1016/j.ijhydene.2007.12.060
Chen, 2008, Improvement of CO tolerance of proton exchange membrane fuel cell by an air-bleeding technique, J Fuel Cell Sci Technol, 5, 014501, 10.1115/1.2784278
Shah, 2007, A transient PEMFC model with CO poisoning and mitigation by O2 bleeding and Ru-containing catalyst, J Power Sources, 166, 1, 10.1016/j.jpowsour.2007.01.020
Franco, 2009, Impact of carbon monoxide on PEFC catalyst carbon support degradation under current-cycled operating conditions, Electrochim Acta, 54, 5267, 10.1016/j.electacta.2009.04.001
Wan, 2006, Novel composite anode with CO “Filter” layers for PEFC, J Power Sources, 162, 41, 10.1016/j.jpowsour.2006.06.074
Siegel NP. Development and validation of a computational model for a proton exchange membrane fuel cell. In: Ph.D. dissertation. Virginia Polytechnic Institute and State University: Blacksburg, VA; 2003.
Siegel, 2003, Single domain PEMFC model based on agglomerate catalyst geometry, J Power Sources, 115, 81, 10.1016/S0378-7753(02)00622-5
Harvey, 2006
Harvey, 2008, A comparison of different approaches to modelling the PEMFC catalyst layer, J Power Sources, 179, 209, 10.1016/j.jpowsour.2007.12.077
Marr, 1999, Composition and performance modelling of catalyst layer in a proton exchange membrane fuel cell, J Power Sources, 77, 17, 10.1016/S0378-7753(98)00161-X
Schwarz, 2007, 3D modeling of catalyst layers in PEM fuel cells, J Electrochem Soc, 154, B1167, 10.1149/1.2777011
Shah, 2007, Transient non-isothermal model of a polymer electrolyte fuel cell, J Power Sources, 163, 793, 10.1016/j.jpowsour.2006.09.022
Mathias, 2003, Handbook of fuel cells: fundamentals
Larminie, 2000
Yi, 1999, Multicomponent transport in porous electrodes of proton exchange membrane fuel cells using the interdigitated gas distributors, J Electrochem Soc, 146, 38, 10.1149/1.1391561
Wang, 2005, Simulation of flow and transport phenomena in a polymer electrolyte fuel cell under low-humidity operation, J Power Sources, 147, 148, 10.1016/j.jpowsour.2005.01.047
Dutta, 2000, Three-dimensional numerical simulation of straight channel PEM fuel cells, J Appl Electrochem, 30, 135, 10.1023/A:1003964201327
Wang, 2005, Modeling polymer electrolyte fuel cells with large density and velocity changes, J Electrochem Soc, 152, A445, 10.1149/1.1851059
Mazumder, 2003, Rigorous 3-D mathematical modeling of PEM fuel cells, J Electrochem Soc, 150, A1503, 10.1149/1.1615608
Hwang, 2006, Thermal-electrochemical modeling of a proton exchange membrane fuel cell, J Electrochem Soc, 153, A216, 10.1149/1.2137652
Wang, 2006, Two-phase model for polymer electrolyte fuel cells, J Electrochem Soc, 153, A1193, 10.1149/1.2193403
Birgersson, 2005, Analysis of a two-phase non-isothermal model for a PEFC, J Electrochem Soc, 152, A1021, 10.1149/1.1877992
Pasaogullari, 2004, Liquid water transport in gas diffusion layer of polymer electrolyte fuel cells, J Electrochem Soc, 151, A399, 10.1149/1.1646148
Nam, 2003, Effective diffusivity and water-saturation distribution in single- and two-layer PEMFC diffusion medium, Int J Heat Mass Transfer, 46, 4595, 10.1016/S0017-9310(03)00305-3
Ralph, 1997, Low cost electrodes for proton exchange membrane fuel cells, J Electrochem Soc, 144, 3845, 10.1149/1.1838101
Wang, 2007, Elucidating differences between carbon paper and carbon cloth in polymer electrolyte fuel cells, Electrochim Acta, 52, 3965, 10.1016/j.electacta.2006.11.012
Wang, 2010, Stochastic modeling and direct simulation of the diffusion media for polymer electrolyte fuel cells, Int J Heat Mass Transfer, 53, 1128, 10.1016/j.ijheatmasstransfer.2009.10.044
Schulz, 2006, Numerical evaluation of effective gas diffusivity – saturation dependence of uncompressed and compressed gas diffusion media in PEFCs, ECS Trans, 3, 1069, 10.1149/1.2356226
Sinha, 2007, Impact of GDL structure and wettability on water management in polymer electrolyte fuel cells, J Mater Chem, 17, 3089, 10.1039/b703485g
Mukherjee, 2009, Mesoscopic modeling of two-phase behavior and flooding phenomena in polymer electrolyte fuel cells, Electrochim Acta, 54, 6861, 10.1016/j.electacta.2009.06.066
Becker, 2008, Numerical determination of two-phase material parameters of a gas diffusion layer using tomography images, J Fuel Cell Sci Technol, 5, 021006, 10.1115/1.2821600
Becker, 2009, Determination of material properties of gas diffusion layers: experiments and simulations using phase contrast tomographic microscopy, J Electrochem Soc, 156, B1175, 10.1149/1.3176876
Benziger, 2005, Water flow in the gas diffusion layer of PEM fuel cells, J Membrane Sci, 261, 98, 10.1016/j.memsci.2005.03.049
Sinha, 2008, Liquid water transport in a mixed-wet gas diffusion layer of a polymer electrolyte fuel cell, Chem Eng Sci, 63, 1081, 10.1016/j.ces.2007.11.007
Gostick, 2007, Pore network modeling of fibrous gas diffusion layers for polymer electrolyte membrane fuel cells, J Power Sources, 173, 277, 10.1016/j.jpowsour.2007.04.059
Lin, 2006, A two-dimensional two-phase model of a PEM fuel cell, J Electrochem Soc, 153, A372, 10.1149/1.2142267
Pasaogullari, 2005, Two-phase modeling and flooding prediction of polymer electrolyte fuel cells, J Electrochem Soc, 152, A380, 10.1149/1.1850339
Wang, 2008, Modeling of two-phase transport in the diffusion media of polymer electrolyte fuel cells, J Power Sources, 185, 261, 10.1016/j.jpowsour.2008.07.007
Gostick, 2009, On the role of the microporous layer in PEMFC operation, Electrochem Commun, 11, 576, 10.1016/j.elecom.2008.12.053
Weber, 2005, Effects of microporous layers in polymer electrolyte fuel cells, J Electrochem Soc, 152, A677, 10.1149/1.1861194
Pasaogullari, 2005, Two-phase transport in polymer electrolyte fuel cells with bilayer cathode gas diffusion media, J Electrochem Soc, 152, A1574, 10.1149/1.1938067
Wang Y, Chen KS. In: Proceedings of the 8th International fuel cell science, engineering & technology conference, Brooklyn, NY; 2010.
Mukundan, 2007, Imaging of water profiles in PEM fuel cells using neutron radiography: effect of operating conditions and GDL composition, ECS Meet Abstracts, 702, 406, 10.1149/MA2007-02/9/406
Hickner, 2008, In situ high-resolution neutron radiography of cross-sectional liquid water profiles in proton exchange membrane fuel cells, J Electrochem Soc, 155, B427, 10.1149/1.2826287
Kramer, 2005, In situ diagnostic of two-phase flow phenomena in polymer electrolyte fuel cells by neutron imaging: Part A. Experimental, data treatment, and quantification, Electrochim Acta, 50, 2603, 10.1016/j.electacta.2004.11.005
Lehmann EH, Oberholzer P, Boillat P. Neutron imaging methods for the investigation of energy related materials: fuel cells, batteries, hydrogen storage, and nuclear fuel. In: Mater res soc symp proc; 2010. p. W05-01.
Ji Y, Luo G, Wang C-Y. Computer simulation of liquid water transport at pore level in MPL and GDL and their interface. In: ASME eighth international fuel cell science, engineering & technology conference, Brooklyn, NY; 2010.
Borup R. FC-35: water transport exploratory studies. In: Energy Do, editor, Hydrogen program review; 2009.
Wang, 2001, Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells, J Power Sources, 94, 40, 10.1016/S0378-7753(00)00662-5
Natarajan, 2001, A two-dimensional, two-phase, multicomponent, transient model for the cathode of a proton exchange membrane fuel cell using conventional gas distributors, J Electrochem Soc, 148, A1324, 10.1149/1.1415032
Mazumder, 2003, Rigorous 3-D mathematical modeling of PEM fuel cells, J Electrochem Soc, 150, A1510, 10.1149/1.1615609
Ohn, 2006, Capillary pressure properties of gas diffusion materials used in PEM fuel cells, ECS Trans, 1, 481, 10.1149/1.2214518
Nguyen, 2006, Measurements of two-phase flow properties of the porous media used in PEM fuel cells, ECS Trans, 3, 415, 10.1149/1.2356162
Fairweather, 2007, A microfluidic approach for measuring capillary pressure in PEMFC gas diffusion layers, Electrochem Commun, 9, 2340, 10.1016/j.elecom.2007.06.042
Sole JD, Ellis MW. Determination of the relationship between capillary pressure and saturation in PEMFC gas diffusion media. In: Fuel cell; 2008.
Wood, 2010, Surface properties of PEMFC gas diffusion layers, J Electrochem Soc, 157, B195, 10.1149/1.3261850
Wood, 2010, Estimation of mass-transport overpotentials during long-term PEMFC operation, J Electrochem Soc, 157, B1251, 10.1149/1.3454740
Mukherjee PP, Mukundan R, Borup RL. Modeling of durability effect on the flooding behavior in the PEFC gas diffusion layer. In: Proceedings of ASME fuel cell 2010, 8th ASME international fuel cell science, engineering, and technology conference; 2010.
Wilkinson, 2003, Handbook of fuel cells: fundamentals
EG&G Technical Services I. Fuel cell handbook, vol. 7. 2004: US Department of Energy, Office of Fossil Energy, National Energy Technology Laboratory.
Li, 2005, Review of bipolar plates in PEM fuel cells: flow-field designs, Int J Hydrogen Energy, 30, 359, 10.1016/j.ijhydene.2004.09.019
Jiang F et al. Simulation of a PEMFC with zigzag flow field. In: ASME eighth international fuel cell science, engineering & technology conference, Brooklyn, NY; 2010.
Jeon, 2008, The effect of serpentine flow-field designs on PEM fuel cell performance, Int J Hydrogen Energy, 33, 1052, 10.1016/j.ijhydene.2007.11.015
Karvonen, 2006, Modeling of flow field in polymer electrolyte membrane fuel cell, J Power Sources, 161, 876, 10.1016/j.jpowsour.2006.04.145
Perng, 2009, Numerical predictions of a PEM fuel cell performance enhancement by a rectangular cylinder installed transversely in the flow channel, Appl Energy, 86, 1541, 10.1016/j.apenergy.2008.11.011
Perng, 2010, Non-isothermal transport phenomenon and cell performance of a cathodic PEM fuel cell with a baffle plate in a tapered channel, Appl Energy, 88, 52, 10.1016/j.apenergy.2010.07.006
Inoue, 2006, Effect of gas channel depth on current density distribution of polymer electrolyte fuel cell by numerical analysis including gas flow through gas diffusion layer, J Power Sources, 157, 136, 10.1016/j.jpowsour.2005.08.004
Wang, 2009, Porous-media flow fields for polymer electrolyte fuel cells, J Electrochem Soc, 156, B1134, 10.1149/1.3183785
Wang, 2009, Channel aspect ratio effect for serpentine proton exchange membrane fuel cell: role of sub-rib convection, J Power Sources, 193, 684, 10.1016/j.jpowsour.2009.04.019
Yang, 2004, Visualization of liquid water transport in a PEFC, Electrochem Solid-State Lett, 7, A408, 10.1149/1.1803051
Zhang, 2006, Liquid water removal from a polymer electrolyte fuel cell, J Electrochem Soc, 153, A225, 10.1149/1.2138675
Bazylak, 2009, Liquid water visualization in PEM fuel cells: a review, Int J Hydrogen Energy, 34, 3845, 10.1016/j.ijhydene.2009.02.084
Tüber, 2003, Visualization of water buildup in the cathode of a transparent PEM fuel cell, J Power Sources, 124, 403, 10.1016/S0378-7753(03)00797-3
Basu, 2009, Two-phase flow and maldistribution in gas channels of a polymer electrolyte fuel cell, J Power Sources, 187, 431, 10.1016/j.jpowsour.2008.11.039
Basu, 2009, Two-phase flow maldistribution and mitigation in polymer electrolyte fuel cells, J Fuel Cell Sci Technol, 6, 031007, 10.1115/1.2971124
Jiao, 2006, Liquid water transport in straight micro-parallel-channels with manifolds for PEM fuel cell cathode, J Power Sources, 157, 226, 10.1016/j.jpowsour.2005.06.041
Zhu, 2008, Three-dimensional numerical simulations of water droplet dynamics in a PEMFC gas channel, J Power Sources, 181, 101, 10.1016/j.jpowsour.2008.03.005
Quan, 2005, Water behavior in serpentine micro-channel for proton exchange membrane fuel cell cathode, J Power Sources, 152, 31, 10.1016/j.jpowsour.2005.02.075
Hao, 2009, Lattice Boltzmann simulations of anisotropic permeabilities in carbon paper gas diffusion layers, J Power Sources, 186, 104, 10.1016/j.jpowsour.2008.09.086
Adrianowycz OL. Next generation bipolar plates for automotive PEM fuel cells. In: DOE 2009 annual progress report V. Fuel cells, GrafTech International Ltd.; 2009
Fleury, 2006, Fe-based amorphous alloys as bipolar plates for PEM fuel cell, J Power Sources, 159, 34, 10.1016/j.jpowsour.2006.04.119
Wang, 2007, An investigation into TiN-coated 316L stainless steel as a bipolar plate material for PEM fuel cells, J Power Sources, 165, 293, 10.1016/j.jpowsour.2006.12.034
Wang, 2006, An investigation into polypyrrole-coated 316L stainless steel as a bipolar plate material for PEM fuel cells, J Power Sources, 163, 500, 10.1016/j.jpowsour.2006.09.048
Wang, 2007, An investigation of the electrochemical properties of PVD TiN-coated SS410 in simulated PEM fuel cell environments, Int J Hydrogen Energy, 32, 895, 10.1016/j.ijhydene.2007.02.006
Silva, 2006, Surface conductivity and stability of metallic bipolar plate materials for polymer electrolyte fuel cells, Electrochim Acta, 51, 3592, 10.1016/j.electacta.2005.10.015
Huang, 2005, Development of fuel cell bipolar plates from graphite filled wet-lay thermoplastic composite materials, J Power Sources, 150, 110, 10.1016/j.jpowsour.2005.02.074
Wolf, 2006, Electrically conductive LCP–carbon composite with low carbon content for bipolar plate application in polymer electrolyte membrane fuel cell, J Power Sources, 153, 41, 10.1016/j.jpowsour.2005.03.182
Yen, 2003, A micro methanol fuel cell operating at near room temperature, Appl Phys Lett, 83, 4056, 10.1063/1.1625429
Brady M. Nitrided metallic bipolar plates. In: DOE 2009 annual progress report V. Fuel cells, Oak Ridge National Laboratory; 2009.
Brady, 2004, Preferential thermal nitridation to form pin-hole free Cr-nitrides to protect proton exchange membrane fuel cell metallic bipolar plates, Scripta Mater, 50, 1017, 10.1016/j.scriptamat.2003.12.028
Brady, 2007, Growth of Cr-Nitrides on commercial Ni–Cr and Fe–Cr base alloys to protect PEMFC bipolar plates, Int J Hydrogen Energy, 32, 3778, 10.1016/j.ijhydene.2006.08.044
Wang, 2006, Ultra large-scale simulation of polymer electrolyte fuel cells, J Power Sources, 153, 130, 10.1016/j.jpowsour.2005.03.207
Yu, 2009, Numerical study to examine the performance of multi-pass serpentine flow-fields for cooling plates in polymer electrolyte membrane fuel cells, J Power Sources, 194, 697, 10.1016/j.jpowsour.2009.06.025
Inoue, 2006, Numerical analysis of relative humidity distribution in polymer electrolyte fuel cell stack including cooling water, J Power Sources, 162, 81, 10.1016/j.jpowsour.2006.07.017
Spernjak, 2007, Experimental investigation of liquid water formation and transport in a transparent single-serpentine PEM fuel cell, J Power Sources, 170, 334, 10.1016/j.jpowsour.2007.04.020
Jiao, 2010, Experimental investigations on liquid water removal from the gas diffusion layer by reactant flow in a PEM fuel cell, Appl Energy, 87, 2770, 10.1016/j.apenergy.2009.04.041
Chen, 2005, Simplified models for predicting the onset of liquid water droplet instability at the gas diffusion layer/gas flow channel interface, Int J Energy Res, 29, 1113, 10.1002/er.1143
He, 2007, A two-fluid model for two-phase flow in PEMFCs, J Power Sources, 163, 864, 10.1016/j.jpowsour.2006.09.059
Zhan, 2006, Characteristics of droplet and film water motion in the flow channels of polymer electrolyte membrane fuel cells, J Power Sources, 160, 1, 10.1016/j.jpowsour.2005.12.081
Cai, 2006, Effects of hydrophilic/hydrophobic properties on the water behavior in the micro-channels of a proton exchange membrane fuel cell, J Power Sources, 161, 843, 10.1016/j.jpowsour.2006.04.110
Park, 2010, Numerical investigations on liquid water removal from the porous gas diffusion layer by reactant flow, Appl Energy, 87, 2180, 10.1016/j.apenergy.2009.11.021
Meng, 2005, Model of two-phase flow and flooding dynamics in polymer electrolyte fuel cells, J Electrochem Soc, 152, A1733, 10.1149/1.1955007
Chen KS. Modeling water-droplet detachment from GDL/channel interface in PEM fuel cells. In: Fuel cell 2008 sixth international conference on fuel cell science, engineering and technology, Denver, Colorado; 2008.
Promislow, 2005, A simple, mathematical model of thermal coupling in fuel cell stacks, J Power Sources, 150, 129, 10.1016/j.jpowsour.2005.02.032
Kim, 2005, Electrical coupling in proton exchange membrane fuel cell stacks, J Power Sources, 152, 210, 10.1016/j.jpowsour.2005.01.029
Berg, 2006, Electrical coupling in proton exchange membrane fuel cell stacks: mathematical and computational modelling, IMA J Appl Math, 71, 241, 10.1093/imamat/hxh092
Karimi, 2005, Performance analysis and optimization of PEM fuel cell stacks using flow network approach, J Power Sources, 147, 162, 10.1016/j.jpowsour.2005.01.023
Baschuk, 2003, Mathematical model of a PEM fuel cell incorporating CO poisoning and O2 (air) bleeding, Int J Global Energy Issues, 20, 245, 10.1504/IJGEI.2003.003966
Chang, 2006, Flow distribution in proton exchange membrane fuel cell stacks, J Power Sources, 162, 340, 10.1016/j.jpowsour.2006.06.081
Park, 2006, Effect of flow and temperature distribution on the performance of a PEM fuel cell stack, J Power Sources, 162, 444, 10.1016/j.jpowsour.2006.07.030
Yu, 2005, Water and thermal management for Ballard PEM fuel cell stack, J Power Sources, 147, 184, 10.1016/j.jpowsour.2005.01.030
Chen, 2007, Flow distribution in the manifold of PEM fuel cell stack, J Power Sources, 173, 249, 10.1016/j.jpowsour.2007.05.007
Chang, 2007, Reduced dimensional computational models of polymer electrolyte membrane fuel cell stacks, J Computat Phys, 223, 797, 10.1016/j.jcp.2006.10.011
DOE-EERE. FCT fuel cells: types of fuel cells; 2009 <https://www1.eere.energy.gov/hydrogenandfuelcells/fuelcells/fc_types.html> [05.28.10].
Adamson K-A. In: Today FC, editor. 2008 Large stationary survey; 2008.
Google. Google image search: fuel cell vehicles. 2010 <http://www.google.com/images?hl=en&q=Fuel±cell±vehicles&um=1&ie=UTF-8&source=univ&ei=cMBVTPfIK5GWsgOt5LTaAg&sa=X&oi=image_result_group&ct=title&resnum=11&ved=0CFwQsAQwCg&biw=1400&bih=855>.
Honda. Honda fuel cell power FCX; December 2004. <http://world.honda.com/FuelCell/FCX/FCXPK.pdf> [02.12.10].
Global-hydrogen-bus-platform.com. HyFLEET: about: history: CUTE. <http://www.global-hydrogen-bus-platform.com/About/History/CUTE> [02.12.10].
DaimlerChrysler. More fuel cell citaros, this time in China and Australia; 2005. <http://www.oxford-chiltern-bus-page.co.uk/130205.htm>.
Hsieh, 2005, SU-8 flow field plates for a micro PEMFC, J Solid State Electrochem, 9, 121, 10.1007/s10008-004-0523-z
H-CELL 2.0 Hybrid hydrogen fuel cell power kit: Q&A FACT SHEET, Horizon fuel cell technologies; 2009.
Wang, 2010, Private Commun
Plug-Power. Image of GenSys system. <http://www.plugpower.com/products/remoteprimegensys/remoteprimegensys.aspx>.
NIST. PEM Fuel Cells. 2006. <http://www.physics.nist.gov/MajResFac/NIF/pemFuelCells.html>.
Shimpalee, 2004, Predicting water and current distributions in a commercial-size PEMFC, J Power Sources, 135, 79, 10.1016/j.jpowsour.2004.03.059
Springer, 1993, Modeling and experimental diagnostics in polymer electrolyte fuel cells, J Electrochem Soc, 140, 3513, 10.1149/1.2221120
Zawodzinski, 1991, Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes, J Phys Chem, 95, 6040, 10.1021/j100168a060
Hinatsu, 1994, Water uptake of perfluorosulfonic acid membranes from liquid water and water vapor, J Electrochem Soc, 141, 1493, 10.1149/1.2054951
Chen, 2008, One dimensional analysis of subzero start-up for polymer electrolyte fuel cells, ECS Trans, 16, 273, 10.1149/1.2981862
Kim, 2009, Reconstruction and effective transport properties of the catalyst layer in PEM fuel cells, J Electrochem Soc, 156, B673, 10.1149/1.3106136
Djilali, 2008, Transport phenomena in fuel cells: from microscale to macroscale, Int J Comput Fluid Dyn, 22, 115, 10.1080/10618560701740017
Williams, 2004, Characterization of gas diffusion layers for PEMFC, J Electrochem Soc, 151, A1173, 10.1149/1.1764779
Schulz, 2007, Modeling of two-phase behavior in the gas diffusion medium of PEFCs via full morphology approach, J Electrochem Soc, 154, B419, 10.1149/1.2472547
Wang, 2010, Stochastic modeling and direct simulation of the diffusion media for polymer electrolyte fuel cells, Int J Heat Mass Transfer, 53, 1128, 10.1016/j.ijheatmasstransfer.2009.10.044
Hao, 2010, Lattice Boltzmann simulations of water transport in gas diffusion layer of a polymer electrolyte membrane fuel cell, J Power Sources, 195, 3870, 10.1016/j.jpowsour.2009.11.125
Wang, 2009, Porous-media flow fields for polymer electrolyte fuel cells, J Electrochem Soc, 156, B1124, 10.1149/1.3183781
NREL, Photographic information exchange #12508, 12508.jpg, Editor, National Renewable Energy Laboratory.
Honda. Honda FCX clarity official web site; 2007. <http://www.automobiles.honda.com/fcx-clarity>.
GM. GM: technology: fuel cell fact sheets; 2010. <http://www.gm.com/experience/technology/fuel_cells/fact_sheets/> [02.02.10].
Toyota. Toyota sustainable mobility – FCHV-adv; 2010. <http://www.sustainablemobility.com/?section=vehicles&sub=fchv> [02.12.10]
Toyota, Toyota 2007 North American Environmental Report, Toyota, 2007. Energy and Climate Section, p. 9.
Toyota. Toyota FCHV acquires vehicle type certification; 2005. <http://www.worldcarfans.com/10506178923/toyota-fchv-acquires-vehicle-type-certification> [02.12.10]
McCausland, E. Autoshows: 2009Kia Borrego FCEV Fuel Cell Vehicle; 2008. <http://www.automobilemag.com/auto_shows/2008_los_angeles/0811_kia_borrego_fcev_fuel_cell_vehicle/index.html>.
Daimler. Mercedes-Benz B-Class F-CELL: First electric car fully suited for everyday driving and with the driving dynamics of a two-litre petrol car; 2009. <http://media.daimler.com/dcmedia/0-921-1258086-1-1258427-1-0-0-0-0-1-11702-854934-0-1-0-0-0-0-0.html?TS=1270254293953>.
Fung D, Cunnigham W. Volkswagen Passat Ling Yu Fuel Cell; 2009 <http://www.cnet.com.au/volkswagen-passat-ling-yu-fuel-cell-339296693.htm>.
Fuel cell vehicles (from Auto Manufacturers). Fuel cells; 2000. <http://www.fuelcells.org/info/charts/carchart.pdf>.
Global-hydrogen-bus-platform.com. HyFLEET: CUTE: technology: buses. <http://www.global-hydrogen-bus-platform.com/Technology/Buses> [02.12.10].
Plug-Power. GenSys Specifications Sheet. <http://www.plugpower.com/userfiles/file/GenSys%20spec%20sheet%20customer%20-%20email%282%29.pdf> [02.12.10].