A review of heat treatment on polyacrylonitrile fiber

Schwartz, 2002

Cato Anthony, 2003, Flow behavior of mesophase pitch, Carbon, 41, 1411, 10.1016/S0008-6223(03)00050-2

Bahl, 1974, Characterization of oxidized PAN fibers, Carbon, 12, 417, 10.1016/0008-6223(74)90007-4

Bahl, 1979, Effect of load on the mechanical properties of carbon fibres from PAN precursor, Fiber Sci Technol, 12, 31, 10.1016/0015-0568(79)90010-1

Donnet, 1984

Wangxi, 2003, Evolution of structure and properties of PAN precursors during their conversion to carbon fibers, Carbon, 41, 2805, 10.1016/S0008-6223(03)00391-9

Sánchez-Soto, 2001, Thermal study of the effect of several solvents on polymerization of acrylonitrile and their subsequent pyrolysis, J Anal Appl Pyrolysis, 58–59, 155, 10.1016/S0165-2370(00)00203-5

Chung, 2001

Wiles KB. Determination of reactivity ratios for acrylonitrile/methyl acrylate radical copolymerization via nonlinear methodologies using real time FTIR. MSc thesis, Faculty of the Virginia Polytechnic Institute and State University: Blacksburg, Virginia; 2002.

Bahl, 1981, Structure of PAN fibers and its relationship with resulting carbon fiber properties, Fiber Sci Technol, 15, 147, 10.1016/0015-0568(81)90067-1

Yang, 1996, Influence of precursor structure on the properties of polyacrylonitrile-based activated carbon hollow fiber, Appl Polym Sci, 59, 1725, 10.1002/(SICI)1097-4628(19960314)59:11<1725::AID-APP8>3.0.CO;2-Q

Donnet, 1990

Mittal, 1997, Post spinning modification of PAN fibers, Carbon, 35, 1713, 10.1016/S0008-6223(97)00126-7

Pamula, 2003, Bulk and surface chemical functionalities of type III PAN-based carbon fibers, Carbon, 41, 1905, 10.1016/S0008-6223(03)00177-5

Fitzer, 1989, PAN based carbon – present state and trend of the technology from the viewpoint of possibilities and limit to influence to control the fiber properties by the process parameter, Carbon, 27, 621, 10.1016/0008-6223(89)90197-8

Chen, 2002, Modification of polyacrylonitrile (PAN) carbon fiber precursor via post-spinning plasticization and stretching in dimethylformamide (DMF), Carbon, 40, 25, 10.1016/S0008-6223(01)00050-1

Ogawa, 2000, Architectural application of carbon fibers development of new carbon fiber reinforced glulam, Carbon, 38, 211, 10.1016/S0008-6223(99)00146-3

Traceski, 1999

Tullo, 2000, Chem Eng News, 78, 11

Bhanu, 2002, Synthesis and characterization of acrylonitrile methyl acrylate statistical copolymers as melt processable carbon fiber precursors, Polymer, 43, 4841, 10.1016/S0032-3861(02)00330-0

Liu, 1994, Continuous carbonization of polyacrylonitrile-based oxidized fibers: aspects on mechanical properties and morphological structure, Appl Polym Sci, 52, 945, 10.1002/app.1994.070520712

Bashir, 1991, A critical review of the stabilization of polyacrylonitrile, Carbon, 29, 1081, 10.1016/0008-6223(91)90024-D

Dalton, 1999, Thermal stabilization of polyacrylonitrile fibers, Polymer, 40, 5531, 10.1016/S0032-3861(98)00778-2

Clingerman ML. Development and modelling of electrically conductive composite materials. PhD thesis, Michigan Technological University: USA; 2001.

Ko, 1991, Influence of continuous stabilization on the physical properties and microstructure of PAN-based carbon fibers, Appl Polym Sci, 42, 1949, 10.1002/app.1991.070420719

David, 2002, Influence of the thermostabilization process and soak time during pyrolysis process on the polyacrylonitrile carbon membranes for O2/N2 separation, J Membr Sci, 213, 285

Setnescu, 1999, IR and X-ray characterization of the ferromagnetic phase of pyrolysed polyacrylonitrile, Carbon, 37, 1, 10.1016/S0008-6223(98)00168-7

Friedlander, 1968, On the chromophore of polyacrylonitrile VI. Mechanism of color formation in polyacrylonitrile, Macromolecules, 1, 79, 10.1021/ma60001a014

Burlant, 1956, Pyrolysis of polyacrylonitrile, J Polym Sci, 22, 249, 10.1002/pol.1956.1202210107

Paiva, 2003, UV stabilization route for melt-processible PAN-based carbon fibers, Carbon, 41, 1399, 10.1016/S0008-6223(03)00041-1

Ko, 1991, The Influence of pyrolysis on physical properties and microstructure of modified PAN fibers during carbonization, Appl Polym Sci, 43, 589, 10.1002/app.1991.070430321

Martin, 2001, In situ NMR investigation into the thermal degradation and stabilization of PAN, Polym Degrad Stab, 74, 407, 10.1016/S0141-3910(01)00173-2

Edie, 1998, The effect of processing on the structure and properties of carbon fiber, Carbon, 36, 345, 10.1016/S0008-6223(97)00185-1

Ogawa, 1995, Oxidation behavior of polyacrylonitrile fibers evaluated by new stabilization index, Carbon, 33, 783, 10.1016/0008-6223(95)00007-Z

Fitzer, 1986, Optimization of stabilization and carbonization of PAN fibers and structural characterization of the resulting carbon fibers, Carbon, 24, 387, 10.1016/0008-6223(86)90257-5

Gupta, 1997, New aspect in the oxidative stabilization of PAN based carbon fibers II, Carbon, 35, 809, 10.1016/S0008-6223(97)00025-0

Gupta, 1996, New aspects in the oxidative stabilization of PAN-based carbon fibers, Carbon, 34, 1427, 10.1016/S0008-6223(96)00094-2

Mittal, 1997, Single step carbonization and graphitization of highly stabilized PAN fibers, Carbon, 35, 1196, 10.1016/S0008-6223(97)84653-2

Mathur, 1992, A new approach to thermal stabilization of PAN fibers, Carbon, 30, 657, 10.1016/0008-6223(92)90185-Y

Bansal, 1988

Beltz, 1996, Cyclization kinetics of polyacrylonitrile, Carbon, 34, 561, 10.1016/0008-6223(96)00005-X

Rangarajan, 2002, Dynamic oscillatory shear properties of potentially melt processable high acrylonitrile terpolymers, Polymer, 43, 2699, 10.1016/S0032-3861(02)00077-0

Fitzer, 1975, The Influence of oxygen on the chemical reaction during stabilization of PAN as carbon fiber precursor, Carbon, 13, 63, 10.1016/0008-6223(75)90259-6

Riggs, 1987, Handbook of composites

Donnet, 1998

Peebles, 1990, On the exotherm of polyacrylonitrile: pyrolysis of the homopolymer under inert conditions, Carbon, 28, 707, 10.1016/0008-6223(90)90073-8

Grassie, 1962, Thermal coloration and insolubilization in polyacrylonitrile, J Polym Sci, 56, 189, 10.1002/pol.1962.1205616316

Takata, 1964, Coloration in acrylonitrile polymers, J Polym Sci Part A Polym Chem, 2, 1567

Brandrup, 1968, On the chromophore of polyacrylonitrile. IV. Thermal oxidation of polyacrylonitrile and other nitrile-containing compounds, Macromolecules, 1, 64, 10.1021/ma60001a012

Grassie, 1971, Pyrolysis of polyacrylonitrile and related polymers. III. Thermal analysis of preheated polymers, Eur Polym J, 7, 1357, 10.1016/0014-3057(71)90032-2

Houtz, 1950, Orlon acrylic fiber: chemistry and properties, Text Res J, 20, 786, 10.1177/004051755002001107

Fourduex, 1971

Grassie, 1970, Pyrolysis of polyacrylonitrile and related polymers – I. Thermal analysis of polyacrylonitrile, Eur Polym J, 6, 1277, 10.1016/0014-3057(70)90046-7

Thompson, 1966, The thermal behavior of acrylonitrile polymers. I. On the decomposition of polyacrylonitrile between 250 and 325°C, Polym Lett, 4, 361, 10.1002/pol.1966.110040511

Grassie, 1972, Pyrolysis of polyacrylonitrile and related polymers – VI. Acrylonitrile copolymers containing carboxylic acid and amide structures, Eur Polym J, 8, 257, 10.1016/0014-3057(72)90032-8

Shurz, 1958, Discoloration effects in acrylonitrile polymers, J Polym Sci, 28, 438, 10.1002/pol.1958.1202811724

Peebles, 1972, Basic dyeability and acid content of high-conversion polyacrylonitrile, J Appl Polym Sci, 16, 3341, 10.1002/app.1972.070161223

Barnett I, Somerville NJ. Thermal modification of acrylonitrile yarns. US patent 2,913,802; 1959.

Longstaff B. Production of carbonized fibers. US patent 3,547,420; 1970.

Prescott R, Jonesboro, Weaver OI. Process for the manufacture of continuous high modulus carbon yarns and monofilaments. US patent 3,533,743; 1970.

Saito K, Ogawa H. Productions of carbon fiber from acrylonitrile based fibers. US patent 4,397,831; 1983.

Townsend BA, Rugby continuous carbon filament production. US patent 3,567,380; 1971.

Wirksworth IW, Johnson JW, Allestree Derby. Method of manufacturing carbon fibers. US patent 3,615,212; 1971.

McLouglin VCR, Moreton R, Watt W. Preparation of carbon fibers. US patent 4,079,122; 1978.

Didchenko R, Amata CD. Rapid stabilization of polyacrylonitrile fibers prior to carbonization. US patent 3,954,947, 1976.

Donnet, 1992, vol. 2

Trinquecoste, 1996, High temperature thermal and mechanical properties of high tensile carbon single filaments, Carbon, 34, 923, 10.1016/0008-6223(96)00052-8

Zhu, 2002, Study of carbon films from PAN/VGCF composites by gelation/crystallization from solution, Carbon, 40, 363, 10.1016/S0008-6223(01)00116-6

Laffont, 2004, An EELS study of the structural and chemical transformation of PAN polymer to solid carbon, Carbon, 42, 2485, 10.1016/j.carbon.2004.04.043

Wu, 1987, Thermal shrinkage behavior of preoxidized polyacrylonitrile fibers during carbonization, Appl Polym Sci, 33, 2877, 10.1002/app.1987.070330821

Lee, 1997, Influence of tension during oxidative stabilization on SO2 adsorption characteristics of polyacrylonitrile (PAN) based activated carbon fibers, Carbon, 35, 837, 10.1016/S0008-6223(97)00040-7

Ko, 1996, Raman spectrum of modified PAN-based carbon fibers during graphitization, Appl Polym Sci, 59, 577, 10.1002/(SICI)1097-4628(19960124)59:4<577::AID-APP2>3.0.CO;2-Q

Wang, 1996, Conversion of polyacrylonitrile fibers to activated carbon fibers: effect of preoxidation extent, Appl Polym Sci, 62, 1771, 10.1002/app.1996.070621031

Lee, 2001, Electrochemical properties of PAN-based carbon fibers as anodes for rechargeable lithium ion batteries, Carbon, 39, 1299, 10.1016/S0008-6223(00)00237-2

Sung, 2001, Strengthening of carbon fibers by imposition of a high magnetic field in a carbonization process, Mater Trans, 43, 2087, 10.2320/matertrans.43.2087

Chand, 2000, Carbon fiber for composites, Mater Sci, 35, 1303, 10.1023/A:1004780301489

Kaburagi, 2003, Small angle X-ray scattering from voids within fibers during the stabilization and carbonization stages, Carbon, 41, 925, 10.1016/S0008-6223(02)00407-4

McCabe. Pretreatment of PAN fiber. US patent 4,662,336; 1987.

Ozbek, 2000, Strain-induced density changes in PAN-based carbon fibers, Carbon, 38, 2007, 10.1016/S0008-6223(00)00060-9

Tsai, 1991, The effect of the side chain of acrylate comonomers on the orientation, pore size distribution, and properties of polyacrylonitrile precursor and resulting carbon fiber, Appl Polym Sci, 42, 3039, 10.1002/app.1991.070421123

Mittal, 1998, Post spinning treatment of PAN fibers using succinic acid to produce high performance carbon fibers, Carbon, 36, 893, 10.1016/S0008-6223(97)00198-X

Riggs, 1982, Graphite fiber and composites, 196

Nielsen, 1995, Formation of toxic gases during pyrolysis of polyacrylonitrile and nylons, Anal Appl Pyrolysis, 34, 43, 10.1016/0165-2370(95)00898-O

Donnet, 1987, vol 2

Manocha, 1980, Role of oxygen during thermal stabilization of PAN fibres, Fiber Sci Technol, 13, 199, 10.1016/0015-0568(80)90004-4

Watt, 1985, vol. 1, 327

Fitzer, 1983

Watt, 1971

Watt, 1974

Mittal, 1998, Denitrogenation behavior and tensile strength increase during carbonization of stabilized PAN fibers, Carbon, 36, 1327, 10.1016/S0008-6223(98)00113-4

Zhu, 1997, Formation of N2 during carbonization of polyacrylonitrile using iron catalyst, Fuel, 76, 155, 10.1016/S0016-2361(96)00182-2

Jain, 1987, Conversion of acrylonitrile-based precursor fibers to carbon fibers, J Mater Sci, 22, 278, 10.1007/BF01160584

Conley, 1963, Examination of the oxidative degradation of polyacrylonitrile using infrared spectroscopy, Appl Polym Sci, 7, 1757, 10.1002/app.1963.070070516

Coleman, 1978, Fourier transform infrared studies on the thermal degradation of polyacrylonitrile, Polym Sci Polym Phys, 16, 821, 10.1002/pol.1978.180160507

Coleman, 1981, Fourier transform IR studies of the degradation of polyacrylonitrile copolymers – I: introduction and comparative rates of the degradation of three copolymers below 200°C and under reduced pressure, Carbon, 19, 123, 10.1016/0008-6223(81)90118-4

Coleman, 1983, Studies of the degradation of acrylonitrile/acrylamide copolymers as a function of composition and temperature, Carbon, 21, 255, 10.1016/0008-6223(83)90089-1

Petcavich, 1979, Fourier-transform infrared studies on the thermal degradation of poly-α-deuteroacrylonitrile under reduced pressure, Polym Sci Polym Phys, 17, 165, 10.1002/pol.1979.180170115

Sivy, 1983, Studies of the degradation of copolymers of acrylonitrile and acrylamide in air at 200°C. Speculations on the role of the preoxidation step in carbon fiber formation, Carbon, 21, 563, 10.1016/0008-6223(83)90241-5

Sivy, 1981, Fourier transform IR studies of the degradation of polyacrylonitrile copolymers – II: acrylonitrile/methacrylic acid copolymers, Carbon, 19, 127, 10.1016/0008-6223(81)90119-6

Ko, 1998, The influence of cobaltous chloride modification on physical properties and microstructure of modified PAN fiber during carbonization, Appl Polym Sci, 70, 2409, 10.1002/(SICI)1097-4628(19981219)70:12<2409::AID-APP13>3.0.CO;2-0

Sauder, 2001, Thermomechanical properties of carbon fibers at high temperature (up to 2000°C), Compos Sci Technol, 62, 499, 10.1016/S0266-3538(01)00140-3