A review: The comparison between alkali-activated slag (Si + Ca) and metakaolin (Si + Al) cements

Cement and Concrete Research - Tập 40 Số 9 - Trang 1341-1349 - 2010
Chao Li1, Henghu Sun2,1, Longtu Li1
1State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
2School of Engineering and Computer Science, University of the Pacific, Stockton, CA, 95211, USA

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Roy, 1999, Alkali-activated cements: opportunities and challenges, Cem. Concr. Res., 29, 249, 10.1016/S0008-8846(98)00093-3

Krivenko, 1997, Alkaline cements: terminology classification, aspects of durability, 6

Deja, 2002, Immobilization of Cr6+, Cd2+, Zn2+ and Pb2+ in alkali-activated slag binders, Cem. Concr. Res., 32, 1971, 10.1016/S0008-8846(02)00904-3

Cho, 1999, Effect of PbII and CrVI on the hydration of slag-alkaline cement and the immobilization of these heavy metal ions, Adv. Cem. Res., 11, 111, 10.1680/adcr.1999.11.3.111

Qian, 2003, Characterization of mercury- and zinc-doped alkali-activated slag matrix, part I. Mercury, Cem. Concr. Res., 33, 1251, 10.1016/S0008-8846(03)00045-0

Qian, 2003, Characterization of mercury- and zincdoped alkali-activated slag matrix, part II, Zinc, Cem. Concr. Res., 33, 1257, 10.1016/S0008-8846(03)00046-2

Palomo, 1999, Alkali-activated fly ashes: a cement for the future, Cem. Concr. Res., 29, 1323, 10.1016/S0008-8846(98)00243-9

Davidovits, 1994, 1, 131

Shi, 2006

Provis, 2009

Balon, 1973, Slag formation in production of steelmaking pig-iron, Steel in the USSR, 4, 268

Mostafa, 2001, Characterization and evaluation of the hydraulic activity of water-cooled slag and air-cooled slag, Cem. Concr. Res., 31, 899, 10.1016/S0008-8846(01)00497-5

Li, 2002, The activation and hydration of glassy cementitious materials, Cem. Concr. Res., 32, 1145, 10.1016/S0008-8846(02)00755-X

Swamy, 1990, Some engineering properties of slag concrete as influenced by mix proportioning and curing, ACI Mater. J., 87, 210

Pal, 2003, Investigation of hydraulic activity of ground granulatedblast furnace slag in concrete, Cem. Concr. Res, 33, 1481, 10.1016/S0008-8846(03)00062-0

Duxson, 2008, Designing precursors for geopolymer cements, J. Am. Ceram. Soc., 91, 3864, 10.1111/j.1551-2916.2008.02787.x

Mysen, 1988

Lee, 2005, Structure and the extent of disorder in quaternary (Ca–Mg and Ca–Na) aluminosilicate glasses and melts, Am. Mineral., 90, 1393, 10.2138/am.2005.1843

Mysen, 2005

Allwardt, 2003, Bonding preferences of nonbridging oxygens in calcium aluminosilicate glass: evidence from O-17MAS and 3QMAS NMR on calcium aluminate glass, Am. Mineral., 88, 949, 10.2138/am-2003-0701

Lee, 2006, Disorder and the extent of polymerization in calcium silicate and aluminosilicate glasses: O-17 NMR results and quantum chemical molecular orbital calculations, Geochim. Cosmochim. Ac., 70, 4275, 10.1016/j.gca.2006.06.1550

Aramaki, 1961, Revised phase diagram for the system Al2O3–SiO2, J. Am. Ceram. Soc., 45, 229, 10.1111/j.1151-2916.1962.tb11133.x

Li, 2009, Effect of phase separation structure on cementitious reactivity of blast furnace slag, Sci. China, Ser., E 52, 2695, 10.1007/s11431-008-0239-x

Wan, 2004, Analysis of geometric characteristics of GGBS particles and their influences on cement properties, Cem. Concr. Res., 34, 133, 10.1016/S0008-8846(03)00252-7

Wang, 2005, Effect of fineness and particle size distribution of granulated blast-furnace slag on the hydraulic reactivity in cement systems, Adv. Cem. Res., 17, 161, 10.1680/adcr.2005.17.4.161

Caldaron, 1994, High-reactivity metakaolin: a new generation mineral, Concr. Int., 11, 37

Pera, 2001, Metakaolin and calcined clays, Cem. Concr. Compos, 23, 10.1016/S0958-9465(00)00098-6

Ambroise, 1985, Hydration reaction and hardening of calcined clays and related minerals: V. Extension of the research and general conclusions, Cem. Concr. Res., 15, 261, 10.1016/0008-8846(85)90037-7

García, 2008, The pozzolanic properties of paper sludge waste, Constr. Build. Mater., 22, 1484, 10.1016/j.conbuildmat.2007.03.033

Duxson, 2007, Geopolymer technology: the current state of the art, J. Mater. Sci., 42, 2917, 10.1007/s10853-006-0637-z

Rahier, 2003, Low-temperature synthesized aluminosilicate glasses — Part IV — modulated DSC study on the effect of particle size of metakaolinite on the production of inorganic polymer glasses, J. Mater. Sci., 38, 3131, 10.1023/A:1024733431657

Brindley, 1958, A new concept of the transformation sequence of kaolinite to mulite, Nature, 181, 1333, 10.1038/1811333a0

Brindley, 1961, The kaolinite–mullite reaction series: IV, The coordination of Aluminum, J. Am. Ceram. Soc., 44, 506, 10.1111/j.1151-2916.1961.tb13714.x

Lee, 2003, Energy-filtering transmission electron microscopy (EF-TEM) study of a modulated structure in metakaolinite, represented by a 14Å modulation, J. Am. Ceram. Soc., 86, 174, 10.1111/j.1151-2916.2003.tb03297.x

MacKenzie, 2007, Formation of aluminosilicate geopolymers from 1:1 layer-lattice minerals pre-treated by various methods: a comparative study, J. Mater. Sci., 42, 4667, 10.1007/s10853-006-0173-x

Buchwald, 2007, Alkali-activated metakaolin–slag blends — performance and structure in dependence of their composition, J. Mater. Sci., 42, 3024, 10.1007/s10853-006-0525-6

Li, 2003, Property improvement of Portland cement by incorporating with metakaolin and slag, Cem. Concr. Res., 33, 579, 10.1016/S0008-8846(02)01025-6

Cheng, 2003, Fire-resistant geopolymer produced by granulated blast furnace slag, Miner. Eng., 16, 205, 10.1016/S0892-6875(03)00008-6

Pacheco-Torgal, 2008, Alkali-activated binders: a review. Part 1. Historical background, terminology, reaction mechanisms and hydration products, Constr. Build. Mater., 22, 1305, 10.1016/j.conbuildmat.2007.10.015

Wang, 1995, Hydration products of alkali activated slag cement, Cem. Concr. Res., 25, 561, 10.1016/0008-8846(95)00045-E

Puertas, 2004, Pore solution in alkali-activated slag cement pastes. Relation to the composition and structure of calcium silicate hydrate, Cem. Concr. Res., 34, 195, 10.1016/S0008-8846(03)00254-0

S-D. Wang, Alkaline activation of slag, PhD Thesis, Imperial College, University of London, 1995.

Wang, 2003, 29Si and 27Al NMR study of alkali-activated slag, Cem. Concr. Res., 33, 769, 10.1016/S0008-8846(02)01044-X

Mozgawa, 2009, Spectroscopic studies of alkaline activated slag geopolymers, J. Mol. Struct., 924–926, 434, 10.1016/j.molstruc.2008.12.026

Yip, 2005, The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation, Cem. Concr. Res., 35, 1688, 10.1016/j.cemconres.2004.10.042

van Jaarsveld, 1999, Effect of the alkali metal activator on the properties of fly ash-based geopolymers, Ind. Eng.Chem. Res., 38, 3932, 10.1021/ie980804b

Van Jaarsveld, 1997, The potential use of geopolymeric materials to immobilise toxic metals: Part I. Theory and applications, Miner. Eng., 10, 659, 10.1016/S0892-6875(97)00046-0

Davidovits, 2005, 1, 9

Granizo, 1997, vol. 3, 3ii113

Granizo, 2002, Alkaline activation of metakaolin: effect of calcium hydroxide in the products of reaction, J. Am. Ceram. Soc., 85, 225, 10.1111/j.1151-2916.2002.tb00070.x

Rahier, 1997, Recent literature in geopolymer science and technology, J. Mater. Sci., 32, 2237, 10.1023/A:1018563914630

Davidovits, 1999, Chemistry of geopolymeric systems, terminology, 9

Lecomte, 2003, Synthesis and characterization of newinorganic polymeric composites based on kaolin or white clay and on ground-granulated blast furnace slag, J. Mater. Res., 18, 2571, 10.1557/JMR.2003.0360

Barbosa, 2000, Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers, Int. J. Inorg. Mater., 2, 309, 10.1016/S1466-6049(00)00041-6

Lecomte, 2006, (Micro)-structural comparison between geopolymers, alkali-activated slag cement and Portland cement, J. Eur. Ceram. Soc., 26, 3789, 10.1016/j.jeurceramsoc.2005.12.021

Glukhovsky, 1980, 3, 164

Duxson, 2005, Effect of alkali cations on aluminum incorporation in geopolymeric gels, Ind. Eng. Chem. Res., 44, 832, 10.1021/ie0494216

Weng, 2007, Dissolution processes, hydrolysis and condensation reactions during geopolymer synthesis: Part I — low Si/Al ratio systems, J. Mater. Sci., 42, 2997, 10.1007/s10853-006-0820-2

Duxson, 2007, The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers, Colloids Surf., A, 292, 8, 10.1016/j.colsurfa.2006.05.044

Provis, 2005, The role of mathematical modeling and gel chemistry in advancing geopolymer technology, Chem. Eng. Res. Des., 83, 853, 10.1205/cherd.04329

Faimon, 1996, Oscillatory silicon and aluminum aqueous concentrations during experimental aluminosilicate weathering, Geochim. Cosmochim. Acta, 60, 2901, 10.1016/0016-7037(96)00130-5

Yip, 2008, Effect of calcium silicate sources on geopolymerisation, Cem. Concr. Res., 38, 554, 10.1016/j.cemconres.2007.11.001

Shimoda, 2008, Total understanding of the local structures of an amorphous slag: perspective from multi-nuclear (29Si, 27Al, 17O, 25Mg, and 43Ca) solid-state NMR, J. Non-Cryst. Solids, 354, 1036, 10.1016/j.jnoncrysol.2007.08.010

Stebbins, 1997, NMR evidence for excess non-bridging oxygen in an aluminosilicate glass, Nature, 390, 60, 10.1038/36312

Xu, 2000, The geopolymerisation of alumino-silicate minerals, Int. J. Miner. Process., 59, 247, 10.1016/S0301-7516(99)00074-5

Song, 1999, Pore solution chemistry of alkali-activated ground granulated blast-furnace slag, Cem. Concr. Res., 29, 159, 10.1016/S0008-8846(98)00212-9

Song, 2000, Hydration of alkali-activated ground granulated blast furnace slag, J. Mater. Sci., 35, 249, 10.1023/A:1004742027117

Duxson, 2007, Geopolymer technology: the current state of the art, J.Mater. Sci., 42, 2917, 10.1007/s10853-006-0637-z

Fernández-Jiménez, 2006, The role played by the reactive alumina content in the alkaline activation of fly ashes, Micropor. Mesopor. Mater., 91, 111, 10.1016/j.micromeso.2005.11.015

Hamilton, 2001, Dissolution of nepheline, jadeite and albite glasses: toward better models for aluminosilicate dissolution, Geochim. Cosmochim. Acta, 65, 3683, 10.1016/S0016-7037(01)00724-4

Davidovits, 1991, Geopolymers: inorganic polymeric new materials, J. Therm. Anal., 37, 1633, 10.1007/BF01912193

Duxson, 2005, 29Si NMR study of structural ordering in aluminosilicate geopolymer gels, Langmuir, 21, 3028, 10.1021/la047336x

Rahier, 1997, Low-temperature synthesized aluminosilicate glasses.3. Influence of the composition of the silicate solution on production, structure and properties, J. Mater. Sci., 32, 2237, 10.1023/A:1018563914630

Luz Test, 2007, Alkali activation of metakaolins: parameters affecting mechanical, structural and microstructural properties, J. Mater. Sci., 42, 2934, 10.1007/s10853-006-0565-y