A priori evaluation of the printability of water-based anode dispersions in inkjet printing
Production Engineering - Trang 1-14 - 2023
Tóm tắt
Inkjet printing represents a disruptive additive manufacturing technology that has emerged as an innovative approach to generate customized lithium-ion batteries by tailored dispersions. However, electrode dispersions cause a complex non-Newtonian behavior which hampers the processability. This paper demonstrates a novel procedure for an a priori evaluation of the printability of aqueous graphite dispersions. Therefore, dispersions with a varying active material content were prepared and the printability was examined through a characterization of the drop formation and the drop deposition behavior. While the drop formation was observed by in-situ monitoring, the drop deposition was analyzed in ex-situ test setups. The rheological properties were systematically determined to calculate nondimensional numbers that describe the dispensing behavior. Consequently, their capability to predict the stability of the drop formation was evaluated. The results revealed that a graphite dispersion with a content of 2 m% allowed for a stable drop formation. No splashing occurred on the substrate during the drop deposition and sufficient wetting can be assumed due to a contact angle of below 90
$$^\circ$$
. Conclusions were drawn to further enhance the active material content. Due to the universality of the proposed approach, it is expected to be applicable to different dispersion systems.
Tài liệu tham khảo
Wijshoff H (2010) The dynamics of the piezo inkjet printhead operation. Phys Rep. https://doi.org/10.1016/j.physrep.2010.03.003
Abbel R, Teunissen P, Rubingh E, van Lammeren T, Cauchois R, Everaars M et al (2014) Industrial-scale inkjet printed electronics manufacturing - production up-scaling from concept tools to a roll-to-roll pilot line. Transl Mater Res. https://doi.org/10.1088/2053-1613/1/015002
Yang Y, Yuan W, Zhang X, Yuan Y, Wang C, Ye Y et al (2020) Overview on the applications of three-dimensional printing for rechargeable lithium-ion batteries. Appl Energy. https://doi.org/10.1016/j.apenergy.2019.114002
Delannoy PE, Riou B, Brousse T, Le Bideau J (2015) Ink-jet printed porous composite \(\rm LiFePO_{4}\) electrode from aqueous suspension for microbatteries. J Power Sources. https://doi.org/10.1016/j.jpowsour.2015.04.067
Huang J, Yang J, Li W, Cai W, Jiang Z (2008) Electrochemical properties of \(\rm LiCoO_{2}\) thin film electrode prepared by ink-jet printing technique. Thin Solid Films. https://doi.org/10.1016/j.tsf.2007.09.039
Zhao Y, Zhou Q, Liu L, Xu J, Yan M, Jiang Z (2006) A novel and facile route of ink-jet printing to thin film \(\rm SnO_{2}\) anode for rechargeable lithium ion batteries. Electrochim Acta. https://doi.org/10.1016/j.electacta.2005.07.050
Zhang F, Wei M, Viswanathan VV, Swart B, Shao Y, Wu G et al (2017) 3D printing technologies for electrochemical energy storage. Nano Energy. https://doi.org/10.1016/j.nanoen.2017.08.037
Tian X, Jin J, Yuan S, Chua CK, Tor SB, Zhou K (2017) Emerging \(\rm 3D-\)printed electrochemical energy storage devices: a critical review. Adv Energy Mater. https://doi.org/10.1002/aenm.201700127
Hawes GF, Rehman S, Rangom Y, Pope MA (2022) Advanced manufacturing approaches for electrochemical energy storage devices. Int Mater Rev. https://doi.org/10.1080/09506608.2022.2086388
Derby B, Reis N (2003) Inkjet printing of highly particulate suspensions. MRS Bull. https://doi.org/10.1557/mrs2003.230
Clasen C, Philipps PM, Palangetic L, Vermant AJ (2012) Dispensing of rheologically complex fluids: the map of misery. AIChE J. https://doi.org/10.1002/aic.13704
Jang D, Kim D, Moon J (2009) Influence of fluid physical properties on ink-jet printability. Langmuir. https://doi.org/10.1021/la900059m
Fromm JE (1984) Numerical calculation of the fluid dynamics of drop-on-demand jets. IBM J Res Dev. https://doi.org/10.1147/rd.283.0322
Derby B (2010) Inkjet printing of functional and structural materials: fluid property requirements, feature stability, and resolution. Annu Rev Mater Res. https://doi.org/10.1146/annurev-matsci-070909-104502
Polsakiewicz DA, Kollenberg W (2011) Highly loaded alumina inks for use in a piezoelectric print head. Materialwiss Werkstofftech. https://doi.org/10.1002/mawe.201100780
Reis N, Derby B (2000) Ink jet deposition of ceramic suspensions: Modeling and experiments of droplet formation. Mat Res Soc Symp Proc. https://doi.org/10.1557/PROC-625-117
Zhong Y, Fang H, Ma Q, Dong X (2018) Analysis of droplet stability after ejection from an inkjet nozzle. J Fluid Mech. https://doi.org/10.1017/jfm.2018.251
Liu Y, Derby B (2019) Experimental study of the parameters for stable drop-on-demand inkjet performance. Phys Fluids 31(3):032004
Aqeel AB, Mohasan M, Lv P, Yang Y, Duan H (2019) Effects of nozzle and fluid properties on the drop formation dynamics in a drop-on-demand inkjet printing. Appl Math Mech. https://doi.org/10.1007/s10483-019-2514-7
Lehmann M, Kolb CG, Klinger F, Zaeh MF (2021) Preparation, characterization, and monitoring of an aqueous graphite ink for use in binder jetting. Mater Des. https://doi.org/10.1016/j.matdes.2021.109871
Hoath SD (2016) Fundamentals of inkjet printing: the science of inkjet and droplets. Wiley, Hoboken
Rioboo R, Marengo M, Tropea C (2002) Time evolution of liquid drop impact onto solid, dry surfaces. Exp Fluids. https://doi.org/10.1007/s00348-002-0431-x
Josserand C, Thoroddsen ST (2016) Drop impact on a solid surface. Annu Rev Fluid Mech 48:365–391
Prabhu KN, Fernandes P, Kumar G (2009) Effect of substrate surface roughness on wetting behaviour of vegetable oils. Mater Des. https://doi.org/10.1016/j.matdes.2008.04.067
Kolb CG, Lehmann M, Kriegler J, Lindemann BAJL, Zaeh MF (2022) Qualifying water-based electrode dispersions for the inkjet printing process: a requirements analysis. Rapid Prototyp J. https://doi.org/10.1108/RPJ-01-2022-0026
Kolb CG, Lehmann M, Kulmer D, Zaeh MF (2022) Modeling of the stability of water-based graphite dispersions using polyvinylpyrrolidone on the basis of the DLVO theory. Heliyon. https://doi.org/10.1016/j.heliyon.2022.e11988
Kolb C, Lehmann M, Lindemann JL, Bachmann A, Zaeh M (2021) Improving the dispersion behavior of organic components in water-based electrode dispersions for inkjet printing processes. Appl Sci. https://doi.org/10.3390/app11052242
Bresser D, Buchholz D, Moretti A, Varzi A, Passerini S (2018) Alternative binders for sustainable electrochemical energy storage—the transition to aqueous electrode processing and bio-derived polymers. Energy Environ Sci. https://doi.org/10.1039/C8EE00640G
Wenzel V, Nirschl H, Nötzel D (2015) Challenges in lithium-ion-battery slurry preparation and potential of modifying electrode structures by different mixing processes. Energy Technol. https://doi.org/10.1002/ente.201402218
Kulicke WM, Clasen C, Lohman C (2005) Characterization of water-soluble cellulose derivatives in terms of the molar mass and particle size as well as their distribution. Macromol Symp 223:151–174
Gulbinska MK (2014) Lithium-ion battery materials and engineering: current topics and problems from the manufacturing perspective. Springer, London
Haselrieder W, Westphal B, Bockholt H, Diener A, Hoeft S, Kwade A (2015) Measuring the coating adhesion strength of electrodes for lithium-ion batteries. Int J Adhes Adhes 60:1–8
Bridel JS, Azais T, Morcrette M, Tarascon JM, Larcher D (2010) Key parameters governing the reversibility of Si/Carbon/CMC electrodes for Li-ion batteries. Chem Mater 22:1229–1241
Traube J (1891) Über die C apillaritätsconstanten organischer Stoffe in wässerigen L ösungen. Justus Liebigs Ann Chem. https://doi.org/10.1002/jlac.18912650103
Tadros TF (2011) Rheology of dispersions: principles and applications. Wiley, Hoboken
Barnes HA (2000) A handbook of elementary rheology. University of Wales, Institute of Non-Newtonian Fluid Mechanics, Wales
Lestriez B (2010) Functions of polymers in composite electrodes of lithium ion batteries. C R Chim. https://doi.org/10.1016/j.crci.2010.01.018
Malkin AY, Isayev AI (2017) Rheology: concepts, methods, and applications. ChemTech Publishing, Scarborough
Benchabane A, Bekkour K (2008) Rheological properties of carboxymethyl cellulose ( CMC ) solutions. Colloid Polym Sci. https://doi.org/10.1007/s00396-008-1882-2
Shaughnessy EJ, Katz IM, Schaeffer JP (2005) Introduction to fluid dynamics. Oxford University Press, New York
Carnicer V, Alcázar MJ, Sánchez E, Moreno R (2021) Microfluidic rheology: a new approach to measure viscosity of ceramic suspensions at extremely high shear rates. Open Ceram. https://doi.org/10.1016/j.oceram.2020.100052
Jeschull F, Brandell D, Wohlfahrt-Mehrens M, Memm M (2017) Water-soluble binders for lithium-ion battery graphite electrodes: slurry rheology, coating adhesion, and electrochemical performance. Energy Technol. https://doi.org/10.1002/ente.201700200
Lanceros-Méndez S, Costa CM (2018) Printed batteries: materials, technologies and applications. Wiley, Hoboken
Abdelrahim KA, Ramaswamy HS, Doyon G, Toupin C (1994) Effects of concentration and temperature on carboxymethylcellulose rheology. Int J Food Sci. https://doi.org/10.1111/j.1365-2621.1994.tb02066.x
Kwon YI, Kim JD, Song YS (2015) Agitation effect on the rheological behavior of lithium-ion battery slurries. J Electron Mater 44:474–481. https://doi.org/10.1007/s11664-014-3349-1
Herschel WH, Bulkley R (1926) Konsistenzmessungen von Gummi-Benzollösungen. Kolloid-Zeitschrift. https://doi.org/10.1007/BF01432034
He P, Wang H, Qi L, Osaka T (2006) Synthetic optimization of spherical LiCoO2 and precursor via uniform-phase precipitation. J Power Sources 158:529–534
Murshed SS, Tan S, Nguyen NT (2008) Temperature dependence of interfacial properties and viscosity of nanofluids for droplet-based microfluidics. J Phys D Appl Phys. https://doi.org/10.1088/0022-3727/41/8/085502
Radiom M, Yang C, Chan WK (2010). Characterization of surface tension and contact angle of nanofluids. In: 4th international conference on experimental mechanics. https://doi.org/10.1117/12.851278
Tanvir S, Qiao L (2012) Surface tension of nanofluid-type fuels containing suspended nanomaterials. Nanoscale Res Lett. https://doi.org/10.1186/1556-276X-7-226
Bhuiyan MHU, Saidur R, Mostafizur RM, Mahbubul IM, Amalina MA (2015) Experimental investigation on surface tension of metal oxide-water nanofluids. Int Commun Heat Mass Transf. https://doi.org/10.1016/j.icheatmasstransfer.2015.01.002
Phan-Thien N, Mai-Duy N (2013) Understanding viscoelasticity: an introduction to rheology. Springer, Berlin
Rapp BE (2016) Microfluidics: modeling, mechanics and mathematics. Elsevier, Amsterdam
Alamán J, Alicante R, Peña JI, Sánchez-Somolinos C (2016) Inkjet printing of functional materials for optical and photonic applications. Materials. https://doi.org/10.3390/ma9110910
Haque RI, Vié R, Germainy M, Valbin L, Benaben P, Boddaert X (2015) Inkjet printing of high molecular weight PVDF-TrFE for flexible electronics. Flex Print Electron. https://doi.org/10.1088/2058-8585/1/1/015001
Huesker J, Froböse L, Kwade A, Winter M, Placke T (2017) In situ dilatometric study of the binder influence on the electrochemical intercalation of bis (trifluoromethanesulfonyl) imide anions into graphite. Electrochim Acta. https://doi.org/10.1016/j.electacta.2017.10.042
Huang Y, Jiang L, Li B, Premaratne P, Jiang S, Qin H (2020) Study effects of particle size in metal nanoink for electrohydrodynamic inkjet printing through analysis of droplet impact behaviors. J Manuf Process. https://doi.org/10.1016/j.jmapro.2020.04.021
Tsai MH, Hwang WS, Chou HH, Hsieh PH (2008) Effects of pulse voltage on inkjet printing of a silver nanopowder suspension. Nanotechnology. https://doi.org/10.1088/0957-4484/19/33/335304
An SM, Lee SY (2012) Maximum spreading of a shear-thinning liquid drop impacting on dry solid surfaces. Exp Therm Fluid Sci. https://doi.org/10.1016/j.expthermflusci.2011.12.003
Fu K, Wang Y, Yan C, Yao Y, Chen Y, Dai J et al (2016) Graphene oxide-based electrode inks for 3D-printed lithium-ion batteries. Adv Mater 28(13):2587–2594
Scheller BL, Bousfield DW (1995) Newtonian drop impact with a solid surface. AIChE J. https://doi.org/10.1002/aic.690410602
Wenzel RN (1949) Surface roughness and contact angle. J Phys Chem. https://doi.org/10.1021/j150474a015
Saulick Y, Lourenco SDN, Baudet BA (2017) A semi-automated technique for repeatable and reproducible contact angle measurements in granular materials using the sessile drop method. Soil Sci Soc Am J. https://doi.org/10.2136/sssaj2016.04.0131
Billot N, Beyer M, Koch N, Ihle C, Reinhart G (2021) Development of an adhesion model for graphite-based lithium-ion battery anodes. J Manuf Syst 58:131. https://doi.org/10.1016/j.jmsy.2020.10.016
Kwok DY, Neumann AW (1999) Contact angle measurement and contact angle interpretation. Adv Colloid Interface Sci. https://doi.org/10.1016/S0001-8686(98)00087-6