Một phương pháp làm mỏng quy mô lớn mới để tăng cường độ ổn định lâu dài của các vật liệu cathode nhiều lớp cho pin Li-ion

Semih Engün1,2, Kamil Burak Dermenci2, Umut Savacı2, Servet Turan2
1Department of Metallurgical and Materials Engineering, Zonguldak Bulent Ecevit University, Zonguldak, Turkey
2Department of Materials Science and Engineering, Eskisehir Technical University, Eskisehir, Turkey

Tóm tắt

Một phương pháp vi khuẩn huyết áp cao được áp dụng cho các vật liệu cathode nhiều lớp nhằm thu được các tấm nano mỏng lần đầu tiên. Ảnh hưởng của vi khuẩn huyết áp đến Li(Ni0.333Mn0.333Co0.333) (NMC) và LiCoO2 được nghiên cứu liên quan đến cấu trúc tinh thể, hình thái và các tính chất điện hóa. Vi khuẩn huyết áp đã tạo điều kiện cho việc tách lớp của các lớp LiCoO2 nhờ vào lực cắt mạnh. Kết quả là, các tấm nano LiCoO2 bị tách lớp thể hiện các hướng ưu tiên với các mặt (003) có cường độ cao hơn. Thêm vào đó, vị trí oxy trong các octahedron CoO6 đã thay đổi, dẫn đến độ dài liên kết Co–O bị rút ngắn sau khi vi khuẩn huyết áp. Nghiên cứu cho thấy rằng NMC và LiCoO2 được xử lý bằng vi khuẩn huyết áp cho thấy hiệu suất chu kỳ vượt trội hơn so với loại nguyên bản. Đáng chú ý, phát hiện rằng LiCoO2 đã được xử lý bằng vi khuẩn huyết áp cho thấy cải thiện đáng kể về duy trì công suất (75%) so với LiCoO2 nguyên bản (21%) sau 100 chu kỳ ở 0.1C. Hiệu suất chu kỳ cao hơn của NMC và LiCoO2 được xử lý bằng vi khuẩn huyết áp được cho là do sự ổn định bề mặt nhờ vào sự tái cấu trúc bề mặt của các tấm mỏng sau khi xử lý vi khuẩn huyết áp.

Từ khóa


Tài liệu tham khảo

Nitta N, Wu F, Lee JT, Yushin G (2015) Li-ion battery materials: present and future. Mater Today 18:252–264. https://doi.org/10.1016/j.mattod.2014.10.040 Delmas C, Fouassier C, Hagenmuller P (1980) Structural classification and properties of the layered oxides. Physica B+C 99:81–85. https://doi.org/10.1016/0378-4363(80)90214-4 Chakraborty A, Kunnikuruvan S, Kumar S et al (2020) Layered cathode materials for lithium-ion batteries: review of computational studies on LiNi1−x−yCoxMnyO2 and LiNi1−x−yCoxAlyO2. Chem Mater 32:915–952. https://doi.org/10.1021/acs.chemmater.9b04066 Kim H, Kong M, Kim K et al (2009) Electrochemical characteristics of LiFeP4/LiCoO2 mixed electrode for Li secondary battery. J Electroceram 23:219–224. https://doi.org/10.1007/s10832-007-9403-0 Radin MD, Hy S, Sina M et al (2017) Narrowing the gap between theoretical and practical capacities in Li-Ion layered oxide cathode materials. Adv Energy Mater 7:1602888–1602921. https://doi.org/10.1002/aenm.201602888 Venkatraman S, Shin Y, Manthiram A (2003) Phase relationships and structural and chemical stabilities of charged Li1 − xCoO2 − δ and Li1 − x Ni0.85Co0.15O2 − δ Cathodes. Electrochem Solid-State Lett 6:A9–A12. https://doi.org/10.1149/1.1525430 Ohzuku T, Makimura Y (2001) Layered lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for lithium-ion batteries. Chem Lett 30:642–643 Manthiram A (2020) A reflection on lithium-ion battery cathode chemistry. Nat Commun 11:1550–1559. https://doi.org/10.1038/s41467-020-15355-0 Novoselov KS, Geim AK, Morozov Sv et al (2004) Electric field effect in atomically thin carbon films. Science 1979(306):666–669. https://doi.org/10.1126/science.1102896 Kim NY, Blake S, De D et al (2020) Two-dimensional nanosheet-based photonic nanomedicine for combined gene and photothermal therapy. Front Pharmacol 10:1573–1587. https://doi.org/10.3389/fphar.2019.01573 Xiong P, Peng L, Chen D et al (2015) Two-dimensional nanosheets based Li-ion full batteries with high rate capability and flexibility. Nano Energy 12:816–823. https://doi.org/10.1016/j.nanoen.2015.01.044 Wu Z-S, Ren W, Xu L et al (2011) Doped graphene sheets as anode materials with superhigh rate and large capacity for lithium ion batteries. ACS Nano 5:5463–5471. https://doi.org/10.1021/nn2006249 Liu SH, Jia HP, Han L et al (2012) Nanosheet-constructed porous TiO2-B for advanced lithium ion batteries. Adv Mater 24:3201–3204. https://doi.org/10.1002/adma.201201036 Wang X, Wu XL, Guo YG et al (2010) Synthesis and lithium storage properties of Co3O4 nanosheet-assembled multishelled hollow spheres. Adv Funct Mater 20:1680–1686. https://doi.org/10.1002/adfm.200902295 Ren MM, Zhou Z, Gao XP et al (2008) LiVOPO4 hollow microspheres: one-pot hydrothermal synthesis with reactants as self-sacrifice templates and lithium intercalation performances. J Phys Chem C 112:13043–13046 Rui X, Zhao X, Lu Z et al (2013) Olivine-type nanosheets for lithium ion battery cathodes. ACS Nano 7:5637–5646. https://doi.org/10.1021/nn4022263 Yan P, Zheng J, Zheng J et al (2016) Ni and Co segregations on selective surface facets and rational design of layered lithium transition-metal oxide cathodes. Adv Energy Mater 6:1502455–1502464. https://doi.org/10.1002/aenm.201502455 Tai Z, Subramaniyam CM, Chou S-L et al (2017) Few atomic layered lithium cathode materials to achieve ultrahigh rate capability in lithium-ion batteries. Adv Mater 29:1700605–1700613. https://doi.org/10.1002/adma.201700605 Lin F, Markus IM, Nordlund D et al (2014) Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Nat Commun 5:3529–3538. https://doi.org/10.1038/ncomms4529 Su Y, Yang Y, Chen L et al (2018) Improving the cycling stability of Ni-rich cathode materials by fabricating surface rock salt phase. Electrochim Acta 292:217–226. https://doi.org/10.1016/j.electacta.2018.09.158 Karagiannidis PG, Hodge SA, Lombardi L et al (2017) Microfluidization of graphite and formulation of graphene-based conductive ınks. ACS Nano 11:2742–2755. https://doi.org/10.1021/acsnano.6b07735 Baskut S, Cinar A, Seyhan AT, Turan S (2018) Tailoring the properties of spark plasma sintered SiAlON containing graphene nanoplatelets by using different exfoliation and size reduction techniques: Anisotropic electrical properties. J Eur Ceram Soc 38:3787–3792. https://doi.org/10.1016/j.jeurceramsoc.2018.04.066 Buzaglo M, Shtein M, Regev O (2016) Graphene quantum dots produced by microfluidization. Chem Mater 28:21–24. https://doi.org/10.1021/acs.chemmater.5b03301 Yurdakul H, Göncü Y, Durukan O et al (2012) Nanoscopic characterization of two-dimensional (2D) boron nitride nanosheets (BNNSs) produced by microfluidization. Ceram Int 38:2187–2193. https://doi.org/10.1016/j.ceramint.2011.10.064 Lutterotti L, Bortolotti M, Ischia G et al (2007) Rietveld texture analysis from diffraction images. Zeitschrift fur Kristallographie 2007:125–130. https://doi.org/10.1524/9783486992540-020 Kalyani P, Kalaiselvi N (2005) Various aspects of LiNiO2 chemistry: a review. Sci Technol Adv Mater 6:689–703. https://doi.org/10.1016/j.stam.2005.06.001 Morales J, Pérez-Vicente C, Tirado JL (1990) Cation distribution and chemical deintercalation of Li1−xNi1+xO2. Mater Res Bull 25:623–630. https://doi.org/10.1016/0025-5408(90)90028-Z Pan T, Alvarado J, Zhu J et al (2019) Structural degradation of layered cathode materials in lithium-ion batteries induced by ball milling. J Electrochem Soc 166:A1964–A1971. https://doi.org/10.1149/2.0091910jes Broussely M, Perton F, Biensan P et al (1995) LixNiO2, a promising cathode for rechargeable lithium batteries. J Power Sources 54:109–114. https://doi.org/10.1016/0378-7753(94)02049-9 Molenda J (2019) Cathode electronic structure impact on lithium and sodium batteries parameters. In: Lithium-ion batteries - thin film for energy materials and devices. London, United Kingdom: IntechOpen, 2019 [Online]. https://www.intechopen.com/chapters/65700. https://doi.org/10.5772/intechopen.83606 Zheng X, Chen Y, Zheng X et al (2019) Electronic structure engineering of LiCoO2 toward enhanced oxygen electrocatalysis. Adv Energy Mater 9:1803482–1803492. https://doi.org/10.1002/aenm.201803482 Rao MC (2010) Raman investigations on laser ablated LiCoO2 and LiTixCo1−xO2 thin film cathodes. Optoelectron Adv Mater Rapid Commun 4:2088–2091 Flores E, Novák P, Berg EJ (2018) In situ and Operando Raman spectroscopy of layered transition metal oxides for Li-ion battery cathodes. Front Energy Res 6:82–98. https://doi.org/10.3389/fenrg.2018.00082 Wang X, Loa I, Kunc K et al (2005) Effect of pressure on the structural properties and Raman modes of LiCoO2. Phys Rev B: Condens Matter Mater Phys 72:224102–224110. https://doi.org/10.1103/PhysRevB.72.224102 Julien C (2000) Structure and electrochemistry of LiCoO2 from disordered to microcrystalline materials. In: Proceedings of the 3rd France-Japan Meeting on Lithium Batteries, Chamonix, May 26–27, 2000 Santana IL, Moreira TFM, Lelis MFF, Freitas MBJG (2017) Photocatalytic properties of Co3O4/LiCoO2 recycled from spent lithium-ion batteries using citric acid as leaching agent. Mater Chem Phys 190:38–44. https://doi.org/10.1016/j.matchemphys.2017.01.003 Yamaki JI, Baba Y, Katayama N et al (2003) Thermal stability of electrolytes with LixCoO2 cathode or lithiated carbon anode. J Power Sour 119–121:789–793 Pokle A, Ahmed S, Schweidler S et al (2020) In situ monitoring of thermally induced effects in nickel-rich layered oxide cathode materials at the atomic level. ACS Appl Mater Interfaces 12(51):57047–57054. https://doi.org/10.1021/acsami.0c16685 Zou L, He Y, Liu Z et al (2020) Unlocking the passivation nature of the cathode–air interfacial reactions in lithium ion batteries. Nat Commun 11:3204–3212. https://doi.org/10.1038/s41467-020-17050-6 Myung ST, Maglia F, Park KJ et al (2017) Nickel-rich layered cathode materials for automotive lithium-ıon batteries: achievements and perspectives. ACS Energy Lett 2:196–223. https://doi.org/10.1021/acsenergylett.6b00594 Hwang S, Chang W, Kim SM et al (2014) Investigation of changes in the surface structure of LixNi0.8Co0.15Al0.05O2 cathode materials induced by the initial charge. Chem Mater 26:1084–1092. https://doi.org/10.1021/cm403332s Zhang H, May BM, Serrano-Sevillano J et al (2018) Facet-dependent rock-salt reconstruction on the surface of layered oxide cathodes. Chem Mater 30:692–699. https://doi.org/10.1021/acs.chemmater.7b03901 Aricò AS, Bruce P, Scrosati B et al (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mater 4:366–377 Mohanty D, Dahlberg K, King DM et al (2016) Modification of Ni-Rich FCG NMC and NCA cathodes by atomic layer deposition: preventing surface phase transitions for high-voltage lithium-ion batteries. Sci Rep 6:26532–26548. https://doi.org/10.1038/srep26532 Zou L, Zhao W, Jia H et al (2020) The role of secondary particle structures in surface phase transitions of Ni-Rich cathodes. Chem Mater 32(7):2884–2892. https://doi.org/10.1021/acs.chemmater.9b04938 Zhu J, Sharifi-Asl S, Garcia JC et al (2020) Atomic-level understanding of surface reconstruction based on Li[NixMnyCo1−x−y]O2 single-crystal studies. ACS Appl Energy Mater 3(5):4799–4811. https://doi.org/10.1021/acsaem.0c00411 Zuo D, Tian G, Chen D et al (2015) Comparative study of Al2O3-coated LiCoO2 electrode derived from different Al precursors: uniformity, microstructure and electrochemical properties. Electrochim Acta 178:447–457. https://doi.org/10.1016/j.electacta.2015.08.039 Daxian Z (2017) Comparative study of the electrochemical behaviors for LiCoO2 electrode coated with two different Al2O3 coating layer. Int J Electrochem Sci 12:5044–5057. https://doi.org/10.20964/2017.06.70 Sheng S, Chen G, Hu B et al (2017) Al2O3-surface modification of LiCoO2 cathode with improved cyclic performance. J Electroanal Chem 795:59–67. https://doi.org/10.1016/j.jelechem.2017.04.026 Wang H (1999) TEM study of electrochemical cycling-induced damage and disorder in LiCoO2 cathodes for rechargeable lithium batteries. J Electrochem Soc 146:473–480. https://doi.org/10.1149/1.1391631 Wen JW, Liu HJ, Wu H, Chen CH (2007) Synthesis and electrochemical characterization of LiCo1/3Ni1/3Mn1/3O2 by radiated polymer gel method. J Mater Sci 42:7696–7701. https://doi.org/10.1007/s10853-007-1673-z Yan P, Zheng J, Zhang J-G, Wang C (2017) Atomic resolution structural and chemical imaging revealing the sequential migration of Ni Co, and Mn upon the battery cycling of layered cathode. Nano Lett 17:3946–3951. https://doi.org/10.1021/acs.nanolett.7b01546 Park J-H, Cho J-H, Kim J-S et al (2012) High-voltage cell performance and thermal stability of nanoarchitectured polyimide gel polymer electrolyte-coated LiCoO2 cathode materials. Electrochim Acta 86:346–351. https://doi.org/10.1016/j.electacta.2012.04.073