A novel high efficiency benzophenone based polymeric photoinitiator from ring-opening polymerization of benzoxazine

Pleiades Publishing Ltd - Tập 56 - Trang 632-638 - 2014
Jingsong Shi1, Penghui Chen1, Kemin Wang1, Jian Lu2, Jun Nie3
1School of Materials Science and Engineering, Changzhou University, Changzhou, Jiangsu, China
2Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Changzhou, Jiangsu, China
3School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, China

Tóm tắt

A novel polymeric photoinitiator based on benzoxazine was synthesized by introducing 4-hydroxy benzophenone, diglycolamine and paraformaldehyde into the macromolecular chain. Its molecular structure was characterized by 1H NMR, FTIR, and UV-Vis spectroscopy. Photopolymerization of tripropylene glycol diacrylate and trimethylolpropane triacrylate initiated by polybenzoxazine, benzoxazine, and benzophenone was studied by real time FTIR spectroscopy. The results obtained are discussed.

Tài liệu tham khảo

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