A novel and sensitive chemosensor based on a KMnO4–rhodamine B–CdS quantum dot chemiluminescence system for meropenem detection

Photochemical & Photobiological Sciences - Tập 16 - Trang 170-177 - 2020
Alireza Khataee1,2, Roya Lotfi1, Aliyeh Hasanzadeh1
1Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
2Department of Materials Science and Nanotechnology, Near East University, Mersin 10, Turkey

Tóm tắt

A sensitive and simple flow injection chemiluminescence (CL) system was constructed for the determination of meropenem, in which the CL intensity of the KMnO4-rhodamine B (Rh B) reaction was enhanced in the presence of CdS quantum dots (QDs). A CL resonance energy transfer (CRET) occurs between CdS QDs as a donor and Rh B as an energy acceptor. Based on the strong specific quenching effect of meropenem on the CL intensity, a novel chemosensor for meropenem sensing was developed. Under the optimized conditions, the quenched CL emission intensity was proportional to the concentration of meropenem in the range of 0.002-10.0 mg L−1 with a detection limit (3s) of 0.8 µg L−1 Moreover, the feasibility of the induced CL system was studied via the meropenem determination in environmental water samples.

Tài liệu tham khảo

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