A new type of poly metallic chain compounds: carboranyl derivatives of thallium (iii) containing a B-Tl-transition metal bond sequence

Springer Science and Business Media LLC - Tập 42 - Trang 554-556 - 1993
A. Ya. Usyatinskii1, G. Z. Suleimanov1, E. A. Zul'fugarly1, V. A. Antonovich1, V. I. Bregadze1, I. P. Beletskaya1
1A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation

Tóm tắt

The interaction of NaM(CO)5 (M=Mn, Re) with (m-H2C2B10H9-9)TlCl2 in THF yields the stable polymetallic chain compounds (m-H2C2B10H9-9)Tl(Cl)M(CO)5. The stability of the compounds obtained is compared to that of the analogous (B-carboranyl)mercury derivatives.

Tài liệu tham khảo

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