A new molecular rectifier device and some research in its processing
Tóm tắt
Organic materials of D-π-A type MR-X (MR-1: p-dimethylaminophenylethenetrica-rbonitrile and MR-2: p-diphenylaminophenylethene tricarbonitrile) were designed and synthesized. The device with a sandwich structure shows good rectificative phenomena. The highest rectification ratio 10000 was achieved in device Cu/MR-1/Ag, and about 100 in other device M/MR-X/M (M: Cu, Ag). It has been found that rectificative phenomena exist only in the atmosphere-liquid interface region by means of liquid adsorption, and electric field could help form the oriented molecular film.
Tài liệu tham khảo
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Lu Yinxiang, The investigation of organic functional materials and organic crystal structures, PhD. Thesis, Department of Materials Science, Fudan University, Shanghai