A family of zeolites with controlled pore size prepared using a top-down method

Nature Chemistry - Tập 5 Số 7 - Trang 628-633 - 2013
Roth, Wieslaw J.1, Nachtigall, Petr2, Morris, Russell E.3, Wheatley, Paul S.3, Seymour, Valerie R.3, Ashbrook, Sharon E.3, Chlubná, Pavla1, Grajciar, Lukáš2, Položij, Miroslav2, Zukal, Arnošt1, Shvets, Oleksiy4, Čejka, Jiří1
1Department of Synthesis and Catalysis, J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of Czech Republic, Prague 8, Czech Republic
2Department of Physical and Macromolecular Chemistry, Faculty of Sciences, Charles University, Prague 2, Czech Republic
3EaStCHEM School of Chemistry, University of St Andrews, St. Andrews, UK
4L. V. Pisarzhevskiy Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Kyiv 03028, Ukraine

Tóm tắt

The properties of zeolites, and thus their suitability for different applications, are intimately connected with their structures. Synthesizing specific architectures is therefore important, but has remained challenging. Here we report a top-down strategy that involves the disassembly of a parent zeolite, UTL, and its reassembly into two zeolites with targeted topologies, IPC-2 and IPC-4. The three zeolites are closely related as they adopt the same layered structure, and they differ only in how the layers are connected. Choosing different linkers gives rise to different pore sizes, enabling the synthesis of materials with predetermined pore architectures. The structures of the resulting zeolites were characterized by interpreting the X-ray powder-diffraction patterns through models using computational methods; IPC-2 exhibits orthogonal 12- and ten-ring channels, and IPC-4 is a more complex zeolite that comprises orthogonal ten- and eight-ring channels. We describe how this method enables the preparation of functional materials and discuss its potential for targeting other new zeolites. The disassembly of a parent zeolite and its reassembly into two zeolites with targeted topologies is described. This process demonstrates that it is possible to target specific ring sizes in a zeolite by replacing one size of unit in the structure with alternative units of a different size.

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Tài liệu tham khảo

citation_title=Zeolite Molecular Sieves; citation_publication_date=1984; citation_id=CR1; citation_author=DW Breck

citation_journal_title=Zeolites; citation_title=Zeolites and their synthesis; citation_author=RM Barrer; citation_volume=1; citation_publication_date=1981; citation_pages=130-140; citation_doi=10.1016/S0144-2449(81)80001-2; citation_id=CR2

citation_title=Hydrothermal Chemistry of Zeolites; citation_publication_date=1982; citation_id=CR3; citation_author=RM Barrer

citation_title=Introduction to Zeolite Science and Practice; citation_publication_date=2007; citation_id=CR4; citation_author=J Čejka; citation_author=H van Bekkum; citation_author=A Corma; citation_author=F Schüth

citation_title=Chemistry of Zeolites and Related Porous Materials; citation_publication_date=2007; citation_id=CR5; citation_author=R Xu; citation_author=W Pang; citation_author=J Yu; citation_author=Q Huo; citation_author=J Chen

citation_journal_title=Science; citation_title=Synthesis and structure determination of the hierarchical meso-microporous zeolite ITQ-43; citation_author=J Jiang; citation_volume=333; citation_publication_date=2011; citation_pages=1131-1134; citation_doi=10.1126/science.1208652; citation_id=CR6

citation_journal_title=Science; citation_title=Unraveling the perplexing structure of the zeolite SSZ-57; citation_author=C Baerlocher, T Weber, LB McCusker, L Palatinus, SI Zones; citation_volume=333; citation_publication_date=2011; citation_pages=1134-1137; citation_doi=10.1126/science.1207466; citation_id=CR7

citation_journal_title=Science; citation_title=Modular organic structure-directing agents for the synthesis of zeolites; citation_author=R Simancas; citation_volume=330; citation_publication_date=2010; citation_pages=1219-1222; citation_doi=10.1126/science.1196240; citation_id=CR8

citation_journal_title=Nature; citation_title=The ITQ-37 mesoporous chiral zeolite; citation_author=J Sun; citation_volume=458; citation_publication_date=2009; citation_pages=1154-U90; citation_doi=10.1038/nature07957; citation_id=CR9

citation_journal_title=Nature Mater.; citation_title=A zeolite family with chiral and achiral structures built from the same building layer; citation_author=L Tang; citation_volume=7; citation_publication_date=2008; citation_pages=381-385; citation_doi=10.1038/nmat2169; citation_id=CR10

citation_journal_title=Nature Mater.; citation_title=Ordered silicon vacancies in the framework structure of the zeolite catalyst SSZ-74; citation_author=C Baerlocher; citation_volume=7; citation_publication_date=2008; citation_pages=631-635; citation_doi=10.1038/nmat2228; citation_id=CR11

citation_journal_title=Science; citation_title=Structure of the polycrystalline zeolite catalyst IM-5 solved by enhanced charge flipping; citation_author=C Baerlocher; citation_volume=315; citation_publication_date=2007; citation_pages=1113-1116; citation_doi=10.1126/science.1137920; citation_id=CR12

citation_journal_title=Science; citation_title=Extra-large-pore zeolites with two-dimensional channels formed by 14 and 12 rings; citation_author=JL Paillaud, B Harbuzaru, J Patarin, N Bats; citation_volume=304; citation_publication_date=2004; citation_pages=990-992; citation_doi=10.1126/science.1098242; citation_id=CR13

Corma, A., Diaz-Cabanas, M. J., Rey, F., Nicolooulas, S. & Boulahya, K. ITQ-15: The first ultralarge pore zeolite with a bi-directional pore system formed by intersecting 14- and 12-ring channels, and its catalytic implications. Chem. Commun. 1356–1357 (2004).

citation_journal_title=J. Am. Chem. Soc.; citation_title=Postsynthesis transformation of three-dimensional framework into a lamellar zeolite with modifiable architecture; citation_author=WJ Roth; citation_volume=133; citation_publication_date=2011; citation_pages=6130-6133; citation_doi=10.1021/ja200741r; citation_id=CR15

citation_journal_title=Phys. Rev. B; citation_title=Higher-accuracy van der Waals density functional; citation_author=K Lee, ED Murray, LZ Kong, BI Lundqvist, DC Langreth; citation_volume=82; citation_publication_date=2010; citation_pages=081101; citation_doi=10.1103/PhysRevB.82.081101; citation_id=CR16

citation_journal_title=Phys. Rev. B; citation_title=Ab-initio molecular-dynamics for open-shell transition-metals; citation_author=G Kresse, J Hafner; citation_volume=48; citation_publication_date=1993; citation_pages=13115-13118; citation_doi=10.1103/PhysRevB.48.13115; citation_id=CR17

citation_journal_title=Nature; citation_title=Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues; citation_author=ER Cooper; citation_volume=430; citation_publication_date=2004; citation_pages=1012-1016; citation_doi=10.1038/nature02860; citation_id=CR18

citation_journal_title=J. Am. Chem. Soc.; citation_title=Methodology for synthesizing crystalline metallosilicates with expanded pore windows through molecular alkoxysilylation of zeolitic lamellar precursors; citation_author=P Wu; citation_volume=130; citation_publication_date=2008; citation_pages=8178-8187; citation_doi=10.1021/ja0758739; citation_id=CR19

Inagaki, S., Yokoi, T., Kubota, Y. & Tatsumi, T. Unique adsorption properties of organic–inorganic hybrid zeolite IEZ-1 with dimethylsilylene moieties. Chem. Commun. 5188–5190 (2007).

citation_journal_title=Chem. Mater.; citation_title=Interlayer expansion of the hydrous layer silicate RUB-36 to a functionalized, microporous framework silicate: crystal structure analysis and physical and chemical characterization; citation_author=H Gies; citation_volume=24; citation_publication_date=2012; citation_pages=1536-1545; citation_doi=10.1021/cm300525u; citation_id=CR21

citation_journal_title=ChemCatChem; citation_title=Interlayer-expanded microporous titanosilicate catalysts with functionalized hydroxyl groups; citation_author=F-S Xiao; citation_volume=3; citation_publication_date=2011; citation_pages=1442-1446; citation_doi=10.1002/cctc.201100144; citation_id=CR22

citation_journal_title=Chem. Mater.; citation_title=Interlayer expansion of the layered zeolite precursor RUB-39: a universal method to synthesize functionalized microporous silicates; citation_author=H Gies; citation_volume=23; citation_publication_date=2011; citation_pages=2545-2554; citation_doi=10.1021/cm103506q; citation_id=CR23

citation_journal_title=Nature Mater.; citation_title=Design of zeolite by inverse sigma transformation; citation_author=E Verheyen; citation_volume=11; citation_publication_date=2012; citation_pages=1059-1064; citation_doi=10.1038/nmat3455; citation_id=CR24

citation_journal_title=J. Mater. Chem.; citation_title=Synthesis of isomorphously substituted extra-large pore UTL zeolites; citation_author=MV Shamzhy; citation_volume=22; citation_publication_date=2012; citation_pages=15793-15803; citation_doi=10.1039/c2jm31725g; citation_id=CR25

citation_title=Atlas of Zeolite Framework Types; citation_publication_date=2007; citation_id=CR26; citation_author=C Baerlocher; citation_author=WM Maier; citation_author=DH Olson

citation_journal_title=Nature Mater.; citation_title=A zeolite with interconnected 8-, 10- and 12-ring pores and its unique catalytic selectivity; citation_author=A Corma, F Rey, S Valencia, JL Jorda, J Rius; citation_volume=2; citation_publication_date=2003; citation_pages=493-497; citation_doi=10.1038/nmat921; citation_id=CR27

citation_journal_title=Angew. Chem. Int. Ed.; citation_title=A zeolite structure (ITQ-13) with three sets of medium-pore crossing channels formed by 9- and 10-rings; citation_author=A Corma, M Puche, F Rey, G Sankar, SJ Teat; citation_volume=42; citation_publication_date=2003; citation_pages=1156-1159; citation_doi=10.1002/anie.200390304; citation_id=CR28

citation_journal_title=J. Am. Chem. Soc.; citation_title=A zeolitic structure (ITQ-34) with connected 9- and 10-ring channels obtained with phosphonium cations as structure directing agents; citation_author=A Corma; citation_volume=130; citation_publication_date=2008; citation_pages=16482-16483; citation_doi=10.1021/ja806903c; citation_id=CR29

citation_journal_title=J. Am. Chem. Soc.; citation_title=Synthesis of a new zeolite structure ITQ-24, with intersecting 10- and 12-membered ring pores; citation_author=R Castaneda, A Corma, V Fornes, F Rey, J Rius; citation_volume=125; citation_publication_date=2003; citation_pages=7820-7821; citation_doi=10.1021/ja035534p; citation_id=CR30

citation_journal_title=J. Am. Chem. Soc.; citation_title=P-derived organic cations as structure-directing agents: synthesis of a high-silica zeolite (ITQ-27) with a two-dimensional 12-ring channel system; citation_author=DL Dorset; citation_volume=128; citation_publication_date=2006; citation_pages=8862-8867; citation_doi=10.1021/ja061206o; citation_id=CR31

citation_journal_title=Eur. J. Mineral.; citation_title=Hydrous layer silicates as precursors for zeolites obtained through topotactic condensation: a review; citation_author=B Marler, H Gies; citation_volume=24; citation_publication_date=2012; citation_pages=405-428; citation_doi=10.1127/0935-1221/2012/0024-2187; citation_id=CR32

citation_journal_title=Catal. Sci. Technol.; citation_title=Two-dimensional zeolites: dream or reality?; citation_author=WJ Roth, J Čejka; citation_volume=1; citation_publication_date=2011; citation_pages=43-53; citation_doi=10.1039/c0cy00027b; citation_id=CR33

citation_journal_title=Chem. Mater.; citation_title=The role of template structure and synergism between inorganic and organic structure directing agents in the synthesis of UTL zeolite; citation_author=OV Shvets, N Kasian, A Zukal, J Pinkas, J Čejka; citation_volume=22; citation_publication_date=2010; citation_pages=3482-3495; citation_doi=10.1021/cm1006108; citation_id=CR34

citation_journal_title=Chem. Mater.; citation_title=3D to 2D routes to ultrathin and expanded zeolitic materials; citation_author=P Chlubna; citation_volume=25; citation_publication_date=2013; citation_pages=542-547; citation_doi=10.1021/cm303260z; citation_id=CR35

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Nature Chemistry

Tập 5 Số 7

628-633

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