A Review of Recent Developments of Mesoporous Materials

Chemical Record - Tập 17 Số 12 - Trang 1169-1183 - 2017
Steven L. Suib1
1Unit 3060, Departments of Chemistry, Chemical and Biomolecular Engineering, and Institute of Materials Science University of Connecticut Storrs, CT 06269-3060

Tóm tắt

AbstractThis personal account concerns novel recent discoveries in the area of mesoporous materials. Most of the papers discussed have been published within the last two to three years. A major emphasis of most of these papers is the synthesis of unique mesoporous materials by a variety of synthetic methods. Many of these articles focus on the control of the pore sizes and shapes of mesoporous materials. Synthetic methods of various types have been used for such control of porosity including soft templating, hard templating, nano‐casting, electrochemical methods, surface functionalization, and trapping of species in pores. The types of mesoporous materials range from carbon materials, metal oxides, metal sulfides, metal nitrides, carbonitriles, metal organic frameworks (MOFs), and composite materials. The vast majority of recent publications have centered around biological applications with a majority dealing with drug delivery systems. Several other bio‐based articles on mesoporous systems concern biomass conversion and biofuels, magnetic resonance imaging (MRI) studies, ultrasound therapy, enzyme immobilization, antigen targeting, biodegradation of inorganic materials, applications for improved digestion, and antitumor activity. Numerous nonbiological applications of mesoporous materials have been pursued recently. Some specific examples are photocatalysis, photo‐electrocatalysis, lithium ion batteries, heterogeneous catalysis, extraction of metals, extraction of lanthanide and actinide species, chiral separations and catalysis, capturing and the mode of binding of carbon dioxide (CO2), optical devices, and magneto‐optical devices. Of this latter class of applications, heterogeneous catalysis is predominant. Some of the types of catalytic reactions being pursued include hydrogen generation, selective oxidations, aminolysis, Suzuki coupling and other coupling reactions, oxygen reduction reactions (ORR), oxygen evolution reactions (OER), and bifunctional catalysis. For perspective, there have been over 40,000 articles on mesoporous materials published in the last 4 years and about 1388 reviews. By no means is this personal account thorough or all inclusive. One objective has been to choose a variety of articles of different types to obtain a flavor of the breadth of diversity involved in the area of mesoporous materials.

Từ khóa


Tài liệu tham khảo

F. Liu C. Liu W. Kong C. Qi A. Zheng S. Dai Design and synthesis of micro-meso-macroporous polymers with versatile active sites and excellent activities in the production of biofuels and fine chemicals Green Chemistry2016 18 6536–6544.

Y. Yue Y. Li C. A. Bridges G. Rother J. Zhang J. Chen D. K. Hensley M. K. Kidder B. C. Richardson P. M. Parans S. Dai Hierarchically Superstructured Metal Sulfides: Facile Perturbation-Assisted Nanofusion Synthesis and Visible Light Photocatalytic Characterizations ChemNanoMat.2016 2 1104–1110.

V. Vega J. Garcia J. M. Montero-Moreno B. Hernando J. Bachmann V. M. Prida K. Nielsch Unveiling the Hard Anodization Regime of Aluminum: Insight into Nanopores Self-Organization and Growth Mechanism ACS Applied Materials & Interfaces2015 7 28682–28692.

X. Y. Yang L. H. Chen Y. Li J. C. Rooke C. Sanchez B. L. Su Hierarchically porous materials: synthesis strategies and structure design Chem. Soc. Rev.2017 46 481–558.

C. Robertson A. W. Lodge P. Basa M. Carravetta A. L. Hector R. J. Kashtiban J. Sloan D. C. Smith J. Spencer A. Walcarius A. Surface modification and porosimetry of vertically aligned hexagonal mesoporous silica films RSC Advances2016 6 113432–113441.

K. Ding A. Corma J. A. Macia-Agullo J. G. Hu S. Kramer P. C. Stair G. D.Stucky Constructing Hierarchical Porous Zeolites via Kinetic Regulation J. Am. Chem. Soc.2015 137 11238–11241.

W. C. Chu D. R. Peng B. P. Bastakoti M. Pramanik V. Malgras T. Ahamad S. M. Alshehri Y. Yamauchi S. W. Kuo Co-templating Synthesis of Bimodal Mesoporous Silica for Potential Drug Carrier Chem. Select2016 1 1339–1346.

M. Bouchoucha M. F. Cote R. C.-Gaudreault M. A. Fortin F. Kleitz Size-Controlled Functionalized Mesoporous Silica Nanoparticles for Tunable Drug Release and Enhanced Anti-Tumoral Activity Chem. Mat.2016 28 4243–4258.

V. Stojanovic F. Cunin J. O. Durand M. Garcia M. Gary-Bobo Potential of porous silicon nanoparticles as an emerging platform for cancer theranostics J. Mat. Chem. B Mat. for Biology and Med.2016 4 7050–7059.

L. Yu Y. Chen M. Wu X. Cai H. Yao L. Zhang H. Chen J. Shi Manganese Extraction Strategy Enables Tumor-Sensitive Biodegradability and Theranostics of Nanoparticles J. Am. Chem. Soc.2016 138 9881–9894.

M. Ma F. Yan M. Yao Z. Wei D. Zhou H. Yao H. Zheng H. Chen J. Shi Template-Free Synthesis of Hollow/Porous Organosilica-Fe3O4 Hybrid Nanocapsules toward Magnetic Resonance Imaging-Guided High-Intensity Focused Ultrasound Therapy ACS Appl. Mat. & Interf.2016 8 29986–29996.

H. Gustafsson A. Kuchler K. Holmberg P. Walde Co-immobilization of enzymes with the help of a dendronized polymer and mesoporous silica nanoparticles J. Mat. Chem. B Mat. Biol. Med.2015 3 6174–6184.

E. Perez-Esteve M. Ruiz-Rico C. de la Torre E. Llorca F. Sancenon M. D. Marcos P. Amoros C. Guillem R. Martinez-Manez J. M. Barat Stability of different mesoporous silica particles during an in vitro digestion Micropor. Mesopor. Mat.2016 230 196–207.

K. Moeller T. Bein Talented Mesoporous Silica Nanoparticles Chem. Mat.2017 29 371–388.

X. Du C. Zhao M. Zhou T. Ma H. Huang M. Jaroniec X. Zhang S. Z. Qiao Hollow Carbon Nanospheres with Tunable Hierarchical Pores for Drug Gene and Photothermal Synergistic Treatment Small2017 13 n/a.

P. Verma Y. Kuwahara K. Mori H. Yamashita Pd/Ag and Pd/Au bimetallic nanocatalysts on mesoporous silica for plasmon-mediated enhanced catalytic activity under visible light irradiation J. Mat. Chem. A2016 4 10142–10150.

T. Li J. Li Q. Zhang E. Blazeby C. Shang H. Xu X. Zhang Y. Chao Hydrogen-terminated mesoporous silicon monoliths with huge surface area as alternative Si-based visible light-active photocatalysts RSC Adv.2016 6 71092–71099.

K. S. Lakhi D. H. Park K. Al-Bahily W. Cha B. Viswanathan J. Choy A.Vinu Mesoporous carbon nitrides: synthesis functionalization and applications Chem. Soc. Rev.2017 46 72–101.

J. Kim B. Kim C. Anand A. Mano J. S. M. Zaidi K. Ariga J. You A. Vinu E. Kim A Single-Step Synthesis of Electroactive Mesoporous ProDOT-Silica Structures Ang. Chem. Int. Ed.2015 54 8407–8410.

P. Bhanja C. Senthil A. K. Patra M. Sasidharan A. Bhaumik NASICON type ordered mesoporous lithium-aluminum-titanium-phosphate as electrode materials for lithium-ion batteries Micropor. Mesopor. Mat.2017 240 57–64.

W. Song Z. Ren S. Y. Chen Y. Meng S. Biswas P. Nandi H. A. Elsen P. X. Gao S. L. Suib Ni- and Mn-Promoted Mesoporous Co3O4: A Stable Bifunctional Catalyst with Surface-Structure-Dependent Activity for Oxygen Reduction Reaction and Oxygen Evolution Reaction ACS Appl. Mat. Interf.2016 8 20802–20813.

Z.Luo T. D. Huan I. M. Mosa A. S. Poyraz R. Miao W. Zhong J. Cloud D. Kriz S. Thanneeru R. Ramprasad S. L. Suib Mesoporous Blue MoO3-xMaterial as Efficient Electrocatalyst for Hydrogen Evolution Reaction Adv. Energy Mat.2016 6.

C. Li O. Dag T. D. Dao T. Nagao Y.Sakamoto T. Kimura O. Terasaki Y. Yamauchi Electrochemical synthesis of mesoporous gold films toward mesospace-stimulated optical properties Nature Comm.2015 6 6608.

P. Bairi K. Minami W. Nakanishi J. P. Hill K. Ariga L. K. Shrestha Hierarchically Structured Fullerene C70 Cube for Sensing Volatile Aromatic Solvent Vapors ACS Nano2016 10 6631–6637.

R. R. Salunkhe Y. V. Kaneti J. Kim J. H. Kim Y. Yamauchi Nanoarchitectures for Metal-Organic Framework-Derived Nanoporous Carbons toward Supercapacitor Applications Acc. Chem. Res.2016 49 2796–2806.

J. Florek S. Giret E. Juere D. Lariviere F. Kleitz Functionalization of mesoporous materials for lanthanide and actinide extraction Dalton Trans.2016 45 14832–14854.

C. P. Canlas T. J. Pinnavaia Silica mesophases intercalated by cross-linked micelles of a sustainable oleyl diamine surfactant and metal ion uptake properties thereof New J. Chem.2016 40 4406–4413.

M. E. Potter S. H. Pang C. W. Jones Adsorption Microcalorimetry of CO2in Confined Aminopolymers Langmuir2017 33 117–124.

C. Gunathilake M. Jaroniec Mesoporous calcium oxide-silica and magnesium oxide-silica composites for CO2capture at ambient and elevated temperatures J. Mat. Chem. A2016 4 10914–10924.

S. N. Talapaneni D. H. Park J. H. Choy K. Ramadass A. Elzatahry A. S. Al Balawi A. M. A. M. Al-Enizi T. Mori A. Vinu Facile Synthesis of Crystalline Nanoporous GaN Templated by Nitrogen Enriched Mesoporous Carbon Nitride for Friedel-Crafts Reaction Chem. Select2016 1 6062–6068.

M. Orazov M. E. Davis Catalysis by framework zinc in silica-based molecular sieves Chem. Sci.2016 7 2264–2274.

S. Biswas K. Mullick S. Y. Chen A. Gudz D. M. Carr C. Mendoza A. M. Angeles-Boza S. L. Suib Facile access to versatile functional groups from alcohol by single multifunctional reusable catalyst Appl. Catal.2017 203 607–614.

M. M. Islam P. Bhanja M. Halder S. K. Kundu A. Bhaumik S. M. Islam Chiral Co(III)-salen complex supported over highly ordered functionalized mesoporous silica for enantioselective aminolysis of racemic epoxides RSC Adv.2016 6 109315–109321.

A. S. Poyraz Ph.D. Thesis University of Connecticut 2015.

H. Y. Chiu H. Leonhardt T. Bein„ Synthesis and functionalization of ordered large-pore mesoporous silica nanoparticles for biomedical applications Chemie Ingen. Technik 2017 Ahead of Print; DOI:10.1002/cite.201700021.

Thông tin
Thông tin xuất bản

Chemical Record

Tập 17 Số 12

1169-1183

Thông tin tác giả