A Modified Synthesis of Oxetan-3-ol

Pleiades Publishing Ltd - Tập 56 - Trang 877-883 - 2020
X. Y. Xia1, W. Sun1, W. He1, Y. Feng1, L. Zhan1, Y. Luo1
1Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, China

Tóm tắt

A highly regioselective ring opening reaction of terminal epoxides with 2-bromobenzoic acid catalyzed by tetrabutylammonium bromide was accomplished. The procedure is operationally simple and practical for the synthesis of a series of β-hydroxy esters. Using this protocol, oxetan-3-ol could be prepared efficiently in a good yield.

Tài liệu tham khảo

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