A Journey of Metal‐metal Bonding beyond Cotton's Quadruple Bonds

Journal of the Chinese Chemical Society - Tập 61 Số 1 - Trang 9-26 - 2014
Shao‐An Hua1, Yi‐Chou Tsai2,3,4, Shie‐Ming Peng1,5,3,4
1Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan
2Department of Chemistry and Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu 30013, Taiwan
3Shie-Ming Peng, Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan, Tel: +886-3-5718232
4Yi-Chou Tsai, Department of Chemistry and Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu 30013, Taiwan, Tel: +886-2-33661655
5Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan, ROC

Tóm tắt

AbstractWhereas the study of the Cotton's quadruple bonding between two metal atoms has been mature, exploration of bonding, potential applications and reactivity in linear oligonuclear metal complexes and quintuple bonded dinuclear compounds is currently underway. Stabilized by four long‐chain organic ligands containing various numbers (3‐13) of nitrogen donors, many metal string complexes featuring a linear metal framework have been recognized. These novel linear oligonuclear metal complexes not only have interesting metal‐metal bonding, but also display potential applications as metal wires for electron conductance. In the relatively young metal‐to‐metal quintuple bonding, the thus far structurally characterized examples are limited to univalent chromium and molybdenum ions supported by sterically encumbered bidentate ligands. These low‐coordinate quintuple bonded dinuclear compounds display ultrashort metal‐metal bond lengths, and interesting reactivity towards inorganic small molecules and unsaturated organics, including complexation, reductive cleavage, and cycloaddition.

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Journal of the Chinese Chemical Society

Tập 61 Số 1

9-26

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