Preparation of Cu/ZnO-based heterogeneous catalysts by photochemical deposition, their characterisation and application for methanol synthesis from carbon dioxide and hydrogen

Fuel Processing Technology - Tập 146 - Trang 39-47 - 2016
M. Pori1, B. Likozar1, M. Marinšek2, Z. Crnjak Orel1
1National Institute of Chemistry, Hajdrihova 19, SI-1000, Ljubljana, Slovenia
2Faculty of Chemistry and Chemical Technology, Večna pot 113, SI-1000 Ljubljana, Slovenia

Tài liệu tham khảo

Karelovic, 2012, Effect of the structural and morphological properties of Cu/ZnO catalysts prepared by citrate method on their activity toward methanol synthesis from CO2 and H2 under mild reaction conditions, Catal. Today, 197, 109, 10.1016/j.cattod.2012.07.029 Wang, 2011, Characterization and performance of Cu/ZnO/Al2O3 catalysts prepared via decomposition of M(Cu,Zn)-ammonia complexes under sub-atmospheric pressure for methanol synthesis from H2 and CO2, J. Nat. Gas Chem., 20, 629, 10.1016/S1003-9953(10)60246-0 Ahouari, 2013, Methanol synthesis from CO2 hydrogenation over copper based catalysts, React. Kinet. Mech. Catal., 110, 131, 10.1007/s11144-013-0587-9 Olah, 2009, Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons, J. Org. Chem., 74, 487, 10.1021/jo801260f Behrens, 2010, The potential of microstructural optimization in metal/oxide catalysts: higher intrinsic activity of copper by partial embedding of copper nanoparticles, ChemCatChem, 2, 816, 10.1002/cctc.201000017 Natesakhawat, 2012, Active sites and structure–activity relationships of copper-based catalysts for carbon dioxide hydrogenation to methanol, ACS Catal., 2, 1667, 10.1021/cs300008g Samei, 2012, Enhancement of stability and activity of Cu/ZnO/Al2O3 catalysts by colloidal silica and metal oxides additives for methanol synthesis from a CO2-rich feed, Fuel Process. Technol., 96, 128, 10.1016/j.fuproc.2011.12.028 Saito, 2004, Development of high performance Cu/ZnO-based catalysts for methanol synthesis and the water–gas shift reaction, Catal. Surv. Asia, 8, 285, 10.1007/s10563-004-9119-y Zhai, 2008, Study on the deactivation phenomena of Cu-based catalyst for methanol synthesis in slurry phase, Fuel, 87, 430, 10.1016/j.fuel.2007.07.008 Twigg, 2003, Deactivation of copper metal catalysts for methanol decomposition, methanol steam reforming and methanol synthesis, Top. Catal., 22, 191, 10.1023/A:1023567718303 Jingfa, 1996, A novel process for preparationj of a Cu/ZnO/Al2O3 ultrafine catalysts for methanol synthesis from CO2+H2: comparison of various preparation methods, Appl. Catal. A, 139, 75, 10.1016/0926-860X(95)00324-X Bitenc, 2008, Preparation and characterization of zinc hydroxide carbonate and porous zinc oxide particles, J. Eur. Ceram. Soc., 28, 2915, 10.1016/j.jeurceramsoc.2008.05.003 Jung, 2002, Effects of zirconia phase on the synthesis of methanol over zirconia-supported copper, Catal. Lett., 80, 63, 10.1023/A:1015326726898 Arena, 2013, How oxide carriers control the catalytic functionality of the Cu–ZnO system in the hydrogenation of CO2 to methanol, Catal. Today, 210, 39, 10.1016/j.cattod.2013.02.016 Fujimoto, 1993, Spillover effect on the stabilization of Cu–Zn catalyst for CO2 hydrogenation to methanol, Stud. Surf. Sci. Catal., 393–6, 10.1016/S0167-2991(08)63219-X Moulijn, 2001, Catalyst deactivation: is it predictable? What to do?, 212, 3 Prakash, 2014, Synthesis and characterization of copper oxide nanopowders and their nanofluids, J. Appl. Chem., 3, 1025 Agarwal, 2005, H2 production by steam reforming of methanol over Cu/ZnO/Al2O3 catalysts: transient deactivation kinetics modeling, Appl. Catal. A Gen., 279, 155, 10.1016/j.apcata.2004.10.026 Guo, 2010, Glycine–nitrate combustion synthesis of CuO–ZnO–ZrO2 catalysts for methanol synthesis from CO2 hydrogenation, J. Catal., 271, 178, 10.1016/j.jcat.2010.01.009 Arena, 2007, Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol, J. Catal., 249, 185, 10.1016/j.jcat.2007.04.003 Agrell, 2003, Production of hydrogen from methanol over Cu/ZnO catalysts promoted by ZrO2 and Al2O3, J. Catal., 219, 389, 10.1016/S0021-9517(03)00221-5 Mehta, 1979, Catalytic synthesis of methanol from CO/H2, J. Catal., 57, 339, 10.1016/0021-9517(79)90001-0 Natesakhawat, 2013, Adsorption and deactivation characteristics of Cu/ZnO-based catalysts for methanol synthesis from carbon dioxide, Top. Catal., 56, 1752, 10.1007/s11244-013-0111-5 Kasatkin, 2007, Role of lattice strain and defects in copper particles on the activity of Cu/ZnO/Al2O3 catalysts for methanol synthesis, Angew. Chem. Int. Ed., 46, 7324, 10.1002/anie.200702600 Liu, 2003, Recent advances in catalysts for methanol synthesis via hydrogenation of CO and CO2, Ind. Eng. Chem. Res., 42, 6518, 10.1021/ie020979s Fujitani, 1998, The effect of ZnO in methanol synthesis catalysts on Cu dispersion and the specific activity, Catal. Lett., 56, 119, 10.1023/A:1019000927366 Spencer, 1998, Role of ZnO in methanol synthesis on copper catalysts, Catal. Lett., 50, 37, 10.1023/A:1019098414820 Burch, 1990, The role of copper and zinc oxide in methanol synthesis catalysts, J. Chem. Soc. Faraday Trans., 86, 2683, 10.1039/ft9908602683 Natesakhawat, 2013, Adsorption and deactivation characteristics of Cu/ZnO-based catalysts for methanol synthesis from carbon dioxide, Top. Catal., 56, 1752, 10.1007/s11244-013-0111-5 Kurtz, 2003, Deactivation of supported copper catalysts for methanol synthesis, Catal. Lett., 86, 77, 10.1023/A:1022663125977 Wu, 2001, The stability of Cu/ZnO-based catalysts in methanol synthesis from a CO2-rich feed and from a CO-rich feed, Appl Catal A, 218, 235, 10.1016/S0926-860X(01)00650-0 Lee, 2005, Liquid phase methanol and dimethyl ether synthesis from syngas, Top. Catal., 32, 197, 10.1007/s11244-005-2891-8 Li, 2014, Development of highly stable catalyst for methanol synthesis from carbon dioxide, Appl. Catal. A Gen., 469, 306, 10.1016/j.apcata.2013.10.010 Karelovic, 2015, The role of copper particle size in low pressure methanol synthesis via CO2 hydrogenation over Cu/ZnO catalysts, Catal. Sci. Technol., 5, 869, 10.1039/C4CY00848K Sun, 1999, Deactivation of Cu/ZnO/Al2O3 methanol synthesis catalyst by sintering, Ind. Eng. Chem. Res., 38, 3868, 10.1021/ie990078s Hartadi, 2015, Methanol formation by CO2 hydrogenation on Au/ZnO catalysts — effect of total pressure and influence of CO on the reaction characteristics, J. Catal., 333, 238, 10.1016/j.jcat.2015.11.002 Liu, 1984, The rate of methanol production on a copper–zinc oxide catalyst: the dependence on the feed composition, J. Catal., 90, 139, 10.1016/0021-9517(84)90094-0 Liu, 1985, The role of CO2 in methanol synthesis on Cu–Zn oxide: an isotope labeling study, J. Catal., 96, 251, 10.1016/0021-9517(85)90378-1 Klier, 1982, Catalytic synthesis of methanol from CO/H2, J. Catal., 74, 343, 10.1016/0021-9517(82)90040-9