Yuan‐Yuan Ma1, Xiaoli Dong1, Yonggang Wang1, Yongyao Xia1
1Department Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, Shanghai, 200433 China
Tóm tắt
AbstractHydrogen production through water splitting is considered a promising approach for solar energy harvesting. However, the variable and intermittent nature of solar energy and the co‐production of H2 and O2 significantly reduce the flexibility of this approach, increasing the costs of its use in practical applications. Herein, using the reversible n‐type doping/de‐doping reaction of the solid‐state polytriphenylamine‐based battery electrode, we decouple the H2 and O2 production in acid water electrolysis. In this architecture, the H2 and O2 production occur at different times, which eliminates the issue of gas mixing and adapts to the variable and intermittent nature of solar energy, facilitating the conversion of solar energy to hydrogen (STH). Furthermore, for the first time, we demonstrate a membrane‐free solar water splitting through commercial photovoltaics and the decoupled acid water electrolysis, which potentially paves the way for a new approach for solar water splitting.
