Designed polymeric conjugation motivates tunable activation of molecular oxygen in heterogeneous organic photosynthesis

Shi, 2012, Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant, Chem Soc Rev, 41, 3381, 10.1039/c2cs15224j Campbell, 2012, Overcoming the “oxidant oroblem”: strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu), Acc Chem Res, 45, 851, 10.1021/ar2002045 Stahl, 2004, Palladium oxidase catalysis: selective oxidation of organic chemicals by direct dioxygen-coupled turnover, Angew Chem Int Ed, 43, 3400, 10.1002/anie.200300630 Wang, 2017, In situ carbon homogeneous doping on ultrathin bismuth molybdate: a dual-purpose strategy for efficient molecular oxygen activation, Adv Funct Mater, 27, 1703923, 10.1002/adfm.201703923 Huang, 2020, Ultrafast O2 activation by copper oxide for 2,4-dichlorophenol degradation: The size-dependent surface reactivity, Chin Chem Lett, 31, 2769, 10.1016/j.cclet.2020.06.040 Lang, 2014, Selective aerobic oxidation mediated by TiO2 photocatalysis, Acc Chem Res, 47, 355, 10.1021/ar4001108 Deng, 2019, Organotellurium catalysis-enabled utilization of molecular oxygen as oxidant for oxidative deoximation reactions under solvent-free conditions, Sci Bull, 64, 1280, 10.1016/j.scib.2019.07.007 Cao, 2020, InP quantum dots on g-C3N4 nanosheets to promote molecular oxygen activation under visible light, Chin Chem Lett, 31, 2689, 10.1016/j.cclet.2020.07.032 Wang, 2020, Ketones as molecular co-catalysts for boosting exciton-based photocatalytic molecular oxygen activation, Angew Chem Int Ed, 59, 11093, 10.1002/anie.202003042 Long, 2013, Surface facet of palladium nanocrystals: a key parameter to the activation of molecular oxygen for organic catalysis and cancer treatment, J Am Chem Soc, 135, 3200, 10.1021/ja311739v Chen, 2019, Designed synthesis of a 2D porphyrin-based sp2 carbon-conjugated covalent organic framework for heterogeneous photocatalysis, Angew Chem Int Ed, 58, 6430, 10.1002/anie.201902543 Shi, 2020, 2D sp2 carbon-conjugated porphyrin covalent organic framework for cooperative photocatalysis with TEMPO, Angew Chem Int Ed, 59, 9088, 10.1002/anie.202000723 Luo, 2015, Carbazolic porous organic framework as an efficient, metal-free visible-light photocatalyst for organic synthesis, ACS Catal, 5, 2250, 10.1021/acscatal.5b00025 Huang, 2021, Enhanced photoelectrocatalytic activities for CH3OH to HCHO conversion on Fe2O3/MoO3: Fe-O-Mo covalency dominates the intrinsic activity, Angew Chem Int Ed, 60, 9546, 10.1002/anie.202101058 Ou, 2019, Photocatalytic cascade radical cyclization approach to bioactive indoline-alkaloids over donor-acceptor type conjugated microporous polymer, ACS Catal, 9, 5178, 10.1021/acscatal.9b00693 Li, 2020, Surface hydrogen bond network spatially confined BiOCl oxygen vacancy for photocatalysis, Sci Bull, 65, 1916, 10.1016/j.scib.2020.06.013 Tang, 2020, Oxidation of aromatic sulfides with molecular oxygen: controllable synthesis of sulfoxides or sulfones, Chin Chem Lett, 31, 2991, 10.1016/j.cclet.2020.03.030 Meng, 2020, 2D and 3D porphyrinic covalent organic frameworks: the influence of dimensionality on functionality, Angew Chem Int Ed, 59, 3624, 10.1002/anie.201913091 Zheng, 2018, Black phosphorus and polymeric carbon nitride heterostructure for photoinduced molecular oxygen activation, Adv Funct Mater, 28, 1705407, 10.1002/adfm.201705407 Lang, 2015, Synergistic photocatalytic aerobic oxidation of sulfides and amines on TiO2 under visible-light irradiation, Chem Sci, 6, 1075, 10.1039/C4SC02891K Lei, 2020, Synergistic effects of crystal structure and oxygen vacancy on Bi2O3 polymorphs: intermediates activation, photocatalytic reaction efficiency, and conversion pathway, Sci Bull, 65, 467, 10.1016/j.scib.2020.01.007 Xu, 2017, Selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using O2 and a photocatalyst of Co-thioporphyrazine bonded to g-C3N4, J Am Chem Soc, 139, 14775, 10.1021/jacs.7b08861 Soni, 2019, Generation of N-centered radicals via a photocatalytic energy transfer: remote double functionalization of arenes facilitated by singlet oxygen, J Am Chem Soc, 141, 10538, 10.1021/jacs.9b05572 Xia, 2020, Designing a 0D/2D s-scheme heterojunction over polymeric carbon nitride for visible-light photocatalytic inactivation of bacteria, Angew Chem Int Ed, 59, 5218, 10.1002/anie.201916012 Wang, 2020, Low-dimensional semiconductors in artificial photosynthesis: an outlook for the interactions between particles/quasiparticles, ACS Cent Sci, 6, 1058, 10.1021/acscentsci.0c00540 Byun, 2020, Designing conjugated porous polymers for visible light-driven photocatalytic chemical transformations, Mater Horiz, 7, 15, 10.1039/C9MH01071H Zhao, 2019, Synergy of dopants and defects in graphitic carbon nitride with exceptionally modulated band structures for efficient photocatalytic oxygen evolution, Adv Mater, 31, 1903545, 10.1002/adma.201903545 Guo, 2020, Steering exciton dissociation and charge migration in green synthetic oxygen-substituted ultrathin porous graphitic carbon nitride for boosted photocatalytic reactive oxygen species generation, Chem Eng J, 385, 10.1016/j.cej.2019.123919 Wang, 2020, An excitonic perspective on low-dimensional semiconductors for photocatalysis, J Am Chem Soc, 142, 14007, 10.1021/jacs.0c06966 Qian, 2020, Photocatalytic molecular oxygen activation by regulating excitonic effects in covalent organic frameworks, J Am Chem Soc, 142, 20763, 10.1021/jacs.0c09727 Wang, 2016, Enhanced singlet oxygen generation in oxidized graphitic carbon nitride for organic synthesis, Adv Mater, 28, 6940, 10.1002/adma.201601413 Wang, 2017, Boosting hot-electron generation: exciton dissociation at the order–disorder interfaces in polymeric photocatalysts, J Am Chem Soc, 139, 2468, 10.1021/jacs.6b12878 Wang, 2017, Rational design of high-mobility semicrystalline conjugated polymers with tunable charge polarity: beyond benzobisthiadiazole-based polymers, Adv Funct Mater, 27, 1604608, 10.1002/adfm.201604608 Cornil, 2001, Interchain interactions in organic π-conjugated materials: Impact on electronic structure, optical response, and charge transport, Adv Mater, 13, 1053, 10.1002/1521-4095(200107)13:14<1053::AID-ADMA1053>3.0.CO;2-7 Li, 2021, Diyne-linked and fully pi-conjugated polymetalloporphyrin nanosheets for outstanding heterogeneous catalysis, Sci Bull, 66, 354, 10.1016/j.scib.2020.06.019 Wang, 2020, Intermolecular cascaded π-conjugation channels for electron delivery powering CO2 photoreduction, Nat Commun, 11, 1149, 10.1038/s41467-020-14851-7 Dereka, 2017, Direct observation of a photochemical alkyne-allene reaction and of a twisted and rehybridized intramolecular charge-transfer state in a donor-acceptor dyad, J Am Chem Soc, 139, 16885, 10.1021/jacs.7b09591 Wang, 2017, Conjugated microporous polymer nanosheets for overall water splitting using visible light, Adv Mater, 29, 1702428, 10.1002/adma.201702428 Zhang, 2020, Trimethyltriazine-derived olefin-linked covalent organic framework with ultralong nanofibers, Sci Bull, 65, 1659, 10.1016/j.scib.2020.05.033 Chen, 2020, Acetylene and diacetylene functionalized covalent triazine frameworks as metal-free photocatalysts for hydrogen peroxide production: a new two-electron water oxidation pathway, Adv Mater, 32, 1904433, 10.1002/adma.201904433 Nosaka, 2017, Generation and detection of reactive oxygen species in photocatalysis, Chem Rev, 117, 11302, 10.1021/acs.chemrev.7b00161 Zhang, 2020, A highly crystalline perylene imide polymer with the robust built-in electric field for efficient photocatalytic water oxidation, Adv Mater, 32, 1907746, 10.1002/adma.201907746 Bi, 2018, Enhanced photocatalytic hydrogen evolution of NiCoP/g-C3N4 with improved separation efficiency and charge transfer efficiency, ChemSusChem, 11, 276, 10.1002/cssc.201701574 Jiang, 2018, Single-crystal TiO2 nanorods assembly for efficient and stable cocatalyst-free photocatalytic hydrogen evolution, Appl Catal B-Environ, 229, 1, 10.1016/j.apcatb.2018.01.079 Wang, 2017, Light-switchable oxygen vacancies in ultrafine Bi5O7Br nanotubes for boosting solar-driven nitrogen fixation in pure water, Adv Mater, 29, 1701774, 10.1002/adma.201701774 Wang, 2017, Giant electron-hole interactions in confined layered structures for molecular oxygen activation, J Am Chem Soc, 139, 4737, 10.1021/jacs.6b12273 Wang, 2018, Oxygen-vacancy-mediated exciton dissociation in BiOBr for boosting charge-carrier-involved molecular oxygen activation, J Am Chem Soc, 140, 1760, 10.1021/jacs.7b10997 Atilgan, 2020, Post-synthetically elaborated BODIPY-based porous organic polymers (POPs) for the photochemical detoxification of a sulfur mustard simulant, J Am Chem Soc, 142, 18554, 10.1021/jacs.0c07784 Zhang, 2019, A full-spectrum metal-free porphyrin supramolecular photocatalyst for dual functions of highly efficient hydrogen and oxygen evolution, Adv Mater, 31, 1806626, 10.1002/adma.201806626 Wang, 2018, Optically switchable photocatalysis in ultrathin black phosphorus nanosheets, J Am Chem Soc, 140, 3474, 10.1021/jacs.8b00719 Wang, 2015, Ultrathin black phosphorus nanosheets for efficient singlet oxygen generation, J Am Chem Soc, 137, 11376, 10.1021/jacs.5b06025 Rigo, 1979, Detection of superoxide ion in aqueous media by N-halopiperidines, Inorg Chim Acta, 35, 161, 10.1016/S0020-1693(00)93434-0 Wang, 1991, Study on superoxide anion groups: stability and trapping of superoxide anion groups in anhydrous acetonitrile, Acta Chim Sin, 49, 821 Wang, 2018, Highly efficient catalytic scavenging of oxygen free radicals with graphene-encapsulated metal nanoshields, Nano Res, 11, 2821, 10.1007/s12274-017-1912-9