Mixed fluoroamine complexes of chromium(III)

Springer Science and Business Media LLC - Tập 10 - Trang 128-130 - 1985
Jaume Casabó1, Andreu Solans1, Carmen Diaz2, Joan Ribas2, Alexandre Seguí2, Montserrat Corbella2
1Department de Química Inorgànica, Universitat Autónoma de Barcelona (Bellaterra), Barcelona, Spain
2Departament de Química Inorgànica, Facultat de Química, Universitat de Barcelona, Barcelona, Spain

Tóm tắt

Mixed difluoro(diamine)(diamme)chromium(III) complexes have been synthesized with ethylenediamine (en), 1,3 propanediamine(tn) and 1,2-cyclohexanediamine(chxn):trans-[CrF2(aa)(bb)]Br (aa=en, bb=tn; aa=tn, bb= chxn) andcis-[CrF2(aa)(bb)]Br (aa=en, bb=chxn). The corresponding fluoroaqua(diamine) (diamine)chromium(III) complexes have been prepared by acid hydrolysis as perchlorate or iodide salts. All have been characterized by chemical analysis, electronic and i.r. spectra and conductivity measurements.

Tài liệu tham khảo

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