Potassium distribution and isotope composition in the lithospheric mantle in relation to global Earth’s reservoirs

Arevalo, 2009, The K/U ratio of the silicate Earth: insights into mantle composition, structure and thermal evolution, Earth Planet. Sci. Lett., 278, 361, 10.1016/j.epsl.2008.12.023 Bedini, 1999, Distribution of incompatible trace elements between the constituents of spinel peridotite xenoliths: ICP-MS data from the East African rift, Geochim. Cosmochim. Acta, 63, 3883, 10.1016/S0016-7037(99)00154-4 Bénard, 2018, Oxidising agents in sub-arc mantle melts link slab devolatilisation and arc magmas, Nat. Commun., 9, 3500, 10.1038/s41467-018-05804-2 Bénard, 2021, Silica-rich spinel harzburgite residues formed by fractional hybridization-melting of the intra-oceanic supra-subduction zone mantle: new evidence from TUBAF seamount peridotites, Geochim. Cosmochim. Acta, 293, 477, 10.1016/j.gca.2020.11.001 Best, 1974, Mantle-derived amphibole within inclusions in alkalic-basaltic lavas, J. Geophys. Res., 79, 2107, 10.1029/JB079i014p02107 Bloom, 2020, Potassium isotope compositions of carbonaceous and ordinary chondrites: Implications on the origin of volatile depletion in the early solar system, Geochim. Cosmochim. Acta, 277, 111, 10.1016/j.gca.2020.03.018 Bodinier, 2004, Silicate, hydrous and carbonate metasomatism at Lherz, France: contemporaneous derivatives of silicate melt-harzburgite reaction, J. Petrol., 45, 299, 10.1093/petrology/egg107 Bodinier, 1990, Mechanisms of mantle metasomatism: geochemical evidence from the Lherz orogenic peridotite, J. Petrol., 31, 597, 10.1093/petrology/31.3.597 Boyd, 1978, Ultramafic nodules from the Kimberley pipes, South Africa, Geochim. Cosmochim. Acta, 42, 1367, 10.1016/0016-7037(78)90042-X Carlson, 2019, Compositional characteristics of the MORB mantle and bulk silicate earth based on spinel peridotites from the Tariat Region, Mongolia, Geochim. Cosmochim. Acta, 257, 206, 10.1016/j.gca.2019.05.010 Chazot, 1996, Silicate glasses in spinel lherzolites from Yemen: origin and composition, Chem. Geol., 134, 159, 10.1016/S0009-2541(96)00086-1 Chen, 2020, Potassium isotope fractionation during chemical weathering of basalts, Earth Planet. Sci. Lett., 539, 10.1016/j.epsl.2020.116192 Chen, 2019, High-precision potassium isotopic analysis by MC-ICP-MS: an inter-laboratory comparison and refined K atomic weight, J. Anal. At. Spectrom., 34, 160, 10.1039/C8JA00303C Dawson, 1982, Contrasting types of mantle metasomatism, Terra Cognita, 2, 232 Dawson, 1977, The MARID (mica-amphibole-rutile-ilmenite-diopside) suite of xenoliths in kimberlite, Geochim. Cosmochim. Acta, 41, 309, 10.1016/0016-7037(77)90239-3 Dawson, 1982, Upper-mantle amphiboles: a review, Mineral. Mag., 45, 35, 10.1180/minmag.1982.045.337.04 Delaney, 1980, Chemistry of micas from kimberlites and xenoliths: II. Primary- and secondary-textured micas from peridotite xenoliths, Geochim. Cosmochim. Acta, 44, 857, 10.1016/0016-7037(80)90266-5 Delpech, 2004, Feldspar from carbonate-rich silicate metasomatism in the shallow oceanic mantle under Kerguelen Islands (South Indian Ocean), Lithos, 75, 209, 10.1016/j.lithos.2003.12.018 Doucet, 2016, Zn isotopic heterogeneity in the mantle: A melting control?, Earth Planet. Sci. Lett., 451, 232, 10.1016/j.epsl.2016.06.040 Frey, 1974, The mineralogy, geochemistry and origin of lherzolite inclusions in Victorian basanites, Geochim. Cosmochim. Acta, 38, 1023, 10.1016/0016-7037(74)90003-9 Frey, 1978, Ultramafic inclusions from San Carlos, Arizona: petrologic and geochemical data bearing on their petrogenesis, Earth Planet Sci Lett, 38, 129, 10.1016/0012-821X(78)90130-9 Green, 1988, Mantle metasomatism by ephemeral carbonatite melts, Nature, 336, 459, 10.1038/336459a0 Grégoire, 2002, Trace element geochemistry of phlogopite-rich mafic mantle xenoliths: their classification and their relationship to phlogopite-bearing peridotites and kimberlites revisited, Contrib. Mineral. Petrol., 142, 603, 10.1007/s00410-001-0315-8 Hart, 1986, In search of a bulk-Earth composition, Chem. Geol., 57, 247, 10.1016/0009-2541(86)90053-7 Hille, 2019, Homogeneous and heavy potassium isotopic composition of global oceans, Sci. Bull., 64, 1740, 10.1016/j.scib.2019.09.024 Hiraga, 2004, Grain boundaries as reservoirs of incompatible elements in the Earth's mantle, Nature, 427, 699, 10.1038/nature02259 Hiraga, 2009, Systematic distribution of incompatible elements in mantle peridotite: importance of intra- and inter-granular melt-like components, Contrib. Miner. Petrol., 158, 149, 10.1007/s00410-009-0375-8 Hofmann, 1988, Chemical differentiation of the Earth: the relationship between mantle, continental crust, and oceanic crust, Earth Planet Sci Lett, 90, 297, 10.1016/0012-821X(88)90132-X Hofmann, 1997, Mantle geochemistry: the message from oceanic volcanism, Nature, 385, 219, 10.1038/385219a0 Hofmann, 2003, Sampling mantle heterogeneity through oceanic basalts: isotopes and trace elements, 61 Hofmann, 1982, Mantle plumes from ancient oceanic crust, Earth Planet Sci Lett, 57, 421, 10.1016/0012-821X(82)90161-3 Hu, 2018, High-precision analysis of potassium isotopes by HR-MC-ICPMS, Chem Geol, 493, 100, 10.1016/j.chemgeo.2018.05.033 Hu, 2021, Potassium isotopic evidence for sedimentary input to the mantle source of Lesser Antilles lavas, Geochim. Cosmochim. Acta, 295, 98, 10.1016/j.gca.2020.12.013 Hu, 2021, Potassium isotope fractionation during magmatic differentiation and the composition of the mantle, J. Geophys. Res. Solid Earth, 126, 10.1029/2020JB021543 Hu, 2020, Magnesium isotopic composition of metasomatized upper sub-arc mantle and its implications to Mg cycling in subduction zones, Geochim. Cosmochim. Acta, 278, 219, 10.1016/j.gca.2019.09.030 Hu, 2020, Potassium isotopic heterogeneity in subducting oceanic plates, Sci. Adv., 6, eabb2472, 10.1126/sciadv.abb2472 Huang, 2020, Heterogeneous potassium isotopic composition of the upper continental crust, Geochim. Cosmochim. Acta, 278, 122, 10.1016/j.gca.2019.05.022 Ionov, 2010, Petrology of mantle wedge lithosphere: new data on supra-subduction zone peridotite xenoliths from the andesitic Avacha volcano, Kamchatka, J. Petrol., 51, 327, 10.1093/petrology/egp090 Ionov, 2005, The provenance of fertile off-craton lithospheric mantle: Sr-Nd isotope and chemical composition of garnet and spinel peridotite xenoliths from Vitim, Siberia, Chem Geol, 217, 41, 10.1016/j.chemgeo.2004.12.001 Ionov, 2011, Melt evolution in subarc mantle: evidence from heating experiments on spinel-hosted melt inclusions in peridotite xenoliths from the andesitic Avacha volcano (Kamchatka, Russia), Contrib. Mineral. Petrol., 162, 1159, 10.1007/s00410-011-0645-0 Ionov, 2005, Hf isotope compositions and HREE variations in off-craton garnet and spinel peridotite xenoliths from central Asia, Geochim. Cosmochim. Acta, 69, 2399, 10.1016/j.gca.2004.11.008 Ionov, 2018, Reworking of Archean mantle in the NE Siberian craton by carbonatite and silicate melt metasomatism: evidence from a carbonate-bearing, dunite-to-websterite xenolith suite from the Obnazhennaya kimberlite, Geochim. Cosmochim. Acta, 224, 132, 10.1016/j.gca.2017.12.028 Ionov, 1999, Feldspar-Ti-oxide metasomatism in off-cratonic continental and oceanic upper mantle, Earth Planet. Sci. Lett., 165, 37, 10.1016/S0012-821X(98)00253-2 Ionov, 1992, Content and isotopic composition of sulphur in ultramafic xenoliths from central Asia, Earth Planet Sci Lett, 111, 269, 10.1016/0012-821X(92)90184-W Ionov, 2006, Discovery of whitlockite in mantle xenoliths: Inferences for water- and halogen-poor fluids and trace element residence in the terrestrial upper mantle, Earth Planet. Sci. Lett., 244, 201, 10.1016/j.epsl.2006.02.012 Ionov, 1994, Metasomatism-induced melting in mantle xenoliths from Mongolia, J. Petrol., 35, 753, 10.1093/petrology/35.3.753 Ionov, 1992, Evolution of the upper mantle beneath the southern Baikal rift zone: a Sr-Nd isotope study of xenoliths from the Bartoy volcanoes, Contrib. Mineral. Petrol., 111, 235, 10.1007/BF00348954 Ionov, 1995, Feldspar-bearing lherzolite xenoliths in alkali basalts from Hamar-Daban, southern Baikal region, Russia, Contrib. Mineral. Petrol., 122, 174, 10.1007/s004100050120 Ionov, 1997, Volatile-bearing minerals and lithophile trace elements in the upper mantle, Chem. Geol., 141, 153, 10.1016/S0009-2541(97)00061-2 Ionov, 1998, A geotherm and lithospheric cross-section for central Mongolia, 127 Ionov, 2019, Calcium isotopic signatures of carbonatite and silicate metasomatism, melt percolation and crustal recycling in the lithospheric mantle, Geochim. Cosmochim. Acta, 248, 1, 10.1016/j.gca.2018.12.023 Irving, 1980, Petrology and geochemistry of composite ultramafic xenoliths in alkalic basalts and implications for magmatic processes within the mantle, Am. J. Sci., 280-A, 389 Kamenetsky, 2012, Ultrafresh salty kimberlite of the Udachnaya-East pipe (Yakutia, Russia): a petrological oddity or fortuitous discovery?, Lithos, 152, 173, 10.1016/j.lithos.2012.04.032 Kang, 2017, Calcium isotopic fractionation in mantle peridotites by melting and metasomatism and Ca isotope composition of the Bulk Silicate Earth, Earth Planet Sci Lett, 474, 128, 10.1016/j.epsl.2017.05.035 Kang, 2019, Calcium isotope sources and fractionation during melt-rock interaction in the lithospheric mantle: evidence from pyroxenites, wehrlites, and eclogites, Chem. Geol., 524, 272, 10.1016/j.chemgeo.2019.06.010 Kang, 2020, Diffusion-driven Ca-Fe isotope fractionations in the upper mantle: implications for mantle cooling and melt infiltration, Geochim. Cosmochim. Acta, 290, 41, 10.1016/j.gca.2020.08.033 Li, 2019, K isotopes as a tracer for continental weathering and geological K cycling, Proc. Natl. Acad. Sci., 116, 8740, 10.1073/pnas.1811282116 Li, 2016, Precise measurement of stable potassium isotope ratios using a single focusing collision cell multi-collector ICP-MS, J. Anal. At. Spectrom., 31, 1023, 10.1039/C5JA00487J Li, 2019, First-principles investigation of equilibrium K isotope fractionation among K-bearing minerals, Geochim. Cosmochim. Acta, 264, 30, 10.1016/j.gca.2019.07.038 Liu, 2020, Extremely light K in subducted low-T altered oceanic crust: implications for K recycling in subduction zone, Geochim. Cosmochim. Acta, 277, 206, 10.1016/j.gca.2020.03.025 Liu, 2021, Contributions of slab-derived fluids to ultrapotassic rocks indicated by K isotopes, Lithos, 396-397, 106202, 10.1016/j.lithos.2021.106202 Lloyd, 1975, Light element metasomatism of the continental mantle: the evidence and the consequences, Phys. Chem. Earth, 9, 389, 10.1016/0079-1946(75)90030-0 Lundstrom, 2005, Observations of Li isotopic variations in the Trinity Ophiolite: evidence for isotopic fractionation by diffusion during mantle melting, Geochim. Cosmochim. Acta, 69, 735, 10.1016/j.gca.2004.08.004 Maaloe, 1977, The major element composition of the upper mantle estimated from the composition of lherzolites, Contrib. Mineral. Petrol., 63, 161, 10.1007/BF00398777 Marschall, 2007, The lithium isotopic composition of orogenic eclogites and deep subducted slabs, Earth Planet Sci Lett, 262, 563, 10.1016/j.epsl.2007.08.005 McDonough, 1990, Constraints on the composition of the continental lithospheric mantle, Earth Planet Sci Lett, 101, 1, 10.1016/0012-821X(90)90119-I McDonough, 1995, The composition of the Earth, Chem. Geol., 120, 223, 10.1016/0009-2541(94)00140-4 McDonough, 1992, Potassium, rubidium and cesium in the Earth and Moon and the evolution of the mantle of the Earth, Geochim. Cosmochim. Acta, 56, 1001, 10.1016/0016-7037(92)90043-I McNell, 1987, Sodium-rich metasomatism in the upper mantle: Implications of experiments on the Pyrolite-Na2O-rich fluid system at 950°C, 20 kbar, Geochim. Cosmochim. Acta, 51, 2285, 10.1016/0016-7037(87)90281-X Menzies, 1987, 500 Menzies, 1985, Interaction of continental lithosphere and asthenospheric melts below the Geronimo volcanic field, Arizona, U.S.A, J. Petrol., 26, 663, 10.1093/petrology/26.3.663 Morgan, 2018, High-precision 41K/39K measurements by MC-ICP-MS indicate terrestrial variability of δ41K, J. Anal. At. Spectrom., 33, 175, 10.1039/C7JA00257B Nakano, 1989, The multiphase grain control percolation: its implication for a partially molten rock, J. Geophys. Res. Solid Earth, 94, 15653, 10.1029/JB094iB11p15653 Navon, 1987, Geochemical consequences of melt percolation: the upper mantle as a chromatographic column, J. Geol., 95, 285, 10.1086/629131 Nielson, 1993, Actualistic models of mantle metasomatism documented in a composite xenolith from Dish Hill, California, Geochim. Cosmochim. Acta, 57, 105, 10.1016/0016-7037(93)90472-9 Palme, 2003, Cosmochemical estimates of mantle composition, 1 Parendo, 2017, K isotopes as a tracer of seafloor hydrothermal alteration, Proc. Natl. Acad. Sci., 114, 1827, 10.1073/pnas.1609228114 Pogge von Strandmann, 2008, Li and Mg isotopes in the mantle: heterogeneity or diffusion?, Geochim. Cosmochim. Acta, 72, A754 Pogge von Strandmann, 2011, Variations of Li and Mg isotope ratios in bulk chondrites and mantle xenoliths, Geochim. Cosmochim. Acta, 75, 5247, 10.1016/j.gca.2011.06.026 Press, 1986, Spinel peridotite xenoliths from the Tariat Depression, Mongolia. I: major element chemistry and mineralogy of a primitive mantle xenolith suite, Geochim. Cosmochim. Acta, 50, 2587, 10.1016/0016-7037(86)90212-7 Richter, 2014, Lithium isotope fractionation by diffusion in minerals. Part 1: pyroxenes, Geochim. Cosmochim. Acta, 126, 352, 10.1016/j.gca.2013.11.008 Richter, 2014, Isotope fractionation of Li and K in silicate liquids by Soret diffusion, Geochim. Cosmochim. Acta, 138, 136, 10.1016/j.gca.2014.04.012 Richter, 2009, Non-traditional fractionation of non-traditional isotopes: evaporation, chemical diffusion and Soret diffusion, Chem Geol, 258, 92, 10.1016/j.chemgeo.2008.06.011 Roden, 1985, Mantle metasomatism, Ann. Rev. Earth Planet. Sci., 13, 269, 10.1146/annurev.ea.13.050185.001413 Rudnick, 2007, Lithium elemental and isotopic disequilibrium in minerals from peridotite xenoliths from far-east Russia: product of recent melt/fluid-rock reaction, Earth Planet Sci Lett, 256, 278, 10.1016/j.epsl.2007.01.035 Salters, 2004, Composition of the depleted mantle, Geochem. Geophys. Geosyst., 5, Q05004, 10.1029/2003GC000597 Santiago Ramos, 2020, Low-temperature oceanic crust alteration and the isotopic budgets of potassium and magnesium in seawater, Earth Planet. Sci. Lett., 541, 116290, 10.1016/j.epsl.2020.116290 Stosch, 1980, Geochemistry and mineralogy of two spinel peridotite suites from Dreiser Weiher, West Germany, Geochim. Cosmochim. Acta, 44, 457, 10.1016/0016-7037(80)90044-7 Strelow, 1970, Accurate determination of traces of sodium and potassium in rocks by ion exchange followed by atomic absorption spectroscopy, Anal. Chim. Acta, 50, 399, 10.1016/0003-2670(70)80036-8 Sun, 2021, Ca isotope systematics of carbonatites: insights into carbonatite source and evolution, Geochem. Perspect. Lett., 17, 11, 10.7185/geochemlet.2107 Sun, 2020, Tracing subducted oceanic slabs in the mantle by using potassium isotopes, Geochim. Cosmochim. Acta, 278, 353, 10.1016/j.gca.2019.05.013 Teng, 2017, Non-traditional stable isotopes: retrospective and prospective, Rev. Mineral. Geochem., 82, 1, 10.2138/rmg.2017.82.1 Teng, 2020, Potassium isotope fractionation during continental weathering and implications for global K isotopic balance, Geochim. Cosmochim. Acta, 278, 261, 10.1016/j.gca.2020.02.029 Teng, 2007, Limited lithium isotopic fractionation during progressive metamorphic dehydration in metapelites: a case study from the Onawa contact aureole, Maine, Chem. Geol., 239, 1, 10.1016/j.chemgeo.2006.12.003 Toramaru, 1986, Connectivity of melt phase in a partially molten peridotite, J. Geophys. Res., 91, 9239, 10.1029/JB091iB09p09239 Tuller-Ross, 2019, Potassium isotope systematics of oceanic basalts, Geochim. Cosmochim. Acta, 259, 144, 10.1016/j.gca.2019.06.001 Tuller-Ross, 2019, Potassium isotope fractionation during magmatic differentiation of basalt to rhyolite, Chem Geol, 525, 37, 10.1016/j.chemgeo.2019.07.017 Wang, 2020, Global average potassium isotope composition of modern seawater, ACS Earth Space Chem., 4, 1010, 10.1021/acsearthspacechem.0c00047 Wang, 2016, An estimate of the Bulk Silicate Earth potassium isotopic composition based on MC-ICPMS measurements of basalts, Geochim. Cosmochim. Acta, 178, 223, 10.1016/j.gca.2015.12.039 Wang, 1999, Subsoliduc and melting experiments of a K-rich basaltic composition to 27 GPa: implication for the behavior of potassium in the mantle, Amer. Mineralogist, 84, 357, 10.2138/am-1999-0319 Wang, 2017, Potassium-rich magmatism from a phlogopite-free source, Geology, 45, 467, 10.1130/G38691.1 Watkins, 2017, Kinetic fractionation of non-traditional stable isotopes by diffusion and crystal growth reactions, Rev. Mineral. Geochem., 82, 85, 10.2138/rmg.2017.82.4 Weyer, 2007, Partial melting and melt percolation in the mantle: the message from Fe isotopes, Earth Planet. Sci. Lett., 259, 119, 10.1016/j.epsl.2007.04.033 Wiechert, 1997, Spinel peridotite xenoliths from the Atsagin-Dush volcano, Dariganga lava plateau, Mongolia: a record of partial melting and cryptic metasomatism in the upper mantle, Contrib. Mineral. Petrol., 126, 345, 10.1007/s004100050255 Witt-Eickschen, 1998, Evidence for the multiple stage evolution of the subcontinental lithospheric mantle beneath the Eifel (Germany) from pyroxenite and composite pyroxenite/peridotite xenoliths, Contrib. Mineral. Petrol., 131, 258, 10.1007/s004100050392 Wu, 2018, Diffusion-driven magnesium and iron isotope fractionation at a gabbro-granite boundary, Geochim. Cosmochim. Acta, 222, 671, 10.1016/j.gca.2017.11.010 Xia, 2017, Chromium isotope heterogeneity in the mantle, Earth Planet. Sci. Lett., 464, 103, 10.1016/j.epsl.2017.01.045 Xu, 1996, K-rich glass-bearing wehrlite xenoliths from Yitong, northeastern China: petrological and chemical evidence for mantle metasomatism, Contrib. Mineral. Petrol., 125, 406, 10.1007/s004100050231 Yaxley, 1998, Carbonate metasomatism in the southeastern Australian lithosphere, J. Petrol., 39, 1917, 10.1093/petroj/39.11-12.1917 Zeng, 2019, Ab Initio calculation of equilibrium isotopic fractionations of potassium and rubidium in minerals and water, ACS Earth Space Chem., 3, 2601, 10.1021/acsearthspacechem.9b00180 Ziberna, 2013, Garnet and spinel in fertile and depleted mantle: insights from thermodynamic modelling, Contrib. Mineral. Petrol., 166, 411, 10.1007/s00410-013-0882-5 Zinngrebe, 1995, Metasomatism in mantle xenoliths from Gees, West Eifel, Germany: evidence for the genesis of calc-alkaline glasses and metasomatic Ca-enrichment, Contrib. Mineral. Petrol., 122, 79, 10.1007/s004100050114