Synthesis and application of biomass-derived magnetic biochar catalyst for simultaneous esterification and trans-esterification of waste cooking oil into biodiesel: modeling and optimization
Tóm tắt
This work created, characterized, and used a magnetic biochar catalyst that is both eco-friendly and very effective. Sugarcane bagasse was selected as primary raw material for catalyst preparation, because it is renewable and ecofriendly biomass. Catalyst created by doping sugarcane bagasse biochar with magnetic material in the form of (FeSO4·7H2O). Thermogravimetric Analysis (TGA) and Fourier Transform Infrared spectroscopy (FTIR) were used to characterize the catalyst. In addition, physical and textural characteristics of the catalyst were identified and interpreted. The characterization outcome showed that the catalyst has good catalytic qualities. For the manufacturing of biodiesel, discarded cooking oil served as the primary feedstock. The experiment was created utilizing the Box–Behnken Design (BBD) technique. There are four variables with the following three levels each: temperature, methanol to oil ratio, catalyst concentration, and reaction time. 29 experiments in total were carried out. Using the RSM function, optimization was done. The optimal conditions for obtaining biodiesel yield—temperature, methanol to oil ratio, reaction time, and catalyst weight—were 43.597 °C, 9.975 mol/L, 49.945 min, and 1.758 wt%. A study of the produced biodiesel using a FTIR showed that the conventional biodiesel IR spectra were confirmed. All physiochemical characteristics found suggested the biodiesel complied with ASTM and EN norms. Overall, the synthesized catalyst had conducted simultaneous reactions in a single batch reactor and had demonstrated suitability for converting used cooking oil to biodiesel.
Tài liệu tham khảo
Abdullahi, K., et al.: Optimization of biodiesel production from Allamanda Seed Oil using design of experiment. Fuel Commun. 14(Novembr 2022), 100081 (2023). https://doi.org/10.1016/j.jfueco.2022.100081
Sun, X., Opulencia, M.J.C., Alexandrovich, T.P., Khan, A., Algarni, M., Abdelrahman, A.: Modeling and optimization of vegetable oil biodiesel production with heterogeneous nano catalytic process: Multi-layer perceptron, decision regression tree, and K-Nearest Neighbor methods. Environ. Technol. Innov. 27, 102794 (2022). https://doi.org/10.1016/j.eti.2022.102794
Abdullahi, K., et al.: Optimization of biodiesel production from Allamanda Seed Oil using design of experiment. Fuel Commun. 14(November 2022), 100081 (2023). https://doi.org/10.1016/j.jfueco.2022.100081
Kim, K., Suh, Y.W., Ha, J.M., An, J., Lee, U.: A comprehensive analysis of biphasic reaction system for economical biodiesel production process. Renew. Sustain. Energy Rev. 173(November 2022), 113122 (2023). https://doi.org/10.1016/j.rser.2022.113122
Roy, D.K., Abedin, M.Z.: Potentiality of biodiesel and bioethanol production from feedstock in Bangladesh: a review. Heliyon 8(11), e11213 (2022). https://doi.org/10.1016/j.heliyon.2022.e11213
Maheshwari, P., et al.: A review on latest trends in cleaner biodiesel production: role of feedstock, production methods, and catalysts. J. Clean. Prod. (2021). https://doi.org/10.1016/j.jclepro.2022.131588
Dhikrah, I., Sm, D., Na, S., As, B., Bu, B., Ms, J.: Optimization of biodiesel production from jatropha seed oil, using sulphated zirconia as catalyst. Chem. Sci. J. (2018). https://doi.org/10.4172/2150-3494.1000184
Muniz Sacco, F.C., Frkova, Z., Venditti, S., Pastore, C., Guignard, C., Hansen, J.: Operation of a pilot-scale lipid accumulation technology employing parameters to select Microthrix parvicella for biodiesel production from wastewater. Bioresour. Technol. 369(November 2022), 128498 (2023). https://doi.org/10.1016/j.biortech.2022.128498
Amenaghawon, A.N., Obahiagbon, K., Isesele, V., Usman, F.: Optimized biodiesel production from waste cooking oil using a functionalized bio-based heterogeneous catalyst. Clean. Eng. Technol. 8(May), 100501 (2022). https://doi.org/10.1016/j.clet.2022.100501
Ozor, P.A., Aigbodion, V.S., Sukdeo, N.I.: Modified calcium oxide nanoparticles derived from oyster shells for biodiesel production from waste cooking oil. Fuel Commun. 14(January), 100085 (2023). https://doi.org/10.1016/j.jfueco.2023.100085
Suzihaque, M.U.H., Syazwina, N., Alwi, H., Ibrahim, U.K., Abdullah, S., Haron, N.: A sustainability study of the processing of kitchen waste as a potential source of biofuel: biodiesel production from waste cooking oil (WCO). Mater. Today Proc. 63, S484–S489 (2022). https://doi.org/10.1016/j.matpr.2022.04.526
Otadi, M., Shahraki, A., Goharrokhi, M., Bandarchian, F.: Reduction of free fatty acids of waste oil by acid-catalyzed esterification. Procedia Eng. 18, 168–174 (2011). https://doi.org/10.1016/j.proeng.2011.11.027
Ahmed, R.A., Rashid, S., Huddersman, K.: Esterification of stearic acid using novel protonated and crosslinked amidoximated polyacrylonitrile ion exchange fibres. J. Ind. Eng. Chem. 119, 550–573 (2023). https://doi.org/10.1016/j.jiec.2022.12.001
Suzihaque, M.U.H., Alwi, H., Kalthum Ibrahim, U., Abdullah, S., Haron, N.: Biodiesel production from waste cooking oil: a brief review. Mater. Today Proc. 63, S490–S495 (2022). https://doi.org/10.1016/j.matpr.2022.04.527
Yaashikaa, P.R., Kumar, P.S., Varjani, S., Saravanan, A.: A critical review on the biochar production techniques, characterization, stability and applications for circular bioeconomy. Biotechnol. Rep. 28, e00570 (2020). https://doi.org/10.1016/j.btre.2020.e00570
Maroa, S., Inambao, F.: A review of sustainable biodiesel production using biomass derived heterogeneous catalysts. Eng. Life Sci. 21(12), 790–824 (2021). https://doi.org/10.1002/elsc.202100025
B. Hazmi, U. Rashid, M. L. Ibrahim, I. A. Nehdi, M. Azam, and S. I. Al-Resayes, “Synthesis and characterization of bifunctional magnetic nano-catalyst from rice husk for production of biodiesel,” Environ. Technol. Innov., vol. 21, p. 101296, 2021, doi: https://doi.org/10.1016/j.eti.2020.101296.
Abdelbasset, W.K., et al.: Development of multiple machine-learning computational techniques for optimization of heterogenous catalytic biodiesel production from waste vegetable oil: Development of multiple machine-learning computational techniques for optimization. Arab. J. Chem. 15(6), 103843 (2022). https://doi.org/10.1016/j.arabjc.2022.103843
Jiang, Y., et al.: Preparation of magnetic biochar and its catalytic role in degradation of Cu-EDTA by heterogeneous Fenton reaction. Water Sci. Technol. 87(2), 492–507 (2023). https://doi.org/10.2166/wst.2022.421
Latebo, S., Bekele, A., Abeto, T., Kasule, J.: Optimization of transesterification process and characterization of biodiesel from soapstock using silica sulfuric acid as a heterogeneous solid acid catalyst. J. Eng. Res. 10(1), 78–100 (2022). https://doi.org/10.36909/jer.12003
Hazmi, B., Rashid, U., Taufiq-Yap, Y.H., Ibrahim, M.L., Nehdi, I.A.: Supermagnetic nano-bifunctional catalyst from rice husk: synthesis, characterization and application for conversion of used cooking oil to biodiesel. Catalysts (2020). https://doi.org/10.3390/catal10020225
Reza, M.S., et al.: Biochar characterization of invasive Pennisetum purpureum grass: effect of pyrolysis temperature. Biochar 2(2), 239–251 (2020). https://doi.org/10.1007/s42773-020-00048-0
di Chen, Y., et al.: Magnetic biochar catalysts from anaerobic digested sludge: production, application and environment impact. Environ. Int. 126(February), 302–308 (2019). https://doi.org/10.1016/j.envint.2019.02.032
Quah, R.V., Tan, Y.H., Mubarak, N.M., Khalid, M., Abdullah, E.C., Nolasco-Hipolito, C.: An overview of biodiesel production using recyclable biomass and non-biomass derived magnetic catalysts. J. Environ. Chem. Eng. 7(4), 103219 (2019). https://doi.org/10.1016/j.jece.2019.103219
Jiang, Q., et al.: Halohydrin dehalogenase immobilization in magnetic biochar for sustainable halocarbon biodegradation and biotransformation. Environ. Technol. Innov. 27(4), 102759 (2022). https://doi.org/10.1016/j.eti.2022.102759
Cheng, L., Ji, Y.: Photocatalytic activation of sulfite by N-doped porous biochar/MnFe2O4 interface-driven catalyst for efficient degradation of tetracycline. Green Energy Environ. (2022). https://doi.org/10.1016/j.gee.2022.07.006
Parida, S., Singh, M., Pradhan, S.: Biomass wastes: A potential catalyst source for biodiesel production. Bioresour. Technol. Rep (2022). https://doi.org/10.1016/j.biteb.2022.101081
Wysoki, A., Olchowski, R., Dobrzy, J.: Raspberry stalks-derived biochar, magnetic biochar and urea modified magnetic biochar - Synthesis, characterization and application for As ( V ) and Cr ( VI ) removal from river water. J. Environ. Manag. (2022). https://doi.org/10.1016/j.jenvman.2022.115260
Ridwan, I., Budiastuti, H., Indarti, R., Wahyuni, N.L.E., Safitri, H.M., Ramadhan, R.L.: The optimization of tetrahydrofuran as a co-solvent on biodiesel production from rubber seeds using response surface methodology. Mater. Sci. Energy Technol. 6, 15–20 (2023). https://doi.org/10.1016/j.mset.2022.11.002
Almohana, A.I., et al.: Theoretical investigation on optimization of biodiesel production using waste cooking oil: machine learning modeling and experimental validation. Energy Rep. 8, 11938–11951 (2022). https://doi.org/10.1016/j.egyr.2022.08.265
Chen, R., Zhao, X., Jiao, J., Li, Y., Wei, M.: Surface-modified biochar with polydentate binding sites for the removal of cadmium. Int. J. Mol. Sci. (2019). https://doi.org/10.3390/ijms20071775
Grace, J.J.: Fourier transform infrared spectrophotometric analysis of functional groups in biodiesel produced from oils of Ricinus communis, Hevea brasiliensis and Jatropha curcas seeds. Int. J. Sci. Environ. Technol. 2(6), 1116–1121 (2013)
Oyerinde, A.Y., Bello, E.I.: Use of fourier transformation infrared ( FTIR ) spectroscopy for analysis of functional groups in peanut oil biodiesel and its blends. BJAST. 13(3), 1–14 (2016). https://doi.org/10.9734/BJAST/2016/22178
Donnell, S.O., et al.: A review on the spectroscopic analyses of biodiesel. Eur. Int. J. Sci. Technol. 2(7), 137–146 (2013)
Rachma Annisa, F., et al.: Reusability test of silica–titania catalyst on biodiesel production from waste cooking oil in various temperatures. Int. J. Sci. Res. Sci. Technol. 6(4), 116–123 (2019). https://doi.org/10.32628/ijsrst196414
Istadi, I., Mabruro, U., Kalimantini, B.A., Buchori, L., Anggoro, D.D.: Reusability and stability tests of calcium oxide based catalyst (K2O/CaO-ZnO) for transesterification of soybean oil to biodiesel. Bull. Chem. React. Eng. Catal. 11(1), 34–39 (2016). https://doi.org/10.9767/bcrec.11.1.413.34-39