Thermo-catalytic decomposition of methane: The effect of reaction parameters on process design and the utilization possibilities of the produced carbon

Energy Conversion and Management - Tập 126 - Trang 923-934 - 2016
Tiina Keipi1, Katariina E.S. Tolvanen1, Henrik Tolvanen1, Jukka Konttinen1
1Department of Chemistry and Bioengineering, Tampere University of Technology, P.O. Box 541, 33101 Tampere, Finland

Tài liệu tham khảo

International Energy Agency (IEA). Energy technology perspectives 2015. Tech rep; 2015. Framework Convention on Climate Change – Paris Agreement. <http://unfccc.int/paris_agreement/items/9485.php>; 2016 [accessed 23 May 2016]. International Energy Agency (IEA). Technology roadmap – carbon capture and storage 2013. Tech rep. <http://www.iea.org/publications/free-publications/publication/technology-roadmap-carbon-capture-and-storage-2013.html>; 2013. Dufour, 2009, Life cycle assessment of processes for hydrogen production. Environmental feasibility and reduction of greenhouse gases emissions, Int J Hydrogen Energy, 34, 1370, 10.1016/j.ijhydene.2008.11.053 Dufour, 2010, Life cycle assessment of hydrogen production by methane decomposition using carbonaceous catalysts, Int J Hydrogen Energy, 35, 1205, 10.1016/j.ijhydene.2009.11.093 Dufour, 2012, Life cycle assessment of alternatives for hydrogen production from renewable and fossil sources, Int J Hydrogen Energy, 37, 1173, 10.1016/j.ijhydene.2011.09.135 Serrano, 2013, Kinetic and autocatalytic effects during the hydrogen production by methane decomposition over carbonaceous catalysts, Int J Hydrogen Energy, 38, 5671, 10.1016/j.ijhydene.2013.02.112 Rokach, 2012, Should we pursue carbon capture for natural gas?, Electr J, 25, 64, 10.1016/j.tej.2012.06.001 International Energy Agency (IEA). Technology roadmap – hydrogen and fuel cells. Tech rep. <https://www.iea.org/publications/freepublications/publication/TechnologyRoadmapHydrogenandFuelCells.pdf>; 2015. International Energy Agency (IEA). World energy outlook 2014. Tech rep. <http://www.worldenergyoutlook.org/publications/weo-2014/>; 2014. Muradov, 1998, CO2-free production of hydrogen by catalytic pyrolysis of hydro-carbon fuel, Energy Fuels, 12, 41, 10.1021/ef9701145 Keipi, 2016, Techno-economic analysis of four concepts for thermal decomposition of methane: Reduction of CO2 emissions in natural gas combustion, Energy Convers Manage, 110, 1, 10.1016/j.enconman.2015.11.057 Triphob, 2012, Integrated methane decomposition and solid oxide fuel cell for efficient electrical power generation and carbon capture, Chem Eng Res Des, 90, 2223, 10.1016/j.cherd.2012.05.014 Muradov, 2001, Hydrogen via methane decomposition: an application for decarbonization of fossil fuels, Int J Hydrogen Energy, 26, 1165, 10.1016/S0360-3199(01)00073-8 Muradov, 2008, Green path from fossil-based to hydrogen economy: An overview of carbon-neutral technologies, Int J Hydrogen Energy, 33, 6804, 10.1016/j.ijhydene.2008.08.054 Fulcheri, 1995, From methane to hydrogen, carbon and water, Int J Hydrogen Energy, 20, 197, 10.1016/0360-3199(94)E0022-Q Kim, 2007, Continuous synthesis of nanostructured sheetlike carbons by thermal plasma decomposition of methane, IEEE Trans Plasma Sci, 35, 434, 10.1109/TPS.2007.892556 Steinberg, 1999, Fossil fuel decarbonization technology for mitigating global warming, Int J Hydrogen Energy, 24, 771, 10.1016/S0360-3199(98)00128-1 Geißler, 2015, Experimental investigation and thermo-chemical modeling of methane pyrolysis in a liquid metal bubble column reactor with a packed bed, Int J Hydrogen Energy, 40, 14134, 10.1016/j.ijhydene.2015.08.102 Geißler, 2016, Hydrogen production via methane pyrolysis in a liquid metal bubble column reactor with a packed bed, Chem Eng J, 299, 192, 10.1016/j.cej.2016.04.066 Schultz, 2015, Decarbonisation of fossil energy via methane pyrolysis using two reactor concepts: fluid wall flow reactor and molten metal capillary reactor, Int J Hydrogen Energy, 40, 11422, 10.1016/j.ijhydene.2015.03.126 Paxman, 2014, Initial experimental and theoretical investigation of solar molten media methane cracking for hydrogen production, Energy Proc, 49, 2027, 10.1016/j.egypro.2014.03.215 Plevan, 2015, Thermal cracking of methane in a liquid metal bubble column reactor: experiments and kinetic analysis, Int J Hydrogen Energy, 40, 8020, 10.1016/j.ijhydene.2015.04.062 Serban, 2003, Hydrogen production by direct contact pyrolysis of natural gas, Energy Fuels, 17, 705, 10.1021/ef020271q 2007 Holmen, 1995, Pyrolysis of natural gas: chemistry and process concepts, Fuel Process Technol, 42, 249, 10.1016/0378-3820(94)00109-7 National Institute of Standards and Technology. NIST-JANAF, thermochemical tables, www. <http://kinetics.nist.gov/janaf/>; 2016 [accessed 23 May 2016]. Villacampa, 2003, Catalytic decomposition of methane over Ni–Al2O3 coprecipitated catalysts: reaction and regeneration studies, Appl Catal A: Gen, 252, 363, 10.1016/S0926-860X(03)00492-7 Snoeck, 1997, Filamentous carbon formation and gasification: Thermodynamics, driving force, nucleation, and steady-state growth, J Catal, 169, 240, 10.1006/jcat.1997.1634 Guil-Lopez, 2011, Comparison of metal and carbon catalysts for hydrogen production by methane decomposition, Appl Catal A: Gen, 396, 40, 10.1016/j.apcata.2011.01.036 Ryu, 2007, Catalytic characteristics of various rubber-reinforcing carbon blacks in decomposition of methane for hydrogen production, Catal Today, 123, 303, 10.1016/j.cattod.2007.02.001 Lee, 2008, Catalytic characteristics of specialty carbon blacks in decomposition of methane for hydrogen production, Carbon, 46, 1978, 10.1016/j.carbon.2008.08.008 Suelves, 2007, Hydrogen production by methane decarbonization: Carbonaceous catalysts, Int J Hydrogen Energy, 32, 3320, 10.1016/j.ijhydene.2007.05.028 Kameya, 2011, Kinetic and Raman spectroscopic study on catalytic characteristics of carbon blacks in methane decomposition, Chem Eng J, 173, 627, 10.1016/j.cej.2011.08.017 Lee, 2004, Catalytic decomposition of methane over carbon blacks for CO2-free hydrogen production, Carbon, 42, 2641, 10.1016/j.carbon.2004.06.003 Wang, 2002, Formation of filamentous carbon during methane decomposition over Co–MgO catalysts, Carbon, 40, 1911, 10.1016/S0008-6223(02)00032-5 Takenaka, 2004, Formation of carbon nanofibers and carbon nanotubes through methane decomposition over supported cobalt catalysts, J Phys Chem B, 108, 11464, 10.1021/jp048827t Pudukudy, 2015, Methane decomposition over Ni, Co and Fe based monometallic catalysts supported on sol gel derived SiO2 microflakes, Chem Eng J, 262, 1009, 10.1016/j.cej.2014.10.077 Awadallah, 2014, Impact of group VI metals addition to Co/MgO catalyst for non-oxidative decomposition of methane into COx-free hydrogen and carbon nanotubes, Fuel, 129, 27, 10.1016/j.fuel.2014.03.038 Konieczny, 2008, Catalyst development for thermocatalytic decomposition of methane to hydrogen, Int J Hydrogen Energy, 33, 264, 10.1016/j.ijhydene.2007.07.054 Shah, 2001, Hydrogen production by catalytic decomposition of methane, Energy Fuels, 15, 1528, 10.1021/ef0101964 Torres, 2014, Hydrogen and multiwall carbon nanotubes production by catalytic decomposition of methane: Thermogravimetric analysis and scaling-up of Fe–Mo catalysts, Int J Hydrogen Energy, 39, 3698, 10.1016/j.ijhydene.2013.12.127 Awadallah, 2014, Catalytic thermal decomposition of methane to COx-free hydrogen and carbon nanotubes over MgO supported bimetallic group VIII catalysts, Appl Surf Sci, 296, 100, 10.1016/j.apsusc.2014.01.055 Pudukudy, 2015, Methane decomposition over Pd promoted Ni/MgAl2O4 catalysts for the production of COx free hydrogen and multiwalled carbon nanotubes, Appl Surf Sci, 356, 1320, 10.1016/j.apsusc.2015.08.246 Takenaka, 2003, Ni/SiO2 catalyst effective for methane decomposition into hydrogen and carbon nanofiber, J Catal, 217, 79 Suelves, 2005, Hydrogen production by thermo catalytic decomposition of methane on Ni-based catalysts: influence of operating conditions on catalyst deactivation and carbon characteristics, Int J Hydrogen Energy, 30, 1555, 10.1016/j.ijhydene.2004.10.006 Zaikovskii, 2001, The relationship between the state of active species in a Ni/Al2O3 catalyst and the mechanism of growth of filamentous carbon, Kinet Catal, 42, 813, 10.1023/A:1013235300777 Reshetenko, 2003, Carbon capacious Ni–Cu–Al2O3 catalysts for high-temperature methane decomposition, Appl Catal A: Gen, 247, 51, 10.1016/S0926-860X(03)00080-2 Uddin, 2015, Co-production of hydrogen and carbon nanofibers from methane decomposition over zeolite Y supported Ni catalysts, Energy Convers Manage, 90, 218, 10.1016/j.enconman.2014.10.060 Ermakova, 1999, New nickel catalysts for the formation of filamentous carbon in the reaction of methane decomposition, J Catal, 187, 77, 10.1006/jcat.1999.2562 Zhang, 1998, Hydrogen production via the direct cracking of methane over silica-supported nickel catalysts, Appl Catal A: Gen, 167, 161, 10.1016/S0926-860X(97)00143-9 Lua, 2014, Hydrogen production by catalytic decomposition of methane over Ni–Cu–Co alloy particles, Appl Catal B: Environ, 156–157, 84, 10.1016/j.apcatb.2014.02.046 Dahl, 2004, Solar-thermal dissociation of methane in a fluid-wall aerosol flow reactor, Int J Hydrogen Energy, 29, 725, 10.1016/j.ijhydene.2003.08.009 Rodat, 2011, Characterisation of carbon blacks produced by solar thermal dissociation of methane, Carbon, 49, 3084, 10.1016/j.carbon.2011.03.030 Muradov, 2005, From hydrocarbon to hydrogen-carbon to hydrogen economy, Int J Hydrogen Energy, 30, 225, 10.1016/j.ijhydene.2004.03.033 Abbas, 2010, Hydrogen production by methane decomposition: a review, Int J Hydrogen Energy, 35, 1160, 10.1016/j.ijhydene.2009.11.036 Ashik, 2015, Production of greenhouse gas free hydrogen by thermocatalytic decomposition of methane – A review, Renew Sustain Energy Rev, 44, 221, 10.1016/j.rser.2014.12.025 Abanades, 2008, Hydrogen production from solar thermal dissociation of methane in a high-temperature fluid-wall chemical reactor, vol. 47, 490 Maag, 2009, Solar thermal cracking of methane in a particle-flow reactor for the co-production of hydrogen and carbon, Int J Hydrogen Energy, 34, 7676, 10.1016/j.ijhydene.2009.07.037 Hirsch, 2004, Solar hydrogen production by thermal decomposition of natural gas using a vortex-flow reactor, Int J Hydrogen Energy, 29, 47, 10.1016/S0360-3199(03)00048-X Dunker, 2006, Production of hydrogen by thermal decomposition of methane in a fluidized-bed reactor – Effects of catalyst, temperature, and residence time, Int J Hydrogen Energy, 31, 473, 10.1016/j.ijhydene.2005.04.023 Lee, 2004, Thermocatalytic hydrogen production from the methane in a fluidized bed with activated carbon catalyst, Catal Today, 93–95, 81, 10.1016/j.cattod.2004.06.080 Ammendola, 2009, Production of hydrogen from thermo-catalytic decomposition of methane in a fluidized bed reactor, Chem Eng J, 154, 287, 10.1016/j.cej.2009.03.048 Weizhong, 2004, Production of hydrogen and carbon nanotubes from methane decomposition in a two-stage fluidized bed reactor, Appl Catal A: Gen, 260, 223, 10.1016/j.apcata.2003.10.018 Pinilla, 2010, Parametric study of the decomposition of methane using a NiCu/Al2O3 catalyst in a fluidized bed reactor, Int J Hydrogen Energy, 35, 9801, 10.1016/j.ijhydene.2009.10.008 Pinilla, 2007, Production of hydrogen and carbon nanofibers by thermal decomposition of methane using metal catalysts in a fluidized bed reactor, Int J Hydrogen Energy, 32, 4821, 10.1016/j.ijhydene.2007.08.013 Shah, 2007, Semi-continuous hydrogen production from catalytic methane decomposition using a fluidized-bed reactor, Int J Hydrogen Energy, 32, 3315, 10.1016/j.ijhydene.2007.04.040 Aiello, 2000, Hydrogen production via the direct cracking of methane over Ni/SiO2: catalyst deactivation and regeneration, Appl Catal A: Gen, 192, 227, 10.1016/S0926-860X(99)00345-2 Amin, 2012, Hydrogen production by methane cracking using Ni-supported catalysts in a fluidized bed, Int J Hydrogen Energy, 37, 10690, 10.1016/j.ijhydene.2012.04.082 Avdeeva, 1996, Coprecipitated Ni-alumina and Ni–Cu-alumina catalysts of methane decomposition and carbon deposition. II. Evolution of the catalysts in reaction, Appl Catal A: Gen, 141, 117, 10.1016/0926-860X(96)00026-9 Al-Hassani, 2014, Hydrogen production via decomposition of methane over activated carbons as catalysts: Full factorial design, Int J Hydrogen Energy, 39, 7004, 10.1016/j.ijhydene.2014.02.075 Kim, 2004, Hydrogen production by catalytic decomposition of methane over activated carbon: kinetic study, Int J Hydrogen Energy, 29, 187, 10.1016/S0360-3199(03)00111-3 Domínguez, 2007, Microwave-assisted catalytic decomposition of methane over activated carbon for CO2-free hydrogen production, Int J Hydrogen Energy, 32, 4792, 10.1016/j.ijhydene.2007.07.041 Fidalgo, 2008, Microwave-assisted pyrolysis of CH4/N2 mixtures over activated carbon, J Anal Appl Pyrol, 82, 158, 10.1016/j.jaap.2008.03.004 Gatica, 2013, Monolithic honeycomb design applied to carbon materials for catalytic methane decomposition, Appl Catal A: Gen, 458, 21, 10.1016/j.apcata.2013.03.016 Gatica, 2015, Unveiling the source of activity of carbon integral honeycomb monoliths in the catalytic methane decomposition reaction, Catal Today, 249, 86, 10.1016/j.cattod.2014.12.015 Heck, 2001, The application of monoliths for gas phase catalytic reactions, Chem Eng J, 82, 149, 10.1016/S1385-8947(00)00365-X Abánades, 2012, Technological challenges for industrial development of hydrogen production based on methane cracking, Energy, 46, 359, 10.1016/j.energy.2012.08.015 Wang, 2014, Deactivation and kinetic studies of unsupported Ni and Ni–Co–Cu alloy catalysts used for hydrogen production by methane decomposition, Chem Eng J, 243, 79, 10.1016/j.cej.2013.12.100 Abbas, 2009, Thermocatalytic decomposition of methane using palm shell based activated carbon: Kinetic and deactivation studies, Fuel Process Technol, 90, 1167, 10.1016/j.fuproc.2009.05.024 Pinilla, 2008, Kinetic study of the thermal decomposition of methane using carbonaceous catalysts, Chem Eng J, 138, 301, 10.1016/j.cej.2007.05.056 Muradov, 2005, Fossil hydrogen with reduced CO2 emission: modeling thermocatalytic decomposition of methane in a fluidized bed of carbon particles, Int J Hydrogen Energy, 30, 1149, 10.1016/j.ijhydene.2005.04.005 Borghei, 2010, Kinetics of methane decomposition to COx-free hydrogen and carbon nanofiber over Ni–Cu/MgO catalyst, Int J Hydrogen Energy, 35, 9479, 10.1016/j.ijhydene.2010.05.072 Ozalp, 2013, Kinetics and heat transfer analysis of carbon catalyzed solar cracking process, Energy, 55, 74, 10.1016/j.energy.2013.02.022 International Carbon Black Association (ICBA). What is carbon black?. <http://www.carbon-black.org/index.php/what-is-carbon-black>; 2016 [accessed 23 June 2016]. The Freedonia Group. World carbon black. <http://www.freedoniagroup.com/DocumentDetails.aspx?ReferrerId=FG-01&studyid=2596>; 2010 [accessed 23 June 2016]. Worldwide P. Activated carbon: US regulatory changes boost market for activated carbon. <http://www.process-worldwide.com/us-regulatory-changes-boost-market-for-activated-carbon-a-366700/>;2012 [accessed 23 June 2016]. Noble Group. Supplying China: examining the role of China in global steel markets. <http://www.slideshare.net/ulziimyagmar/23032012-examing-the-role-of-china-in-global-steel-markets-neil-t-dhar>; 2012 [accessed 23 June 2016]. Nanowerk. Global carbon nanotubes market – industry beckons. <http://www.nanowerk.com/spotlight/spotid=23118.php>;2011 [accessed 23 June 2016]. Díez, 2002, Coal for metallurgical coke production: predictions of coke quality and future requirements for cokemaking, Int J Coal Geol, 50, 389, 10.1016/S0166-5162(02)00123-4 Sid Richardson Carbon and Energy Co. Carbon black pricing. <http://www.sidrich.com/products-and-pricing/pricing/carbon-black-pricing/>; 2014 [accessed 7 March 2015]. Viet Delta Corp. Market analysis and price activated carbon coconut shell charcoal, activated carbon from December 2012 to November 2013. <http://vdeltafuel.com/news.html>; 2014. Steelonthenet.com. Met coke prices – Europe 2010-2016. <http://www.steelonthenet.com/files/blast-furnace-coke.html>; 2016. Cheap Tubes Inc. Cheap tubes: products. <https://www.cheaptubes.com/cheap-tubes-inc-online-shop/>; 2016. International Energy Agency (IEA). Energy technology network, hydrogen production & distribution. <http://www.iea-etsap.org/Energy_Technologies/Energy_Supply/Hydrogen_Production_and_Distribution.asp>; 2014 [accessed 21 June 2016]. Bolland, 2003, A novel methodology for comparing CO2 capture options for natural gas-fired combined cycle plants, Adv Environ Res, 7, 901, 10.1016/S1093-0191(02)00085-0 Gibbins, 2005, Maximizing the effectiveness of post combustion CO2 capture systems