Dielectric properties and electromagnetic simulation of molybdenum disulfide and ferric oxide-modified Ti3C2TX MXene hetero-structure for potential microwave absorption

Springer Science and Business Media LLC - Tập 5 - Trang 1548-1556 - 2022
Nannan Wu1, Beibei Zhao1, Xiaoyue Chen1, Chuanxin Hou2, Mina Huang3, A. Alhadhrami4, Gaber A. M. Mersal4, Mohamed M. Ibrahim4, Jian Tian1
1School of Material Science and Engineering, Shandong University of Science and Technology, Qingdao, People’s Republic of China
2School of Environmental and Material Engineering, Yantai University, Yantai, China
3College of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan, China
4Department of Chemistry, College of Science, Taif University, Taif, Saudi Arabia

Tóm tắt

As newly emerged 2D materials, Ti3C2TX MXene have exhibited great potential to be used as high-performance microwave absorption materials (MAs). In this study, multilayer accordion-like Ti3C2TX MXene coated by molybdenum disulfide (Ti3C2TX@MoS2) and ferric oxide (Ti3C2TX@Fe2O3) were fabricated through hydrothermal method. The dielectric properties of the paraffin wax consisting of 50 wt% Ti3C2TX, Ti3C2TX@MoS2, and Ti3C2TX@Fe2O3 were evaluated in 2–18 GHz, respectively. It is found that Ti3C2TX@MoS2 and Ti3C2TX@Fe2O3 displayed enhanced impedance matching than pure Ti3C2TX. The as-fabricated composites showed great potential for microwave absorption, for sample Ti3C2TX@MoS2 (mass ratio 1:1), which has the largest reflection loss (RL) value of − 60.2 dB at 16.6 GHz. The Ti3C2TX@Fe2O3 achieved optimal RL of − 18.6 dB at 17.4 GHz with thickness of 1.97 mm, and the effective absorption bandwidth (EAB) achieved 4.3 GHz (13.4–17.7 GHz) corresponding to thickness of 2.25 mm. The attenuation mechanisms were clarified by high-frequency structure simulator (HFSS). The interface polarization and multi-scattering make the dominant contributions for the improved microwave absorption.

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