Chu, S.: Carbon capture and sequestration. Science 325, 1599 (2009). https://doi.org/10.1126/science.1181637
Beuttler, C., Charles, L., Wurzbacher, J.: The role of direct air capture in mitigation of anthropogenic greenhouse gas emissions. Front. Clim. 1, 10 (2019). https://doi.org/10.3389/fclim.2019.00010
Al-Mamoori, A., Krishnamurthy, A., Rownaghi, A.A., et al.: Carbon capture and utilization update. Energy Technol. 5, 834–849 (2017). https://doi.org/10.1002/ente.201600747
Baena-Moreno, F.M., Rodríguez-Galán, M., Vega, F., et al.: Carbon capture and utilization technologies: a literature review and recent advances. Energy Sources A Recovery Util Environ. Eff. 41, 1403–1433 (2019)
Chemistry Industry Association of Canada: Chemistry: essential to Canada’s transition to a low-carbon energy future. https://canadianchemistry.ca/wp-content/uploads/2021/09/CIAC_LowCarbonPaper_English_June2019_FINAL.pdf (2018)
Ravanchi, M.T., Sahebdelfar, S.: Carbon dioxide capture and utilization in petrochemical industry: potentials and challenges. Appl. Petrochem. Res. 4, 63–77 (2014)
Griffin, P.W., Hammond, G.P., Norman, J.B.: Industrial energy use and carbon emissions reduction in the chemicals sector: a UK perspective. Appl. Energy 227, 587–602 (2018). https://doi.org/10.1016/j.apenergy.2017.08.010
De Luna, P., Hahn, C., Higgins, D., et al.: What would it take for renewably powered electrosynthesis to displace petrochemical processes? Science 364, eaav3506 (2019)
Teeter, T.E., Van Rysselberghe, P.: Reduction of carbon dioxide on mercury cathodes. J. Chem. Phys. 22, 759–760 (1954). https://doi.org/10.1063/1.1740178
Russell, P.G., Kovac, N., Srinivasan, S., et al.: The electrochemical reduction of carbon dioxide, formic acid, and formaldehyde. J. Electrochem. Soc. 124, 1329–1338 (1977). https://doi.org/10.1149/1.2133624
Udupa, K.S., Subramanian, G.S., Udupa, H.V.K.: The electrolytic reduction of carbon dioxide to formic acid. Electrochim. Acta 16, 1593–1598 (1971). https://doi.org/10.1016/0013-4686(71)80028-2
Hori, Y., Kikuchi, K., Suzuki, S.: Production of CO and CH4 in electrochemical reduction of CO2 at metal electrodes in aqueous hydrogencarbonate solution. Chem. Lett. 14, 1695–1698 (1985). https://doi.org/10.1246/cl.1985.1695
Hori, Y., Kikuchi, K., Murata, A., et al.: Production of methane and ethylene in electrochemical reduction of carbon dioxide at copper electrode in aqueous hydrogencarbonate solution. Chem. Lett. 15, 897–898 (1986). https://doi.org/10.1246/cl.1986.897
Hori, Y., Murata, A., Takahashi, R., et al.: Enhanced formation of ethylene and alcohols at ambient temperature and pressure in electrochemical reduction of carbon dioxide at a copper electrode. J. Chem. Soc. Chem. Commun. 1, 17–19 (1988). https://doi.org/10.1039/c39880000017
Hori, Y., Wakebe, H., Tsukamoto, T., et al.: Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media. Electrochim. Acta 39, 1833–1839 (1994). https://doi.org/10.1016/0013-4686(94)85172-7
Hori, Y., Murata, A., Takahashi, R.: Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution. J. Chem. Soc. Faraday Trans. 85, 2309 (1989). https://doi.org/10.1039/f19898502309
Hori, Y.: Electrochemical CO2 reduction on metal electrodes. In: Vayenas, C.G., White, R.E., Gamboa-Aldeco, M.E. (eds.) Modern Aspects of Electrochemistry, pp. 89–189. Springer, New York (2008)
Nitopi, S., Bertheussen, E., Scott, S.B., et al.: Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte. Chem. Rev. 119, 7610–7672 (2019). https://doi.org/10.1021/acs.chemrev.8b00705
Zhao, J., Xue, S., Barber, J., et al.: An overview of Cu-based heterogeneous electrocatalysts for CO2 reduction. J. Mater. Chem. A 8, 4700–4734 (2020). https://doi.org/10.1039/C9TA11778D
Usman, M., Humayun, M., Garba, M.D., et al.: Electrochemical reduction of CO2: a review of cobalt based catalysts for carbon dioxide conversion to fuels. Nanomaterials (Basel) 11, 2029 (2021)
Pei, Y.H., Zhong, H., Jin, F.M.: A brief review of electrocatalytic reduction of CO2: materials, reaction conditions, and devices. Energy Sci. Eng. 9, 1012–1032 (2021). https://doi.org/10.1002/ese3.935
Liu, A.M., Gao, M.F., Ren, X.F., et al.: Current progress in electrocatalytic carbon dioxide reduction to fuels on heterogeneous catalysts. J. Mater. Chem. A 8, 3541–3562 (2020). https://doi.org/10.1039/C9TA11966C
Zhang, X.L., Guo, S.X., Gandionco, K.A., et al.: Electrocatalytic carbon dioxide reduction: from fundamental principles to catalyst design. Mater. Today. Adv. 7, 100074 (2020). https://doi.org/10.1016/j.mtadv.2020.100074
Lees, E.W., Mowbray, B.A.W., Parlane, F.G.L., et al.: Gas diffusion electrodes and membranes for CO2 reduction electrolysers. Nat. Rev. Mater. 7, 55–64 (2022). https://doi.org/10.1038/s41578-021-00356-2
Ye, K., Zhang, G.R., Ma, X.Y., et al.: Resolving local reaction environment toward an optimized CO2-to-CO conversion performance. Energy Environ. Sci. 15, 749–759 (2022). https://doi.org/10.1039/D1EE02966E
Li, H., Oloman, C.: Development of a continuous reactor for the electro-reduction of carbon dioxide to formate. Part 2. Scale-up. J. Appl. Electrochem. 37, 1107–1117 (2007). https://doi.org/10.1007/s10800-007-9371-8
Subramanian, K., Asokan, K., Jeevarathinam, D., et al.: Electrochemical membrane reactor for the reduction of carbon dioxide to formate. J. Appl. Electrochem. 37, 255–260 (2007). https://doi.org/10.1007/s10800-006-9252-6
Weekes, D.M., Salvatore, D.A., Reyes, A., et al.: Electrolytic CO2 reduction in a flow cell. Acc. Chem. Res. 51, 910–918 (2018). https://doi.org/10.1021/acs.accounts.8b00010
Zhang, M., Wei, W.B., Zhou, S.H., et al.: Engineering a conductive network of atomically thin bismuthene with rich defects enables CO2 reduction to formate with industry-compatible current densities and stability. Energy Environ. Sci. 14, 4998–5008 (2021). https://doi.org/10.1039/D1EE01495A
Delacourt, C., Ridgway, P.L., Kerr, J.B., et al.: Design of an electrochemical cell making syngas (CO + H2) from CO2 and H2O reduction at room temperature. J. Electrochem. Soc. 155, B42 (2008). https://doi.org/10.1149/1.2801871
Narayanan, S.R., Haines, B., Soler, J., et al.: Electrochemical conversion of carbon dioxide to formate in alkaline polymer electrolyte membrane cells. J. Electrochem. Soc. 158, A167 (2011). https://doi.org/10.1149/1.3526312
Whipple, D.T., Finke, E.C., Kenis, P.J.A.: Microfluidic reactor for the electrochemical reduction of carbon dioxide: the effect of pH. Electrochem. Solid State Lett. 13, B109 (2010). https://doi.org/10.1149/1.3456590
Shironita, S., Karasuda, K., Sato, K., et al.: Methanol generation by CO2 reduction at a Pt–Ru/C electrocatalyst using a membrane electrode assembly. J. Power Sources 240, 404–410 (2013). https://doi.org/10.1016/j.jpowsour.2013.04.034
Lee, S., Ocon, J.D., Son, Y.I., et al.: Alkaline CO2 electrolysis toward selective and continuous HCOO– production over SnO2 nanocatalysts. J. Phys. Chem. C 119, 4884–4890 (2015). https://doi.org/10.1021/jp512436w
Surya Prakash, G.K., Viva, F.A., Olah, G.A.: Electrochemical reduction of CO2 over Sn-Nafion® coated electrode for a fuel-cell-like device. J. Power Sources 223, 68–73 (2013). https://doi.org/10.1016/j.jpowsour.2012.09.036
Li, Y.C., Zhou, D.K., Yan, Z.F., et al.: Electrolysis of CO2 to syngas in bipolar membrane-based electrochemical cells. ACS Energy Lett. 1, 1149–1153 (2016). https://doi.org/10.1021/acsenergylett.6b00475
Masel, R.I., Liu, Z.C., Sajjad, S.: Anion exchange membrane electrolyzers showing 1 A cm–2 at less than 2 V. ECS Trans. 75, 1143–1146 (2016). https://doi.org/10.1149/07514.1143ecst
Shao, B., Zhang, Y., Sun, Z.Y., et al.: CO2 capture and in-situ conversion: recent progresses and perspectives. Green Chem. Eng. 3, 189–198 (2022). https://doi.org/10.1016/j.gce.2021.11.009
Matin, A.J., Larrazábal, G.O., Pérez-Ramírez, J.: Towards sustainable fuels and chemicals through the electrochemical reduction of CO2: lessons from water electrolysis. Green Chem. 17, 5114–5130 (2015). https://doi.org/10.1039/C5GC01893E
Hydrogen and Fuel Cell Technologies Office: DOE technical targets for hydrogen production from electrolysis. https://www.energy.gov/eere/fuelcells/hydrogen-production-electrolysis
Verma, S., Kim, B., Jhong, H.R.M., et al.: A gross-margin model for defining technoeconomic benchmarks in the electroreduction of CO2. ChemSusChem 9, 1972–1979 (2016). https://doi.org/10.1002/cssc.201600394
Bushuyev, O.S., De Luna, P., Dinh, C.T., et al.: What should we make with CO2 and how can we make it? Joule 2, 825–832 (2018). https://doi.org/10.1016/j.joule.2017.09.003
Jouny, M., Luc, W., Jiao, F.: General techno-economic analysis of CO2 electrolysis systems. Ind. Eng. Chem. Res. 57, 2165–2177 (2018). https://doi.org/10.1021/acs.iecr.7b03514
Verma, S., Lu, S., Kenis, P.J.A.: Co-electrolysis of CO2 and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption. Nat. Energy 4, 466–474 (2019). https://doi.org/10.1038/s41560-019-0374-6
Yadegari, H., Ozden, A., Alkayyali, T., et al.: Glycerol oxidation pairs with carbon monoxide reduction for low-voltage generation of C2 and C3 product streams. ACS Energy Lett. 6, 3538–3544 (2021). https://doi.org/10.1021/acsenergylett.1c01639
Endrődi, B., Kecsenovity, E., Samu, A., et al.: High carbonate ion conductance of a robust PiperION membrane allows industrial current density and conversion in a zero-gap carbon dioxide electrolyzer cell. Energy Environ. Sci. 13, 4098–4105 (2020). https://doi.org/10.1039/D0EE02589E
Liang, S.Y., Altaf, N., Huang, L., et al.: Electrolytic cell design for electrochemical CO2 reduction. J. CO2 Util. 35, 90–105 (2020). https://doi.org/10.1016/j.jcou.2019.09.007
Chaplin, R.P.S., Wragg, A.A.: Effects of process conditions and electrode material on reaction pathways for carbon dioxide electroreduction with particular reference to formate formation. J. Appl. Electrochem. 33, 1107–1123 (2003). https://doi.org/10.1023/B:JACH.0000004018.57792.b8
Varela, A.S.: The importance of pH in controlling the selectivity of the electrochemical CO2 reduction. Curr. Opin. Green Sustain. Chem. 26, 100371 (2020). https://doi.org/10.1016/j.cogsc.2020.100371
Zhang, Z.S., Melo, L., Jansonius, R.P., et al.: pH matters when reducing CO2 in an electrochemical flow cell. ACS Energy Lett. 5, 3101–3107 (2020). https://doi.org/10.1021/acsenergylett.0c01606
Vennekoetter, J.B., Sengpiel, R., Wessling, M.: Beyond the catalyst: how electrode and reactor design determine the product spectrum during electrochemical CO2 reduction. Chem. Eng. J. 364, 89–101 (2019). https://doi.org/10.1016/j.cej.2019.01.045
Varcoe, J.R., Atanassov, P., Dekel, D.R., et al.: Anion-exchange membranes in electrochemical energy systems. Energy Environ. Sci. 7, 3135–3191 (2014). https://doi.org/10.1039/C4EE01303D
Du, N.Y., Roy, C., Peach, R., et al.: Anion-exchange membrane water electrolyzers. Chem. Rev. 122, 11830–11895 (2022). https://doi.org/10.1021/acs.chemrev.1c00854
Vermaas, D.A., Smith, W.A.: Synergistic electrochemical CO2 reduction and water oxidation with a bipolar membrane. ACS Energy Lett. 1, 1143–1148 (2016). https://doi.org/10.1021/acsenergylett.6b00557
Pärnamäe, R., Mareev, S., Nikonenko, V., et al.: Bipolar membranes: a review on principles, latest developments, and applications. J. Membr. Sci. 617, 118538 (2021). https://doi.org/10.1016/j.memsci.2020.118538
Oener, S.Z., Foster, M.J., Boettcher, S.W.: Accelerating water dissociation in bipolar membranes and for electrocatalysis. Science 369, 1099–1103 (2020). https://doi.org/10.1126/science.aaz1487
Hohenadel, A., Powers, D., Wycisk, R., et al.: Electrochemical characterization of hydrocarbon bipolar membranes with varying junction morphology. ACS Appl. Energy Mater. 2, 6817–6824 (2019). https://doi.org/10.1021/acsaem.9b01257
Li, T.F., Lees, E.W., Zhang, Z.S., et al.: Conversion of bicarbonate to formate in an electrochemical flow reactor. ACS Energy Lett. 5, 2624–2630 (2020). https://doi.org/10.1021/acsenergylett.0c01291
Küngas, R.: Review—electrochemical CO2 reduction for CO production: comparison of low- and high-temperature electrolysis technologies. J. Electrochem. Soc. 167, 044508 (2020). https://doi.org/10.1149/1945-7111/ab7099
Salvatore, D.A., Gabardo, C.M., Reyes, A., et al.: Designing anion exchange membranes for CO2 electrolysers. Nat. Energy 6, 339–348 (2021). https://doi.org/10.1038/s41560-020-00761-x
Chen, N.J., Wang, H.H., Kim, S.P., et al.: Poly(fluorenyl aryl piperidinium) membranes and ionomers for anion exchange membrane fuel cells. Nat. Commun. 12, 2367 (2021). https://doi.org/10.1038/s41467-021-22612-3
Ran, J., Wu, L., He, Y.B., et al.: Ion exchange membranes: new developments and applications. J. Membr. Sci. 522, 267–291 (2017). https://doi.org/10.1016/j.memsci.2016.09.033
Dang, H.S., Jannasch, P.: A comparative study of anion-exchange membranes tethered with different hetero-cycloaliphatic quaternary ammonium hydroxides. J. Mater. Chem. A 5, 21965–21978 (2017). https://doi.org/10.1039/C7TA06029G
Kusoglu, A., Weber, A.Z.: New insights into perfluorinated sulfonic-acid ionomers. Chem. Rev. 117, 987–1104 (2017). https://doi.org/10.1021/acs.chemrev.6b00159
Duarte, M., De Mot, B., Hereijgers, J., et al.: Electrochemical reduction of CO2: effect of convective CO2 supply in gas diffusion electrodes. ChemElectroChem 6, 5596–5602 (2019). https://doi.org/10.1002/celc.201901454
Zhang, X., Li, J.C., Li, Y.Y., et al.: Selective and high current CO2 electro-reduction to multicarbon products in near-neutral KCl electrolytes. J. Am. Chem. Soc. 143, 3245–3255 (2021). https://doi.org/10.1021/jacs.0c13427
Sen, S., Brown, S.M., Leonard, M., et al.: Electroreduction of carbon dioxide to formate at high current densities using tin and tin oxide gas diffusion electrodes.J. Appl. Electrochem. 49, 917–928 (2019). https://doi.org/10.1007/s10800-019-01332-z
Gabardo, C.M., O’Brien, C.P., Edwards, J.P., et al.: Continuous carbon dioxide electroreduction to concentrated multi-carbon products using a membrane electrode assembly. Joule 3, 2777–2791 (2019). https://doi.org/10.1016/j.joule.2019.07.021
Kaczur, J.J., Yang, H.Z., Liu, Z.C., et al.: Carbon dioxide and water electrolysis using new alkaline stable anion membranes. Front. Chem. 6, 263 (2018). https://doi.org/10.3389/fchem.2018.00263
Chen, K.J., Cao, M.Q., Lin, Y.Y., et al.: Ligand engineering in nickel phthalocyanine to boost the electrocatalytic reduction of CO2. Adv. Funct. Mater. 32, 2111322 (2022). https://doi.org/10.1002/adfm.202111322
Lees, E.W., Goldman, M., Fink, A.G., et al.: Electrodes designed for converting bicarbonate into CO. ACS Energy Lett. 5, 2165–2173 (2020). https://doi.org/10.1021/acsenergylett.0c00898
Ramdin, M., Morrison, A.R.T., de Groen, M., et al.: High pressure electrochemical reduction of CO2 to formic acid/formate: a comparison between bipolar membranes and cation exchange membranes. Ind. Eng. Chem. Res. 58, 1834–1847 (2019). https://doi.org/10.1021/acs.iecr.8b04944
He, G.W., Li, Z., Zhao, J., et al.: Nanostructured ion-exchange membranes for fuel cells: recent advances and perspectives. Adv. Mater. 27, 5280–5295 (2015). https://doi.org/10.1002/adma.201501406
Hou, Y., Liang, Y.L., Shi, P.C., et al.: Atomically dispersed Ni species on N-doped carbon nanotubes for electroreduction of CO2 with nearly 100% CO selectivity. Appl. Catal. B Environ. 271, 118929 (2020). https://doi.org/10.1016/j.apcatb.2020.118929
Zhou, Y., Zhou, R., Zhu, X.R., et al.: Mesoporous PdAg nanospheres for stable electrochemical CO2 reduction to formate. Adv. Mater. 32, e2000992 (2020). https://doi.org/10.1002/adma.202000992
Tang, J.K., Zhu, C.Y., Jiang, T.W., et al.: Anion exchange-induced single-molecule dispersion of cobalt porphyrins in a cationic porous organic polymer for enhanced electrochemical CO2 reduction via secondary-coordination sphere interactions. J. Mater. Chem. A 8, 18677–18686 (2020). https://doi.org/10.1039/D0TA07068H
Lv, X.M., Shang, L.M., Zhou, S., et al.: Electron-deficient Cu sites on Cu3Ag1 catalyst promoting CO2 electroreduction to alcohols. Adv. Energy Mater. 10, 2001987 (2020). https://doi.org/10.1002/aenm.202001987
Ma, W.C., Xie, S.J., Liu, T.T., et al.: Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper. Nat. Catal. 3, 478–487 (2020). https://doi.org/10.1038/s41929-020-0450-0
Sato, M., Ogihara, H., Yamanaka, I.: Electrocatalytic reduction of CO2 to CO and CH4 by Co–N–C catalyst and Ni co-catalyst with PEM reactor. ISIJ Int. 59, 623–627 (2019). https://doi.org/10.2355/isijinternational.isijint-2018-551
Zhang, Z.S., Lees, E.W., Ren, S.X., et al.: Conversion of reactive carbon solutions into CO at low voltage and high carbon efficiency. ACS Cent. Sci. 8, 749–755 (2022). https://doi.org/10.1021/acscentsci.2c00329
Ogungbemi, E., Ijaodola, O., Khatib, F.N., et al.: Fuel cell membranes: pros and cons. Energy 172, 155–172 (2019). https://doi.org/10.1016/j.energy.2019.01.034
junge Puring, K., Evers, O., Prokein, M., et al.: Assessing the influence of supercritical carbon dioxide on the electrochemical reduction to formic acid using carbon-supported copper catalysts. ACS Catal. 10, 12783–12789 (2020). https://doi.org/10.1021/acscatal.0c02983
Rasul, S., Pugnant, A., Xiang, H., et al.: Low cost and efficient alloy electrocatalysts for CO2 reduction to formate. J. CO2 Util. 32, 1–10 (2019). https://doi.org/10.1016/j.jcou.2019.03.016
Bose, S., Kuila, T., Nguyen, T.X.H., et al.: Polymer membranes for high temperature proton exchange membrane fuel cell: recent advances and challenges. Prog. Polym. Sci. 36, 813–843 (2011). https://doi.org/10.1016/j.progpolymsci.2011.01.003
Gutiérrez-Guerra, N., Valverde, J.L., Romero, A., et al.: Electrocatalytic conversion of CO2 to added-value chemicals in a high-temperature proton-exchange membrane reactor. Electrochem. Commun. 81, 128–131 (2017). https://doi.org/10.1016/j.elecom.2017.06.018
Luo, T., Abdu, S., Wessling, M.: Selectivity of ion exchange membranes: a review. J. Membr. Sci. 555, 429–454 (2018). https://doi.org/10.1016/j.memsci.2018.03.051
Kamcev, J., Paul, D.R., Manning, G.S., et al.: Ion diffusion coefficients in ion exchange membranes: significance of counterion condensation. Macromolecules 51, 5519–5529 (2018). https://doi.org/10.1021/acs.macromol.8b00645
Thampan, T., Malhotra, S., Tang, H., et al.: Modeling of conductive transport in proton-exchange membranes for fuel cells. J. Electrochem. Soc. 147, 3242 (2000). https://doi.org/10.1149/1.1393890
Weng, L.C., Bell, A.T., Weber, A.Z.: Towards membrane-electrode assembly systems for CO2 reduction: a modeling study. Energy Environ. Sci. 12, 1950–1968 (2019). https://doi.org/10.1039/C9EE00909D
Peckham, T.J., Holdcroft, S.: Structure-morphology-property relationships of non-perfluorinated proton-conducting membranes. Adv. Mater. 22, 4667–4690 (2010). https://doi.org/10.1002/adma.201001164
DeLuca, N.W., Elabd, Y.A.: Polymer electrolyte membranes for the direct methanol fuel cell: a review. J. Polym. Sci. B Polym. Phys. 44, 2201–2225 (2006). https://doi.org/10.1002/polb.20861
Choi, P., Jalani, N.H., Datta, R.: Thermodynamics and proton transport in Nafion. J. Electrochem. Soc. 152, E123 (2005). https://doi.org/10.1149/1.1859814
Hickner, M.A.: Ion-containing polymers: new energy & clean water. Mater. Today 13, 34–41 (2010). https://doi.org/10.1016/S1369-7021(10)70082-1
Ersöz, M.: Diffusion and selective transport of alkali cations on cation-exchange membrane. Sep. Sci. Technol. 30, 3523–3533 (1995). https://doi.org/10.1080/01496399508015133
Liao, W.C., Tsai, D.H., Hong, W.Z., et al.: Enabling direct CO2 electrolysis by alkali metal cation substituted membranes in a gas diffusion electrode reactor. Chem. Eng. J. 434, 134765 (2022). https://doi.org/10.1016/j.cej.2022.134765
Huang, J.E., Li, F.W., Ozden, A., et al.: CO2 electrolysis to multicarbon products in strong acid. Science 372, 1074–1078 (2021). https://doi.org/10.1126/science.abg6582
Resasco, J., Chen, L.D., Clark, E., et al.: Promoter effects of alkali metal cations on the electrochemical reduction of carbon dioxide. J. Am. Chem. Soc. 139, 11277–11287 (2017). https://doi.org/10.1021/jacs.7b06765
Ringe, S., Clark, E.L., Resasco, J., et al.: Understanding cation effects in electrochemical CO2 reduction. Energy Environ. Sci. 12, 3001–3014 (2019). https://doi.org/10.1039/C9EE01341E
Alerte, T., Edwards, J.P., Gabardo, C.M., et al.: Downstream of the CO2 electrolyzer: assessing the energy intensity of product separation. ACS Energy Lett. 6, 4405–4412 (2021). https://doi.org/10.1021/acsenergylett.1c02263
Wang, N., MiaoLee, rkG., et al.: Suppressing the liquid product crossover in electrochemical CO2 reduction. SmartMat 2, 12–16 (2021). https://doi.org/10.1002/smm2.1018
Zhang, J., Luo, W., Züttel, A.: Crossover of liquid products from electrochemical CO2 reduction through gas diffusion electrode and anion exchange membrane. J. Catal. 385, 140–145 (2020). https://doi.org/10.1016/j.jcat.2020.03.013
Tschinder, T., Schaffer, T., Fraser, S.D., et al.: Electro-osmotic drag of methanol in proton exchange membranes. J. Appl. Electrochem. 37, 711–716 (2007). https://doi.org/10.1007/s10800-007-9304-6
Neburchilov, V., Martin, J., Wang, H.J., et al.: A review of polymer electrolyte membranes for direct methanol fuel cells. J. Power Sources 169, 221–238 (2007). https://doi.org/10.1016/j.jpowsour.2007.03.044
Heinzel, A., Barragán, V.M.: A review of the state-of-the-art of the methanol crossover in direct methanol fuel cells. J. Power Sources 84, 70–74 (1999). https://doi.org/10.1016/S0378-7753(99)00302-X
Awang, N., Ismail, A.F., Jaafar, J., et al.: Functionalization of polymeric materials as a high performance membrane for direct methanol fuel cell: a review. React. Funct. Polym. 86, 248–258 (2015). https://doi.org/10.1016/j.reactfunctpolym.2014.09.019
Ahmad, H., Kamarudin, S.K., Hasran, U.A., et al.: Overview of hybrid membranes for direct-methanol fuel-cell applications. Int. J. Hydrog. Energy 35, 2160–2175 (2010). https://doi.org/10.1016/j.ijhydene.2009.12.054
Antonucci, P.L., Aricò, A.S., Cretı̀, P., et al.: Investigation of a direct methanol fuel cell based on a composite Nafion®-silica electrolyte for high temperature operation. Solid State Ion. 125, 431–437 (1999). https://doi.org/10.1016/S0167-2738(99)00206-4
Vaivars, G., Maxakato, N.W., Mokrani, T., et al.: Zirconium phosphate based inorganic direct methanol fuel cell. Mater. Sci. 10, 162–165 (2004)
Rao, A.S., Rashmi, K.R., Manjunatha, D.V., et al.: Methanol crossover reduction and power enhancement of methanol fuel cells with polyvinyl alcohol coated Nafion membranes. Mater. Today Proc. 35, 344–351 (2021). https://doi.org/10.1016/j.matpr.2020.02.093
Chabi, S., Papadantonakis, K.M., Lewis, N.S., et al.: Membranes for artificial photosynthesis. Energy Environ. Sci. 10, 1320–1338 (2017). https://doi.org/10.1039/C7EE00294G
Burton, N.A., Padilla, R.V., Rose, A., et al.: Increasing the efficiency of hydrogen production from solar powered water electrolysis. Renew. Sustain. Energy Rev. 135, 110255 (2021). https://doi.org/10.1016/j.rser.2020.110255
Masel, R.I., Liu, Z.C., Yang, H.Z., et al.: An industrial perspective on catalysts for low-temperature CO2 electrolysis. Nat. Nanotechnol. 16, 118–128 (2021). https://doi.org/10.1038/s41565-020-00823-x
ZatoÅ, M., Rozière, J., Jones, D.J.: Current understanding of chemical degradation mechanisms of perfluorosulfonic acid membranes and their mitigation strategies: a review. Sustain. Energy Fuels 1, 409–438 (2017). https://doi.org/10.1039/C7SE00038C
Papakonstantinou, G., Algara-Siller, G., Teschner, D., et al.: Degradation study of a proton exchange membrane water electrolyzer under dynamic operation conditions. Appl. Energy 280, 115911 (2020). https://doi.org/10.1016/j.apenergy.2020.115911
Inaba, M., Kinumoto, T., Kiriake, M., et al.: Gas crossover and membrane degradation in polymer electrolyte fuel cells. Electrochim. Acta 51, 5746–5753 (2006). https://doi.org/10.1016/j.electacta.2006.03.008
Grigoriev, S.A., Dzhus, K.A., Bessarabov, D.G., et al.: Failure of PEM water electrolysis cells: case study involving anode dissolution and membrane thinning. Int. J. Hydrog. Energy 39, 20440–20446 (2014). https://doi.org/10.1016/j.ijhydene.2014.05.043
Maurya, S., Shin, S.H., Kim, Y., et al.: A review on recent developments of anion exchange membranes for fuel cells and redox flow batteries. RSC Adv. 5, 37206–37230 (2015). https://doi.org/10.1039/C5RA04741B
Laconti, A., Liu, H., Mittelsteadt, C., et al.: Polymer electrolyte membrane degradation mechanisms in fuel cells: findings over the past 30 years and comparison with electrolyzers. ECS Trans. 1, 199–219 (2006). https://doi.org/10.1149/1.2214554
Yamazaki, K.: High proton conductive and low gas permeable sulfonated graft copolyimide membrane. Macromolecules 43, 7185–7191 (2010)
Adamski, M., Skalski, T.J.G., Britton, B., et al.: Highly stable, low gas crossover, proton-conducting phenylated polyphenylenes. Angew. Chem. Int. Ed. 56, 9058–9061 (2017). https://doi.org/10.1002/anie.201703916
Adamski, M., Peressin, N., Holdcroft, S.: On the evolution of sulfonated polyphenylenes as proton exchange membranes for fuel cells. Mater. Adv. 2, 4966–5005 (2021). https://doi.org/10.1039/d1ma00511a
Klose, C., Saatkamp, T., Münchinger, A., et al.: All-hydrocarbon MEA for PEM water electrolysis combining low hydrogen crossover and high efficiency. Adv. Energy Mater. 10, 1903995 (2020). https://doi.org/10.1002/aenm.201903995
Besha, A.T., Tsehaye, M.T., Aili, D., et al.: Design of monovalent ion selective membranes for reducing the impacts of multivalent ions in reverse electrodialysis. Membranes 10, 7 (2019). https://doi.org/10.3390/membranes10010007
Safronova, E.Y., Golubenko, D.V., Shevlyakova, N.V., et al.: New cation-exchange membranes based on cross-linked sulfonated polystyrene and polyethylene for power generation systems. J. Membr. Sci. 515, 196–203 (2016). https://doi.org/10.1016/j.memsci.2016.05.006
Kienitz, B., Kolde, J., Priester, S., et al.: Ultra-thin reinforced ionomer membranes to meet next generation fuel cell targets. ECS Trans. 41, 1521–1530 (2011). https://doi.org/10.1149/1.3635683
Li, D.G., Motz, A.R., Bae, C., et al.: Durability of anion exchange membrane water electrolyzers. Energy Environ. Sci. 14, 3393–3419 (2021). https://doi.org/10.1039/d0ee04086j
Wang, Y.X., Niu, C.L., Zhu, Y.C., et al.: Tunable syngas formation from electrochemical CO2 reduction on copper nanowire arrays. ACS Appl. Energy Mater. 3, 9841–9847 (2020). https://doi.org/10.1021/acsaem.0c01504
He, M., Li, C.S., Zhang, H.C., et al.: Oxygen induced promotion of electrochemical reduction of CO2 via co-electrolysis. Nat. Commun. 11, 3844 (2020). https://doi.org/10.1038/s41467-020-17690-8
Liu, X.Y., Schlexer, P., Xiao, J.P., et al.: pH effects on the electrochemical reduction of CO2 towards C2 products on stepped copper. Nat. Commun. 10, 32 (2019). https://doi.org/10.1038/s41467-018-07970-9
Chen, Z.P., Zhang, X.X., Liu, W., et al.: Amination strategy to boost the CO2 electroreduction current density of M-N/C single-atom catalysts to the industrial application level. Energy Environ. Sci. 14, 2349–2356 (2021). https://doi.org/10.1039/D0EE04052E
O’Brien, C.P., MiaoLiu, rkS.J., et al.: Single pass CO2 conversion exceeding 85% in the electrosynthesis of multicarbon products via local CO2 regeneration. ACS Energy Lett. 6, 2952–2959 (2021). https://doi.org/10.1021/acsenergylett.1c01122
Niu, Z.Z., Chi, L.P., Liu, R., et al.: Rigorous assessment of CO2 electroreduction products in a flow cell. Energy Environ. Sci. 14, 4169–4176 (2021). https://doi.org/10.1039/D1EE01664D
Ma, M., Clark, E.L., Therkildsen, K.T., et al.: Insights into the carbon balance for CO2 electroreduction on Cu using gas diffusion electrode reactor designs. Energy Environ. Sci. 13, 977–985 (2020). https://doi.org/10.1039/D0EE00047G
Ma, M., Kim, S., Chorkendorff, I., et al.: Role of ion-selective membranes in the carbon balance for CO2 electroreduction via gas diffusion electrode reactor designs. Chem. Sci. 11, 8854–8861 (2020). https://doi.org/10.1039/d0sc03047c
Mardle, P., Cassegrain, S., Habibzadeh, F., et al.: Carbonate ion crossover in zero-gap, KOH anolyte CO2 electrolysis. J. Phys. Chem. C 125, 25446–25454 (2021). https://doi.org/10.1021/acs.jpcc.1c08430
Lee, W.H., Ko, Y.J., Choi, Y., et al.: Highly selective and scalable CO2 to CO: electrolysis using coral-nanostructured Ag catalysts in zero-gap configuration. Nano Energy 76, 105030 (2020). https://doi.org/10.1016/j.nanoen.2020.105030
Wei, P.F., Li, H.F., Lin, L., et al.: CO2 electrolysis at industrial current densities using anion exchange membrane based electrolyzers. Sci. China Chem. 63, 1711–1715 (2020)
Wheeler, D.G., Mowbray, B.A.W., Reyes, A., et al.: Quantification of water transport in a CO2 electrolyzer. Energy Environ. Sci. 13, 5126–5134 (2020). https://doi.org/10.1039/D0EE02219E
Leonard, M.E., Clarke, L.E., Forner-Cuenca, A., et al.: Investigating electrode flooding in a flowing electrolyte, gas-fed carbon dioxide electrolyzer. Chemsuschem 13, 400–411 (2020). https://doi.org/10.1002/cssc.201902547
Aeshala, L.M., Verma, A.: Amines as reaction environment regulator for CO2 electrochemical reduction to CH4. Macromol. Symp. 357, 79–85 (2015). https://doi.org/10.1002/masy.201400193
Aeshala, L.M., Uppaluri, R., Verma, A.: Electrochemical conversion of CO2 to fuels: tuning of the reaction zone using suitable functional groups in a solid polymer electrolyte. Phys. Chem. Chem. Phys. 16, 17588–17594 (2014). https://doi.org/10.1039/C4CP02389G
Mao, M.J., Zhang, M.D., Meng, D.L., et al.: Imidazolium-functionalized cationic covalent triazine frameworks stabilized copper nanoparticles for enhanced CO2 electroreduction. ChemCatChem 12, 3530–3536 (2020). https://doi.org/10.1002/cctc.202000387
Li, X.Q., Duan, G.Y., Chen, J.W., et al.: Regulating electrochemical CO2RR selectivity at industrial current densities by structuring copper@poly(ionic liquid) interface. Appl. Catal. B Environ. 297, 120471 (2021). https://doi.org/10.1016/j.apcatb.2021.120471
Ratschmeier, B., Braunschweig, B.: Cations of ionic liquid electrolytes can act as a promoter for CO2 electrocatalysis through reactive intermediates and electrostatic stabilization. J. Phys. Chem. C 125, 16498–16507 (2021). https://doi.org/10.1021/acs.jpcc.1c02898
Rosen, B.A., Salehi-Khojin, A., Thorson, M.R., et al.: Ionic liquid-mediated selective conversion of CO2 to CO at low overpotentials. Science 334, 643–644 (2011). https://doi.org/10.1126/science.1209786
Kemna, A., García Rey, N., Braunschweig, B.: Mechanistic insights on CO2 reduction reactions at platinum/[BMIM][BF4] interfaces from in operando spectroscopy. ACS Catal. 9, 6284–6292 (2019). https://doi.org/10.1021/acscatal.9b01033
Tanner, E.E.L., Batchelor-McAuley, C., Compton, R.G.: Carbon dioxide reduction in room-temperature ionic liquids: the effect of the choice of electrode material, cation, and anion. J. Phys. Chem. C 120, 26442–26447 (2016). https://doi.org/10.1021/acs.jpcc.6b10564
Sajjad, S.D., Gao, Y., Liu, Z.C., et al.: Tunable-high performance sustainion™ anion exchange membranes for electrochemical applications. ECS Trans. 77, 1653–1656 (2017). https://doi.org/10.1149/07711.1653ecst
Yin, Z.L., Peng, H.Q., Wei, X., et al.: An alkaline polymer electrolyte CO2 electrolyzer operated with pure water. Energy Environ. Sci. 12, 2455–2462 (2019). https://doi.org/10.1039/C9EE01204D
Giffin, G.A., Lavina, S., Pace, G., et al.: Interplay between the structure and relaxations in Selemion AMV hydroxide conducting membranes for AEMFC applications. J. Phys. Chem. C 116, 23965–23973 (2012). https://doi.org/10.1021/jp3094879
Carter, B.M., Dobyns, B.M., Beckingham, B.S., et al.: Multicomponent transport of alcohols in an anion exchange membrane measured by in-situ ATR FTIR spectroscopy. Polymer 123, 144–152 (2017). https://doi.org/10.1016/j.polymer.2017.06.070
Krödel, M., Carter, B.M., Rall, D., et al.: Rational design of ion exchange membrane material properties limits the crossover of CO2 reduction products in artificial photosynthesis devices. ACS Appl. Mater. Interfaces 12, 12030–12042 (2020). https://doi.org/10.1021/acsami.9b21415
Carmo, M., Doubek, G., Sekol, R.C., et al.: Development and electrochemical studies of membrane electrode assemblies for polymer electrolyte alkaline fuel cells using FAA membrane and ionomer. J. Power Sources 230, 169–175 (2013). https://doi.org/10.1016/j.jpowsour.2012.12.015
Ziv, N., Mondal, A.N., Weissbach, T., et al.: Effect of CO2 on the properties of anion exchange membranes for fuel cell applications. J. Membr. Sci. 586, 140–150 (2019). https://doi.org/10.1016/j.memsci.2019.05.053
Torbensen, K., Joulié, D., Ren, S.X., et al.: Molecular catalysts boost the rate of electrolytic CO2 reduction. ACS Energy Lett. 5, 1512–1518 (2020). https://doi.org/10.1021/acsenergylett.0c00536
Larrazábal, G.O., Strøm-Hansen, P., Heli, J.P., et al.: Analysis of mass flows and membrane cross-over in CO2 reduction at high current densities in an MEA-type electrolyzer. ACS Appl. Mater. Interfaces 11, 41281–41288 (2019). https://doi.org/10.1021/acsami.9b13081
Lees, E.W., Mowbray, B.A.W., Salvatore, D.A., et al.: Linking gas diffusion electrode composition to CO2 reduction in a flow cell. J. Mater. Chem. A 8, 19493–19501 (2020). https://doi.org/10.1039/D0TA03570J
Liu, Z.C., Yang, H.Z., Kutz, R., et al.: CO2 electrolysis to CO and O2 at high selectivity, stability and efficiency using Sustainion membranes. J. Electrochem. Soc. 165, J3371–J3377 (2018). https://doi.org/10.1149/2.0501815jes
Durst, J., Siebel, A., Simon, C., et al.: New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism. Energy Environ. Sci. 7, 2255–2260 (2014). https://doi.org/10.1039/C4EE00440J
Feaster, J.T., Shi, C., Cave, E.R., et al.: Understanding selectivity for the electrochemical reduction of carbon dioxide to formic acid and carbon monoxide on metal electrodes. ACS Catal. 7, 4822–4827 (2017). https://doi.org/10.1021/acscatal.7b00687
Nørskov, J.K., Bligaard, T., Rossmeisl, J., et al.: Towards the computational design of solid catalysts. Nat. Chem. 1, 37–46 (2009). https://doi.org/10.1038/nchem.121
Strmcnik, D., Uchimura, M., Wang, C., et al.: Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption. Nat. Chem. 5, 300–306 (2013). https://doi.org/10.1038/nchem.1574
Cheng, T., Wang, L., Merinov, B.V., et al.: Explanation of dramatic pH-dependence of hydrogen binding on noble metal electrode: greatly weakened water adsorption at high pH. J. Am. Chem. Soc. 140, 7787–7790 (2018). https://doi.org/10.1021/jacs.8b04006
Hori, Y., Takahashi, R., Yoshinami, Y., et al.: Electrochemical reduction of CO at a copper electrode. J. Phys. Chem. B 101, 7075–7081 (1997). https://doi.org/10.1021/jp970284i
Kim, C., Bui, J.C., Luo, X.Y., et al.: Tailored catalyst microenvironments for CO2 electroreduction to multicarbon products on copper using bilayer ionomer coatings. Nat. Energy 6, 1026–1034 (2021). https://doi.org/10.1038/s41560-021-00920-8
Unlu, M., Zhou, J.F., Kohl, P.A.: Anion exchange membrane fuel cells: experimental comparison of hydroxide and carbonate conductive ions. Electrochem. Solid State Lett. 12, B27 (2009). https://doi.org/10.1149/1.3058999
Pătru, A., Binninger, T., Pribyl, B., et al.: Design principles of bipolar electrochemical co-electrolysis cells for efficient reduction of carbon dioxide from gas phase at low temperature. J. Electrochem. Soc. 166, F34–F43 (2019). https://doi.org/10.1149/2.1221816jes
Rabinowitz, J.A., Kanan, M.W.: The future of low-temperature carbon dioxide electrolysis depends on solving one basic problem. Nat. Commun. 11, 5231 (2020). https://doi.org/10.1038/s41467-020-19135-8
Keith, D.W., Holmes, G., St Angelo, D., et al.: A process for capturing CO2 from the atmosphere. Joule 2, 1573–1594 (2018). https://doi.org/10.1016/j.joule.2018.05.006
Sisler, J., Khan, S., Ip, A.H., et al.: Ethylene electrosynthesis: a comparative techno-economic analysis of alkaline vs membrane electrode assembly vs CO2–CO–C2H4 tandems. ACS Energy Lett. 6, 997–1002 (2021). https://doi.org/10.1021/acsenergylett.0c02633
Bohra, D., Chaudhry, J.H., Burdyny, T., et al.: Modeling the electrical double layer to understand the reaction environment in a CO2 electrocatalytic system. Energy Environ. Sci. 12, 3380–3389 (2019). https://doi.org/10.1039/C9EE02485A
Ziv, N., Mustain, W.E., Dekel, D.R.: The effect of ambient carbon dioxide on anion-exchange membrane fuel cells. Chemsuschem 11, 1136–1150 (2018). https://doi.org/10.1002/cssc.201702330
Ziv, N., Dekel, D.R.: A practical method for measuring the true hydroxide conductivity of anion exchange membranes. Electrochem. Commun. 88, 109–113 (2018). https://doi.org/10.1016/j.elecom.2018.01.021
Cao, X.Z., Novitski, D., Holdcroft, S.: Visualization of hydroxide ion formation upon electrolytic water splitting in an anion exchange membrane. ACS Mater. Lett. 1, 362–366 (2019). https://doi.org/10.1021/acsmaterialslett.9b00195
Díaz-Sainz, G., Alvarez-Guerra, M., Solla-Gullón, J., et al.: Catalyst coated membrane electrodes for the gas phase CO2 electroreduction to formate. Catal. Today 346, 58–64 (2020). https://doi.org/10.1016/j.cattod.2018.11.073
Ashdot, A., Kattan, M., Kitayev, A., et al.: Design strategies for alkaline exchange membrane-electrode assemblies: optimization for fuel cells and electrolyzers. Membranes 11, 686 (2021). https://doi.org/10.3390/membranes11090686
Díaz-Sainz, G., Alvarez-Guerra, M., Irabien, A.: Continuous electrochemical reduction of CO2 to formate: comparative study of the influence of the electrode configuration with Sn and Bi-based electrocatalysts. Molecules 25, 4457 (2020). https://doi.org/10.3390/molecules25194457
Li, Y.C., Yan, Z.F., Hitt, J., et al.: Bipolar membranes inhibit product crossover in CO2 electrolysis cells. Adv. Sustain. Syst. 2, 1700187 (2018). https://doi.org/10.1002/adsu.201700187
Lim, J., Kang, P.W., Jeon, S.S., et al.: Electrochemically deposited Sn catalysts with dense tips on a gas diffusion electrode for electrochemical CO2 reduction. J. Mater. Chem. A 8, 9032–9038 (2020). https://doi.org/10.1039/D0TA00569J
Yang, H.Z., Kaczur, J.J., Sajjad, S.D., et al.: CO2 conversion to formic acid in a three compartment cell with Sustainion™ membranes. ECS Trans. 77, 1425–1431 (2017). https://doi.org/10.1149/07711.1425ecst
Papakonstantinou, P., Deimede, V.: Self-cross-linked quaternary phosphonium based anion exchange membranes: assessing the influence of quaternary phosphonium groups on alkaline stability. RSC Adv. 6, 114329–114343 (2016). https://doi.org/10.1039/C6RA24102F
Thomas, O.D., Soo, K.J.W.Y., Peckham, T.J., et al.: A stable hydroxide-conducting polymer. J. Am. Chem. Soc. 134, 10753–10756 (2012). https://doi.org/10.1021/ja303067t
Wright, A.G., Holdcroft, S.: Hydroxide-stable ionenes. ACS Macro Lett. 3, 444–447 (2014). https://doi.org/10.1021/mz500168d
Long, H., Pivovar, B.: Hydroxide degradation pathways for imidazolium cations: a DFT study. J. Phys. Chem. C 118, 9880–9888 (2014). https://doi.org/10.1021/jp501362y
Hugar, K.M., KostalikCoates, H.A.G.W.: Imidazolium cations with exceptional alkaline stability: a systematic study of structure-stability relationships. J. Am. Chem. Soc. 137, 8730–8737 (2015). https://doi.org/10.1021/jacs.5b02879
Fan, J.T., Wright, A.G., Britton, B., et al.: Cationic polyelectrolytes, stable in 10 M KOHaq at 100 °C. ACS Macro Lett. 6, 1089–1093 (2017). https://doi.org/10.1021/acsmacrolett.7b00679
Fan, J.T., Willdorf-Cohen, S., Schibli, E.M., et al.: Poly(bis-arylimidazoliums) possessing high hydroxide ion exchange capacity and high alkaline stability. Nat. Commun. 10, 2306 (2019). https://doi.org/10.1038/s41467-019-10292-z
Mustain, W.E., Chatenet, M., Page, M., et al.: Durability challenges of anion exchange membrane fuel cells. Energy Environ. Sci. 13, 2805–2838 (2020). https://doi.org/10.1039/D0EE01133A
Müller, J., Zhegur, A., Krewer, U., et al.: Practical ex-situ technique to measure the chemical stability of anion-exchange membranes under conditions simulating the fuel cell environment. ACS Mater. Lett. 2, 168–173 (2020). https://doi.org/10.1021/acsmaterialslett.9b00418
Yang, K.L., Kas, R., Smith, W.A., et al.: Role of the carbon-based gas diffusion layer on flooding in a gas diffusion electrode cell for electrochemical CO2 reduction. ACS Energy Lett. 6, 33–40 (2021). https://doi.org/10.1021/acsenergylett.0c02184
Münchinger, A., Kreuer, K.D.: Selective ion transport through hydrated cation and anion exchange membranes. I. The effect of specific interactions. J. Membr. Sci. 592, 117372 (2019)
Geise, G.M., Hickner, M.A., Logan, B.E.: Ionic resistance and permselectivity tradeoffs in anion exchange membranes. ACS Appl. Mater. Interfaces 5, 10294–10301 (2013). https://doi.org/10.1021/am403207w
Xu, Y., Edwards, J.P., Liu, S.J., et al.: Self-cleaning CO2 reduction systems: unsteady electrochemical forcing enables stability. ACS Energy Lett. 6, 809–815 (2021). https://doi.org/10.1021/acsenergylett.0c02401
Varcoe, J.R., Slade, R.C.T.: Prospects for alkaline anion-exchange membranes in low temperature fuel cells. Fuel Cells 5, 187–200 (2005). https://doi.org/10.1002/fuce.200400045
Overton, P., Li, W., Cao, X.Z., et al.: Tuning ion exchange capacity in hydroxide-stable poly(arylimidazolium) ionenes: increasing the ionic content decreases the dependence of conductivity and hydration on temperature and humidity. Macromolecules 53, 10548–10560 (2020). https://doi.org/10.1021/acs.macromol.0c02014
Ozden, A., Wang, Y.H., Li, F.W., et al.: Cascade CO2 electroreduction enables efficient carbonate-free production of ethylene. Joule 5, 706–719 (2021). https://doi.org/10.1016/j.joule.2021.01.007
Mayerhöfer, B., McLaughlin, D., Böhm, T., et al.: Bipolar membrane electrode assemblies for water electrolysis. ACS Appl. Energy Mater. 3, 9635–9644 (2020). https://doi.org/10.1021/acsaem.0c01127
Peugeot, A., Creissen, C.E., Schreiber, M.W., et al.: Advancing the anode compartment for energy efficient CO2 reduction at neutral pH. ChemElectroChem 8, 2726–2736 (2021). https://doi.org/10.1002/celc.202100742
De Mot, B., Hereijgers, J., Daems, N., et al.: Insight in the behavior of bipolar membrane equipped carbon dioxide electrolyzers at low electrolyte flowrates. Chem. Eng. J. 428, 131170 (2022). https://doi.org/10.1016/j.cej.2021.131170
Yan, Z.F., Hitt, J.L., Zeng, Z.C., et al.: Improving the efficiency of CO2 electrolysis by using a bipolar membrane with a weak-acid cation exchange layer. Nat. Chem. 13, 33–40 (2021). https://doi.org/10.1038/s41557-020-00602-0
Luo, J.S., Vermaas, D.A., Bi, D.Q., et al.: Bipolar membrane-assisted solar water splitting in optimal pH. Adv. Energy Mater. 6, 1600100 (2016). https://doi.org/10.1002/aenm.201600100
Huang, C.H., Xu, T.W.: Electrodialysis with bipolar membranes for sustainable development. Environ. Sci. Technol. 40, 5233–5243 (2006). https://doi.org/10.1021/es060039p
Chen, Y.Y., Vise, A., Klein, W.E., et al.: A robust, scalable platform for the electrochemical conversion of CO2 to formate: identifying pathways to higher energy efficiencies. ACS Energy Lett. 5, 1825–1833 (2020). https://doi.org/10.1021/acsenergylett.0c00860
Peng, S.K., Xu, X., Lu, S.F., et al.: A self-humidifying acidic–alkaline bipolar membrane fuel cell. J. Power Sources 299, 273–279 (2015). https://doi.org/10.1016/j.jpowsour.2015.08.104
Chen, Y.Y., Wrubel, J.A., Klein, W.E., et al.: High-performance bipolar membrane development for improved water dissociation. ACS Appl. Polym. Mater. 2, 4559–4569 (2020). https://doi.org/10.1021/acsapm.0c00653
Balster, J., Srinkantharajah, S., Sumbharaju, R., et al.: Tailoring the interface layer of the bipolar membrane. J. Membr. Sci. 365, 389–398 (2010). https://doi.org/10.1016/j.memsci.2010.09.034
Ge, Z.J., Shehzad, M.A., Yang, X.Q., et al.: High-performance bipolar membrane for electrochemical water electrolysis. J. Membr. Sci. 656, 120660 (2022). https://doi.org/10.1016/j.memsci.2022.120660
McDonald, M.B., Freund, M.S.: Graphene oxide as a water dissociation catalyst in the bipolar membrane interfacial layer. ACS Appl. Mater. Interfaces 6, 13790–13797 (2014). https://doi.org/10.1021/am503242v
Strathmann, H., Krol, J.J., Rapp, H.J., et al.: Limiting current density and water dissociation in bipolar membranes. J. Membr. Sci. 125, 123–142 (1997). https://doi.org/10.1016/S0376-7388(96)00185-8
Vermaas, D.A., Wiegman, S., Nagaki, T., et al.: Ion transport mechanisms in bipolar membranes for (photo)electrochemical water splitting. Sustain. Energy Fuels 2, 2006–2015 (2018). https://doi.org/10.1039/C8SE00118A
Donnan, F.G.: The theory of membrane equilibria. Chem. Rev. 1, 73–90 (1924). https://doi.org/10.1021/cr60001a003
Tufa, R.A., Blommaert, M.A., Chanda, D., et al.: Bipolar membrane and interface materials for electrochemical energy systems. ACS Appl. Energy Mater. 4, 7419–7439 (2021). https://doi.org/10.1021/acsaem.1c01140
Vermaas, D.A., Sassenburg, M., Smith, W.A.: Photo-assisted water splitting with bipolar membrane induced pH gradients for practical solar fuel devices. J. Mater. Chem. A 3, 19556–19562 (2015). https://doi.org/10.1039/C5TA06315A
Sun, K., Liu, R., Chen, Y.K., et al.: A stabilized, intrinsically safe, 10% efficient, solar-driven water-splitting cell incorporating earth-abundant electrocatalysts with steady-state pH gradients and product separation enabled by a bipolar membrane. Adv. Energy Mater. 6, 1600379 (2016). https://doi.org/10.1002/aenm.201600379
Hohenadel, A., Gangrade, A.S., Holdcroft, S.: Spectroelectrochemical detection of water dissociation in bipolar membranes. ACS Appl. Mater. Interfaces 13, 46125–46133 (2021). https://doi.org/10.1021/acsami.1c12544
Shen, C.H., Wycisk, R., Pintauro, P.N.: High performance electrospun bipolar membrane with a 3D junction. Energy Environ. Sci. 10, 1435–1442 (2017). https://doi.org/10.1039/C7EE00345E
Mel’nikov, S.S., Shapovalova, O.V., Shel’deshov, N.V., et al.: Effect of d-metal hydroxides on water dissociation in bipolar membranes. Petroleum Chem. 51, 577–584 (2011)
Oda, Y., Yawataya, T.: Neutrality-disturbance phenomenon of membrane-solution systems. Desalination 5, 129–138 (1968). https://doi.org/10.1016/S0011-9164(00)80208-8
Rajesh, A.M., Chakrabarty, T., Prakash, S., et al.: Effects of metal alkoxides on electro-assisted water dissociation across bipolar membranes. Electrochim. Acta 66, 325–331 (2012). https://doi.org/10.1016/j.electacta.2012.01.102
Li, T.F., Lees, E.W., Goldman, M., et al.: Electrolytic conversion of bicarbonate into CO in a flow cell. Joule 3, 1487–1497 (2019). https://doi.org/10.1016/j.joule.2019.05.021
Mandal, M.: Highly efficient bipolar membrane CO2 electrolysis. ChemElectroChem 8, 1448–1450 (2021). https://doi.org/10.1002/celc.202100243
Pribyl-Kranewitter, B., Beard, A., Schuler, T., et al.: Investigation and optimisation of operating conditions for low-temperature CO2 reduction to CO in a forward-bias bipolar-membrane electrolyser. J. Electrochem. Soc. 168, 043506 (2021). https://doi.org/10.1149/1945-7111/abf063
Panha, K., Fowler, M., Yuan, X.Z., et al.: Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells. Appl. Energy 93, 90–97 (2012). https://doi.org/10.1016/j.apenergy.2011.05.011
Giesbrecht, P.K., Freund, M.S.: Recent advances in bipolar membrane design and applications. Chem. Mater. 32, 8060–8090 (2020). https://doi.org/10.1021/acs.chemmater.0c02829
Muroyama, A.P., Pătru, A., Gubler, L.: Review: CO2 separation and transport via electrochemical methods. J. Electrochem. Soc. 167, 133504 (2020). https://doi.org/10.1149/1945-7111/abbbb9
Oener, S.Z., Twight, L.P., Lindquist, G.A., et al.: Thin cation-exchange layers enable high-current-density bipolar membrane electrolyzers via improved water transport. ACS Energy Lett. 6, 1–8 (2021). https://doi.org/10.1021/acsenergylett.0c02078
Dege, G.J. Chlanda, F.P. Lee, L.T.C., et al.: Method of making novel two component bipolar ion exchange membranes. US Patent 4,253,900, 3 Mar 1981
Pan, J.F., Hou, L.X., Wang, Q.Y., et al.: Preparation of bipolar membranes by electrospinning. Mater. Chem. Phys. 186, 484–491 (2017). https://doi.org/10.1016/j.matchemphys.2016.11.023
Powers, D., Mondal, A.N., Yang, Z.Z., et al.: Freestanding bipolar membranes with an electrospun junction for high current density water splitting. ACS Appl. Mater. Interfaces 14, 36092–36104 (2022). https://doi.org/10.1021/acsami.2c07680
Blommaert, M.A., Aili, D., Tufa, R.A., et al.: Insights and challenges for applying bipolar membranes in advanced electrochemical energy systems. ACS Energy Lett. 6, 2539–2548 (2021). https://doi.org/10.1021/acsenergylett.1c00618
Garza, A.J., Bell, A.T., Head-Gordon, M.: Mechanism of CO2 reduction at copper surfaces: pathways to C2 products. ACS Catal. 8, 1490–1499 (2018). https://doi.org/10.1021/acscatal.7b03477
Ozden, A., Liu, Y.J., Dinh, C.T., et al.: Gold adparticles on silver combine low overpotential and high selectivity in electrochemical CO2 conversion. ACS Appl. Energy Mater. 4, 7504–7512 (2021). https://doi.org/10.1021/acsaem.1c01577
Chen, B.T., Li, B.R., Tian, Z.Q., et al.: Enhancement of mass transfer for facilitating industrial-level CO2 electroreduction on atomic Ni–N4 sites. Adv. Energy Mater. 11, 2102152 (2021). https://doi.org/10.1002/aenm.202102152
Wang, Q.Y., Liu, K., Fu, J.W., et al.: Atomically dispersed s-block magnesium sites for electroreduction of CO2 to CO. Angew. Chem. Int. Ed. 60, 25241–25245 (2021). https://doi.org/10.1002/anie.202109329
Chae, S.Y., Lee, S.Y., Joo, O.S.: Directly synthesized silver nanoparticles on gas diffusion layers by electrospray pyrolysis for electrochemical CO2 reduction. Electrochim. Acta 303, 118–124 (2019). https://doi.org/10.1016/j.electacta.2019.02.046
Dinh, C.T., García de Arquer, F.P., Sinton, D., et al.: High rate, selective, and stable electroreduction of CO2 to CO in basic and neutral media. ACS Energy Lett. 3, 2835–2840 (2018). https://doi.org/10.1021/acsenergylett.8b01734
Qi, Z., Biener, M.M., Kashi, A.R., et al.: Electrochemical CO2 to CO reduction at high current densities using a nanoporous gold catalyst. Mater. Res. Lett. 9, 99–104 (2021). https://doi.org/10.1080/21663831.2020.1842534
Wei, S.T., Zou, H.Y., Rong, W.F., et al.: Conjugated nickel phthalocyanine polymer selectively catalyzes CO2-to-CO conversion in a wide operating potential window. Appl. Catal. B Environ. 284, 119739 (2021). https://doi.org/10.1016/j.apcatb.2020.119739
Salvatore, D.A., Weekes, D.M., He, J.F., et al.: Electrolysis of gaseous CO2 to CO in a flow cell with a bipolar membrane. ACS Energy Lett. 3, 149–154 (2018). https://doi.org/10.1021/acsenergylett.7b01017
Yang, K.L., Li, M.R., Subramanian, S., et al.: Cation-driven increases of CO2 utilization in a bipolar membrane electrode assembly for CO2 electrolysis. ACS Energy Lett. 6, 4291–4298 (2021). https://doi.org/10.1021/acsenergylett.1c02058
Li, Y.C., Lee, G., Yuan, T.G., et al.: CO2 electroreduction from carbonate electrolyte. ACS Energy Lett. 4, 1427–1431 (2019). https://doi.org/10.1021/acsenergylett.9b00975
Blommaert, M.A., Sharifian, R., Shah, N.U., et al.: Orientation of a bipolar membrane determines the dominant ion and carbonic species transport in membrane electrode assemblies for CO2 reduction. J. Mater. Chem. A Mater. 9, 11179–11186 (2021). https://doi.org/10.1039/d0ta12398f
Fan, T.T., Ma, W.C., Xie, M.C., et al.: Achieving high current density for electrocatalytic reduction of CO2 to formate on bismuth-based catalysts. Cell Rep. Phys. Sci. 2, 100353 (2021). https://doi.org/10.1016/j.xcrp.2021.100353
Grigioni, I., Sagar, L.K., Li, Y.C., et al.: CO2 electroreduction to formate at a partial current density of 930 mA cm–2 with InP colloidal quantum dot derived catalysts. ACS Energy Lett. 6, 79–84 (2021). https://doi.org/10.1021/acsenergylett.0c02165
Li, J., Jiao, J.Q., Zhang, H.C., et al.: Two-dimensional SnO2 nanosheets for efficient carbon dioxide electroreduction to formate. ACS Sustainable Chem. Eng. 8, 4975–4982 (2020). https://doi.org/10.1021/acssuschemeng.0c01070
Fan, L., Xia, C., Zhu, P., et al.: Electrochemical CO2 reduction to high-concentration pure formic acid solutions in an all-solid-state reactor. Nat. Commun. 11, 3633 (2020). https://doi.org/10.1038/s41467-020-17403-1
Yang, J., Wang, X.L., Qu, Y.T., et al.: Bi-based metal-organic framework derived leafy bismuth nanosheets for carbon dioxide electroreduction. Adv. Energy Mater. 10, 2001709 (2020). https://doi.org/10.1002/aenm.202001709
Gong, Q.F., Ding, P., Xu, M.Q., et al.: Structural defects on converted bismuth oxide nanotubes enable highly active electrocatalysis of carbon dioxide reduction. Nat. Commun. 10, 2807 (2019). https://doi.org/10.1038/s41467-019-10819-4
Liu, H., Su, Y.Q., Kuang, S.Y., et al.: Highly efficient CO2 electrolysis within a wide operation window using octahedral tin oxide single crystals. J. Mater. Chem. A 9, 7848–7856 (2021). https://doi.org/10.1039/D1TA00285F
Zhao, Y., Liu, X.L., Liu, Z.X., et al.: Spontaneously Sn-doped Bi/BiOx core–shell nanowires toward high-performance CO2 electroreduction to liquid fuel. Nano Lett. 21, 6907–6913 (2021). https://doi.org/10.1021/acs.nanolett.1c02053
Díaz-Sainz, G., Alvarez-Guerra, M., Irabien, A.: Continuous electroreduction of CO2 towards formate in gas-phase operation at high current densities with an anion exchange membrane. J. CO2 Util. 56, 1018 (2022)
Bienen, F.B., Kopljar, D., Löwe, A., et al.: Utilizing formate as an energy carrier by coupling CO2 electrolysis with fuel cell devices. Chemie Ingenieur Tech. 91, 872–882 (2019). https://doi.org/10.1002/cite.201800212
Xing, Z., Hu, X., Feng, X.F.: Tuning the microenvironment in gas-diffusion electrodes enables high-rate CO2 electrolysis to formate. ACS Energy Lett. 6, 1694–1702 (2021). https://doi.org/10.1021/acsenergylett.1c00612
He, S.S., Ni, F.L., Ji, Y.J., et al.: The p-orbital delocalization of main-group metals to boost CO2 electroreduction. Angew. Chem. Int. Ed. 57, 16114–16119 (2018). https://doi.org/10.1002/anie.201810538
Sen, S., Skinn, B., Hall, T., et al.: Pulsed electrodeposition of tin electrocatalysts onto gas diffusion layers for carbon dioxide reduction to formate. MRS Adv. 2, 451–458 (2017). https://doi.org/10.1557/adv.2016.652
Díaz-Sainz, G., Alvarez-Guerra, M., Solla-Gullón, J., et al.: CO2 electroreduction to formate: continuous single-pass operation in a filter-press reactor at high current densities using Bi gas diffusion electrodes. J. CO2 Util. 34, 12–19 (2019). https://doi.org/10.1016/j.jcou.2019.05.035
Wang, Z.T., Qi, R.J., Liu, D.Y., et al.: Exfoliated ultrathin ZnIn2S4 nanosheets with abundant zinc vacancies for enhanced CO2 electroreduction to formate. Chemsuschem 14, 852–859 (2021). https://doi.org/10.1002/cssc.202002785
Deng, P.L., Yang, F., Wang, Z.T., et al.: Metal-organic framework-derived carbon nanorods encapsulating bismuth oxides for rapid and selective CO2 electroreduction to formate. Angew. Chem. Int. Ed. 59, 10807–10813 (2020). https://doi.org/10.1002/anie.202000657
Xia, C., Zhu, P., Jiang, Q., et al.: Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices. Nat. Energy 4, 776–785 (2019). https://doi.org/10.1038/s41560-019-0451-x
Díaz-Sainz, G., Alvarez-Guerra, M., Solla-Gullón, J., et al.: Gas–liquid–solid reaction system for CO2 electroreduction to formate without using supporting electrolyte. Aiche J. 66, e16299 (2020). https://doi.org/10.1002/aic.16299
Del Castillo, A., Alvarez-Guerra, M., Solla-Gullón, J., et al.: Sn nanoparticles on gas diffusion electrodes: synthesis, characterization and use for continuous CO2 electroreduction to formate. J. CO2 Util. 18, 222–228 (2017). https://doi.org/10.1016/j.jcou.2017.01.021
Kopljar, D., Inan, A., Vindayer, P., et al.: Electrochemical reduction of CO2 to formate at high current density using gas diffusion electrodes. J. Appl. Electrochem. 44, 1107–1116 (2014)
Pavesi, D., van de Poll, R.C.J., Krasovic, J.L., et al.: Cathodic disintegration as an easily scalable method for the production of Sn- and Pb-based catalysts for CO2 reduction. ACS Sustain. Chem. Eng. 8, 15603–15610 (2020). https://doi.org/10.1021/acssuschemeng.0c04875
Fujinuma, N., Lofland, S.: Acid-compatible catalyst development and machine-learning-assisted cell optimization toward cost-effective CO2 reduction reaction: Co-P4VP-derived catalyst and Nafion-based membrane electrode assembly. Meet. Abstr. (2021). https://doi.org/10.1149/ma2021-02281848mtgabs
Cao, C.S., Ma, D.D., Gu, J.F., et al.: Metal-organic layers leading to atomically thin bismuthene for efficient carbon dioxide electroreduction to liquid fuel. Angew. Chem. Int. Ed. 59, 15014–15020 (2020). https://doi.org/10.1002/anie.202005577
Wang, D., Liu, C.W., Zhang, Y.N., et al.: CO2 electroreduction to formate at a partial current density up to 590 mA mg−1 via micrometer-scale lateral structuring of bismuth nanosheets. Small 17, e2100602 (2021). https://doi.org/10.1002/smll.202100602
Lou, Y.Y., Fu, D., Fabre, B., et al.: Bismuth coated graphite felt modified by silver particles for selective electroreduction of CO2 into formate in a flow cell. Electrochimica Acta 371, 137821 (2021). https://doi.org/10.1016/j.electacta.2021.137821
Zhao, F.: Exploring electrochemical flow-cell designs and parameters for CO2 reduction to formate under industrially relevant conditions. J. Electrochem. Soc. 169, 054511 (2022). https://doi.org/10.1149/1945-7111/ac6bc1
Duan, G.Y., Li, X.Q., Ding, G.R., et al.: Highly efficient electrocatalytic CO2 reduction to C2+ products on a poly(ionic liquid)-based Cu0–CuI tandem catalyst. Angew. Chem. Int. Ed. 61, e202110657 (2022). https://doi.org/10.1002/anie.202110657
Lu, J.N., Liu, J., Zhang, L., et al.: Crystalline mixed-valence copper supramolecular isomers for electroreduction of CO2 to hydrocarbons. J. Mater. Chem. A 9, 23477–23484 (2021). https://doi.org/10.1039/D1TA07148C
Zhao, X., Du, L.J., You, B., et al.: Integrated design for electrocatalytic carbon dioxide reduction. Catal. Sci. Technol. 10, 2711–2720 (2020). https://doi.org/10.1039/D0CY00453G
Chen, X.Y., Chen, J.F., Alghoraibi, N.M., et al.: Electrochemical CO2-to-ethylene conversion on polyamine-incorporated Cu electrodes. Nat. Catal. 4, 20–27 (2021). https://doi.org/10.1038/s41929-020-00547-0
Liu, W.Q., Wei, S.L., Bai, P.Y., et al.: Robust coal matrix intensifies electron/substrate interaction of nickel–nitrogen (Ni–N) active sites for efficient CO2 electroreduction at industrial current density. Appl. Catal. B Environ. 299, 120661 (2021). https://doi.org/10.1016/j.apcatb.2021.120661
Kutz, R.B., Chen, Q.M., Yang, H.Z., et al.: Sustainion imidazolium-functionalized polymers for carbon dioxide electrolysis. Energy Technol. 5, 929–936 (2017). https://doi.org/10.1002/ente.201600636