A novel hyperbranched phosphorus-boron polymer for transparent, flame-retardant, smoke-suppressive, robust yet tough epoxy resins

Özmen, 2020, Cleaner production of flame-retardant-glass reinforced epoxy resin composite for aviation and reducing smoke toxicity, J Clean Prod, 276, 124065, 10.1016/j.jclepro.2020.124065

Gao, 2022, Luteolin-based epoxy resin with exceptional heat resistance, mechanical and flame retardant properties, Chem Eng J, 428, 131173, 10.1016/j.cej.2021.131173

Huo, 2020, A liquid phosphaphenanthrene-derived imidazole for improved flame retardancy and smoke suppression of epoxy resin, ACS Appl Polym Mater, 2, 3566, 10.1021/acsapm.0c00577

Murat Unlu, 2017, Effect of boron compounds on fire protection properties of epoxy based intumescent coating, Fire Mater, 41, 17, 10.1002/fam.2360

Rallini, 2013, Effect of boron carbide nanoparticles on the fire reaction and fire resistance of carbon fiber/epoxy composites, Polymer, 54, 5154, 10.1016/j.polymer.2013.07.038

Dogan, 2014, Flame retardant effect of boron compounds on red phosphorus containing epoxy resins, Polym Degrad Stabil, 99, 12, 10.1016/j.polymdegradstab.2013.12.017

Zhang, 2016, Synthesis of a boron/nitrogen-containing compound based on triazine and boronic acid and its flame retardant effect on epoxy resin, High Perform Polym, 29, 513, 10.1177/0954008316650929

Huo, 2021, Phosphorus-containing flame retardant epoxy thermosets: recent advances and future perspectives, Prog Polym Sci, 114, 101366, 10.1016/j.progpolymsci.2021.101366

Fang, 2020, A bio-based ionic complex with different oxidation states of phosphorus for reducing flammability and smoke release of epoxy resins, Compos Commun, 17, 104, 10.1016/j.coco.2019.11.011

Wang, 2018, Ultra-low phosphorus loading to achieve the superior flame retardancy of epoxy resin, Polym Degrad Stabil, 149, 119, 10.1016/j.polymdegradstab.2018.01.024

Yuan, 2020, Facile synthesis of aluminum branched oligo(phenylphosphonate) submicro-particles with enhanced flame retardance and smoke toxicity suppression for epoxy resin composites, J Hazard Mater, 381, 121233, 10.1016/j.jhazmat.2019.121233

Velencoso, 2018, Molecular firefighting-how modern phosphorus Chemistry can help solve the challenge of flame retardancy, Angew Chem Int Ed Engl, 57, 10450, 10.1002/anie.201711735

Rao, 2021, High strength, low flammability, and smoke suppression for epoxy thermoset enabled by a low-loading phosphorus-nitrogen-silicon compound, Compos B Eng, 211, 108640, 10.1016/j.compositesb.2021.108640

Misasi, 2017, Hybrid POSS-Hyperbranched polymer additives for simultaneous reinforcement and toughness improvements in epoxy networks, Polymer, 117, 54, 10.1016/j.polymer.2017.04.007

Ma, 2018, Facile synthesis of a novel hyperbranched poly(urethane-phosphine oxide) as an effective modifier for epoxy resin, Polym Degrad Stabil, 154, 157, 10.1016/j.polymdegradstab.2018.05.021

Battig, 2021, Hyperbranched rigid aromatic phosphorus‐containing flame retardants for epoxy resins, Macromol Mater Eng, 306, 2000731, 10.1002/mame.202000731

Ma, 2016, Facile synthesis of a highly efficient, halogen-free, and intumescent flame retardant for epoxy resins: thermal properties, combustion behaviors, and flame-retardant mechanisms, Ind Eng Chem Res, 55, 10868, 10.1021/acs.iecr.6b01899

Li, 2021, Scalable production of hydrophobic and photo-thermal conversion bio-based 3D scaffold: towards oil-water separation and continuous oil collection, J Clean Prod, 319, 128567, 10.1016/j.jclepro.2021.128567

Zhang, 2018, Flame retardant polyurethane foam prepared from compatible blends of soybean oil-based polyol and phosphorus containing polyol, J Appl Polym Sci, 135, 45779, 10.1002/app.45779

Hai, 2015, An acid-free microwave approach to prepare highly luminescent boron-doped graphene quantum dots for cell imaging, J Mater Chem B, 3, 9109, 10.1039/C5TB01954K

Najafi, 2018, Sol-gel synthesis and characterization of B4C nanopowder, Ceram Int, 44, 21386, 10.1016/j.ceramint.2018.08.196

Wang, 2015, Intumescent flame retardant-derived P,N co-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction, Chem Commun, 51, 14801, 10.1039/C5CC05960G

Sun, 2018, In situ doping boron atoms into porous carbon nanoparticles with increased oxygen graft enhances both affinity and durability toward electrolyte for greatly improved supercapacitive performance, Adv Funct Mater, 28, 1804190, 10.1002/adfm.201804190

Sai, 2021, Transparent, highly thermostable and flame retardant polycarbonate enabled by rod-like phosphorous-containing metal complex aggregates, Chem Eng J, 409, 128223, 10.1016/j.cej.2020.128223

Huo, 2022, Flame-retardant, transparent, mechanically-strong and tough epoxy resin enabled by high-efficiency multifunctional boron-based polyphosphonamide, Chem Eng J, 427, 131578, 10.1016/j.cej.2021.131578

Ai, 2020, Mechanically strong and flame-retardant epoxy resins with anti-corrosion performance, Compos B Eng, 193, 108019, 10.1016/j.compositesb.2020.108019

Ma, 2017, Economical and environment-friendly synthesis of a novel hyperbranched poly(aminomethylphosphine oxide-amine) as co-curing agent for simultaneous improvement of fire safety, glass transition temperature and toughness of epoxy resins, Chem Eng J, 322, 618, 10.1016/j.cej.2017.04.070

Teng, 2022, Hyperbranched flame retardant for epoxy resin modification: simultaneously improved flame retardancy, toughness and strength as well as glass transition temperature, Chem Eng J, 428, 131226, 10.1016/j.cej.2021.131226

Foix, 2012, Improvement of epoxy thermosets using a thiol‐ene based polyester hyperbranched polymer as modifier, Polym Int, 61, 727, 10.1002/pi.3230

Cheng, 2020, Aminobenzothiazole-substituted cyclotriphosphazene derivative as reactive flame retardant for epoxy resin, React Funct Polym, 146, 104412, 10.1016/j.reactfunctpolym.2019.104412

Fang, 2018, A facile way to prepare phosphorus-nitrogen-functionalized graphene oxide for enhancing the flame retardancy of epoxy resin, Compos Commun, 10, 97, 10.1016/j.coco.2018.08.001

Yang, 2021, A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate, Compos B Eng, 207, 108601, 10.1016/j.compositesb.2020.108601

Huo, 2020, A liquid phosphorus-containing imidazole derivative as flame-retardant curing agent for epoxy resin with enhanced thermal latency, mechanical, and flame-retardant performances, J Hazard Mater, 386, 121984, 10.1016/j.jhazmat.2019.121984

Cai, 2021, Barrier function of graphene for suppressing the smoke toxicity of polymer/black phosphorous nanocomposites with mechanism change, J Hazard Mater, 404, 124106, 10.1016/j.jhazmat.2020.124106

Huang, 2019, Realizing simultaneous improvements in mechanical strength, flame retardancy and smoke suppression of ABS nanocomposites from multifunctional graphene, Compos B Eng, 177, 107377, 10.1016/j.compositesb.2019.107377

Wang, 2021, Synthesis of a hyperbranched polyamide charring agent and its flame-retarding and toughening behavior in epoxy resin, Polym Degrad Stabil, 184, 109479, 10.1016/j.polymdegradstab.2020.109479

Chen, 2021, Novel phosphorus/nitrogen/boron-containing carboxylic acid as co-curing agent for fire safety of epoxy resin with enhanced mechanical properties, J Hazard Mater, 402, 123769, 10.1016/j.jhazmat.2020.123769

Chen, 2021, An effective strategy to enhance the flame retardancy and mechanical properties of epoxy resin by using hyperbranched flame retardant, J Mater Sci, 56, 5956, 10.1007/s10853-020-05691-3

Zhang, 2020, A bio-based hyperbranched flame retardant for epoxy resins, Chem Eng J, 381, 122719, 10.1016/j.cej.2019.122719

Liu, 2020, A novel phosphorus-containing semi-aromatic polyester toward flame retardancy and enhanced mechanical properties of epoxy resin, Chem Eng J, 380, 122471, 10.1016/j.cej.2019.122471

Fang, 2020, Fabrication of polyphosphazene covalent triazine polymer with excellent flame retardancy and smoke suppression for epoxy resin, Chem Eng J, 385, 123830, 10.1016/j.cej.2019.123830

Chu, 2020, Renewable vanillin-based flame retardant toughening agent with ultra-low phosphorus loading for the fabrication of high-performance epoxy thermoset, Compos B Eng, 190, 107925, 10.1016/j.compositesb.2020.107925

Chen, 2020, Synthesis of chitosan-based flame retardant and its fire resistance in epoxy resin, Carbohydr Polym, 245, 116530, 10.1016/j.carbpol.2020.116530

Yang, 2019, Synthesis of a novel phosphazene-based flame retardant with active amine groups and its application in reducing the fire hazard of Epoxy Resin, J Hazard Mater, 366, 78, 10.1016/j.jhazmat.2018.11.093

Ma, 2019, Synthesis of (1,4‐methylenephenylphosphinic acid) piperazine and its application as a flame retardant in epoxy thermosets, Macromol Mater Eng, 304, 1900419, 10.1002/mame.201900419

Li, 2019, Simultaneously improving the thermal, flame‐retardant and mechanical properties of epoxy resins modified by a novel multi‐element synergistic flame retardant, Macromol Mater Eng, 304, 1800619, 10.1002/mame.201800619

Li, 2019, Highly efficient multielement flame retardant for multifunctional epoxy resin with satisfactory thermal, flame‐retardant, and mechanical properties, Polym Adv Technol, 31, 146, 10.1002/pat.4758

Jian, 2019, Single component phosphamide-based intumescent flame retardant with potential reactivity towards low flammability and smoke epoxy resins, J Hazard Mater, 371, 529, 10.1016/j.jhazmat.2019.03.045

Duan, 2019, A novel phosphorus/nitrogen-containing polycarboxylic acid endowing epoxy resin with excellent flame retardance and mechanical properties, Chem Eng J, 375, 121916, 10.1016/j.cej.2019.121916

Shi, 2018, Novel phosphorus-containing halogen-free ionic liquid toward fire safety epoxy resin with well-balanced comprehensive performance, Chem Eng J, 354, 208, 10.1016/j.cej.2018.08.023

Hu, 2019, Facile synthesis of a novel transparent hyperbranched phosphorous/nitrogen-containing flame retardant and its application in reducing the fire hazard of epoxy resin, J Hazard Mater, 379, 120793, 10.1016/j.jhazmat.2019.120793

Zhang, 2021, Construction of durable eco-friendly biomass-based flame-retardant coating for cotton fabrics, Chem Eng J, 410, 128361, 10.1016/j.cej.2020.128361

Li, 2021, Bio-based multifunctional carbon aerogels from sugarcane residue for organic solvents adsorption and solar-thermal-driven oil removal, Chem Eng J, 426, 129580, 10.1016/j.cej.2021.129580

Sonnier, 2016, Flame retardancy of phosphorus-containing ionic liquid based epoxy networks, Polym Degrad Stabil, 134, 186, 10.1016/j.polymdegradstab.2016.10.009

Ye, 2021, One-step and green synthesis of a bio-based high-efficiency flame retardant for poly (lactic acid), Polym Degrad Stabil, 192, 109696, 10.1016/j.polymdegradstab.2021.109696

Zhao, 2020, Novel organophosphorus compound with amine groups towards self-extinguishing epoxy resins at low loading, Mater Des, 193, 108838, 10.1016/j.matdes.2020.108838

Liu, 2020, Synthesis of a novel nonflammable eugenol-based phosphazene epoxy resin with unique burned intumescent char, Chem Eng J, 390, 124620, 10.1016/j.cej.2020.124620

Yang, 2015, Preparation and flame retardancy of an intumescent flame-retardant epoxy resin system constructed by multiple flame-retardant compositions containing phosphorus and nitrogen heterocycle, Polym Degrad Stabil, 119, 251, 10.1016/j.polymdegradstab.2015.05.019

Seraji, 2021, Phosphazene as an effective flame retardant for rapid curing epoxy resins, React Funct Polym, 164, 104910, 10.1016/j.reactfunctpolym.2021.104910

Wang, 2017, Highly efficient flame-retardant epoxy resin with a novel DOPO-based triazole compound: thermal stability, flame retardancy and mechanism, Polym Degrad Stabil, 137, 138, 10.1016/j.polymdegradstab.2017.01.014