Surface Defect Engineering in 2D Nanomaterials for Photocatalysis

Advanced Functional Materials - Tập 28 Số 39 - 2018
Jun Xiong1,2, Jun Di1,3, Jiexiang Xia1, Wenshuai Zhu1, Huaming Li1
1School of Chemistry and Chemical Engineering, Institute for Energy Research, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, P. R. China
2School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798, Singapore
3School of Materials Science & Engineering Nanyang Technological University Singapore 639798 Singapore

Tóm tắt

Abstract2D Nanomaterials, with unique structural and electronic features, have shown enormous potential toward photocatalysis fields. However, the photocatalytic behavior of pristine 2D photocatalysts are still unsatisfactory, and far below the requirements of practical applications. In this regard, surface defect engineering can serve as an effective means to tune photoelectric parameters of 2D photocatalysts through tailoring the local surface microstructure, electronic structure, and carrier concentration. In this review, recent progress in the design of surface defects with the classified anion vacancy, cation vacancy, vacancy associates, pits, distortions, and disorder on 2D photocatalysts to boost the photocatalytic performance is summarized. The strategies for controlling defects formation and technique to distinguish various surface defects are presented. The crucial roles of surface defects for photocatalysis performance optimization are proposed and advancement of defective 2D photocatalysts toward versatile applications such as water oxidation, hydrogen production, CO2 reduction, nitrogen fixation, organic synthesis, and pollutants removal are discussed. Surface defect modulated 2D photocatalysts thus represent a powerful configuration for further development toward photocatalysis.

Từ khóa


Tài liệu tham khảo

10.1039/B800489G

10.1002/anie.201411096

10.1021/acs.chemrev.6b00396

10.1021/cr500008u

10.1016/j.ccr.2017.08.010

10.1002/adfm.201401636

10.1002/adfm.201702624

10.1016/j.joule.2018.02.019

10.1039/C6TA00284F

10.1021/cr400621z

10.1002/adma.201600301

10.1016/j.cej.2016.11.045

10.1016/j.nanoen.2015.10.011

10.1016/j.apcatb.2018.02.019

10.1021/cr400634p

10.1002/adma.201704548

10.1038/nnano.2015.340

10.1021/acs.chemrev.6b00164

10.1021/acs.chemrev.6b00558

10.1039/C6CS00343E

10.1021/jacs.6b11263

10.1016/j.nanoen.2017.03.030

10.1039/C4CS00236A

10.1002/anie.201705628

10.1039/C4CS00469H

10.1103/PhysRevB.80.233102

10.1002/aenm.201600436

10.1021/jp5033349

10.1002/adma.201606459

10.1016/j.nanoen.2016.12.054

10.1021/ja501866r

10.1021/jacs.5b03105

10.1002/adma.201503730

10.1016/j.carbon.2016.05.028

10.1002/adma.201605148

10.1002/smll.201503067

10.1103/PhysRevLett.109.035503

10.1002/adfm.201503221

10.1021/ja5085157

10.1021/ja512047k

10.1016/j.nanoen.2014.06.029

10.1016/j.apcatb.2015.04.022

10.1016/j.apcatb.2017.09.009

10.1021/jacs.7b02290

10.1002/anie.201708709

10.1002/adfm.201501009

10.1021/ja402956f

10.1038/ncomms3899

10.1039/C7TA03624H

10.1002/aenm.201601273

10.1002/aenm.201600437

10.1002/adma.201501939

10.1021/jacs.6b08748

10.1038/ncomms2066

10.1002/anie.201204675

10.1002/aenm.201300611

10.1039/C3SC52546E

10.1039/C4CS00330F

10.1126/science.1200448

10.1002/adma.201404057

10.1016/j.apcatb.2014.05.031

10.1002/anie.201406017

10.1016/j.jpowsour.2015.05.101

10.1002/smll.201303548

10.1039/c3nr03597b

10.1039/c1cc10537j

10.1021/ja4092903

10.1039/c1cc11015b

10.1039/C1CP22876E

10.1039/C4SC00565A

10.1002/anie.201406695

10.1016/j.apcatb.2016.01.012

10.1038/nmat4465

10.1002/anie.201600687

10.1038/ncomms8261

10.1039/C5EE01290B

10.1103/RevModPhys.85.1583

10.1021/jacs.5b01863

10.1021/jp307573c

Di J., 2018, Mater. Today

10.1002/chem.201503778

10.1038/ncomms11480

10.1021/acsnano.7b07974

10.1002/anie.201710509

10.1039/C6EE00383D

10.1021/jacs.7b00452

10.1021/acs.accounts.6b00523

10.1002/adma.201701774

10.1016/j.apcatb.2016.07.025

10.1002/adma.201703828

10.1039/C4SC03229B

10.1021/jacs.6b04629

10.1016/j.apcatb.2017.04.050

Thông tin
Thông tin xuất bản

Advanced Functional Materials

Tập 28 Số 39

Thông tin tác giả