Theoretical prediction on a special bridging metal–Xe–metal bond with remarkable stability in Re2Cp2(PF3)4Xe

Science in China Series B: Chemistry - Tập 59 Số 6 - Trang 760-764 - 2016
Liu, Nannan1, Ding, Yihong2
1Chemistry Center, College of Food Engineering, Harbin University of Commerce, Harbin, China
2Institute of Theoretical Chemistry, Jilin University, Changchun, China

Tóm tắt

The bridging Re–Xe–Re bond with a remarkable stability is firstly predicted. The average binding energies for Re–Xe bond in Re2Cp2(PF3)4Xe with bridging Xe are calculated to be higher than that in ReCp(CO)2Xe, ReCp(CO)(PF3)Xe and ReCp(PF3)2Xe with terminal Xe. The interaction between two ReCp(PF3)2 fragments provides an additional contribution for the stability of bridging Re–Xe–Re bond. Besides, the Re2Cp2(PF3)4Xe isomers with bridging Xe are also stable in energy than the isomers with bridging PF3. As the terminal Re–Xe bond was found to exist in experiments, the more stable bridging Re–Xe–Re bond might be existent under similar or even milder condition.

Tài liệu tham khảo

citation_journal_title=J Am Chem Soc; citation_author=BH Weiller; citation_volume=114; citation_publication_date=1992; citation_pages=10910-10915; citation_doi=10.1021/ja00053a030; citation_id=CR1 citation_journal_title=J Am Chem Soc; citation_author=RH Schultz, AA Bengali, MJ Tauber, BH Weiller, EP Wasserman, KR Kyle, CB Moore, RG Bergman; citation_volume=116; citation_publication_date=1994; citation_pages=7369-7377; citation_doi=10.1021/ja00095a047; citation_id=CR2 citation_journal_title=J Am Chem Soc; citation_author=XZ Sun, DC Grills, SM Nikiforov, M Poliakoff, MW George; citation_volume=119; citation_publication_date=1997; citation_pages=7521-7525; citation_doi=10.1021/ja962939j; citation_id=CR3 citation_journal_title=J Chem Soc, Dalton Trans; citation_author=GI Childs, CS Colley, J Dyer, DC Grills, XZ Sun, JX Yang, MW George; citation_volume=12; citation_publication_date=2000; citation_pages=1901-1906; citation_doi=10.1039/b001987i; citation_id=CR4 citation_title=Chem Commun; citation_publication_date=2000; citation_id=CR5; citation_author=DC Grills; citation_author=GI Child; citation_author=MW George citation_journal_title=Chem Soc Rev; citation_author=W Grochala; citation_volume=36; citation_publication_date=2007; citation_pages=1632-1655; citation_doi=10.1039/b702109g; citation_id=CR6 citation_journal_title=J Phys Chem A; citation_author=D Manna, A Ghosh, TK Ghanty; citation_volume=117; citation_publication_date=2013; citation_pages=14282-14292; citation_doi=10.1021/jp410631y; citation_id=CR7 citation_journal_title=J Phys Chem A; citation_author=A Ghosh, D Manna, TK Ghanty; citation_volume=119; citation_publication_date=2015; citation_pages=2233-2243; citation_doi=10.1021/jp5042266; citation_id=CR8 citation_journal_title=J Phys Chem A; citation_author=A Ghosh, S Dey, D Manna, TK Ghanty; citation_volume=119; citation_publication_date=2015; citation_pages=5732-5741; citation_doi=10.1021/jp512520y; citation_id=CR9 citation_journal_title=J Chem Phys; citation_author=K Gao, S Li; citation_volume=142; citation_publication_date=2015; citation_pages=144301; citation_doi=10.1063/1.4916648; citation_id=CR10 citation_journal_title=Comput Theor Chem; citation_author=NN Liu, YH Ding; citation_volume=1045; citation_publication_date=2014; citation_pages=29-34; citation_doi=10.1016/j.comptc.2014.06.019; citation_id=CR11 citation_journal_title=Organometallics; citation_author=AW Ehlers, G Frenking, EJ Baerends; citation_volume=16; citation_publication_date=1997; citation_pages=4896-4902; citation_doi=10.1021/om9704962; citation_id=CR12 citation_journal_title=Organometallics; citation_author=J McMaster, P Portius, GE Ball, JP Pourke, MW George; citation_volume=25; citation_publication_date=2006; citation_pages=5242-5248; citation_doi=10.1021/om060485l; citation_id=CR13 citation_journal_title=Phys Rev A; citation_author=AD Becke; citation_volume=38; citation_publication_date=1988; citation_pages=3098-3100; citation_doi=10.1103/PhysRevA.38.3098; citation_id=CR14 citation_journal_title=Phys Rev B; citation_author=C Lee, W Yang, RG Parr; citation_volume=37; citation_publication_date=1988; citation_pages=785-789; citation_doi=10.1103/PhysRevB.37.785; citation_id=CR15 citation_journal_title=Phys Rev Lett; citation_author=B Miehlich, A Savin, H Stoll, H Preuss; citation_volume=157; citation_publication_date=1989; citation_pages=200-206; citation_id=CR16 citation_journal_title=Phys Rev Lett; citation_author=JP Perdew, K Burke, M Ernzerhof; citation_volume=77; citation_publication_date=1996; citation_pages=3865-3868; citation_doi=10.1103/PhysRevLett.77.3865; citation_id=CR17 citation_journal_title=Phys Rev B; citation_author=JP Perdew; citation_volume=33; citation_publication_date=1986; citation_pages=8822-8824; citation_doi=10.1103/PhysRevB.33.8822; citation_id=CR18 citation_journal_title=J Comp Chem; citation_author=D Feller; citation_volume=17; citation_publication_date=1996; citation_pages=1571-1586; citation_doi=10.1002/(SICI)1096-987X(199610)17:13<1571::AID-JCC9>3.0.CO;2-P; citation_id=CR19 citation_journal_title=Phys Chem Chem Phys; citation_author=JD Chai, M Head-Gordon; citation_volume=10; citation_publication_date=2008; citation_pages=6615-6620; citation_doi=10.1039/b810189b; citation_id=CR20 citation_journal_title=J Chem Inf Model; citation_author=KL Schuchardt, BT Didier, T Elsethagen, L Sun, V Gurumoorthi, J Chase, J Li, TL Windus; citation_volume=47; citation_publication_date=2007; citation_pages=1045-1052; citation_doi=10.1021/ci600510j; citation_id=CR21 citation_title=Gaussian 09; citation_publication_date=2009; citation_id=CR22; citation_author=MJ Frisch; citation_author=GW Trucks; citation_author=HB Schlegel citation_journal_title=J Comp Chem; citation_author=T Lu, F Chen; citation_volume=33; citation_publication_date=2012; citation_pages=580-592; citation_doi=10.1002/jcc.22885; citation_id=CR23 citation_journal_title=Proc Natl Acad Sci USA; citation_author=GE Ball, TA Darwish, S Geftakis, MW George, DJ Lawes, P Portius, JP Rourke; citation_volume=102; citation_publication_date=2005; citation_pages=1853-1858; citation_doi=10.1073/pnas.0406527102; citation_id=CR24