Synthesis and Sensor Activity of a PET-based 1,8-naphthalimide Probe for Zn2+ and pH Determination

Journal of Fluorescence - Tập 24 - Trang 1621-1628 - 2014
Stefan M. Dimov1, Nikolai I. Georgiev1, Abdullah M. Asiri2,3, Vladimir B. Bojinov1,2
1Department of Organic Synthesis, University of Chemical Technology and Metallurgy, Sofia, Bulgaria
2Chemistry Department, Faculty of Sciences, King Abdulaziz University, Jeddah, Saudi Arabia
3Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz University, Jeddah, Saudi Arabia

Tóm tắt

A novel blue-emitting 1,8-naphthalimide fluorophore designed as a molecular PET-based probe for determination of pH and detection of transition metal ions in the environment was successfully synthesized. Novel compound was configured on the “fluorophore-spacer-receptor” format. Due to the tertiary amine receptor the novel system showed “off-on” switching properties under the transition from alkaline to acid media (FE = 3.2) and in the presence of Zn2+ ions (FE = 2.5). The results obtained illustrate the high potential of the synthesized blue-emitting 1,8-naphthalimide fluorophore as an efficient pH chemosensing material and a selective probe for Zn2+ ions.

Tài liệu tham khảo

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