Geochemical evolution of organic-rich shales with increasing maturity: A STXM and TEM study of the Posidonia Shale (Lower Toarcian, northern Germany)
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Aagaard, 1990, Diagenetic albitization of detrital K-feldspars in Jurassic, lower Cretaceous and tertiary clastic reservoir rocks from offshore Norway, II. Formation water chemistry and kinetic considerations, Journal of Sedimentary Petrology, 60, 575, 10.1306/212F91EC-2B24-11D7-8648000102C1865D
Ahuja, 1996, Theoretical and experimental study of the graphite 1s X-ray absorption edges, Physical Review B, 54, 14396, 10.1103/PhysRevB.54.14396
Bakr, 1991, Role of pyrite during the thermal degradation of kerogen using in situ high-temperature ESR technique, Energy & Fuels, 5, 441, 10.1021/ef00027a014
Bartlett, 2009, S-34 tracer study of pollutant sulfate behaviour in a lowland peatland, Biogeochemistry, 95, 261, 10.1007/s10533-009-9335-7
Bazin, 1997, Chemistry of oil-field brines in relation to diagenesis of reservoirs–2. Reconstruction of palaeo-water composition for modelling illite diagenesis in the greater Alwyn area (North Sea), Marine and Petroleum Geology, 14, 497, 10.1016/S0264-8172(97)00005-6
Behar, 1987, Chemical modeling of kerogens, Organic Geochemistry, 11, 15, 10.1016/0146-6380(87)90047-7
Behar, 1992, Experimental simulation in a confined system and kinetic modeling of kerogen and oil cracking, Organic Geochemistry, 19, 173, 10.1016/0146-6380(92)90035-V
Behar, 1997, Thermal cracking of kerogen in open and closed systems: determination of kinetic parameters and stoichiometric coefficients for oil and gas generation, Organic Geochemistry, 26, 321, 10.1016/S0146-6380(97)00014-4
Behar, 2008, Role of NSO compounds during primary cracking of a type II kerogen and a type III lignite, Organic Geochemistry, 39, 1, 10.1016/j.orggeochem.2007.10.007
Behar, 2008, Elaboration of a new compositional kinetic schema for oil cracking, Organic Geochemistry, 39, 764, 10.1016/j.orggeochem.2008.03.007
Behar, 2010, Artificial maturation of a Type I kerogen in closed system: mass balance and kinetic modelling, Organic Geochemistry, 41, 1235, 10.1016/j.orggeochem.2010.08.005
Benzerara, 2004, Scanning transmission X-ray microscopy study of microbial calcification, Geobiology, 2, 249, 10.1111/j.1472-4677.2004.00039.x
Benzerara, 2005, TEM study of a silicate-carbonate-microbe interface prepared by focused ion beam milling, Geochimica et Cosmochimica Acta, 69, 1413, 10.1016/j.gca.2004.09.008
Benzerara, 2007, Alteration of submarine basaltic glass from the Ontong Java Plateau: a STXM and TEM study, Earth and Planetary Science Letters, 260, 187, 10.1016/j.epsl.2007.05.029
Bernard, 2007, Exceptional preservation of plant fossils in high-pressure metamorphic rocks, Earth and Planetary Science Letters, 262, 257, 10.1016/j.epsl.2007.07.041
Bernard, 2009, Ultrastructural and chemical study of modern and fossil sporoderms by scanning transmission X-ray microscopy (STXM), Review of Palaeobotany and Palynology, 156, 248, 10.1016/j.revpalbo.2008.09.002
Bernard, 2010, Multi-scale detection of organic and inorganic signatures provides insights into gas shale properties and evolution, Chemie der Erde - Geochemistry, 70, 119, 10.1016/j.chemer.2010.05.005
Bernard, 2010, Multiscale characterization of pyritized plant tissues in blueschist facies metamorphic rocks, Geochimica et Cosmochimica Acta, 74, 5054, 10.1016/j.gca.2010.06.011
Bernard, 2010, XANES, Raman and XRD signatures of anthracene-based cokes and saccharose-based chars submitted to high temperature pyrolysis, Carbon, 48, 2506, 10.1016/j.carbon.2010.03.024
Berner, 1984, Sedimentary pyrite formation: an update, Geochimica et Cosmochimica Acta, 48, 605, 10.1016/0016-7037(84)90089-9
Bluhm, 2006, Soft X-ray microscopy and spectroscopy at the molecular environmentalscience beamline at the Advanced Light Source, Journal of Electron Spectroscopy and Related Phenomena, 150, 86, 10.1016/j.elspec.2005.07.005
Bottrell, 2009, Sulphur cycling in organic-rich marine sediments from a Scottish fjord, Sedimentology, 56, 1159, 10.1111/j.1365-3091.2008.01024.x
Boyce, 2002, Organic chemical differentiation within fossil plant cell walls detected with X-Ray spectromicroscopy, Geology, 30, 1039, 10.1130/0091-7613(2002)030<1039:OCDWFP>2.0.CO;2
Boyce, 2004, Evolution of xylem lignification and hydrogel transport regulation, Proceedings of the National Academy of Sciences of the United States of America, 101, 17555, 10.1073/pnas.0408024101
Brandes, 2008, Carbon K-edge XANES spectromicroscopy of natural graphite, Carbon, 46, 1424, 10.1016/j.carbon.2008.06.020
Brandes, 2010, Carbon K-edge spectra of carbonate minerals, Journal of Synchrotron Radiation, 17, 676, 10.1107/S0909049510020029
Braun, 2005, Advantages of soft X-ray absorption over TEM-EELS for solid carbon studies: a comparative study on diesel soot with EELS and NEXAFS, Carbon, 43, 117, 10.1016/j.carbon.2004.08.029
Braun, 2006, Impact of ferrocene on the structure of diesel exhaust soot as probed with wide-angle X-ray scattering and C(1s) NEXAFS spectroscopy, Carbon, 44, 2904, 10.1016/j.carbon.2006.05.051
Braun, 2009, Radiation damage from EELS and NEXAFS in diesel soot and diesel soot extracts, Journal of Electron Spectroscopy and Related Phenomena, 170, 42, 10.1016/j.elspec.2007.08.002
Burnham, 1990, Development of a detailed model of petroleum formation, destruction and expulsion from lacustrine source rocks, Organic Geochemistry, 16, 27, 10.1016/0146-6380(90)90023-S
Carravetta, 1998, High resolution NEXAFS spectroscopy study of gas-phase phenylacetylene: experiment and theory, Chemical Physics Letters, 288, 37, 10.1016/S0009-2614(98)00143-2
Clarkson, 1996, Variation in micropore capacity and size distribution with composition in bituminous coal of the Western Canadian sedimentary basin - implications for coalbed methane potential, Fuel, 75, 1483, 10.1016/0016-2361(96)00142-1
Clarkson, 1999, The effect of pore structure and gas pressure upon the transport properties of coal: a laboratory and modeling study. 1. Isotherms and pore volume distributions, Fuel, 78, 1333, 10.1016/S0016-2361(99)00055-1
Cody, 1996, The application of soft X-ray microscopy to the in-situ analysis of sporinite in coal, International Journal of Coal Geology, 32, 69, 10.1016/S0166-5162(96)00031-6
Cody, 1998, Determination of chemical-structural changes in vitrinite accompanying luminescence alteration using C-NEXAFS analysis, Organic Geochemistry, 28, 441, 10.1016/S0146-6380(98)00010-2
Crampon, 1973, Metamorphisme hydrothermal en facies salins et penesalins sur l’exemple du complexe salifere de l’extreme Nord Tunisien, Contributions to Mineralogy and Petrology, 39, 117, 10.1007/BF00375735
Curiale, 1986, Origin of solid bitumens, with emphasis on biological marker results, Organic Geochemistry, 10, 559, 10.1016/0146-6380(86)90054-9
Curtis, 2002, Fractured shale-gas systems, AAPG Bulletin, 86, 1921
de Groot, 1990, L2,3 X-ray-absorption edges of d0 compounds: K+, Ca2+, Sc3+ and Ti4+ in Oh (octahedral) symmetry, Physical Review B, 41, 928, 10.1103/PhysRevB.41.928
Dembicki, 2009, Three common source rock evaluation errors made by geologists during prospect or play appraisals, AAPG Bulletin, 93, 341, 10.1306/10230808076
Dieckmann, 1998, Kinetics of petroleum generation and cracking by programmed-temperature closed-system pyrolysis of Toarcian Shales, Fuel, 77, 23, 10.1016/S0016-2361(97)00165-8
Drobne, 2007, Surface damage induced by FIB milling and imaging of biological samples is controllable, Microscopy Research and Technique, 70, 895, 10.1002/jemt.20494
Erdmann, 2006, Enhanced late gas generation potential of petroleum source rocks via recombination reactions: evidence from the Norwegian North Sea, Geochimica et Cosmochimica Acta, 70, 3943, 10.1016/j.gca.2006.04.003
Francis, 1992, Inner-shell spectroscopy of p-benzoquinone, hydroquinone, and phenol: distinguishing quinoid and benzenoid structures, The Journal of Physical Chemistry, 96, 6598, 10.1021/j100195a018
Guo, 2009, Distinguishing gases derived from oil cracking and kerogen maturation: insights from laboratory pyrolysis experiments, Organic Geochemistry, 40, 1074, 10.1016/j.orggeochem.2009.07.007
Heaney, 2001, Focused ion beam milling: a method of site-specific sample extraction for microanalysis of Earth and planetary materials, American Mineralogist, 86, 1094, 10.2138/am-2001-8-917
Hebting, 2006, Biomarker evidence for a major preservation pathway of sedimentary organic carbon, Science, 312, 1627, 10.1126/science.1126372
Helgeson, 1993, Petroleum, oil field waters, and authigenic mineral assemblages are they in metastable equilibrium in hydrocarbon reservoirs, Geochimica et Cosmochimica Acta, 57, 3295, 10.1016/0016-7037(93)90541-4
Hill, 1996, The influence of pressure on the thermal cracking of oil, Energy and Fuels, 10, 873, 10.1021/ef9501408
Hill, 2003, Insights into oil cracking based on laboratory experiments, Organic Geochemistry, 34, 1651, 10.1016/S0146-6380(03)00173-6
Hitchcock, 2001, Chemical mapping with soft X-ray spectromicroscopy, American Laboratory, 33, 30
Hitchcock, 2007, X-ray absorption spectroscopy of polyureas and polyurethanes and their use in characterizing chemical gradients in thin-walled polyuria capsules, Journal of Electron Spectroscopy and Related Phenomena, 156, 467, 10.1016/j.elspec.2006.11.061
Hitchcock, 2008, Comparison of NEXAFS microscopy and TEM-EELS for studies of soft matter, Micron, 39, 311, 10.1016/j.micron.2007.09.008
Horsfield, 1989, Practical criteria for classifying kerogens: some observations from pyrolysis-gas chromatography, Geochimica et Cosmochimica Acta, 53, 891, 10.1016/0016-7037(89)90033-1
Horsfield, 1991, The decomposition of Posidonia Shale and green river shale kerogens using microscale sealed vessel (MSSV) pyrolysis, Journal of Analytical and Applied Pyrolysis, 20, 107, 10.1016/0165-2370(91)80066-H
Horsfield, 1992, An investigation of the in-reservoir conversion of oil to gas: compositional and kinetic findings from closed-system programmed-temperature pyrolysis, Organic Geochemistry, 19, 191, 10.1016/0146-6380(92)90036-W
Horsfield, 1997, The bulk composition of first-formed petroleum in source rocks, 335
Hwang, 1998, Geochemical comparison of reservoir solid bitumens with diverse origins, Organic Geochemistry, 29, 505, 10.1016/S0146-6380(98)00078-3
Ishii, 1988, The oscillator strengths for C1s and O1s excitation of some saturated and unsaturated organic alcohols, acids and esters, Journal of Electron Spectroscopy and Related Phenomena, 46, 55, 10.1016/0368-2048(88)80005-7
Jarvie, 2007, Unconventional shale-gas systems: the Mississippian Barnett Shale of north-central Texas as one model for thermogenic shale-gas assessment, AAPG Bulletin, 91, 475, 10.1306/12190606068
Jenkins, 2008, Coalbed and shale-gas reservoirs, Journal of Petroleum Technology, 60, 92, 10.2118/103514-MS
Jochum, 1995, Intraformational redistribution of selected trace elements in the Posidonia Shale (Hils Syncline, NW Germany) caused by the thermal influence of the Vlotho Massif, Ore Geology Reviews, 9, 353, 10.1016/0169-1368(94)00018-J
Jochum, 1995, Hydrocarbon-bearing fluid inclusions in calcite-tilled horizontal fractures from mature Posidonia Shale (Hils Syncline, NW Germany), Ore Geology Reviews, 9, 363, 10.1016/0169-1368(94)00019-K
Kastner, 1979, Low temperature feldspars in sedimentary rocks, American Journal of Science, 279, 435, 10.2475/ajs.279.4.435
Katsube, 1994, Effects of diagenesis on shale nano-pore structure and implications for sealing capacity, Clay Minerals, 29, 451, 10.1180/claymin.1994.029.4.05
Kaznatcheev, 2007, Soft X-ray spectromicroscopy beamline at the CLS: commissioning results, Nuclear Instruments and Methods in Physics Research A, 582, 96, 10.1016/j.nima.2007.08.083
Kelemen, 2007, Direct characterization of kerogen by X-ray and solid-state C-13 nuclear magnetic resonance methods, Energy & Fuels, 21, 1548, 10.1021/ef060321h
Kelemen, 2010, Characterization of solid bitumens originating from thermal chemical alteration and thermochemical sulfate reduction, Geochimica et Cosmochimica Acta, 74, 5305, 10.1016/j.gca.2010.06.013
Kilcoyne, 2003, Interferometer-controlled scanning transmission X-ray microscopes at the Advanced Light Source, Journal of Synchrotron Radiation, 10, 125, 10.1107/S0909049502017739
Kim, 1999, Electron microscopic observations of shale diagenesis, offshore Louisiana, USA, Gulf of Mexico, Geo-marine Letters, 18, 234, 10.1007/s003670050073
Kruge, 1997, Separation and artificial maturation of macerals from Type II kerogen, Energy & Fuels, 11, 503, 10.1021/ef960191k
Langford, 2006, Focused ion beams techniques for nanomaterials characterization, Microscopy Research and Technique, 69, 538, 10.1002/jemt.20324
Larter, 1993, Determination of structural components of kerogen using analytical pyrolysis methods, 271
Leif, 1995, Ketones in hydrothermal petroleums and sediment extracts from Guaymas Basin, Gulf of California, Organic Geochemistry, 23, 889, 10.1016/0146-6380(95)00085-2
Lepot, 2009, Organic matter heterogeneities in 2.72 Ga stromatolites: alteration versus preservation by sulfur incorporation, Geochimica et Cosmochimica Acta, 73, 6579, 10.1016/j.gca.2009.08.014
Lewan, 1979, Generation of oil-like pyrolyzates from organic-rich shales, Science, 203, 897, 10.1126/science.203.4383.897
Lewan, 1985, Evaluation of petroleum generation by hydrous pyrolysis experimentation, Philosophical Transactions of the Royal Society of London Series A, 315, 123, 10.1098/rsta.1985.0033
Lewan, 1997, Experiments on the role of water in petroleum formation, Geochimica et Cosmochimica Acta, 61, 3691, 10.1016/S0016-7037(97)00176-2
Lewan, 2011, Role of water in hydrocarbon generation from Type-I kerogen in Mahogany oil shale of the Green River Formation, Organic Geochemistry, 42, 31, 10.1016/j.orggeochem.2010.10.004
Leythaeuser, 1988, Geochemical effects of petroleum migration and expulsion from Toarcian source rocks in the Hils syncline area, NW-Germany, Organic Geochemistry, 13, 489, 10.1016/0146-6380(88)90070-8
Lis, 2005, FTIR absorption indices for thermal maturity in comparison with vitrinite reflectance R-0 in type-II kerogens from Devonian black shales, Organic Geochemistry, 36, 1533, 10.1016/j.orggeochem.2005.07.001
Lis, 2008, Increasing maturity of kerogen type II reflected by alkylbenzene distribution from pyrolysis-gas chromatography-mass spectrometry, Organic Geochemistry, 39, 440, 10.1016/j.orggeochem.2008.01.007
Littke, 1987, Mikroskopische und makroskopische Unterschiede zwischen Profilen unreifen und reifen Posidonienschiefers aus der Hilsmulde, Facies, 17, 171, 10.1007/BF02536781
Littke, 1988, Microscopic and sedimentologic evidence for the generation and migration of hydrocarbons in Toarcian source rocks of different maturities, Organic Geochemistry, 13, 549, 10.1016/0146-6380(88)90075-7
Littke, 1991, Keys to the depositional history of the Posidonia Shale (Toarcian) in the Hils syncline, northern Germany, Geological Society of London, Special Publications, 58, 311, 10.1144/GSL.SP.1991.058.01.20
Littke, 1991, Quantification of loss of calcite, pyrite, and organic matter due to weathering of Toarcian black shales and effects on kerogen and bitumen characteristics, Geochimica et Cosmochimica Acta, 55, 3369, 10.1016/0016-7037(91)90494-P
Liu, 2005, Photochemical production of oligothiophene and polythiophene micropatternsfrom 2,5-diiodothiophene on Au in UHV, Surface Science, 592, L305, 10.1016/j.susc.2005.07.011
Lomando, 1992, The influence of solid reservoir bitumen on reservoir quality, AAPG Bulletin, 76, 1137
Lorant, 1998, Carbon isotopic and molecular constraints on the formation and the expulsion of thermogenic hydrocarbon gases, Chemical Geology, 147, 249, 10.1016/S0009-2541(98)00017-5
Lorant, 2002, Late generation of methane from mature kerogens, Energy & Fuels, 16, 412, 10.1021/ef010126x
Loucks, 2009, Morphology, genesis, and distribution of nanometer-scale pores in siliceous mudstones of the Mississippian Barnett shale, Journal of Sedimentary Research, 79, 848, 10.2110/jsr.2009.092
Mann, 1987, Veränderung von Mineralmatrix und Porosität eines Erdömuttergesteins durch einen Intrusivkörper, Facies, 17, 181, 10.1007/BF02536782
Mann, 1988, Source rock evaluation by well log analysis (lower Toarcian, Hils syncline), Organic Geochemistry, 13, 109, 10.1016/0146-6380(88)90031-9
Mann, 1991, Determination of molecular-structure of kerogens using C-13 NMR-spectroscopy .1. The effects of variation in kerogen type, Geochimica et Cosmochimica Acta, 55, 2259, 10.1016/0016-7037(91)90102-B
Mao, 2010, Chemical and nanometer-scale structure of kerogen and its change during thermal maturation investigated by advanced solid-state 13C NMR spectroscopy, Geochimica et Cosmochimica Acta, 74, 2110, 10.1016/j.gca.2009.12.029
Mastalerz, 2000, In-situ analysis of solid bitumen in coal: examples from the Bowen basin and the Illinois Basin, International Journal of Coal Geology, 42, 207, 10.1016/S0166-5162(99)00040-3
Mastalerz, 2008, Variations in pore characteristics in high volatile bituminous coals: implications for coal bed gas content, International Journal of Coal Geology, 76, 205, 10.1016/j.coal.2008.07.006
Michels, 1996, Evolution of asphaltenes during artificial maturation: a record of the chemical processes, Energy & Fuels, 10, 39, 10.1021/ef9501410
Montgomery, 2005, Mississippian Barnett Shale, Fort Worth Basin, north-central Texas: gas-shale play with multi-trillion cubic foot potential, AAPG Bulletin, 89, 155, 10.1306/09170404042
Muscio, 1991, Compositional changes in the macromolecular organic matter (kerogens, asphaltenes and resins) of a naturally matured source rock sequence from northern Germany as revealed by pyrolysis methods, 447
Myneni, 2002, Soft X-ray spectroscopy and spectromicroscopy studies of organic molecules in the environment, Reviews in Mineralogy and Geochemistry, 49, 485, 10.2138/gsrmg.49.1.485
Nelson, 2009, Pore throat sizes in sandstones, tight sandstones, and shales, AAPG Bulletin, 93, 1, 10.1306/10240808059
Obst, 2005, TEM-specimen preparation of cell/mineral interfaces by focused ion beam milling, American Mineralogist, 90, 1270, 10.2138/am.2005.1743
Orr, 1974, Changes in sulfur content and isotopic-ratios of sulfur during petroleum maturation - study of big horn basin Paleozoic oils, AAPG Bulletin, 58, 2295
Orr, 1986, Kerogen asphaltene sulfur relationships in sulfur-rich Monterey oils, Organic Geochemistry, 10, 499, 10.1016/0146-6380(86)90049-5
Pan, 2009, Kerogen pyrolysis in the presence and absence of water and minerals: amounts and compositions of bitumen and liquid hydrocarbons, Fuel, 88, 909, 10.1016/j.fuel.2008.11.024
Papineau, 2010, Ancient graphite in the Eoarchean quartz-pyroxene rocks from Akilia in southern West Greenland I: petrographic and spectroscopic characterization, Geochimica et Cosmochimica Acta, 74, 5862, 10.1016/j.gca.2010.05.025
Patience, 1992, Determination of molecular-structure of kerogens using C-13 NMR-spectroscopy .2. The effects of thermal maturation on kerogens from marine-sediments, Geochimica et Cosmochimica Acta, 56, 2725, 10.1016/0016-7037(92)90356-N
Pelet, 1986, Resins and asphaltenes in the generation and migration of petroleum, Organic Geochemistry, 10, 481, 10.1016/0146-6380(86)90048-3
Petersen, 2008, Oxygen groups in coals and alginite-rich kerogen revisited, International Journal of Coal Geology, 74, 93, 10.1016/j.coal.2007.11.007
Petmecky, 1999, High thermal maturity in the lower Saxony basin: intrusion or deep burial?, Tectonophysics, 304, 317, 10.1016/S0040-1951(99)00030-X
Pepper, 1995, Simple kinetic models of petroleum formation. Part I: oil and gas generation from kerogen, Marine and Petroleum Geology, 12, 291, 10.1016/0264-8172(95)98381-E
Pepper, 1995, Simple kinetic models of petroleum formation. Part II: oil-gas cracking, Marine and Petroleum Geology, 12, 291, 10.1016/0264-8172(95)98381-E
Putschew, 1998, Release of sulfur- and oxygen-bound components from a sulfur-rich kerogen during simulated maturation by hydrous pyrolysis, Organic Geochemistry, 29, 1875, 10.1016/S0146-6380(98)00191-0
Radke, 1980, Preparative hydrocarbon group type determination by automated medium pressure liquid chromatography, Analytical Chemistry, 52, 406, 10.1021/ac50053a009
Rais, 2008, Distribution of authigenic albites in a limestone succession of the Helvetic Domain, eastern Switzerland, Swiss Journal of Geosciences, 101, 99, 10.1007/s00015-007-1231-3
Ravel, 2005, ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT, Journal of Synchrotron Radiation, 12, 537, 10.1107/S0909049505012719
Requejo, 1992, Maturation of petroleum source rocks .1. Changes in kerogen structure and composition associated with hydrocarbon generation, Energy & Fuels, 6, 203, 10.1021/ef00032a015
Rightor, 1997, Spectromicroscopy of poly(ethylene terephthalate): comparison of spectra and radiation damage rates in X-ray absorption and electron energy loss, Journal of Physical Chemistry B, 101, 1950, 10.1021/jp9622748
Ross, 2009, The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs, Marine and Petroleum Geology, 26, 916, 10.1016/j.marpetgeo.2008.06.004
Rullkötter, 1988, Natural and artificial maturation of biological markers in a Toarcian shale from northern Germany, Organic Geochemistry, 13, 639, 10.1016/0146-6380(88)90084-8
Rullkötter, 1988, Organic matter maturation under the influence of a deep intrusive heat source: a natural experiment for quantitation of hydrocarbon generation and expulsion from a petroleum source rock (Toarcian shale, northern Germany), Organic Geochemistry, 13, 847, 10.1016/0146-6380(88)90237-9
Schenk, 1986, Infrared estimates of aliphatic kerogen carbon in sedimentary rocks, Organic Geochemistry, 10, 1099, 10.1016/S0146-6380(86)80050-X
Schenk, 1997, The conversion of oil into gas in petroleum reservoirs. Part 1: comparative kinetic investigation of gas generation from crude oils of lacustrine, marine and fluviodeltaic origin by programmed-temperature closed-system pyrolysis, Organic Geochemistry, 26, 467, 10.1016/S0146-6380(97)00024-7
Schiffbauer, 2009, Novel application of focused ion beam electron microscopy (FIB-EM) in preparation and analysis of microfossil ultrastructures: a new view of complexity in early Eukaryotic organisms, Palaios, 24, 616, 10.2110/palo.2009.p09-003r
Seewald, 1998, Laboratory and theoretical constraints on the generation and composition of natural gas, Geochimica et Cosmochimica Acta, 62, 1599, 10.1016/S0016-7037(98)00000-3
Seewald, 2001, Model for the origin of carboxylic acids in basinal brines, Geochimica et Cosmochimica Acta, 65, 3779, 10.1016/S0016-7037(01)00702-5
Seewald, 2001, Aqueous geochemistry of low molecular weight hydrocarbons at elevated temperatures and pressures: constraints from mineral buffered laboratory experiments, Geochimica et Cosmochimica Acta, 65, 1641, 10.1016/S0016-7037(01)00544-0
Shi, 2005, Study on amorphous carbon nitride film prepared by facing target sputtering, Thin Solid Films, 483, 169, 10.1016/j.tsf.2005.01.019
Simoneit, 1996, Phenols in hydrothermal petroleums and sediment bitumen from Guaymas Basin, Gulf of California, Organic Geochemistry, 24, 377, 10.1016/0146-6380(96)00008-3
Sinninghe Damsté, 1990, Analysis, structure and geochemical significance of organically-bound sulphur in the geosphere: state of the art and future research, Organic Geochemistry, 16, 1077, 10.1016/0146-6380(90)90145-P
Smernik, 2006, Assessing the quantitative reliability of solid-state C-13 NMR spectra of kerogens across a gradient of thermal maturity, Solid State Nuclear Magnetic Resonance, 29, 312, 10.1016/j.ssnmr.2005.10.014
Snowdon, 1979, Errors in extrapolation of experimental kinetic parameters to organic geochemical systems, AAPG Bulletin, 63, 1128
Solomon, 2009, Carbon (1s) NEXAFS spectroscopy of Biogeochemically relevant reference organic compounds, Soil Science Society of America Journal, 73, 1817, 10.2136/sssaj2008.0228
Spötl, 1999, Authigenic albite in carbonate rocks - a tracer for deep-burial brine migration?, Sedimentology, 46, 649, 10.1046/j.1365-3091.1999.00237.x
Stasiuk, 1997, The origin of pyrobitumens in upper Devonian Leduc formation gas reservoirs, Alberta, Canada: an optical and EDS study of oil to gas transformation, Marine and Petroleum Geology, 14, 915, 10.1016/S0264-8172(97)00031-7
Smith, 2001, FIB preparation of a sensitive porous catalyst for TEM elemental mapping at high magnifications, Journal of Materials Science, 36, 3519, 10.1023/A:1017984618032
Strapoc, 2010, Geochemical constraints on the origin and volume of gas in the New Albany shale (Devonian-Mississippian), eastern Illinois Basin, AAPG Bulletin, 94, 1713, 10.1306/06301009197
Theuerkorn, 2008, A reproducible and linear method for separating asphaltenes from crude oil, Organic Geochemistry, 39, 929, 10.1016/j.orggeochem.2008.02.009
Thieme, 2010, X-ray spectromicroscopy in soil and environmental sciences, Journal of Synchrotron Radiation, 17, 149, 10.1107/S0909049509049905
Thompson, 2006, Imaging thin films of nanoporous low-k dielectrics: comparison between ultramicrotomy and focused ion beam preparations for transmission electron microscopy, Microscopy & Microanalysis, 12, 156, 10.1017/S1431927606060041
Tian, 2008, New insights into the volume and pressure changes during the thermal cracking of oil to gas in reservoirs: implications for the in-situ accumulation of gas cracked from oils, AAPG Bulletin, 92, 181, 10.1306/09210706140
Tiem, 2008, Influence of in-situ bitumen on the generation of gas and oil in New Zealand coals, Organic Geochemistry, 39, 1606, 10.1016/j.orggeochem.2008.07.005
Tissot, 1984
Vandenbroucke, 1993, Kerogen maturation in a reference kerogen Type II series: the Toarcian shales of the Hils syncline, NW Germany, Organic Geochemistry, 20, 961, 10.1016/0146-6380(93)90106-L
Vandenbroucke, 2007, Kerogen origin, evolution and structure, Organic Geochemistry, 38, 719, 10.1016/j.orggeochem.2007.01.001
Wang, 2009, Radiation damage in soft X-ray microscopy, Journal of Electron Spectroscopy and Related Phenomena, 170, 25, 10.1016/j.elspec.2008.01.002
Waples, 2000, The kinetics of in-reservoir oil destruction and gas formation: constraints from experimental and empirical data, and from thermodynamics, Organic Geochemistry, 31, 553, 10.1016/S0146-6380(00)00023-1
Wei, 2005, Assessment of thermal evolution of kerogen geopolymers with their structural parameters measured by solid-state C-13 NMR spectroscopy, Energy & Fuels, 19, 240, 10.1021/ef0498566
Wilkes, 1998, Fluoren-9-ones and carbazoles in the Posidonia Shale, Hils syncline, northwest Germany, Fuel, 77, 657, 10.1016/S0016-2361(97)00224-X
Wilkes, 1998, Aromatic aldehydes and ketones in the Posidonia Shale, Hils syncline, Germany, Organic Geochemistry, 29, 107, 10.1016/S0146-6380(98)00138-7
Wirth, 2004, Focused ion beam (FIB): a novel technology for advanced application of micro- and nanoanalysis in geosciences and applied mineralogy, European Journal of Mineralogy, 16, 863, 10.1127/0935-1221/2004/0016-0863