Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters

Chemical Engineering Journal - Tập 151 Số 1-3 - Trang 19-29 - 2009
Bingjun Pan1, Bingcai Pan1, Weiming Zhang1, Lu Lv1, Quanxing Zhang1, Shourong Zheng1
1State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210093, PR China

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Kalderis, 2008, Adsorption of polluting substances on activated carbons prepared from rice husk and sugarcane bagasse, Chem. Eng. J., 144, 42, 10.1016/j.cej.2008.01.007

Qiu, 2008, Surface characteristics of crop-residue-derived black carbon and lead(II) adsorption, Water Res., 42, 567, 10.1016/j.watres.2007.07.051

Karaca, 2008, Adsorption of cationic dye from aqueous solutions by activated carbon, Micropor. Mesopor. Mater., 115, 376, 10.1016/j.micromeso.2008.02.008

Yu, 2008, Adsorption characteristics of selected pharmaceuticals and an endocrine disrupting compound—Naproxen, carbamazepine and nonylphenol-on activated carbon, Water Res., 42, 2873, 10.1016/j.watres.2008.02.020

Karanfil, 2004, Trichloroethylene adsorption by fibrous and granular activated carbons: aqueous phase, gas phase, and water vapor adsorption studies, Environ. Sci. Technol., 38, 5834, 10.1021/es0497936

Hernandez-Ramirez, 2008, Novel and modified materials for wastewater treatment applications, J. Mater. Chem., 18, 2751, 10.1039/b716941h

Tripathy, 2008, Abatement of fluoride from water using manganese dioxide-coated activated alumina, J. Hazard. Mater., 153, 1043

Johnson, 2008, Agricultural and agro-processing wastes as low cost adsorbents for metal removal from wastewater: a review, J. Sci. Ind. Res., 67, 647

Rios, 2008, Removal of heavy metals from acid mine drainage (AMD) using coal fly ash, natural clinker and synthetic zeolites, J. Hazard. Mater., 156, 23, 10.1016/j.jhazmat.2007.11.123

Vilar, 2008, Metal biosorption by algae Gelidium derived materials from binary solutions in a continuous stirred adsorber, Chem. Eng. J., 141, 42, 10.1016/j.cej.2007.10.011

Memon, 2008, Sawdust: a green and economical sorbent for thallium removal, Chem. Eng. J., 140, 235, 10.1016/j.cej.2007.09.044

Abburi, 2003, Adsorption of phenol and p-chlorophenol from their single and bisolute aqueous solutions on Amberlite XAD-16 resin, J. Hazard. Mater., B105, 143, 10.1016/j.jhazmat.2003.08.004

Otero, 2005, Comparative study of the adsorption of phenol and salicylic acid from aqueous solution onto nonionic polymeric resins, Sep. Purif. Technol., 45, 86, 10.1016/j.seppur.2005.02.011

Yang, 2003, Adsorption and desorption dynamics of amino acids in a nonionic polymeric sorbent XAD-16 column, Korean J. Chem. Eng., 20, 922, 10.1007/BF02697300

Deosarkar, 2004, Adsorptive separation and recovery of organics from PHBA and SA plant effluents, Sep. Purif. Technol., 38, 241, 10.1016/j.seppur.2003.11.012

Xu, 1997, Adsorption of naphthalene derivatives on different macroporous polymeric adsorbents, Chemosphere, 35, 2269, 10.1016/S0045-6535(97)00305-6

Long, 2008, Polanyi-based models for the adsorption of naphthalene from aqueous solutions onto nonpolar polymeric adsorbents, J. Colloid Interface Sci., 319, 12, 10.1016/j.jcis.2007.10.052

Lee, 2005, Adsorption of dichloromethane from water onto a hydrophobic polymer resin XAD-1600, Water Res., 39, 617, 10.1016/j.watres.2004.10.001

Musty, 1974, Use of Amberlite XAD-4 for extraction and recovery of chlorinated insecticides and polychlorinated biphenyls from water, J. Chromatogr., 89, 185, 10.1016/S0021-9673(01)99391-4

Pan, 1999, Treatment and resource reuse of industrial wastewater from production process of phenyl acetic acid, Chin. J. React. Polym., 8, 82

Pan, 2005, Sorption enhancement of aromatic sulfonates onto an aminated hyper-cross-linked polymer, Environ. Sci. Technol., 39, 3308, 10.1021/es048548j

Zheng, 2007, Enhanced adsorption of p-nitroaniline from water by a carboxylated polymeric adsorbent, Sep. Purif. Technol., 57, 250, 10.1016/j.seppur.2007.04.017

Swallow, 1980, Sorption of copper and lead by hydrous ferric oxide, Environ. Sci. Technol., 14, 1326, 10.1021/es60171a003

Kinniburgh, 1976, Adsorption of alkaline-earth, transition, and heavy-metal cations by hydrous oxide gels of iron and aluminum, Soil Sci. Soc. Am. J., 40, 796, 10.2136/sssaj1976.03615995004000050047x

Fan, 2005, Modeling Pb sorption to microporous amorphous oxides as discrete particles and coatings, J. Colloid Interface Sci., 281, 39, 10.1016/j.jcis.2004.08.050

Jang, 2008, Coadsorption of arsenic(III) and arsenic(V) onto hydrous ferric oxide: effects on abiotic oxidation of arsenic(III), extraction efficiency, and model accuracy, Environ. Sci. Technol., 42, 2893, 10.1021/es702318f

Trivedi, 2001, XAS studies of Ni and Zn sorbed to hydrous manganese oxide, Environ. Sci. Technol., 35, 4515, 10.1021/es0109848

Kawashima, 1986, Phosphate adsorption onto hydrous manganese(IV) oxide in the presence of divalent-cations, Water Res., 20, 471, 10.1016/0043-1354(86)90195-8

Bargar, 1997, Surface complexation of Pb(II) at oxide–water interfaces. 1. XAFS and bond-valence determination of mononuclear and polynuclear Pb(II) sorption products on aluminum oxides, Geochim. Cosmochim. Acta, 61, 2617, 10.1016/S0016-7037(97)00124-5

Pearson, 2005, Degradation of chloropicrin in the presence of zero-valent iron, Environ. Toxicol. Chem., 24, 3037, 10.1897/04-614Ra.1

Gopal, 2007, Chlorination byproducts, their toxicodynamics and removal from drinking water, J. Hazard. Mater., 140, 1, 10.1016/j.jhazmat.2006.10.063

Jang, 2008, Preloading hydrous ferric oxide into granular activated carbon for arsenic removal, Environ. Sci. Technol., 42, 3369, 10.1021/es7025399

Zhuang, 2008, Arsenate sorption by hydrous ferric oxide incorporated onto granular activated carbon with phenol formaldehyde resins coating, Environ. Technol., 29, 401, 10.1080/09593330801984399

Vaughan, 2005, Modeling As(V) removal by a iron oxide impregnated activated carbon using the surface complexation approach, Water Res., 39, 1005, 10.1016/j.watres.2004.12.034

Guo, 2005, Removal of arsenic by bead cellulose loaded with iron oxyhydroxide from groundwater, Environ. Sci. Technol., 39, 6808, 10.1021/es048080k

Zouboulis, 2002, Arsenic removal using iron oxide loaded alginate beads, Ind. Eng. Chem. Res., 41, 6149, 10.1021/ie0203835

Chen, 2007, Enhanced aggregation of alginate-coated iron oxide (hematite) nanoparticles in the presence of calcium, strontium, and barium cations, Langmuir, 23, 5920, 10.1021/la063744k

Jang, 2007, Hydrous ferric oxide incorporated diatomite for remediation of arsenic contaminated groundwater, Environ. Sci. Technol., 41, 3322, 10.1021/es062359e

Jang, 2006, Removal of arsenite and arsenate using hydrous ferric oxide incorporated into naturally occurring porous diatomite, Environ. Sci. Technol., 40, 1636, 10.1021/es051501t

Hansen, 2001, Use of iron oxide-coated sand to remove strontium from simulated hanford tank wastes, Environ. Sci. Technol., 35, 4905, 10.1021/es0108990

Tsadilas, 1998, Boron sorption by manganese oxide-coated sand, Commun. Soil Sci. Plan., 29, 2347, 10.1080/00103629809370115

Zachara, 1995, Adsorption and dissociation of Co-EDTA complexes in iron oxide-containing subsurface sands, Geochim. Cosmochim. Acta, 59, 4825, 10.1016/0016-7037(95)00340-1

Szecsody, 1994, Adsorption–dissolution reactions affecting the distribution and stability of Co(II)EDTA in iron-coated sand, Environ. Sci. Technol., 28, 1706, 10.1021/es00058a024

Kunin, 1976, The use of macroreticular polymeric adsorbents for the treatment of waste effluents, Pure Appl. Chem., 46, 205, 10.1351/pac197646020205

Cornel, 1986, Sorption of dissolved organics from aqueous solution by polystyrene resins. I. Resin characterization and sorption equilibrium, Chem. Eng. Sci., 41, 1791, 10.1016/0009-2509(86)87058-0

Cornel, 1986, Sorption of dissolved organics from aqueous solution by polystyrene resins. II. External and internal mass transfer, Chem. Eng. Sci., 41, 1801, 10.1016/0009-2509(86)87059-2

Kunin, 1977, Polymeric adsorbents for treatment of waste effluents, Polym. Eng. Sci., 17, 58, 10.1002/pen.760170111

Pan, 2007, Improved adsorption of 4-nitrophenol onto a novel hyper-cross-linked polymer, Environ. Sci. Technol., 41, 5057, 10.1021/es070134d

Kunin, 1980, vol. 163

Dinu, 2008, Heavy metals adsorption on some iminodiacetate chelating resins as a function of the adsorption parameters, React. Funct. Polym., 68, 1346, 10.1016/j.reactfunctpolym.2008.06.011

Pan, 2008, Adsorptive removal of phenol from aqueous phase by using a porous acrylic ester polymer, J. Hazard. Mater., 157, 293, 10.1016/j.jhazmat.2007.12.102

Okay, 2000, Macroporous copolymer networks, Prog. Polym. Sci., 25, 711, 10.1016/S0079-6700(00)00015-0

V.A. Davankov, S.V. Rogoshin, M.P. Tsyurupa, Patent USSR 299165 (1969a).

V.A. Davankov, S.V. Rogoshin, M.P. Tsyurupa, Macronet polystyrene structures for ionites and method of producing same, Patent USA 3729457 (1969b).

Veverka, 1999, Mechanism of hypercrosslinking of chloromethylated styrenedivinylbenzene copolymers, React. Funct. Polym., 41, 21, 10.1016/S1381-5148(99)00030-9

Pan, 2008, Removal of aromatic sulfonates from aqueous media by aminated polymeric sorbents: concentration-dependent selectivity and the application, Micropor. Mesopor. Mater., 116, 63, 10.1016/j.micromeso.2008.03.016

Feng, 1999, Treatment of wastewater from production process of 2,3-acid, Chin. J. React. Polym., 8, 68

Lv, 2000, Study on the treatment of industrial wastewater containing triethylamine with polymeric adsorbents, Chin. J. React. Polym., 9, 174

Zhang, 2002, Treatment of wastewater from 2,6-dihydroxybenzene carboxylic acid synthetic process, Ind. Water Treat., 28, 155

Sun, 2003, Study on the treatment of sulfanilamide intermediate wastewater by resin adsorption process, Environ. Protect. Chem. Ind., 23, 9

Freitas, 2008, Adsorption of di-2-pyridyl ketone salicyloylhydrazone on Amberlite XAD-2 and XAD-7 resins: characteristics and isotherms, J. Colloid Interface Sci., 323, 1, 10.1016/j.jcis.2008.04.001

Gusler, 1993, Sorption of organics from aqueous solution onto polymeric resins, Ind. Eng. Chem. Res., 32, 2727, 10.1021/ie00023a040

Zhang, 2008, Equilibrium and heat of adsorption of diethyl phthalate on heterogeneous adsorbents, J. Colloid Interface Sci., 325, 41, 10.1016/j.jcis.2008.05.030

Simpson, 1993, Sorption equilibrium isotherms for volatile organics in aqueous solution: comparison of headspace gas chromatography and on-line UV stirred cell results, Ind. Eng. Chem. Res., 32, 2269, 10.1021/ie00022a011

Garcia, 1999, Binary adsorption of phenol and m-cresol mixtures onto a polymeric adsorbents, Adsorption, 5, 359, 10.1023/A:1008904631147

Nastaj, 2008, Adsorption of phenol on water-fluidized polymeric Amberlite XAD-4 and XAD-16 adsorbents, Przem. Chem., 87, 300

Bilgili, 2006, Adsorption of 4-chlorophenol from aqueous solutions by XAD-4 resin: isotherm, kinetic, and thermodynamic analysis, J. Hazard. Mater., 137, 157, 10.1016/j.jhazmat.2006.01.005

Bautista, 2006, Functionalized adsorbents for the purification of cephalosporin C and deacetylcephalosporin C, Ind. Eng. Chem. Res., 45, 3230, 10.1021/ie051221m

Doulia, 1997, Removal of atrazine from water by use of nonionic polymeric resins, J. Environ. Sci. Health A, 32, 2635, 10.1080/10934529709376708

Yang, 2007, Adsorption mechanism of aromatic sulfonates onto resins with different matrices, Ind. Eng. Chem. Res., 46, 6971, 10.1021/ie0615281

Oha, 2003, Adsorptive removal of phenolic compounds by using hypercrosslinked polystyrenic beads with bimodal pore size distribution, React. Funct. Polym., 57, 103, 10.1016/j.reactfunctpolym.2003.08.003

Bohra, 1994, Adsorptive recovery of water soluble essential oil components, J. Chem. Technol. Biotechnol., 60, 97, 10.1002/jctb.280600115

C. Long, A.M. Li, G.D. Gao, Z.H. Fei, Q.X. Zhang, J.L. Chen, Chinese patent: CN 200410014428.8 (2005).

Li, 2002, Adsorption of phenolic compounds from aqueous solutions by a water-compatible hypercrosslinked polymeric adsorbent, Chemosphere, 47, 981, 10.1016/S0045-6535(01)00222-3

Hand, 1999, Adsorption equilibrium modeling of space station wastewaters, J. Environ. Eng., 125, 540, 10.1061/(ASCE)0733-9372(1999)125:6(540)

Saikia, 2008, Revisiting adsorption of biomolecules on polymeric resins, Colloid Surf. A, 315, 196, 10.1016/j.colsurfa.2007.07.026

Azanova, 1999, Sorption properties of macroporous and hypercrosslinked copolymers, React. Funct. Polym., 41, 163, 10.1016/S1381-5148(99)00029-2

Juang, 1999, Adsorption isotherms of phenols from water onto macroreticular resins, J. Hazard. Mater., 70, 171, 10.1016/S0304-3894(99)00152-1

Zhang, 2006, Adsorption of dyes and phenol from water on resin adsorbents: effect of adsorbate size and pore size distribution, J. Hazard. Mater. B, 137, 1115, 10.1016/j.jhazmat.2006.03.061

Sun, 2005, Adsorption of resorcinol and catechol from aqueous solution by aminated hypercrosslinked polymers, React. Funct. Polym., 64, 63, 10.1016/j.reactfunctpolym.2005.03.004

W.M. Zhang, Z.W. Xu, Q.J. Zhang, B.C. Pan, W. Du, Q.R. Zhang, Q.X. Zhang, J.L. Chen, Chinese patent: CN 1935776A (2007).

Q.X. Zhang, G. Luo, A.M. Li, L. Shao, Chinese patent: CN1400171 (2003).

J.L. Chen, R.X. Wei, Z.Q. Cheng, A.M. Li, H.L. Wang, B.H. Ye, Q.X. Zhang, Chinese patent: CN 1375463 (2002).

Q.X. Zhang, B.C. Pan, K. Zheng, W.M. Zhang, B. Liu, F.Q. Liu, J.L. Chen, Chinese patent: CN 1680195 (2005).

Fontanals, 2005, Evaluation of a new hypercrosslinked polymer as a sorbent for solid-phase extraction of polar compounds, J. Chromatogr. A, 1075, 51, 10.1016/j.chroma.2005.04.010

Pan, 2002, Adsorption of aromatic acids on an aminated hypercrosslinked macroporous polymer, React. Funct. Polym., 53, 63, 10.1016/S1381-5148(02)00123-2

Streat, 1997, Physical and adsorptive properties of Hypersol–Macronet™ polymers, React. Funct. Polym., 35, 99, 10.1016/S1381-5148(97)00049-7

Xu, 2003, Applications of porous resin sorbents in industrial wastewater treatment and resource recovery, Crit. Rev. Environ. Sci. Technol., 33, 363, 10.1080/10643380390249512

Pan, 2008, Effective removal of aromatic sulfonates from wastewater by a recyclable polymer: 2-naphathalene sulfonate as a representative pollutant, Environ. Sci. Technol., 42, 7411, 10.1021/es801370n

Davankov, 1974, Macronet isoporous gels through crosslinking of dissolved polystyrene, J. Polym. Sci.: Symposium, 47, 95, 10.1002/polc.5070470113

A.M. Li, W.B. Yang, G.H. Meng, L.C. Yang, J. Fan, Z.L. Zhu, J.J. Ge, X. Zhang, J.N. Wang, Q.X. Zhang, Chinese patent: CN1837078 (2006).

Maity, 1991, Adsorptive separations based on the differences in solute-sorbent hydrogen-bonding strengths, Ind. Eng. Chem. Res., 30, 2456, 10.1021/ie00059a015

J.P. Jiang, Y.R. Zhou, C.L. Yang, Chinese patent: CN 1673107A (2005).

Heitzsch, 1994, Removal of ethoxylated aliphatic amines from zinc containing effluents by adsorption on macroporous resins, Chem. Eng. Technol., 17, 30, 10.1002/ceat.270170105

A.M. Li, J. Fan, W.B. Yang, J.G. Cai, X. Zhang, J.Y. Zhou, Q.X. Zhang, C. Long, F.Q. Liu, Q.X. Zhang, Chinese patent: CN1858007A (2006).

Kyriakopoulos, 2007, Morphology of polymeric resins in adsorption of organic pesticides, Fresen. Environ. Bull., 16, 731

Streat, 1998, Removal of pesticides from water using hypercrosslinked polymer phases. Part 2. Sorption studies, Trans. Inst. Chem. Eng., B76, 127

Jafvert, 1990, Distribution of hydrophobic ionogenic organic compounds between octanol and water: organic acids, Environ. Sci. Technol., 4, 1795, 10.1021/es00082a002

Stapleton, 1994, Sorption of pentachlorphenol to HDTMA-clay as a function of ionic-strength and pH, Environ. Sci. Technol., 28, 2330, 10.1021/es00062a017

Chang, 2008, Adsorptive removal of the pesticide methomyl using hypercrosslinked polymers, J. Hazard. Mater., 155, 295, 10.1016/j.jhazmat.2007.11.057

Yu, 2001, Adsorption of water-soluble dye onto functionalized resin, J. Colloid Interface Sci., 242, 288, 10.1006/jcis.2001.7780

Wang, 2005, The study of adsorption of phenol and aniline on aminated-macroporous hypercrosslinked resins, Acta Polym. Sin., 3, 339

A.M. Li, J.G. Cai, H.Y. Zhang, J.J. Ge, Z.B. Li, C. Long, F.Q. Liu, Q.X. Zhang, Chinese patent: CN 1712365A (2005).

J.L. Chen, B.C. Pan, Y. Xiong, A.M. Li, C. Long, Y.Z. Han, Y. Sun, Q.X. Zhang, Chinese patent: CN1384069 (2002).

Y.S. Lee, S.J. Ryoo, US patent: US6369169 (2002).

Masque, 1999, Influence of chemical modification of polymeric resin on retention of polar compounds in solid-phase extraction, Chromotographia, 50, 21, 10.1007/BF02493612

Zhu, 2000, Bile salt anion sorption by polymeric resins: comparison of a functionalized polyacrylamide resin with cholestyramine, J. Colloid Interface Sci., 232, 282, 10.1006/jcis.2000.7157

Memon, 2007, The efficacy of nitrosonaphthol functionalized XAD-16 resin for the preconcentration/sorption of Ni(II) and Cu(II) ions, Talanta, 72, 1738, 10.1016/j.talanta.2006.12.017

Dutta, 2007, Synthesis, characterization, and application of a new chelating resin functionalized with dithiooxamide, J. Appl. Polym. Sci., 103, 2281, 10.1002/app.25436

Kaur, 2005, Functionalization of XAD-4 resin for the separation of lanthanides using chelation ion exchange liquid chromatography, React. Funct. Polym., 65, 277, 10.1016/j.reactfunctpolym.2005.06.010

Dogutan, 2003, Preconcentration of manganese(II) from natural and sea water on a palmitoyl quinolin-8-ol functionalized XAD copolymer resin and spectrophotometric determination with the formaldoxime reagent, Anal. Chim. Acta, 485, 205, 10.1016/S0003-2670(03)00408-2

Mondal, 2003, Determination of mercury species with a resin functionalized with a 1,2-bis(o-aminophenylthio)ethane moiety, Anal. Chim. Acta, 477, 73, 10.1016/S0003-2670(02)01372-7

Bernard, 2008, Synthesis and characterization of a polystyrenic resin functionalized by catechol: application to retention of metal ions, React. Funct. Polym., 68, 1362, 10.1016/j.reactfunctpolym.2008.06.014

Mondal, 2002, Synthesis and characterization of a new resin functionalized with 2-naphthol-3,6-disulfonic acid and its application for the speciation of chromium in natural water, Talanta, 56, 145, 10.1016/S0039-9140(01)00558-6

Lee, 2001, A chelating resin containing 1-(2-thiazolylazo)-2-naphthol as the functional group; synthesis and sorption behavior for trace metal ions, Microchem. J., 70, 195, 10.1016/S0026-265X(01)00132-1

Rivas, 2001, Sorption properties of poly(styrene-co-divinylbenzene) amine functionalized weak resin, J. Appl. Polym. Sci., 80, 2123, 10.1002/app.1313

Dogutan, 2000, The use of palmitoyl hydroxyquinoline-functionalized Amberlite XAD-2 copolymer resin for the preconcentration and speciation analysis of gallium(III), Sep. Sci. Technol., 35, 2083, 10.1081/SS-100102090

Dev, 1999, Sorption behaviour of lanthanum(III), neodymium(III), terbium(III), thorium(IV) and uranium(VI) on Amberlite XAD-4 resin functionalized with bicine ligands, Talanta, 48, 579, 10.1016/S0039-9140(98)00274-4

Q.X. Zhang, A.M. Li, F.Q. Liu, Z.H. Fei, B.C. Pan, C. Long, J.L. Chen, Chinese patent: ZL 01 1 34143.2 (2004).

J.L. Chen, B.C. Pan, Y. Xiong, A.M. Li, C. Long, Y.Z. Han, Y. Sun, Q.X. Zhang, Chinese patent: ZL 01 1 13797.5 (2004).

Q.X. Zhang, C. Long, Z.Y. Xu, Y.Z. Han, A.M. Li, J.L. Chen, Chinese patent: ZL ZL01108020.5 (2001).

Denizli, 2004, Methacryloylamidoglutamic acid incorporated porous poly(methyl methacrylate) beads for heavy-metal removal, Ind. Eng. Chem. Res., 43, 6095, 10.1021/ie030204z

Leinonen, 2000, Ion-exchange of nickel by iminodiacetic acid chelating resin Chelex 100, React. Funct. Polym., 43, 1, 10.1016/S1381-5148(98)00082-0

Nastasovic, 2004, Metal sorption on macroporous poly(GMA-co-EGDMA) modified with ethylene diamine, React. Funct. Polym., 58, 139, 10.1016/j.reactfunctpolym.2003.11.015

Atia, 2008, Removal of some hazardous heavy metals from aqueous solution using magnetic chelating resin with iminodiacetate functionality, Sep. Purif. Technol., 61, 348, 10.1016/j.seppur.2007.11.008

W.A. Burke, US patent: US 5525315 (1996).

H.P. Schneider, U. Wallbaum, US patent: US 4895905 (1990).

Saygi, 2008, Chromium speciation by solid phase extraction on Dowex M 4195 chelating resin and determination by atomic absorption spectrometry, J. Hazard. Mater., 153, 1009, 10.1016/j.jhazmat.2007.09.051

Hosseini, 2006, Synthesis and application of a new chelating resin functionalized with 2,3-dihydroxy benzoic acid for Fe(III) determination in water samples by flame atomic absorption spectrometry, React. Funct. Polym., 66, 1539, 10.1016/j.reactfunctpolym.2006.05.003

Chen, 2008, Recovery of Cu(II) and Cd(II) by a chelating resin containing aspartate groups, J. Hazard. Mater., 152, 986, 10.1016/j.jhazmat.2007.07.074

Alberti, 2007, A chelating resin as a probe for the copper(II) distribution in grape wines, React. Funct. Polym., 67, 1083, 10.1016/j.reactfunctpolym.2007.07.001

Meesri, 2007, Extraction and preconcentration of toxic metal ions from aqueous solution using benzothiazole-based chelating resins, Microchem. J., 87, 47, 10.1016/j.microc.2007.05.006

Chen, 2007, Removal of heavy metal ions by a chelating resin containing glycine as chelating groups, Sep. Purif. Technol., 54, 396, 10.1016/j.seppur.2006.10.020

Pramanik, 2007, A new chelating resin containing azophenolcarboxylate functionality: synthesis, characterization and application to chromium speciation in wastewater, Anal. Chim. Acta, 584, 469, 10.1016/j.aca.2006.11.041

Bosch, 2003, Cadmium cuts two ways: the heavy metal mutates DNA, and then prevents cells from repairing the damage, Science, 1

Singh, 2008, Genotoxic effects of arsenic: prevention by functional food-jaggery, Cancer Lett., 268, 325, 10.1016/j.canlet.2008.04.011

Pan, 2007, Selective heavy metals removal from waters by amorphous zirconium phosphate: behavior and mechanism, Water Res., 41, 3103, 10.1016/j.watres.2007.03.004

Jia, 2008, Adsorption of Pb2+, Zn2+, and Cd2+ from waters by amorphous titanium phosphate, J. Colloid Interface Sci., 318, 160, 10.1016/j.jcis.2007.10.043

Cumbal, 2005, Arsenic removal using polymer-supported hydrated iron(III) oxide nanoparticles: role of Donnan membrane effect, Environ. Sci. Technol., 39, 6508, 10.1021/es050175e

Pan, 2007, Highly effective removal of heavy metals by polymer-based zirconium phosphate: a case study of lead ion, J. Colloid Interface Sci., 310, 99, 10.1016/j.jcis.2007.01.064

Blaney, 2007, Hybrid anion exchanger for trace phosphate removal from water and wastewater, Water Res., 41, 1603, 10.1016/j.watres.2007.01.008

Zhang, 2008, Preparation of polymer-supported hydrated ferric oxide based on Donnan membrane effect and its application for arsenic removal, Sci. China Ser. B, 51, 379, 10.1007/s11426-007-0117-6

Sylvester, 2007, A hybrid sorbent utilizing nanoparticles of hydrous iron oxide for arsenic removal from drinking water, Environ. Eng. Sci., 24, 104, 10.1089/ees.2007.24.104

Manju, 2002, An investigation into the sorption of heavy metals from wastewaters by polyacrylamide-grafted iron(III) oxide, J. Hazard. Mater., B91, 221, 10.1016/S0304-3894(01)00392-2

DeMarco, 2003, Arsenic removal using a polymeric/inorganic hybrid sorbent, Water Res., 37, 164, 10.1016/S0043-1354(02)00238-5

Moller, 2008, Effect of silica and pH on arsenic uptake by resin/iron oxide hybrid media, Water Res., 42, 1760, 10.1016/j.watres.2007.10.044

Katsoyiannis, 2002, Removal of arsenic from contaminated water sources by sorption onto iron-oxide-coated polymeric materials, Water Res., 36, 5141, 10.1016/S0043-1354(02)00236-1

J.E. Etzel, J. Kurek, US patent: US 5591346 (1997).

Vatutsina, 2007, A new hybrid (polymer/inorganic) fibrous sorbent for arsenic removal from drinking water, React. Funct. Polym., 67, 184, 10.1016/j.reactfunctpolym.2006.10.009

Zhang, 2008, Selective sorption of lead, cadmium and zinc ions by a polymeric cation exchanger containing nano-Zr(HPO3S)2, Environ. Sci. Technol., 42, 4140, 10.1021/es800354b

B.C. Pan, B.J. Pan, W.M. Zhang, Q.J. Zhang, Q.R. Zhang, P.J. Jiang, Q.X. Zhang, Chinese patent: CN 200710191355.3 (2007).

B.C. Pan, Q. Su, W.M. Zhang, Q.X. Zhang, H.Q. Ren, Q.R. Zhang, B.J. Pan, Chinese patent: CN 101224408A (2008).

Jang, 2004

Pierce, 1982, Adsorption of As(III) and As(V) on amorphous iron hydroxide, Water Res., 6, 1247, 10.1016/0043-1354(82)90143-9

Dzombak, 1990

A.K. Sengupta, L.H. Cumbal, US patent: US 7291578 (2005).

B.C. Pan, X.Q. Chen, W.M. Zhang, B.J. Pan, W. Shen, Q.J. Zhang, W. Du, Q.X. Zhang, J.L. Chen, Chinese patent: CN 200510095177.5 (2007).