Thio-analogues of 2-(1H-Heteroarylidene)-1H-indene-1,3(2H)-diones, synthesis and formation of metal complexes
Tóm tắt
2-(1H-Heteroarylidene)-1H-indene-1,3(2H)-diones were converted into anils and dianils and then into monothio- and dithio-derivatives by treatment with hydrogen sulphide. The 2-pyridinyl monothioderivate was converted into S-alkyl ethers. In contrast with the dione1 the thio-derivatives readily formed isolable complexes with transition metals. Spectroscopic and magnetic data are reported.
Tài liệu tham khảo
Buggle K.,O'Sullivan D.,Ryan N. D., Chem. and Ind.1974, 164.
Buggle K.,Nangle M., Chem. and Ind.1976, 111.
Buggle K.,Power J., J. Chem. Soc. Perkin I1980, 1070.
Eibner A., Lobering M., Chem. Ber.39, 2450 (1906).
Eibner A., Lange O., Ann. Chem.315, 347 (1901).
Batterham T. J., in: N.M.R. Spectra of Simple Heterocycles (Taylor E. C.,Weissberger A., eds.), pp. 47–50. Wiley. 1973.
Dou H. J. M., Hassanaly P., Kister J. Metzger J., Phosphorus and Sulphur3, 355 (1977).
Freimanis Ya. F., Popelis Yu. Yu., Shrets A. E., Bleidelis Ya. Ya., Kemme A. A., Zhur. Obshehei. Khim.43, 1388 (1973).
Mondelli R., Merlini L., Tetrahedron22, 3253 (1966).
Kuhn R., Bahr F., Ann. Chem.516, 155 (1935).
Manly D., Richardson A., Stock A. M., Tilford C., Amstutz E., J. Org. Chem.32, 373 (1958).
Lombardino J. G., J. Org. Chem.32, 1988 (1967).
Kacens J.,Neilands O.,Linabergs J., Latv. PSR. Zinat. Akad. Vestis Kyim. Ser.1972, 576.
Amiel J.,Ploquin J.,Sparfel L.,Le Baut G.,Floch R., Bull. Soc. Chim. Fr.1974, 2154.
Friedmanis J., Laurinovics E., Otkrytiya izobret., prom. obratzky, tovarnyl znaki53 (43) 63 (1976); C. A.87, 23054.
Cook J., Martin D., J. Inorg. Nucl. Chem.26, 572 (1964).
Apsit A., Dorfmann K., Oshkaya V., Zhur. Neorg. Khim.19, 182 (1974).
Akbar Ali M., Livingstone S. E., Coord. Chem. Reviews13, 133 (1974).
Adams D. M., Metal Ligand and Related Vibrations, pp. 269 and 316. London: Edward Arnold. 1967.
Maki A., McGarvey B., J. Chem. Phys.29, 31 35 (1958).