Low-temperature synthesis of high-performance nano-MoS2-based catalyst via non-thermal plasma for higher alcohol synthesis from syngas

Ao, 2018, Active centers of catalysts for higher alcohol synthesis from syngas: a review, ACS Catal., 8, 7025, 10.1021/acscatal.8b01391 Xiong, 2015, Shaped carbons as supports for the catalytic conversion of syngas to clean fuels, ACS Catal., 5, 2640, 10.1021/acscatal.5b00090 Spivey, 2007, Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas, Chem. Soc. Rev., 36, 1514, 10.1039/b414039g Fang, 2009, A short review of heterogeneous catalytic process for mixed alcohols synthesis via syngas, Catal. Today, 147, 133, 10.1016/j.cattod.2009.01.038 Anton, 2016, The effect of sodium on the structure–activity relationships of cobalt-modified Cu/ZnO/Al2O3 catalysts applied in the hydrogenation of carbon monoxide to higher alcohols, J. Catal., 335, 175, 10.1016/j.jcat.2015.12.016 Liakakou, 2017, On the Mn promoted synthesis of higher alcohols over Cu derived ternary catalysts, Catal. Sci. Technol., 7, 988, 10.1039/C7CY00018A Guo, 2018, Mixed oxides confined and tailored cobalt nanocatalyst for direct ethanol synthesis from syngas: a catalyst designing by using perovskite-type oxide as the precursor, Ind. Eng. Chem. Res., 57, 2404, 10.1021/acs.iecr.7b04336 Sun, 2018, Synergetic catalysis of bimetallic copper–cobalt nanosheets for direct synthesis of ethanol and higher alcohols from syngas, Catal. Sci. Technol., 8, 3936, 10.1039/C8CY01074A Gao, 2015, Core–shell Cu@(CuCo-alloy)/Al2O3 catalysts for the synthesis of higher alcohols from syngas, Green Chem., 17, 1525, 10.1039/C4GC01633E Prieto, 2014, Design and synthesis of copper–cobalt catalysts for the selective conversion of synthesis gas to ethanol and higher alcohols, Angew. Chem. Int. Ed., 53, 6397, 10.1002/anie.201402680 Zhao, 2018, Preparation, structural characteristics, and catalytic performance of Cu–Co alloy supported on Mn–Al oxide for higher alcohol synthesis via syngas, Ind. Eng. Chem. Res., 57, 14957, 10.1021/acs.iecr.8b03304 Yang, 2016, Intrinsic selectivity and structure sensitivity of rhodium catalysts for C2+ oxygenate production, J. Am. Chem. Soc., 138, 3705, 10.1021/jacs.5b12087 Chen, 2016, Highly efficient β-SiC-supported 0.5% Rh-based catalyst for CO hydrogenation to C2 oxygenates, Catal. Commun., 85, 44, 10.1016/j.catcom.2016.07.016 Zhang, 2018, Synthesis of higher alcohols by CO hydrogenation on a K-promoted Ni–Mo catalyst derived from Ni–Mo phyllosilicate, Catal. Sci. Technol., 8, 4219, 10.1039/C8CY01095A Morrill, 2013, Origins of unusual alcohol selectivities over mixed MgAl oxide-supported K/MoS2 catalysts for higher alcohol synthesis from syngas, ACS Catal., 3, 1665, 10.1021/cs400147d Luan, 2018, Tungsten-doped molybdenum sulfide with dominant double-layer structure on mixed MgAl oxide for higher alcohol synthesis in CO hydrogenation, Ind. Eng. Chem. Res., 57, 10170, 10.1021/acs.iecr.8b01378 Dorokhov, 2016, Experimental and computational study of syngas and ethanol conversion mechanisms over K-modified transition metal sulfide catalysts, J. Catal., 344, 841, 10.1016/j.jcat.2016.08.005 Yong, 2017, Tuning the metal–support interaction in supported K-promoted NiMo catalysts for enhanced selectivity and productivity towards higher alcohols in CO hydrogenation, Catal. Sci. Technol., 7, 4206, 10.1039/C7CY01295K Claure, 2015, Tuning of higher alcohol selectivity and productivity in CO hydrogenation reactions over K/MoS2 domains supported on mesoporous activated carbon and mixed MgAl oxide, J. Catal., 324, 88, 10.1016/j.jcat.2015.01.015 Wang, 2016, Remarkable enhancement of the catalytic performance of molybdenum sulfide catalysts via an in situ decomposition method for higher alcohol synthesis from syngas, RSC Adv., 6, 112356, 10.1039/C6RA24406H H. Li, W. Zhang, Y. Wang, M. Shui, S. Sun, J. Bao, C. Gao, Nanosheet-structured K–Co–MoS2 catalyst for the higher alcohol synthesis from syngas: Synthesis and activation, J. Energy Chem. https://doi.org/10.1016/j.jechem.2018.03.019. Santos, 2013, Mechanistic insight into the synthesis of higher alcohols from syngas: the role of K promotion on MoS2 catalysts, ACS Catal., 3, 1634, 10.1021/cs4003518 Luk, 2018, Carbon nanofibres-supported KCoMo catalysts for syngas conversion into higher alcohols, Catal. Sci. Technol., 8, 187, 10.1039/C7CY01908D Okamoto, 2003, Preparation of Co–Mo/Al2O3 model sulfide catalysts for hydrodesulfurization and their application to the study of the effects of catalyst preparation, J. Catal., 217, 12 Jalowiecki, 1990, Quantitative detection of reactive hydrogen on MoS2/γ-Al2O3 and on γ-Al2O3, J. Catal., 126, 101, 10.1016/0021-9517(90)90050-T Wang, 2018, Enhanced catalytic performance and promotional effect of molybdenum sulfide cluster-derived catalysts for higher alcohols synthesis from syngas, Catal. Today, 316, 177, 10.1016/j.cattod.2018.03.007 Wang, 2016, Porous MS2/MO2 (M= W, Mo) nanorods as efficient hydrogen evolution reaction catalysts, ACS Catal., 6, 6585, 10.1021/acscatal.6b01927 Ponec, 1992, Active centres for synthesis gas reactions, Catal. Today, 12, 227, 10.1016/0920-5861(92)85043-L Wang, 2018, Catalyst preparation with plasmas: how does it work?, ACS Catal., 8, 2093, 10.1021/acscatal.7b03723 Liu, 2002, Catalyst preparation using plasma technologies, Catal. Today, 72, 173, 10.1016/S0920-5861(01)00491-6 Hong, 2018, Plasma-assisted preparation of highly dispersed cobalt catalysts for enhanced Fischer-Tropsch synthesis performance, ACS Catal., 8, 6177, 10.1021/acscatal.8b00960 Wang, 2013, Preparation and characterization of a plasma treated NiMgSBA-15 catalyst for methane reforming with CO2 to produce syngas, Catal. Sci. Technol., 3, 2278, 10.1039/c3cy00299c Tan, 2018, Effective removal of the protective ligands from Au nanoclusters by ambient pressure nonthermal plasma treatment for CO oxidation, Chin. J. Catal., 39, 929, 10.1016/S1872-2067(18)63018-9 Ni, 2018, Microplasma-assisted electrochemical synthesis of Co3O4 nanoparticles in absolute ethanol for energy applications, Green Chem., 20, 2101, 10.1039/C8GC00200B Li, 2017, Selective hydrogenation of acetylene over Pd/Al2O3 catalysts: effect of non-thermal RF plasma preparation methodologies, Top. Catal., 60, 997, 10.1007/s11244-017-0765-5 Ananth, 2014, Synthesis of RuO2 nanomaterials under dielectric barrier discharge plasma at atmospheric pressure–influence of substrates on the morphology and application, Chem. Eng. J., 239, 290, 10.1016/j.cej.2013.11.036 Zhao, 2018, Bimetallic Ni–Co catalysts supported on Mn–Al oxide for selective catalytic CO hydrogenation to higher alcohols, Catal. Sci. Technol., 8, 2066, 10.1039/C7CY02555F Zhao, 2017, One-step synthesis of Cu–Co alloy/Mn2O3–Al2O3 composites and their application in higher alcohol synthesis from syngas, Int. J. Hydrogen Energy, 42, 17414, 10.1016/j.ijhydene.2017.03.143 Han, 2016, Synthesis of higher alcohols over highly dispersed Cu–Fe based catalysts derived from layered double hydroxides, J. Colloid Interface Sci., 470, 162, 10.1016/j.jcis.2015.09.062 Zhao, 2018, A novel catalyst for higher alcohol synthesis from syngas: Co–Zn supported on Mn–Al oxide, Fuel Process. Technol., 177, 16, 10.1016/j.fuproc.2018.04.006 Zhao, 2014, Synthesis of highly dispersed metal sulfide catalysts via low temperature sulfidation in dielectric barrier discharge plasma, Green Chem., 16, 2619, 10.1039/C3GC42313A Liu, 2006, Plasma application for more environmentally friendly catalyst preparation, Pure Appl. Chem., 78, 1227, 10.1351/pac200678061227 Zou, 2006, Control of the metal−support interface of NiO-loaded photocatalysts via cold plasma treatment, Langmuir, 22, 2334, 10.1021/la052135u Cheng, 2008, Plasma decomposition and reduction in supported metal catalyst preparation, Catal. Surv. Asia, 12, 145, 10.1007/s10563-008-9046-4 Dai, 2015, Facile synthesis of in–situ nitrogenated graphene decorated by few–layer MoS2 for hydrogen evolution reaction, Electrochim. Acta, 171, 72, 10.1016/j.electacta.2015.05.017 Yang, 1996, Powder X-ray diffraction of turbostratically stacked layer systems, J. Mater. Res., 11, 1733, 10.1557/JMR.1996.0217 Liang, 1986, Structure of poorly crystalline MoS2–a modeling study, J. Non-Cryst. Solids, 79, 251, 10.1016/0022-3093(86)90226-7 Lacroix, 1999, Hydrogen activation on alumina supported MoS2 based catalysts: role of the promoter, J. Catal., 185, 219, 10.1006/jcat.1999.2505 Larrubia Vargas, 2007, An IR study of methanol steam reforming over ex-hydrotalcite Cu–Zn–Al catalysts, J. Mol. Catal. A, 266, 188, 10.1016/j.molcata.2006.08.085 Zou, 2009, The effect of dopant Cu, Fe, Ni or La on the structures and properties of mesoporous Co-Ce-O compound catalysts, J. Alloys Comp., 470, 96, 10.1016/j.jallcom.2008.03.049 Yang, 2010, Characterization of fused Fe–Cu based catalyst for higher alcohols synthesis and DRIFTS investigation of TPSR, Fuel Process. Technol., 91, 1168, 10.1016/j.fuproc.2010.03.032 Surisetty, 2009, Synthesis of higher alcohols from syngas over alkali promoted MoS2 catalysts supported on multi-walled carbon nanotubes, Appl. Catal. A, 365, 243, 10.1016/j.apcata.2009.06.017 Woo, 1991, Mixed alcohol synthesis from carbon monoxide and dihydrogen over potassium-promoted molybdenum carbide catalysts, Appl. Catal., 75, 267, 10.1016/S0166-9834(00)83136-X Wanger, 1979 Fridman, 2008 Karamé, 2012 Toyoda, 2013, Mixed alcohol synthesis over sulfided molybdenum-based catalysts, Energy Fuel, 27, 3769, 10.1021/ef400262a Surisetty, 2012, Comparative study of higher alcohols synthesis over alumina and activated carbon-supported alkali-modified MoS2 catalysts promoted with group VIII metals, Fuel, 96, 77, 10.1016/j.fuel.2011.12.054 Park, 1997, Kinetic analysis of mixed alcohol synthesis from syngas over K/MoS2 catalyst, Ind. Eng. Chem. Res., 36, 5246, 10.1021/ie9605701 Labruyère, 1997, High-pressure temperature-programmed reduction of sulfided catalysts, J. Catal., 167, 464, 10.1006/jcat.1997.1602 París, 2015, Higher alcohol synthesis over nickel-modified alkali-doped molybdenum sulfide catalysts prepared by conventional coprecipitation and coprecipitation in microemulsions, Catal. Today, 258, 294, 10.1016/j.cattod.2014.12.003 Qi, 2003, Nickel and manganese co-modified K/MoS2 catalyst: high performance for higher alcohols synthesis from CO hydrogenation, Catal. Commun., 4, 339, 10.1016/S1566-7367(03)00061-X Surisetty, 2012, Comparative study of higher alcohols synthesis over alumina and activated carbon-supported alkali-modified MoS2 catalysts promoted with group VIII metals, Fuel, 96, 77, 10.1016/j.fuel.2011.12.054 Li, 2004, Higher alcohol synthesis over a La promoted Ni/K2CO3/MoS2 catalyst, Catal. Commun., 5, 605, 10.1016/j.catcom.2004.07.011 Li, 2001, Effect of cobalt promoter on Co–Mo–K/C catalysts used for mixed alcohol synthesis, Appl. Catal. A, 220, 21, 10.1016/S0926-860X(01)00646-9