Biopolymer@Metal-Organic Framework Hybrid Materials: A Critical Survey

Zhou, 2012, Introduction to metal-organic frameworks, Chem Rev, 112, 673, 10.1021/cr300014x Matsuda, 2005, Highly controlled acetylene accommodation in a metal-organic microporous material, Nature, 436, 238, 10.1038/nature03852 Chae, 2004, A route to high surface area, porosity and inclusion of large molecules in crystals, Nature, 427, 523, 10.1038/nature02311 Farha, 2012, Metal-organic framework materials with ultrahigh surface areas: is the sky the limit?, J Am Chem Soc, 134, 15016, 10.1021/ja3055639 Van de Voorde, 2014, Adsorptive separation on metal-organic frameworks in the liquid phase, Chem Soc Rev, 43, 5766, 10.1039/C4CS00006D Li, 2016, One-step asymmetric growth of continuous metal-organic framework thin films on two-dimensional colloidal crystal arrays: a facile approach toward multifunctional superstructures, Cryst Growth Des, 16, 2700, 10.1021/acs.cgd.5b01817 Carné-Sánchez, 2014, Metal-organic frameworks: from molecules/metal ions to crystals to superstructures, Chem A Eur J, 20, 5192, 10.1002/chem.201304529 Deng, 2010, Multiple functional groups of varying ratios in metal-organic frameworks, Science, 327, 846, 10.1126/science.1181761 Butova, 2016, Metal-organic frameworks: structure, properties, methods of synthesis and characterization, Russ Chem Rev, 85, 280, 10.1070/RCR4554 Nenoff, 2015, Hydrogen purification: MOF membranes put to the test, Nat Chem, 7, 377, 10.1038/nchem.2218 Zhang, 2014, Rational design of metal-organic frameworks with anticipated porosities and functionalities, CrystEngComm, 16, 4069, 10.1039/C4CE00321G Sun, 2015, Recent progress in the synthesis of metal–organic frameworks, Sci Technol Adv Mater, 16, 10.1088/1468-6996/16/5/054202 Wang, 2009, Postsynthetic modification of metal-organic frameworks, Chem Soc Rev, 38, 1315, 10.1039/b802258p Deria, 2014, Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement, Chem Soc Rev, 43, 5896, 10.1039/C4CS00067F McGuire, 2015, The surface chemistry of metal-organic frameworks, Chem Commun, 51, 5199, 10.1039/C4CC04458D Han, 2014, Substitution reactions in metal-organic frameworks and metal-organic polyhedra, Chem Soc Rev, 43, 5952, 10.1039/C4CS00033A Hu, 2016, Void engineering in metal-organic frameworks via synergistic etching and surface functionalization, Adv Funct Mater, 26, 5827, 10.1002/adfm.201601193 Evans, 2014, Post-synthetic metalation of metal-organic frameworks, Chem Soc Rev, 43, 5933, 10.1039/C4CS00076E Wang, 2016, Crystalline central-metal transformation in metal-organic frameworks, Coord Chem Rev, 307, 130, 10.1016/j.ccr.2015.05.009 Thirion, 2016, Synthesis and easy functionalization of highly porous networks through exchangeable fluorines for target specific applications, Chem Mater, 28, 5592, 10.1021/acs.chemmater.6b02152 Barea, 2014, Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours, Chem Soc Rev, 43, 5419, 10.1039/C3CS60475F Furukawa, 2013, The chemistry and applications of metal-organic frameworks, Science, 341, 10.1126/science.1230444 Ricco, 2016, Emerging applications of metal–organic frameworks, CrystEngComm, 18, 6532, 10.1039/C6CE01030J Qiu, 2014, Metal-organic framework membranes: from synthesis to separation application, Chem Soc Rev, 43, 6116, 10.1039/C4CS00159A Chen, 2016, The road to MOF-related functional materials and beyond: desire, design, decoration, and development, Chem Rec, 16, 1456, 10.1002/tcr.201500304 Bag, 2016, Outstanding drug loading capacity by water stable microporous MOF: a potential drug carrier, Chem Commun, 52, 3669, 10.1039/C5CC09925K Sun, 2013, Metal-organic frameworks as potential drug delivery systems, Exp Opin Drug Deliv, 10, 89, 10.1517/17425247.2013.741583 Cai, 2015, Metal-organic framework-based nanomedicine platforms for drug delivery and molecular imaging, Small, 11, 4806, 10.1002/smll.201500802 Liu, 2014, Applications of metal-organic frameworks in heterogeneous supramolecular catalysis, Chem Soc Rev, 43, 6011, 10.1039/C4CS00094C Dhakshinamoorthy, 2014, Metal-organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles, Chem Soc Rev, 43, 5750, 10.1039/C3CS60442J Zhang, 2014, Metal-organic frameworks for artificial photosynthesis and photocatalysis, Chem Soc Rev, 43, 5982, 10.1039/C4CS00103F Meyer, 2015, Metal organic frameworks for photo-catalytic water splitting, Energy Environ Sci, 8, 1923, 10.1039/C5EE00161G Dhakshinamoorthy, 2016, Metal–organic framework (MOF) compounds: photocatalysts for redox reactions and solar fuel production, Angew Chem Int Ed, 55, 5414, 10.1002/anie.201505581 Zeng, 2016, Metal-organic frameworks: versatile materials for heterogeneous photocatalysis, ACS Catal, 6, 7935, 10.1021/acscatal.6b02228 Canivet, 2014, Water adsorption in MOFs: fundamentals and applications, Chem Soc Rev, 43, 5594, 10.1039/C4CS00078A Van de Voorde, 2014, Adsorptive separation on metal–organic frameworks in the liquid phase, Chem Soc Rev, 43, 5766, 10.1039/C4CS00006D Schoedel, 2016, The role of metal–organic frameworks in a carbon-neutral energy cycle, Nat Energy, 1, 16034, 10.1038/nenergy.2016.34 Ahmed, 2017, Applications of metal-organic frameworks in adsorption/separation processes via hydrogen bonding interactions, Chem Eng J, 30, 197, 10.1016/j.cej.2016.10.115 Vellingiri, 2016, Coordination polymers: challenges and future scenarios for capture and degradation of volatile organic compounds, Nano Res, 9, 3181, 10.1007/s12274-016-1230-7 Hu, 2014, Luminescent metal–organic frameworks for chemical sensing and explosive detection, Chem Soc Rev, 43, 5815, 10.1039/C4CS00010B Kreno, 2011, Metal–organic framework materials as chemical sensors, Chem Rev, 112, 1105, 10.1021/cr200324t Zhao, 2016, Sensing-functional luminescent metal-organic frameworks, CrystEngComm, 18, 3746, 10.1039/C6CE00545D Yi, 2016, Chemical sensors based on metal-organic frameworks, ChemPlusChem., 81, 675, 10.1002/cplu.201600137 Stavila, 2014, MOF-based electronic and opto-electronic devices, Chem Soc Rev, 43, 5994, 10.1039/C4CS00096J Dalstein, 2016, Nanoimprinted, submicrometric, MOF-based 2D photonic structures: toward easy selective vapors sensing by a smartphone camera, Adv Funct Mater, 26, 81, 10.1002/adfm.201503016 Ramaswamy, 2014, MOFs as proton conductors–challenges and opportunities, Chem Soc Rev, 43, 5913, 10.1039/C4CS00093E Zhao, 2016, Metal organic frameworks for energy storage and conversion, Energy Storage Mater, 2, 35, 10.1016/j.ensm.2015.11.005 Wang, 2016, Metal–organic frameworks for energy storage: batteries and supercapacitors, Coord Chem Rev, 307, 361, 10.1016/j.ccr.2015.09.002 Lin, 2016, Preface for the forum on metal-organic frameworks for energy applications, Inorg Chem, 55, 7189, 10.1021/acs.inorgchem.6b01680 Xia, 2015, Metal-organic frameworks and their derived nanostructures for electrochemical energy storage and conversion, Energy Environ Sci, 8, 1837, 10.1039/C5EE00762C Li, 2016, Porous metal-organic frameworks: promising materials for methane storage, Chem, 1, 557, 10.1016/j.chempr.2016.09.009 Broom, 2016, Outlook and challenges for hydrogen storage in nanoporous materials, Appl Phys A, 122, 151, 10.1007/s00339-016-9651-4 Furukawa, 2014, Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale, Chem Soc Rev, 43, 5700, 10.1039/C4CS00106K Chen, 2016, Shaping of metal-organic frameworks: from fluid to shaped bodies and robust foams, J Am Chem Soc, 138, 10810, 10.1021/jacs.6b06959 Akhtar, 2014, Structuring adsorbents and catalysts by processing of porous powders, J Eur Ceram Soc, 34, 1643, 10.1016/j.jeurceramsoc.2014.01.008 Ren, 2015, Review on processing of metal–organic framework (MOF) materials towards system integration for hydrogen storage, Int J Energy Res, 39, 607, 10.1002/er.3255 Reinsch, 2016, “Green” synthesis of metal-organic frameworks, Eur J Inorg Chem, 2016, 4290, 10.1002/ejic.201600286 Imaz, 2011, Metal-biomolecule frameworks (MBioFs), Chem Commun, 47, 7287, 10.1039/c1cc11202c Aceituno Melgar, 2015, Zeolitic imidazolate framework membranes for gas separation: a review of synthesis methods and gas separation performance, J Ind Eng Chem, 28, 1, 10.1016/j.jiec.2015.03.006 Seoane, 2016, Multi-scale crystal engineering of metal organic frameworks, Coord Chem Rev, 307, 147, 10.1016/j.ccr.2015.06.008 Gascon, 2012, Practical approach to zeolitic membranes and coatings: state of the art, opportunities, barriers, and future perspectives, Chem Mater, 24, 2829, 10.1021/cm301435j Forgan, 2011, Metal-organic frameworks: edible frameworks Giménez-Marqués, 2016, Nanostructured metal–organic frameworks and their bio-related applications, Coord Chem Rev, 307, 342, 10.1016/j.ccr.2015.08.008 Li, 2015, Metal-organic framework composites: from fundamentals to applications, Nanoscale, 7, 7482, 10.1039/C5NR00518C Falcaro, 2016, Application of metal and metal oxide nanoparticles@MOFs, Coord Chem Rev, 307, 237, 10.1016/j.ccr.2015.08.002 Aguilera-Sigalat, 2016, Synthesis and applications of metal-organic framework–quantum dot (QD@MOF) composites, Coord Chem Rev, 307, 267, 10.1016/j.ccr.2015.08.004 Ahmed, 2014, Composites of metal–organic frameworks: preparation and application in adsorption, Mater Today, 17, 136, 10.1016/j.mattod.2014.03.002 Zhu, 2014, Metal-organic framework composites, Chem Soc Rev, 43, 5468, 10.1039/C3CS60472A Zacher, 2009, Thin films of metal-organic frameworks, Chem Soc Rev, 38, 1418, 10.1039/b805038b Liang, 2015, Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules, Nat Commun, 6, 7240, 10.1038/ncomms8240 Bradshaw, 2012, Metal-organic framework growth at functional interfaces: thin films and composites for diverse applications, Chem Soc Rev, 41, 2344, 10.1039/C1CS15276A Falcaro, 2014, MOF positioning technology and device fabrication, Chem Soc Rev, 43, 5513, 10.1039/C4CS00089G Ricco, 2016, Emerging applications of metal-organic frameworks, CrystEngComm, 18, 6532, 10.1039/C6CE01030J Allendorf, 2015, Crystal engineering, structure-function relationships, and the future of metal-organic frameworks, CrystEngComm, 17, 229, 10.1039/C4CE01693A Mounfield, 2016, Synergistic effect of mixed oxide on the adsorption of ammonia with metal-organic frameworks, Ind Eng Chem Res, 55, 6492, 10.1021/acs.iecr.6b01045 Hermes, 2007, Selective growth and MOCVD loading of small single crystals of MOF-5 at alumina and silica surfaces modified with organic self-assembled monolayers, Chem Mater, 19, 2168, 10.1021/cm062854+ Bétard, 2012, Metal-organic framework thin films: from fundamentals to applications, Chem Rev, 112, 1055, 10.1021/cr200167v Boury, 2017, Biopolymers for biomimetic processing of metal oxides, 135 Rai, 2015, Bioactivity of noble metal nanoparticles decorated with biopolymers and their application in drug delivery, Int J Pharm, 496, 159, 10.1016/j.ijpharm.2015.10.059 Zafar, 2016, Polysaccharide based bionanocomposites, properties and applications: a review, Int J Biol Macromol, 92, 1012, 10.1016/j.ijbiomac.2016.07.102 Meyer, 2015, Biodegradable polymer iron oxide nanocomposites: the future of biocompatible magnetism, Nanomedicine, 10, 3421, 10.2217/nnm.15.165 Echazu, 2016, Advances in collagen, chitosan and silica biomaterials for oral tissue regeneration: from basics to clinical trials, J Mater Chem B, 4, 6913, 10.1039/C6TB02108E Doonan, 2017, Metal-organic frameworks at the biointerface: synthetic strategies and applications, Acc Chem Res, 50, 1423, 10.1021/acs.accounts.7b00090 Rojas, 2017, Metal organic frameworks based on bioactive components, J Mater Chem B, 5, 2560, 10.1039/C6TB03217F Zhang, 2015, Biomimicry in metal–organic materials, Coord Chem Rev, 293–294, 327, 10.1016/j.ccr.2014.05.031 Qin, 2018, Stable metal–organic frameworks as a host platform for catalysis and biomimetics, Chem Commun, 54, 4231, 10.1039/C7CC09173G Kempahanumakkagari, 2018, Biomolecule-embedded metal-organic frameworks as an innovative sensing platform, Biotechnol Adv, 36, 467, 10.1016/j.biotechadv.2018.01.014 Majewski, 2017, Enzyme encapsulation in metal–organic frameworks for applications in catalysis, CrystEngComm, 19, 4082, 10.1039/C7CE00022G Friščić, 2014, Environmentally-friendly designs and syntheses of metal-organic frameworks (MOFs), 161 Zhang, 2015, Macrocycle-based metal-organic frameworks, Coord Chem Rev, 292, 74, 10.1016/j.ccr.2015.02.012 Liu, 2014, Extended metal-carbohydrate frameworks, Pure Appl Chem, 1323, 10.1515/pac-2014-0303 McGonigal, 2016, 388 Index. Cyclodextrins and Their Complexes. Wiley-VCH Verlag GmbH & Co. KGaA; 2006. p. 475-89. Menuel, 2007, Synthesis and inclusion ability of a bis-β-cyclodextrin pseudo-cryptand towards Busulfan anticancer agent, Tetrahedron, 63, 1706, 10.1016/j.tet.2006.10.070 Antoniuk, 2016, Cyclodextrin-mediated hierarchical self-assembly and its potential in drug delivery applications, J Pharm Sci, 105, 2570, 10.1016/j.xphs.2016.05.010 Ryzhakov, 2016, Self-assembly of cyclodextrins and their complexes in aqueous solutions, J Pharm Sci, 105, 2556, 10.1016/j.xphs.2016.01.019 Del Valle, 2004, Cyclodextrins and their uses: a review, Process Biochem, 39, 1033, 10.1016/S0032-9592(03)00258-9 Chen, 2014, Metal-organic frameworks: rise of the ligands, Chem Mater, 26, 4322, 10.1021/cm501657d Smaldone, 2010, Metal-organic frameworks from edible natural products, Angew Chem Int Ed, 49, 8630, 10.1002/anie.201002343 Zhou, 2012, β-Cyclodextrin inclusion complex: preparation, characterization, and its aspirin release in vitro, Front Mater Sci, 6, 259, 10.1007/s11706-012-0176-2 Forgan, 2012, Nanoporous carbohydrate metal-organic frameworks, J Am Chem Soc, 134, 406, 10.1021/ja208224f Michida, 2015, Crystal growth of cyclodextrin-based metal-organic framework with inclusion of ferulic acid, Cryst Res Technol, 50, 556, 10.1002/crat.201500053 Al-Ghamdi, 2016, Synthesis of nanoporous carbohydrate metal-organic framework and encapsulation of acetaldehyde, J Cryst Growth, 451, 72, 10.1016/j.jcrysgro.2016.07.004 Sha, 2016, Nontoxic and renewable metal-organic framework based on [small alpha]-cyclodextrin with efficient drug delivery, RSC Adv, 6, 82977, 10.1039/C6RA16549D Sumida, 2012, Carbon dioxide capture in metal-organic frameworks, Chem Rev, 112, 724, 10.1021/cr2003272 Liu, 2012, Recent advances in carbon dioxide capture with metal-organic frameworks, Greenh Gases Sci Technol, 2, 239, 10.1002/ghg.1296 Yan, 2016, Crystal growth of cyclodextrin-based metal-organic framework for carbon dioxide capture and separation, Proc Eng, 148, 30, 10.1016/j.proeng.2016.06.480 Gassensmith, 2011, Strong and reversible binding of carbon dioxide in a green metal-organic framework, J Am Chem Soc, 133, 15312, 10.1021/ja206525x Wu, 2013, Direct calorimetric measurement of enthalpy of adsorption of carbon dioxide on CD-MOF-2, a green metal-organic framework, J Am Chem Soc, 135, 6790, 10.1021/ja402315d Gassensmith, 2014, A metal-organic framework-based material for electrochemical sensing of carbon dioxide, J Am Chem Soc, 136, 8277, 10.1021/ja5006465 Norkus, 2009, Metal ion complexes with native cyclodextrins. an overview, J Incl Phenom Macrocycl Chem, 65, 237, 10.1007/s10847-009-9586-x Klüfers, 1994, Sixteenfold deprotonated γ-cyclodextrin tori as anions in a hexadecanuclear lead(II) alkoxide, Angew Chem Int Ed Engl, 33, 1863, 10.1002/anie.199418631 Wei, 2012, Pb(ii) metal-organic nanotubes based on cyclodextrins: biphasic synthesis, structures and properties, Chem Sci, 3, 2282, 10.1039/c2sc20187a Xin, 2016, Cyclodextrin-based metal-organic nanotube as fluorescent probe for selective turn-on detection of hydrogen sulfide in living cells based on H2S-involved coordination mechanism, Sci Rep, 6, 21951, 10.1038/srep21951 Han, 2013, A metal-organic framework stabilizes an occluded photocatalyst, Chem A Eur J, 19, 11194, 10.1002/chem.201302141 Wei, 2012, Nanoparticle core/shell architectures within MOF crystals synthesized by reaction diffusion, Angew Chem Int Ed, 51, 7435, 10.1002/anie.201202549 Han, 2015, Tunneling electrical connection to the interior of metal-organic frameworks, J Am Chem Soc, 137, 8169, 10.1021/jacs.5b03263 Ma, 2016, Sensitive insulin detection based on electrogenerated chemiluminescence resonance energy transfer between Ru(bpy)32+ and Au nanoparticle-doped β-cyclodextrin-Pb (II) metal-organic framework, ACS Appl Mater Interfaces, 8, 10121, 10.1021/acsami.5b11991 Anselmi, 2006, Analytical characterization of a ferulic acid/γ-cyclodextrin inclusion complex, J Pharm Biomed Anal, 40, 875, 10.1016/j.jpba.2005.08.019 Sha, 2015, Synthesis and structure of new carbohydrate metal–organic frameworks and inclusion complexes, J Mol Struct, 1101, 14, 10.1016/j.molstruc.2015.08.020 Bernini, 2014, Screening of bio-compatible metal-organic frameworks as potential drug carriers using Monte Carlo simulations, J Mater Chem B, 2, 766, 10.1039/C3TB21328E Gassensmith, 2012, Polyporous Metal-Coordination Frameworks, Org Lett, 14, 1460, 10.1021/ol300199a Lu, 2015, Study on a new cyclodextrin based metal–organic framework with chiral helices, Inorg Chem Commun, 61, 48, 10.1016/j.inoche.2015.08.015 Holcroft, 2015, Carbohydrate-mediated purification of petrochemicals, J Am Chem Soc, 137, 5706, 10.1021/ja511878b Hartlieb, 2016, CD-MOF: a versatile separation medium, J Am Chem Soc, 138, 2292, 10.1021/jacs.5b12860 Furukawa, 2012, Nano- and microsized cubic gel particles from cyclodextrin metal-organic frameworks, Angew Chem Int Ed, 51, 10566, 10.1002/anie.201204919 Li, 2016, Facile stabilization of cyclodextrin metal-organic frameworks under aqueous conditions via the incorporation of C60 in their matrices, Chem Commun, 52, 5973, 10.1039/C6CC01620K Xu, 2016, A first cyclodextrin-transition metal coordination polymer, Cryst Growth Des, 16, 5598, 10.1021/acs.cgd.6b01115 Sumida, 2017, Sol-gel processing of metal-organic frameworks, Chem Mater, 29, 2626, 10.1021/acs.chemmater.6b03934 Abbaspour, 2012, A cyclodextrin host-guest recognition approach to a label-free electrochemical DNA hybridization biosensor, Analyst, 137, 1860, 10.1039/c2an15683k Hernández-Jiménez, 2016, Voltammetric determination of metronidazole using a sensor based on electropolymerization of α-cyclodextrin over a carbon paste electrode, Electroanalysis, 28, 704, 10.1002/elan.201500452 Wang, 2014, Metal-organic frameworks and [small beta]-cyclodextrin-based composite electrode for simultaneous quantification of guanine and adenine in a lab-on-valve manifold, Analyst, 139, 6197, 10.1039/C4AN00901K Agostoni, 2015, A “green” strategy to construct non-covalent, stable and bioactive coatings on porous MOF nanoparticles, Sci Rep, 5, 7925, 10.1038/srep07925 Wang, 2015, A multifunctional metal-organic framework based tumor targeting drug delivery system for cancer therapy, Nanoscale, 7, 16061, 10.1039/C5NR04045K George, 2015, Cellulose nanocrystals: synthesis, functional properties, and applications, Nanotechnol Sci Appl, 8, 45, 10.2147/NSA.S64386 Kim, 2006, Discovery of cellulose as a smart material, Macromolecules, 39, 4202, 10.1021/ma060261e Perelshtein, 2009, CuO–cotton nanocomposite: formation, morphology, and antibacterial activity, Surf Coat Technol, 204, 54, 10.1016/j.surfcoat.2009.06.028 Mintova, 1996, Deposition of zeolite A on vegetal fibers, Zeolites, 16, 31, 10.1016/0144-2449(95)00078-X Huang, 2003, Nano-precision replication of natural cellulosic substances by metal oxides, J Am Chem Soc, 125, 11834, 10.1021/ja037419k Tian, 2016, Cellulose as a scaffold for self-assembly: from basic research to real applications, Langmuir, 32, 12269, 10.1021/acs.langmuir.6b02033 Foresti, 2017, Applications of bacterial cellulose as precursor of carbon and composites with metal oxide, metal sulfide and metal nanoparticles: a review of recent advances, Carbohydr Polym, 157, 447, 10.1016/j.carbpol.2016.09.008 Fujisawa, 2012, Superior reinforcement effect of TEMPO-oxidized cellulose nanofibrils in polystyrene matrix: optical, thermal, and mechanical studies, Biomacromolecules, 13, 2188, 10.1021/bm300609c Cherian, 2011, Cellulose nanocomposites with nanofibres isolated from pineapple leaf fibers for medical applications, Carbohydr Polym, 86, 1790, 10.1016/j.carbpol.2011.07.009 Serizawa, 2013, Hydrolytic activities of crystalline cellulose nanofibers, Biomacromolecules, 14, 613, 10.1021/bm4000822 Nagashima, 2014, Cellulose nanofiber paper as an ultra flexible nonvolatile memory, Sci Rep, 4, 5532, 10.1038/srep05532 Shopsowitz, 2014, Biopolymer templated glass with a twist: controlling the chirality, porosity, and photonic properties of silica with cellulose nanocrystals, Adv Funct Mater, 24, 327, 10.1002/adfm.201301737 Giese, 2014, Responsive mesoporous photonic cellulose films by supramolecular cotemplating, Angew Chem Int Ed, 53, 8880, 10.1002/anie.201402214 Kaushik, 2016, Review: nanocelluloses as versatile supports for metal nanoparticles and their applications in catalysis, Green Chem, 18, 622, 10.1039/C5GC02500A Yang, 2015, Supercapacitors cellulose nanocrystal aerogels as universal 3D lightweight substrates for supercapacitor materials (Adv. Mater. 40/2015), Adv Mater, 27, 6077-, 10.1002/adma.201570266 Avendano, 2016, Multiwalled carbon nanotube/cellulose composite: from aqueous dispersions to pickering emulsions, Langmuir, 32, 3907, 10.1021/acs.langmuir.6b00380 Hamedi, 2014, Highly conducting, strong nanocomposites based on nanocellulose-assisted aqueous dispersions of single-wall carbon nanotubes, ACS Nano, 8, 2467, 10.1021/nn4060368 Zhang, 2016, Challenges and recent advances in MOF-polymer composite membranes for gas separation, Inorg Chem Front, 3, 896, 10.1039/C6QI00042H Küsgens, 2009, Crystal growth of the metal—organic framework Cu3(BTC)2 on the SURFACE OF PULP FIBERS, Adv Eng Mater, 11, 93, 10.1002/adem.200800274 Abdelhameed, 2016, Cu-BTC@cotton composite: design and removal of ethion insecticide from water, RSC Adv, 6, 42324, 10.1039/C6RA04719J Bazer-Bachi, 2014, Towards industrial use of metal-organic framework: Impact of shaping on the MOF properties, Powder Technol, 255, 52, 10.1016/j.powtec.2013.09.013 Laredo, 2016, Comparison of the metal–organic framework MIL-101 (Cr) versus four commercial adsorbents for nitrogen compounds removal in diesel feedstocks, Fuel, 180, 284, 10.1016/j.fuel.2016.04.038 Zhu, 2016, Flexible and porous nanocellulose aerogels with high loadings of metal–organic-framework particles for separations applications, Adv Mater, 28, 7652, 10.1002/adma.201601351 Moon, 2011, Cellulose nanomaterials review: structure, properties and nanocomposites, Chem Soc Rev, 40, 3941, 10.1039/c0cs00108b Lewis, 2016, Hydrothermal gelation of aqueous cellulose nanocrystal suspensions, Biomacromolecules, 17, 2747, 10.1021/acs.biomac.6b00906 Yang, 2014, Chemically cross-linked cellulose nanocrystal aerogels with shape recovery and superabsorbent properties, Chem Mater, 26, 6016, 10.1021/cm502873c Yang, 2013, Injectable polysaccharide hydrogels reinforced with cellulose nanocrystals: morphology, rheology, degradation, and cytotoxicity, Biomacromolecules, 14, 4447, 10.1021/bm401364z Zacher, 2007, Deposition of microcrystalline [Cu3(btc)2] and [Zn2(bdc)2(dabco)] at alumina and silica surfaces modified with patterned self assembled organic monolayers: evidence of surface selective and oriented growth, J Mater Chem, 17, 2785, 10.1039/b703098c da Silva, 2012, In situ synthesis of a Cu-BTC metal–organic framework (MOF 199) onto cellulosic fibrous substrates: cotton, Cellulose, 19, 1771, 10.1007/s10570-012-9752-y Rodríguez, 2014, Antibacterial activity against Escherichia coli of Cu-BTC (MOF-199) metal-organic framework immobilized onto cellulosic fibers, J Appl Polym Sci, 131, n/a-n/a, 10.1002/app.40815 Lange, 2015, Functionalization of cotton fiber by partial etherification and self-assembly of polyoxometalate encapsulated in Cu3(BTC)2 metal-organic framework, ACS Appl Mater Interfaces, 7, 3974, 10.1021/am506510q Bunge, 2015, Modification of fibers with nanostructures using reactive dye chemistry, Ind Eng Chem Res, 54, 3821, 10.1021/acs.iecr.5b00089 Ozer, 2015, One-step growth of isoreticular luminescent metal-organic frameworks on cotton fibers, RSC Adv, 5, 15198, 10.1039/C4RA15161E Isogai, 2011, TEMPO-oxidized cellulose nanofibers, Nanoscale, 3, 71, 10.1039/C0NR00583E Fukuzumi, 2009, Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation, Biomacromolecules, 10, 162, 10.1021/bm801065u Matsumoto, 2016, Ultraselective gas separation by nanoporous metal−organic frameworks embedded in gas-barrier nanocellulose films, Adv Mater, 28, 1765, 10.1002/adma.201504784 Liang, 2016, Highly sensitive analysis of polycyclic aromatic hydrocarbons in environmental water with porous cellulose/zeolitic imidazolate framework-8 composite microspheres as a novel adsorbent coupled with high-performance liquid chromatography, J Sep Sci, 39, 2806, 10.1002/jssc.201600348 Richardson, 2016, Innovation in layer-by-layer assembly, Chem Rev, 116, 14828, 10.1021/acs.chemrev.6b00627 Shekhah, 2009, Growth mechanism of metal-organic frameworks: insights into the nucleation by employing a step-by-step route, Angew Chem Int Ed, 48, 5038, 10.1002/anie.200900378 Ariga, 2007, Layer-by-layer assembly as a versatile bottom-up nanofabrication technique for exploratory research and realistic application, PCCP, 9, 2319, 10.1039/b700410a Shekhah, 2007, Step-by-step route for the synthesis of metal−organic frameworks, J Am Chem Soc, 129, 15118, 10.1021/ja076210u Shekhah, 2009, Controlling interpenetration in metal-organic frameworks by liquid-phase epitaxy, Nat Mater., 8, 481, 10.1038/nmat2445 Liu, 2011, Chemistry of SURMOFs: layer-selective installation of functional groups and post-synthetic covalent modification probed by fluorescence microscopy, J Am Chem Soc, 133, 1734, 10.1021/ja1109826 Stavila, 2012, Kinetics and mechanism of metal-organic framework thin film growth: systematic investigation of HKUST-1 deposition on QCM electrodes, Chem Sci, 3, 1531, 10.1039/c2sc20065a Neufeld, 2015, Immobilization of metal-organic framework copper(II) benzene-1,3,5-tricarboxylate (CuBTC) onto cotton fabric as a nitric oxide release catalyst, ACS Appl Mater Interfaces, 7, 26742, 10.1021/acsami.5b08773 Laurila, 2015, Enhanced synthesis of metal-organic frameworks on the surface of electrospun cellulose nanofibers, Adv Eng Mater, 17, 1282, 10.1002/adem.201400565 Zhao, 2014, Highly adsorptive, MOF-functionalized nonwoven fiber mats for hazardous gas capture enabled by atomic layer deposition, Adv Mater Interfaces, 1, 10.1002/admi.201400040 Zhao, 2015, Conformal and highly adsorptive metal-organic framework thin films via layer-by-layer growth on ALD-coated fiber mats, J Mater Chem A, 3, 1458, 10.1039/C4TA05501B Chen, 2016, Hybrid polymer/UiO-66(Zr) and polymer/NaY fiber sorbents for mercaptan removal from natural gas, ACS Appl Mater Interfaces, 8, 9700, 10.1021/acsami.6b00897 Kadib, 2014, Recent progress in chitosan bio-based soft nanomaterials, J Nanosci Nanotechnol, 14, 308, 10.1166/jnn.2014.9012 Kumar, 2004, Chitosan chemistry and pharmaceutical perspectives, Chem Rev, 104, 6017, 10.1021/cr030441b Pavinatto, 2010, Chitosan in nanostructured thin films, Biomacromolecules, 11, 1897, 10.1021/bm1004838 Berger, 2004, Structure and interactions in covalently and ionically crosslinked chitosan hydrogels for biomedical applications, Eur J Pharm Biopharm, 57, 19, 10.1016/S0939-6411(03)00161-9 El Kadib, 2012, Chitosan bio-based organic-inorganic hybrid aerogel microspheres, Chem A Eur J, 18, 8264, 10.1002/chem.201104006 El Kadib, 2015, Chitosan as a sustainable organocatalyst: a concise overview, ChemSusChem, 8, 217, 10.1002/cssc.201402718 Frindy, 2016, Insightful understanding of the role of clay topology on the stability of biomimetic hybrid chitosan-clay thin films and CO2-dried porous aerogel microspheres, Carbohydr Polym, 146, 353, 10.1016/j.carbpol.2016.03.077 Ennajih, 2012, Chitosan–montmorillonite bio-based aerogel hybrid microspheres, Micropor Mesopor Mater, 152, 208, 10.1016/j.micromeso.2011.11.032 Frindy, 2015, Pd embedded in chitosan microspheres as tunable soft-materials for Sonogashira cross-coupling in water-ethanol mixture, Green Chem, 17, 1893, 10.1039/C4GC02175D Frindy, 2015, Copper nanoparticles stabilized in a porous chitosan aerogel as a heterogeneous catalyst for C−S cross-coupling, ChemCatChem, 7, 3307, 10.1002/cctc.201500565 El Kadib, 2011, Nanosized vanadium, tungsten and molybdenum oxide clusters grown in porous chitosan microspheres as promising hybrid materials for selective alcohol oxidation, Chem A Eur J, 17, 7940, 10.1002/chem.201003740 Kadib, 2010, Improving catalytic activity by synergic effect between base and acid pairs in hierarchically porous chitosan@titania nanoreactors, Org Lett, 12, 948, 10.1021/ol9029319 Kadib, 2008, Design of stable nanoporous hybrid chitosan/titania as cooperative bifunctional catalysts, Chem Mater, 20, 2198, 10.1021/cm800080s Zhou, 2012, Challenging fabrication of hollow ceramic fiber supported Cu3(BTC)2 membrane for hydrogen separation, J Mater Chem, 22, 10322, 10.1039/c2jm16371c Frindy, 2017, Chitosan–graphene oxide films and CO2-dried porous aerogel microspheres: interfacial interplay and stability, Carbohydr Polym, 167, 297, 10.1016/j.carbpol.2017.03.034 Darder, 2003, Biopolymer−clay nanocomposites based on chitosan intercalated in montmorillonite, Chem Mater, 15, 3774, 10.1021/cm0343047 Yang, 2016, Covalent immobilization of Cu3(btc)2 at chitosan-electroreduced graphene oxide hybrid film and its application for simultaneous detection of dihydroxybenzene isomers, J Phys Chem C, 120, 9794, 10.1021/acs.jpcc.6b01574 Chowdhuri, 2016, Carbon dots embedded magnetic nanoparticles @chitosan @metal organic framework as a nanoprobe for ph sensitive targeted anticancer drug delivery, ACS Appl Mater Interfaces, 8, 16573, 10.1021/acsami.6b03988 Liu, 2016, Facile preparation of chitosan enwrapping Fe3O4 nanoparticles and MIL-101(Cr) magnetic composites for enhanced methyl orange adsorption, J Porous Mater, 23, 1363, 10.1007/s10934-016-0195-y Wang, 2016, Cu-hemin metal-organic-frameworks/chitosan-reduced graphene oxide nanocomposites with peroxidase-like bioactivity for electrochemical sensing, Electrochim Acta, 213, 691, 10.1016/j.electacta.2016.07.162 Halder RN, Boddu V, Uchimiya MS, Kapila S, Bednar AJ, Paikoff S. Metal organic frameworks (MOFs) for degrdation of nerve agent simulant Parathion; 2011. Spjelkavik, 2014, Forming MOFs into spheres by use of molecular gastronomy methods, Chem A Eur J, 20, 8973 Kang, 2013, Synthesis of ZIF-7/chitosan mixed-matrix membranes with improved separation performance of water/ethanol mixtures, J Membr Sci, 438, 105, 10.1016/j.memsci.2013.03.028 Li, 2010, Molecular sieve membrane: supported metal-organic framework with high hydrogen selectivity, Angew Chem Int Ed, 49, 548, 10.1002/anie.200905645 Casado-Coterillo, 2015, Synthesis and characterisation of MOF/ionic liquid/chitosan mixed matrix membranes for CO2/N2 separation, RSC Adv, 5, 102350, 10.1039/C5RA19331A Han, 2014, A novel anode material derived from organic-coated ZIF-8 nanocomposites with high performance in lithium ion batteries, Chem Commun, 50, 8057, 10.1039/C4CC02691H Wisser, 2015, Biological Chitin–MOF composites with hierarchical pore systems for air-filtration applications, Angew Chem Int Ed, 54, 12588, 10.1002/anie.201504572 Ehrlich, 2010, Three-dimensional chitin-based scaffolds from Verongida sponges (Demospongiae: Porifera). Part I. Isolation and identification of chitin, Int J Biol Macromol, 47, 132, 10.1016/j.ijbiomac.2010.05.007 Martinsen, 1989, Alginate as immobilization material: I. Correlation between chemical and physical properties of alginate gel beads, Biotechnol Bioeng, 33, 79, 10.1002/bit.260330111 Lee, 2012, Alginate: properties and biomedical applications, Prog Polym Sci, 37, 106, 10.1016/j.progpolymsci.2011.06.003 Boury, 2015, Metal oxides and polysaccharides: an efficient hybrid association for materials chemistry, Green Chem, 17, 72, 10.1039/C4GC00957F Leong, 2016, Advances in fabricating spherical alginate hydrogels with controlled particle designs by ionotropic gelation as encapsulation systems, Particuology, 24, 44, 10.1016/j.partic.2015.09.004 Vashist, 2016, Recent trends on hydrogel based drug delivery systems for infectious diseases, Biomater Sci, 4, 1535, 10.1039/C6BM00276E Madrigal, 2016, Microfluidic generation of alginate microgels for the controlled delivery of lentivectors, J Mater Chem B, 4, 6989, 10.1039/C6TB02150F Dasgupta, 2015, Adsorption properties and performance of CPO-27-Ni/alginate spheres during multicycle pressure-vacuum-swing adsorption (PVSA) CO2 capture in the presence of moisture, Chem Eng Sci, 137, 525, 10.1016/j.ces.2015.06.064 Bhat, 2007, Pervaporation separation using sodium alginate and its modified membranes—a review, Sep Purif Rev, 36, 203, 10.1080/15422110701539061 Kashima, 2009, Molecular sieving character of calcium alginate membrane relate with polymeric framework and mechanical strength, J Biosci Bioeng, 108, S69, 10.1016/j.jbiosc.2009.08.204 Kashima, 2012 Su, 2015, Amine-functionalized metal organic framework (NH2-MIL-125(Ti)) incorporated sodium alginate mixed matrix membranes for dehydration of acetic acid by pervaporation, RSC Adv, 5, 99008, 10.1039/C5RA21073A Liu, 2017, Microfluidic preparation of yolk/shell ZIF-8/alginate hybrid microcapsules from Pickering emulsion, Chem Eng J, 307, 408, 10.1016/j.cej.2016.08.097 Guo, 2014, Versatile preparation of nonspherical multiple hydrogel core PAM/PEG emulsions and hierarchical hydrogel microarchitectures, Angew Chem Int Ed, 53, 7504, 10.1002/anie.201403256 Guo, 2015, Preparation of monodispersed porous polyacrylamide microspheres via phase separation in microchannels, React Funct Polym, 91–92, 77, 10.1016/j.reactfunctpolym.2015.04.006 Zhang, 2015, Stability of ZIF-8 membranes and crystalline powders in water at room temperature, J Membr Sci, 485, 103, 10.1016/j.memsci.2015.03.023 Mahou, 2015, Tuning the properties of hydrogel microspheres by adding chemical cross-linking functionality to sodium alginate, Chem Mater, 27, 4380, 10.1021/acs.chemmater.5b01098 Zhu, 2016, Alginate hydrogel: a shapeable and versatile platform for in situ preparation of metal-organic framework–polymer composites, ACS Appl Mater Interfaces, 8, 17395, 10.1021/acsami.6b04505 Du, 2015, Versatile controlled ion release for synthesis of recoverable hybrid hydrogels with high stretchability and notch-insensitivity, Chem Commun, 51, 15534, 10.1039/C5CC06721A Yang, 2013, Strengthening alginate/polyacrylamide hydrogels using various multivalent cations, ACS Appl Mater Interfaces, 5, 10418, 10.1021/am403966x Sun, 2012, Highly stretchable and tough hydrogels, Nature, 489, 133, 10.1038/nature11409 Han, 2011, Imprinting chemical and responsive micropatterns into metal-organic frameworks, Angew Chem Int Ed, 50, 276, 10.1002/anie.201004332 Gil-Hernandez, 2012, Homochiral lanthanoid(iii) mesoxalate metal-organic frameworks: synthesis, crystal growth, chirality, magnetic and luminescent properties, CrystEngComm, 14, 2635, 10.1039/c2ce06496k Huo, 2015, Magnetic MOF microreactors for recyclable size-selective biocatalysis, Chem Sci, 6, 1938, 10.1039/C4SC03367A Hirsh, 1994, Guide to anticoagulant therapy, I: heparin, Circulation, 89, 1449, 10.1161/01.CIR.89.3.1449 Bogdan, 2012, Bio-functionalization of ligand-free upconverting lanthanide doped nanoparticles for bio-imaging and cell targeting, Nanoscale., 4, 3647, 10.1039/c2nr30982c Jiang, 2013, Surface-functionalized nanoparticles for biosensing and imaging-guided therapeutics, Nanoscale., 5, 3127, 10.1039/c3nr34005h Bellido, 2015, Heparin-engineered mesoporous iron metal-organic framework nanoparticles: toward stealth drug nanocarriers, Adv Healthc Mater, 4, 1246, 10.1002/adhm.201400755 Elangovan, 2011, Poly(l-lactic acid) metal organic framework composites. Mass transport properties, Ind Eng Chem Res, 50, 11136, 10.1021/ie201378u Elangovan, 2012, Poly(L-lactic acid) metal organic framework composites: optical, thermal and mechanical properties, Polym Int, 61, 30, 10.1002/pi.3186 Kathuria, 2013, Toughening of poly(l-lactic acid) with Cu3BTC2 metal organic framework crystals, Polymer, 54, 6979, 10.1016/j.polymer.2013.11.005 Dai, 2016, Non-isothermal crystallization kinetics, thermal degradation behavior and mechanical properties of poly(lactic acid)/MOF composites prepared by melt-blending methods, RSC Adv, 6, 71461, 10.1039/C6RA14190K Kathuria, 2015, The influence of Cu3(BTC)2 metal organic framework on the permeability and perm-selectivity of PLLA-MOF mixed matrix membranes, J Appl Polym Sci, 132, n/a-n/a, 10.1002/app.42764 Kathuria, 2013, Deterioration of metal–organic framework crystal structure during fabrication of poly(l-lactic acid) mixed-matrix membranes, Polym Int, 62, 1144, 10.1002/pi.4478 Quirós, 2015, Antimicrobial metal–organic frameworks incorporated into electrospun fibers, Chem Eng J, 262, 189, 10.1016/j.cej.2014.09.104 Gamage, 2016, MOF-5-polystyrene: direct production from monomer, improved hydrolytic stability, and unique guest adsorption, Angew Chem Int Ed, 55, 12099, 10.1002/anie.201606926 Zhu, 2011, Design properties of hydrogel tissue-engineering scaffolds, Exp Rev Med Dev, 8, 607, 10.1586/erd.11.27 Etxabide, 2017, Development of active gelatin films by means of valorisation of food processing waste: a review, Food Hydrocoll, 68, 192, 10.1016/j.foodhyd.2016.08.021 Sahoo, 2015, Recent advancement of gelatin nanoparticles in drug and vaccine delivery, Int J Biol Macromol, 81, 317, 10.1016/j.ijbiomac.2015.08.006 Santoro, 2014, Gelatin carriers for drug and cell delivery in tissue engineering, J Control Release, 190, 210, 10.1016/j.jconrel.2014.04.014 Elzoghby, 2013, Gelatin-based nanoparticles as drug and gene delivery systems: Reviewing three decades of research, J Control Release, 172, 1075, 10.1016/j.jconrel.2013.09.019 Dhawale, 2013, Enhanced supercapacitor performance of N-doped mesoporous carbons prepared from a gelatin biomolecule, ChemPhysChem, 14, 1563, 10.1002/cphc.201300132 Nam, 2014, Metal-free ketjenblack incorporated nitrogen-doped carbon sheets derived from gelatin as oxygen reduction catalysts, Nano Lett, 14, 1870, 10.1021/nl404640n Garai, 2013, Biomineral-inspired growth of metal-organic frameworks in gelatin hydrogel matrices, J Mater Chem B, 1, 3678, 10.1039/c3tb20814a Hu, 2015, Room temperature synthesis of ZIF-8 membranes from seeds anchored in gelatin films for gas separation, CrystEngComm, 17, 1576, 10.1039/C4CE02322F Marquez, 2016, Biocompatible polymer-metal-organic framework composite patches for cutaneous administration of cosmetic molecules, J Mater Chem B, 4, 7031, 10.1039/C6TB01652A Hardy, 2010, Composite materials based on silk proteins, Prog Polym Sci, 35, 1093, 10.1016/j.progpolymsci.2010.04.005 Zhang, 2016, Synthesis and fluorescent pH sensing properties of nanoscale lanthanide metal-organic frameworks with silk fibroin powder as polymer ligands, Dyes Pigm, 130, 129, 10.1016/j.dyepig.2016.03.027 Abbasi, 2012, Dense coating of surface mounted CuBTC Metal-Organic Framework nanostructures on silk fibers, prepared by layer-by-layer method under ultrasound irradiation with antibacterial activity, Ultrason Sonochem, 19, 846, 10.1016/j.ultsonch.2011.11.016 Khanjani, 2014, Ultrasound-promoted coating of MOF-5 on silk fiber and study of adsorptive removal and recovery of hazardous anionic dye “congo red”, Ultrason Sonochem, 21, 1424, 10.1016/j.ultsonch.2013.12.012 Abbasi, 2014, Synthesis, characterization and antibacterial properties of nano-porous Zn3(BTC)2·12H2O upon silk yarn under ultrasound irradiation, J Inorg Organomet Polym Mater, 24, 1096, 10.1007/s10904-014-0101-5 Abbasi, 2015, Synthesis and characterization of TMU-16-NH2 metal-organic framework nanostructure upon silk fiber: study of structure effect on morphine and methyl orange adsorption affinity, Fib Polym, 16, 1193, 10.1007/s12221-015-1193-4 Abbasi, 2016, Synthesis and characterization of azine-functionalized zinc cation metal–organic frameworks nanostructures upon silk fibers under ultrasound irradiation, study of pores effect on morphine adsorption affinity, Colloids Surf A Physicochem Eng Asp, 498, 58, 10.1016/j.colsurfa.2016.02.038 López-Maya, 2015, Textile/metal–organic-framework composites as self-detoxifying filters for chemical-warfare agents, Angew Chem Int Ed, 54, 6790, 10.1002/anie.201502094 Li, 2006, Hydrogen storage in metal−organic frameworks by bridged hydrogen spillover, J Am Chem Soc, 128, 8136, 10.1021/ja061681m Huang, 2012, Glucose-promoted Zn-based metal-organic framework/graphene oxide composites for hydrogen sulfide removal, ACS Appl Mater Interfaces, 4, 4942, 10.1021/am3013104 Ren, 2015, A more efficient way to shape metal-organic framework (MOF) powder materials for hydrogen storage applications, Int J Hydrogen Energy, 40, 4617, 10.1016/j.ijhydene.2015.02.011 Zhang, 2014, ZIF-derived in situ nitrogen-doped porous carbons as efficient metal-free electrocatalysts for oxygen reduction reaction, Energy Environ Sci, 7, 442, 10.1039/C3EE42799D Kobayashi, 2016, The controlled synthesis of polyglucose in one-dimensional coordination nanochannels, Chem Commun, 52, 5156, 10.1039/C6CC01357K Kitao, 2017, Hybridization of MOFs and polymers, Chem Soc Rev, 46, 3108, 10.1039/C7CS00041C Kinik, 2017, Ionic liquid/metal organic framework composites: from synthesis to applications, ChemSusChem, 10, 2842, 10.1002/cssc.201700716 Liu, 2017, Molecular biodynamers: dynamic covalent analogues of biopolymers, Acc Chem Res, 50, 376, 10.1021/acs.accounts.6b00594 Sultan, 2019, CelloMOF: nanocellulose enabled 3D printing of metal-organic frameworks, Adv Funct Mater, 29, 1805372, 10.1002/adfm.201805372