Lipase catalyzed synthesis of ester‐based surfactants from biomass derivatives

Biofuels, Bioproducts and Biorefining - Tập 2 Số 2 - Trang 144-154 - 2008
Sanjib Kumar Karmee1
1RWTH Aachen University, Germany

Tóm tắt

AbstractNon‐ionic surfactants find a unique place in pharmaceutical, detergent, food, and cosmetic industries because of their ready availability from biomass, low cost, and renewability. Generally these surfactants are esters obtained from the reaction of glycerol, L‐ascorbic acid, and sugar, with long or medium chain fatty acids. Problems encountered during the synthesis of these surfactants are the immiscibility of highly polar substrates in organic solvents and non‐regioselective reaction. Therefore, lipases as a catalyst and t‐butanol or acetone, a mixture of solvent and ionic liquid as solvents, have been used for the synthesis of ester‐based surfactants. This review focuses on the uses of lipases for the synthesis of surfactants obtained from biomass derivatives viz. fats and oils, sugar and vitamin‐C. © 2008 Society of Chemical Industry and John Wiley & Sons, Ltd

Từ khóa


Tài liệu tham khảo

10.1162/108819803323059398

10.1016/S1359-0294(01)00076-0

10.1002/1521-3773(20000703)39:13<2206::AID-ANIE2206>3.0.CO;2-P

10.1351/pac200072071255

10.1002/3527606033

10.1016/j.cattod.2004.06.048

10.1016/0141-0229(94)00096-A

10.1007/BF02541058

10.1002/lipi.19930950504

10.1007/BF02523518

10.1007/BF01027678

10.1111/j.1749-6632.1984.tb29892.x

10.1271/bbb1961.49.335

10.1016/0922-338X(91)90210-8

10.1111/j.1749-6632.1990.tb18229.x

10.1111/j.1749-6632.1990.tb18213.x

10.1002/bit.260400116

10.1007/BF02540583

10.1271/bbb1961.51.2153

10.1007/BF02931345

10.5650/jos.55.65

10.5650/jos.55.537

10.1021/jf063366p

10.1007/BF02931100

10.1016/j.foodchem.2006.11.036

Tripathi V, 2006, Production of mono‐ and diacylglycerols by lipase‐catalyzed hydrolysis of rice bran oil, J Lipid Sci Technol, 38, 122

10.1111/j.1745-4522.2005.00025.x

10.1039/b511117j

10.5650/jos.53.497

10.1016/j.enzmictec.2004.04.011

10.1002/ejlt.200390019

10.1016/S1381-1177(00)00079-5

10.1007/s11746-000-0143-0

10.1023/A:1005604406705

10.1007/s11746-999-0162-8

10.1023/A:1005464021613

10.1111/j.1749-6632.1998.tb10319.x

10.1002/lipi.19970990705

10.1007/s11746-997-0104-2

10.1007/s11746-997-0152-7

Adamczak M, 1994, Application of enzymic glycerolysis for production of monoglycerides from waste fats, Pol J Food Nutr Sci, 3, 129

10.1007/BF00131762

10.1007/BF02635898

Papendorf O, 1995, Monoacylglycerols:(bio) chemical production and interfacial properties, Chimica Oggi, 13, 17

10.1007/BF01029137

10.1002/lipi.19950970403

10.1039/b506763d

10.1016/0009-3084(96)02591-1

10.1016/S0168-1656(98)00069-8

10.1016/S1381-1177(98)00090-3

10.1007/s11746-999-0141-0

10.1023/A:1005620125533

10.1023/A:1005675111042

10.1039/b307715b

10.5458/jag.50.373

10.1081/PB-200054729

10.1016/j.procbio.2005.01.016

10.1007/BF02541458

10.1007/BF02541426

10.1002/(SICI)1097-0290(19991005)65:1<10::AID-BIT2>3.0.CO;2-L

10.1016/S0168-1656(02)00037-8

10.1002/bit.260310305

10.1007/BF01024726

10.1021/ja00210a045

10.1007/BF00131205

10.1016/0141-0229(91)90062-F

10.1055/s-1990-26802

10.1002/bit.260420616

Pulido R, 1992, Enzymatic regioselective acylation of hexoses and pentoses using oxime esters, J Chem Soc Perkin Trans, 1, 2981

10.1016/0167-7799(91)90119-3

Cao L, 1996, Lipase‐catalyzed solid phase synthesis of sugar esters, Fat Sci Technol, 98, 332

10.3109/10242429809003620

10.1016/S1381-1177(98)00083-6

10.3109/10242429609110280

Saxena RK, 2005, Efficient microwave‐assisted hydrolysis of triolein and synthesis of bioester, bio‐surfactant and glycerides using Aspergillus carneus lipase, Curr Sc, 89, 1000

10.1016/j.jfoodeng.2005.08.016

10.1021/ol0511169

10.1002/(SICI)1097-0290(19981005)60:1<53::AID-BIT6>3.0.CO;2-#

10.1002/(SICI)1097-0290(19980305)57:5<505::AID-BIT1>3.0.CO;2-K

10.1016/S0040-4020(00)00319-7

10.1023/A:1005439801354

10.1002/(SICI)1097-0290(19990805)64:3<267::AID-BIT2>3.0.CO;2-B

10.1016/j.enzmictec.2004.02.009

10.1080/07328309708005752