Control the Entire Journey of Pesticide Application on Superhydrophobic Plant Surface by Dynamic Covalent Trimeric Surfactant Coacervation

Advanced Functional Materials - Tập 31 Số 5 - 2021
Bin Liu1, Yaxun Fan1, Haofei Li1, Weiwei Zhao1, Siqi Luo1, Hua Wang1, Bo Guan1, Qiaolian Li1, Jiling Yue1, Zhichao Dong2,3, Yilin Wang1, Lei Jiang2,3
1CAS Key Laboratory of Colloid Interface and Chemical Thermodynamics CAS Research/Education Center for Excellence in Molecular Sciences and Beijing National Laboratory for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100190 P. R. China
2CAS Key Laboratory of Bio-inspired Materials and Interfacial Sciences, Technical Institute of Physics and Chemistry Chinese Academy of Sciences, Beijing 100190, P.R. China
3University of Chinese Academy of Sciences, Beijing 100049, P.R. China

Tóm tắt

Abstract

Vast wastage of pesticides has caused significant environmental pollution and economic loss, which occurs in any step during the entire process of pesticide application. However, the existing strategies for controlling pesticide losses are step specific. Here, a comprehensive strategy to substantively improve pesticide efficiency on the basis of precise designs from beginning to end is developed. A water‐based coacervate with synthesized imine‐based dynamic covalent trimeric surfactants to synergistically control encapsulation, deposition, retention, and release of pesticides on water‐repellent plants is constructed. The coacervate consists of nanosized networks and abundant tightly bonded water, leading to effective encapsulation of hydrophilic/hydrophobic pesticides. Meanwhile, the network‐like microstructure entangles with the micro/nanostructures of superhydrophobic surface, ensuring complete deposition on superhydrophobic plant surface after high‐speed impact and inhibition of wind/rainwater erosion. Moreover, the CO2‐induced degradative surfactant coacervate determines the precise pesticide release. The dynamic coacervate as an innovative pesticide formula provides a prospective way for pesticide application, and is expected to promote productive and sustainable agriculture.

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Advanced Functional Materials

Tập 31 Số 5

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